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Fluorous   |   Gyroscopes   |   Molecular Wires   |   Werner Complexes



Molecular Wires Using Platinum

246.     "C8 and C12 sp Carbon Chains that Span Two Platinum Atoms; The First Structurally Characterized 1,3,5,7,9,11-hexayne", Peters, T. B.; Bohling, J. C.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 3261-3263. DOI: 10.1021/om990448c. [Abstract][PDF]

248.     "Wire-Like sp Carbon Chains that Span Two Platinum Atoms: Synthesis and Crystal Structures of Building Blocks of the Formula trans-(p-tolyl)(Ph3P)2Pt(C≡C)nSiMe3", Bohling, J. C.; Peters, T. B.; Arif, A. M.; Hampel, F.; Gladysz, J. A., in Coordination Chemistry at the Turn of the Century; Ondrejoviç, G.; Sirota, A. Eds.; Slovak Technical University Press: Bratislava, Slovokia, 1999; pp. 47-52.

274.     "Syntheses and Structures of Monoplatinum Model Complexes for Diplatinum Polyynediyl Adducts LnPt(C≡C)zPtLn", Peters, T. B.; Zheng, Q.; Stahl, J.; Bohling, J. C.; Arif, A. M.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2002, 641, 53-61. (invited article, interactions of π systems with metals thematic issue) DOI: 10.1016/ S0022-328X(01)01311-0. [Abstract][PDF]

276.     "An Unexpected Insertion of Acetone into the Silicon-Carbon Terminus of an sp Carbon Chain: Syntheses and Structures of Model Monoplatinum Hexatriynyl and Octatetraynyl Complexes", Mohr, W.; Peters, T. B.; Bohling, J. C.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Comptes Rendus Chemie 2002, 5, 111-118. (invited article, Gecom-Concoord thematic issue) DOI: 10.1016/S1631-0748(02)01351-6. [Abstract][PDF]

282.     (a) "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. DOI: 10.1021/ja0716103. [Abstract][PDF]

(b) "Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte mole­kulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957. DOI: 10.1002/1521-3757(20020603)114:11<1951::AID-ANGE1951>3.0.CO;2-Z. [Abstract][PDF]

295.     "Synthesis, Structure, and Reactivity of sp Carbon Chains with bis(phosphine) Pentafluorophenylplatinum Endgroups: Butadiynediyl (C4) through Hexadecaoctaynediyl (C16) Bridges, and Beyond", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324-3340. DOI: 10.1002/chem.200204741. [Abstract][PDF]

 

315.     "Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, In which the sp Carbon Chains are shielded by sp3 Carbon Chains", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889-5892. DOI: 10.1021/om0493558. [Abstract][PDF]

 

316.     "Syntheses and Structures of Tetraplatinum bis(Polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains", Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893-5895. DOI: 10.1021/om049354f. [Abstract][PDF]

 

317.     "Longitudinally Extended Molecular Wires based upon PtC≡CC≡CC≡CC≡C Repeat Units; Iterative Syntheses of Functionalized Linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt Assemblies", Zheng, Q.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5896-5899. DOI: 10.1021/om049353n. [Abstract][PDF]

320.     "Electronic Structure and Chain Length Effects in Diplatinum Polyynediyl Complexes trans, trans-[(X)(R3P)2Pt(C≡C)nPt(PR3)2(X)]: A Computational Investigation", Zhuravlev, F.; Gladysz, J. A. Chem. Eur. J. 2004, 10, 6510-6522. DOI: 10.1002/chem.200400643. [Abstract][PDF]

 

330. "A Synthetic Breakthrough into an Unanticipated Stability Regime: Readily Isolable Complexes in which C16-C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Gladysz, J. A. J. Am. Chem. Soc. 2005, 127, 10508-10509. DOI: 10.1021/ja0534598. [Abstract][PDF]

