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Department of Chemistry Texas A&M University
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College Station, TX 77843-3012

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Texas A&M University
580 Ross Street
MS3255 TAMU
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Publications By Oldest -- Publications by Area

Publications


1970   |   1980   |   1990   |   2000 |   2010 

456. "Cleaning of pH Selective Electrodes with Ionophore-Doped Fluorous Membranes in Na-OH Solution at 90 °C", Lugert-Thom, E. C.; Gladysz, J. A.; Rábai, J.; Buhlmann, P. Electroanalysis 2017, 29, in press DOI: 10.1002/elan.201700228. [Abstract] [PDF]

455. "Syntheses and Structures of Square Planar Diplatinum Butadiynediyl Complexes with two Different Monophopshine Ligands on each Terminus; Probing the Feasibility of a New Type of Inorganic Atropisomerism", Dey, S.; Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2017, 849-850, 237-255. DOI: 10.1016/j.jorganchem.2017.05.006. [Abstract] [PDF]

454. "Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene) (PTFE); "Catalyst-on-a-Tape"", Dinh, L. V.; Jurisch, M.; Fiedler, T.; Gladysz, J. A. ACS Sustainable Chemistry & Engineering 2017, 5, 10875-10888. DOI: 10.1021/acssuschemeng.7b02770. [Abstract] [PDF]

453. "Octahedral Gyroscope-like Molecules Consisting of Rhenium Rotators Within Cage-like Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Hess, G. D.; Fiedler, T.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2017, 56, 7454-7469. DOI: 10.1021/acs.inorgchem.7b00909. [Abstract] [PDF]

452. "Syntheses, Structures, and Stabilities of Aliphatic and Aromatic Fluorous Iodine(I) and Iodine(III) Compounds; the Role of Iodine Atom Lewis Basicity", Mukherjee, T.; Biswas, S.; Ehnbom, A.; Ghosh, S.; El-Zoghbi, I.; Bhuvanesh, N.; Bazzi, H. S.; Gladysz, J. A. Beilstein J. Org. Chem. 2017, 13, 2486-2501. DOI: 10.3762/bjoc/13/246. (invited contribution, special issue on "Organo-fluorine Chemistry IV") [Abstract] [PDF]

451. "Hydrogen Bonding Motifs in Structurally Characterized Salts of the Tris(ethylenediamine) Cobalt Trication, [Co(en)3]3+; an Interpretive Review, including Implications for Catalysis", Ghosh, S. K.; Ehnbom, A.; Lewis, K. G.; Gladysz, J. A. Coord. Chem. Rev. 2017, 350, 30-48. DOI: 10.1016/j.ccr.2017.04.002. [Abstract] [PDF]

450. "Partially Shielded Fe(CO)3 Rotors: Syntheses, Structures, and Dynamic Properties of the Doubly Trans Spanning Diphosphine Complexes trans-Fe(CO)3(PhP((CH2)n)2PPh)", Steigleder, E.; Shima, T.; Lang, G. M.; Ehnbom, A.; Hampel, F.; Gladysz, J. A. Organometallics 2017, 36, 2891-2901. DOI: 10.1021/acs.organomet.7b00330. [Abstract] [PDF]

449. "Enantioselective Additions of Stabilized Carbanions to Imines Generated from α-Amido Sulfones by Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt (III) Trications as Hydrogen Bond Donor Catalysts", Joshi, H.; Ghosh, S. K.; Gladysz, J. A. Synthesis 2017, 3905-3915. DOI: 10.1055/s-0036-1590502. (invited contribution, special issue on cobalt in organic synthesis) [Abstract] [PDF]

448. (a) "Gigging Benzene", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem., Int. Ed. 2017, 58, 5664-5666. DOI: 10.1002/anie.201702942. [Abstract] [PDF]

(b) "Vom Aufspießen des Benzols", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem. 2017, 129, 5756–5758. DOI: 10.1002/ange.201702942. [Abstract] [PDF]

447. "Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3+", Ghosh, S. K.; Lewis, K. G.; Kumar, A.; Gladysz, J. A. Inorg. Chem. 2017, 56, 2304-2320. DOI: 10.1021/acs.inorg chem.6b03042. [Abstract] [PDF]

446. "Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl2 Species (M = Pt, Pd, Ni)", 2016, Kharel, S.; Joshi, H.; Bierschenk, S.; Stollenz, M.; Taher, D.; Bhuvanesh, N.; Gladysz, J. A. J. Am. Chem. Soc. 2017, 139, 2172-2175. DOI: 10.1021/jacs.6b12788. [Abstract] [PDF]