336. "Wire-Like PtC≡CC≡CC≡CC≡CPt Moieties Surrounded by Double-Helical 'Insulation': New Motifs Featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P Linkages", de Quadras, L.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2006, 2929-2933. DOI: 10.1039/b604465b. [Abstract][PDF]

344. "A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Bohling, J. C.; Peters, T. B.; Frisch, A. C.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 6486-6505. DOI: 10.1002/chem.200600615. [Abstract][PDF]

 

350. "Update 1 of: Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2006, 106, PR1–PR33. (inaugural "Perennial Review") DOI: 10.1021/cr030041o. [Abstract][PDF]

354. "Monophosphine and Diphosphine Ligands for Diplatinum Polyyendiyl Complexes: Efficient Syntheses of New Functionality-Containing Systems and Model Compounds", de Quadras, L.; Stahl,J.; Zhuravlev, F.; Gladysz, J. A. J. Organomet. Chem. 2007, 692, 1859-1870. DOI: 10.1016/J.JORGANCHEM.2006.12.023. [Abstract][PDF]

357. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Coordination-Driven Self Assembly of Wirelike Pt(C≡C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages", Stahl, J.; Mohr, W.; de Quadras, L.; Peters, T. B.; Bohling, J. C.; Martín-Alvarez, J. M.; Owen, G. R.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8282-8295. DOI: 10.1021/ja0716103. [Abstract][PDF]

358. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices:  Directed Syntheses of Wirelike Pt(C≡C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alva­rez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. DOI: 10.1021/ja071612n. [Abstract][PDF]

361. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Wire-Like Pt(C≡C)nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]

 

364. "Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains", Farley, R.; Zheng, Q.; Gladysz, J. A.; Schanze, K. S. Inorg. Chem. 2008, 47, 2955-2963. DOI: 10.1021/ic701220t. [Abstract][PDF]

367. "Coordination-Driven Self Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp3 Carbon Chains: Towards Endgroup-Endgroup Interactions", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 73-87. DOI: 10.1002/ chem.200701268. [Abstract][PDF]

369. "En Route to Diplatinum Polyynediyl Complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold Tales, Including End-Group Strategies", Stahl, J.; Bohling, J. C.; Peters, T. B.; de Quadras, L.; Gladysz, J. A. Pure Appl. Chem. 2008, 80, 459-474. (invited article, ISNA-12 thematic issue) DOI: 10.1351/pac200880030459. [Abstract][PDF]

373. "Syntheses, Structures, and Electronic Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C6F5)(R3P)2Pt, (p-tol)(R3P)2Pt, and (Ph3P)Au End-Groups", de Quadras, L.; Shelton, A. H.; Kuhn, H.; Hampel, F.; Schanze, K. S.; Gladysz, J. A. Organometallics 2008, 27, 4979-4991. DOI: 10.1021/om800493x. [Abstract][PDF]

 

375. "Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains", Samoc, M.; Dalton, G. T.; Gladysz, J. A.; Zheng, Q.; Yelkov, Y.; Ågren, H.; Norman, P.; Humphrey, M. G. Inorg. Chem. 2008, 47, 9946-9957. DOI: 10.1021/ic801145c. [Abstract][PDF]

 

377. "Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes", Kuhn, H.; Hampel, F.; Gladysz, J. A. Organometallics 2009, 28, 4979-4987. DOI: 10.1021/om9005017. [Abstract][PDF]

 

379. "'Click' Chemistry in Metal Coordination Spheres: Copper(I) Catalyzed 3+2 Cycloaddi­tions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol3P)2Pt(C≡C)nH (n = 2-6)", Gauthier, S.; Weisbach, N.; Gladysz, J. A Organometallics 2009, 28, 5597-5599. DOI: 10.1021/om900680q. [Abstract][PDF]

 

385. "Molecular Wires in Single Molecule Junctions: Charge Transport and Vibrational Exci­tations", Ballmann, S.; Hieringer, W.; Secker, D.; Zheng, Q.; Gladysz, J. A.; Görling, A.; Weber, H. B. ChemPhysChem 2010, 11, 2256-2260. DOI: 10.1002/cphc.200900974. [Abstract][PDF]

 

387. "Towards Multistranded Molecular Wires: Syntheses, Structures, and Reactivities of Tetraplatinum bis(Polyynediyl) Complexes with Pt-Cx-Pt-(P(CH2)3P)2-Pt-Cx-Pt-(P(CH2)3­P)2 Cores (x = 4, 6, 8)", Owen, G. R.; Gauthier, S.; Weisbach, N.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Dalton Trans. 2010, 5260-5271. DOI: 10.1039/c002041a. [Abstract][PDF]

 

403. "A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated polyyne", Weisbach, N.; Baranová, Z.; Gauthier, S.; Reibenspies, J. H.; Gladysz, J. A. Chem. Commun. 2012, 48, 7562-7564. DOI: 10.1039/C2CC33321J. [Abstract][PDF]

 

406. "Toward Permetalated Alkyne/Azide 3+2 or 'Click' Cycloadducts", Clough, M. C.; Zeits, P. D. Bhuvanesh, N.; Gladysz, J. A. Organometallics 2012, 31, 5231-5234. DOI: 10.1021/om300542a. [Abstract][PDF]

 

409. "A Metal-capped Conjugated Polyyne Threaded Through a Phenanthroline-based Macrocycle. Probing Beyond the Mechanical Bond to Interactions in Interlocked Molecular Ar­chitectures", Sahnoune, H.; Baranová, Z.; Bhuvanesh, N.; Gladysz, J. A.; Halet, J.-F. Organometallics, 2013, 32, 6360-6367. DOI: 10.1021om400709q. [Abstract][PDF]

 

414. "Photophysics of Platinum Tetrayne Oligomers: Delocalization of Triplet Exciton", Li, Y.; Winkel, R. W.; Weisbach, N.; Gladysz, J. A.; Schanze, K. S. J. Phys. Chem. A. 2014, 115, 10333-10339. DOI: 10.1021/jp5021388. [Abstract][PDF]

416. "Synthesis, Photovoltaic Perfomances, and TD-DFT Modeling of Push-Pull Diacetylide Platinum Complexes in TiO2 Based Dye-Sensitized Solar Cells", Gauthier, S.; Caro, B.; Robin-Le Guen, F.; Bhuvanesh, N.; Gladysz, J. A.; Wojcik, L.; Le Poul, N.; Planchat, A.; Pellegrin, Y.; Blart, E.; Jacquemin, D.; Odobel, F. Dalton Trans. 2014, 43, 11233-11242. DOI:10.1039/C4DT00301B [Abstract][PDF]

421. "Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles", Baranová, Z.; Amini, H.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6746-6749. DOI:10.1021/om501026u. [Abstract][PDF]

433. "A Phase Based Approach to Insulated Molecular Wires: Diplatinum Octatetraynediyl Complexes Bearing Fluorous Trialkylphosphine Ligands", Clough, M. C.; Fiedler, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2016, 812, 34-42. DOI:10.1016/j.jorganchem.2015.09.020. (invited contribution, special issue dedicated to Jack Lewis) [Abstract] [PDF]

444. "A Quest for Atropisomerism in Cojoined Square Planar Metal Complexes: Syntheses and Structures of Sterically Congested Diplatinum Ethynediyl Adducts", Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. Eur. J. Inorg. Chem. 2017, 2017, 1017-1025. DOI: 10.1002/ejic.201601307. [Abstract] [PDF]

455. "Syntheses and Structures of Square Planar Diplatinum Butadiynediyl Complexes with two Different Monophopshine Ligands on each Terminus; Probing the Feasibility of a New Type of Inorganic Atropisomerism", Dey, S.; Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2017, 849-850, 237-255. DOI: 10.1016/j.jorganchem.2017.05.006. [Abstract] [PDF]





Molecular Wires Using Rhenium

148.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkyne Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(RC≡CR')]+ BF4-", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079-1088. DOI: 10.1021/om00050a045. [Abstract][PDF]

177.     "Deprotonation of Rhenium Terminal Acetylide Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(C≡CH): Generation and Reactivity of Rhenium/Lithium C2 Complexes", Ramsden, J. A.; Weng, W.; Gladysz, J. A. Organometallics 1992, 11, 3635-3645. DOI: 10.1021/om00059a029. [Abstract][PDF]

207.     "Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula ((η5-C5Me5)Re(NO)(PPh3)(C≡CX); Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C4H3 and C4H4 Species", Weng, W.; Bartik, T.; Johnson, M. T.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 889-897. DOI: 10.1021/om00002a041. [Abstract][PDF]

217.     "Synthesis, Structure and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M' and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (η5-C5Me5)Re(NO)(PPh3)(C≡CLi) and (η5-C5Me5)Re(NO)(PPh3)(C≡CC≡CLi)", Weng, W.; Bartik, T. ; Brady, M.; Bartik, B.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11922-11931. DOI: 10.1021/ja953523t. [Abstract][PDF]

225.     "Consanguineous Families of Coordinated Carbon: A ReC4Re Assembly that is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC≡CC≡CRe and +Re=C=C=C=C=Re+ Adducts and a Radical Cation in which Charge is Delocalized Be­tween Rhenium Termini", Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, A. J.; Arif, A. M.; Böhme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788. DOI: 10.1021/ja9631817. [Abstract][PDF]

229.     "Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C≡CC(OMe)=)Mm(CO)n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in which a C3 Chain Links two Metals and Spans a Third", Falloon, S. B.; Weng, W.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2008-2015. DOI: 10.1021/om970055i. [Abstract][PDF]

232.     "Synthesis and Crystal Structure of the Conjugated Tetrayne (η5-C5H5)Re(NO)(PPh3)(C≡CC≡CC≡CC≡CSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp Carbon Wires", Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. New J. Chem. 1997, 21, 739-750. (invited article, 13th summer school in coordination chemistry thematic issue)

238.     "Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries more Distorted than Planar Tetracoordinate", Falloon, S. B.; Szafert, S.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1998, 4, 1033-1042. DOI:10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P. [Abstract][PDF]

240.     "New Forms of Coordinated Carbon: Wire-Like Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer", Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071-11081. DOI: 10.1021/ja981927q. [Abstract][PDF]

244.     "Appreciably Bent sp Carbon Chains: Synthesis, Structure, and Protonation of Organometallic 1,3,5-Triynes and 1,3,5,7-Tetraynes of the Formula (η5-C5Me5)Re(NO)(PPh3)((C≡C)n-p-C6H4Me)", Dembinski, R.; Lis, T.; Szafert, S.; Mayne, C. L.; Bartik, T.; Gladysz, J. A. J. Organomet. Chem. 1999, 578, 229-246. DOI:10.1016/S0022-328X(98)01128-0. [Abstract][PDF]

250.     "A New Route to Heterobimetallic C3 Complexes via C≡C Metatheses of 1,3-Diynyl Ligands: Synthesis and Structure of (η5-C5Me5)Re(NO)(PPh3)(C≡CC≡)W(O-t-Bu)3", Dembinski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438-5440. DOI: 10.1021/om990766b. [Abstract][PDF]

251. "Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C6-C20 Polyynediyl Chains that Span Two Redox-Active (η5-C5Me5)Re(NO)(PPh3) Endgroups", Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810-822. DOI: 10.1021/ja992747z. [Abstract][PDF]

252.     " Synthesis and Properties of Chiral Rhenium Pentatetraenylidene Complexes of the Formula [(η5-C5Me5)Re(NO)(PPh3)(=C=C=C=C=CAr2)]+BF4- (CAr2 = 9-fluorenylidene)", Szafert, S.; Haquette, P.; Falloon, S. B.; Gladysz, J. A. J. Organomet. Chem. 2000, 604, 52-58. DOI:10.1016/S0022-328X(00)00201-1. [Abstract][PDF]

254.     "A 'Conjugal' Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C4 Species", Paul, F.; Meyer, W. E.; Toupet, L.; Jiao, H.; Gladysz, J. A.; Lapinte, C. J. Am. Chem. Soc. 2000, 122, 9405-9414. DOI: 10.1021/ja0011055. [Abstract][PDF]

257.    "Synthesis and Oxidation of Chiral Rhenium Phosphine Methyl Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(CH3): In Search of Radical Cations with Enhanced Kinetic Stabilities", Meyer, W. E.; Amoroso, A. J.; Jaeger, M.; Le Bras, J.; Wong W.-T.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 44-53. DOI: 10.1016/S0022-328X(00)00528-3. [Abstract][PDF]

258.     "Synthesis, Crystal Structure, and Reactions of the Seventeen-Valence-Electron Rhenium Methyl Complex [(η5-C5Me5)Re(NO)(P(4-C6H4CH3)3)(CH3)]·+ (B(3,5-C6H3(CF3)2)4-: Experimental and Computational Bonding Comparisons with Eighteen-Electron Methyl and Methylidene Complexes", Le Bras, J.; Jiao, H.; Meyer, W. E.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 54-66. DOI: 10.1016/S0022-328X(00)00531-3- [Abstract][PDF]

264.     "Synthesis and Oxidation of Dirhenium C4, C6, and C8 Complexes of the Formula (η5-C5Me5)Re(NO)(PR3)(C≡C)n(R3P)(ON)Re(η5-C5Me5) (R = 4-C6H4R', c-C6H11): In Search of Dications and Radical Cations with Enhanced Stabilities", Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115-1127. DOI: 10.1021/om000961m. [Abstract][PDF]

265.     "Metal-Metal Interactions Across Bridging Elemental Carbon Chains: A Computational Study of Odd-Carbon Complexes", Jiao, H.; Gladysz, J. A. New J. Chem. 2001, 25, 551-562. DOI: 10.1039/b008786f. [Abstract][PDF]

288.     "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η5-C5Me5)Re(NO)(PR3)(C≡CC≡C­C≡CC≡C)(R3P)(ON)Re(η5-C5Me5)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. DOI: 10.1021/om020676y. [Abstract][PDF]

297. "Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear bis(1,3-Butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)­dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)]", Horn, C. R.; Gladysz, J. A. Eur. J. Inorg. Chem. 2003, 9, 2211-2218. (feature article). DOI: 10.1002/ejic.200300043. [Abstract][PDF]

 

300.     "Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M']n+: Computational Analyses of the Effect of the Metal", Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; La­pinte, C. J. Am. Chem. Soc. 2003, 125, 9511-9522. DOI: 10.1021/ja034619n. [Abstract][PDF]

326.     "Theoretical Study on the Spin State Energy Splittings and Local Spin in Cationic [Re]-Cn-[Re] Complexes", Herrmann, C.; Neugebauer, J.; Gladysz, J. A.; Reiher, M. Inorg. Chem. 2005, 44, 6174-6182. DOI: 10.1021/ic050240l. [Abstract][PDF]

 

371. "Synthesis and Reactivity of New Heterodinuclear Iron/Rhenium Cx Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C≡C)n(η2-dppe)Fe(η5-C5Me5) (n = 3, 4); Redox Properties and a Dicobalt Hexacarbonyl Adduct", Szafert, S.; Paul, F.; Meyer, W. E.; Gladysz, J. A.; Lapinte, C. C. R. Chimie 2008, 11, 693-701. (invited article, Gecom-Concoord thematic issue) DOI:10.1016/j.crci.2007.10.009. [Abstract][PDF]