445. "Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 1,7-Dihydroxynaphthalene", Baranová, Z.; Amini, H.; Neupane, H.; Garrett, S. C.; Ehnbom, A.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Aust. J. Chem. 2017, 70, 373-386. DOI: 10.1071/CH16587 (invited contribution, special issue, Heron Island Conference on Reactive Intermediates) [Abstract] [PDF]

444. "A Quest for Atropisomerism in Cojoined Square Planar Metal Complexes: Syntheses and Structures of Sterically Congested Diplatinum Ethynediyl Adducts", Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. Eur. J. Inorg. Chem. 2017, 2017, 1017-1025. DOI: 10.1002/ejic.201601307. [Abstract] [PDF]

443. "Mono- and Disubstitution Reactions of Gyroscope Like Complexes Derived from Cl-Pt-Cl Rotators within Cage Like Dibridgehead Diphosphine Ligands", Taher, D.; Nawara-Hultzsch, A. J.; Bhuvanesh, N.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2016, 821, 136-141. DOI: 10.1016/j.jorganchem.2016.03.022. (invited contribution, special issue dedicated to Heinrich Lang) [Abstract] [PDF]

442. "Synthesis, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Complexes with Dibridgehead Diphosphine Cages: Pre- vs. Post-Metathesis Substitutions as Routes to Adducts with Neutral Dipolar Fe(CO)(NO)(X) Rotors", Lang, G. M.; Skaper, D.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2016, 45, 16190-16204. DOI: 10.1039/c6dt03258c. [Abstract] [PDF]

441. "Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Carbonyl Complexes based upon Dibridgehead Diarsine Cages", Lang, G. M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2016, 35, 2873-2889. DOI: 10.1021/acs.organomet.6b00447. [Abstract] [PDF]

440. " Convenient Protocols for Mizoroki-Heck Reactions of Aromatic Bromides and Polybromides with Fluorous Alkenes of the Formula H2C=CH(CF2)n–1CF3 (n = 8, 10)", Su, H.-L.; Balogh, J.; Al-Hashimi, M.; Seapy, D. G.; Bazzi, H. S.; Gladysz, J. A. Org. Biomol. Chem. 2016, 10058-10069. DOI:10.1039/c6ob01980c. [Abstract] [PDF]

439. "Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR", Fiedler, T.; Chen, L.; Wagner, N. D.; Russell, D. R.; Gladysz, J. A. Organometallics 2016, 35, 2071-2075. DOI:10.1021/acs.organomet.6b00249 [Abstract] [PDF]

438. "Octahedral Werner Complexes with Substituted Ethylenediamine Ligands: A Stereochemical Primer for a Historic Series of Compounds now Emerging as a Modern Family of Catalysts", Ehnbom, A.; Ghosh, S. K.; Lewis, K. G.; Gladysz, J. A. Chem. Soc. Rev. 2016, 45, 6799-6811. DOI:10.1039/c6cs00604c [Abstract] [PDF]

437. " Gyroscope Like Complexes based upon Dibridgehead Diphosphine Cages that are Accessed by Three Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)+ and Fe(CO)3(H)+ Rotators", Lang, G. M.; Shima, T.; Wang, L.; Cluff, K. J.; Skopek, K.; Hampel, F.; Blümel, J.; Gladysz, J. A. J. Am. Chem. Soc. 2016, 138, 7649-7663. DOI:10.1021/jacs.6b03178 [Abstract] [PDF]

436. " Tris(1,2-diphenylethylenediamine) Cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds", Kumar, A.; Ghosh, S. K.; Gladysz, J. A. Org. Lett. 2016, 18, 760-763. DOI:10.1021/acs.orglett.6b00023 [Abstract] [PDF]

435. "Gyroscope Like Molecules Consisting of Trigonal or Square Planar Osmium Rotators Within Three-Spoked Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Fiedler, T.; Bhuvanesh, N.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Dalton Trans. 2016, 45, 7131-7147. DOI:10.1039/c6dt00692b [Abstract] [PDF]

434. (a) "Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen Bond Donor Catalysts for Highly Enantioselective Michael Additions", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2016, 55, 4356-4360. DOI: 10.1002/anie.201511314. [Abstract][PDF]

(b) "Werner-Komplexe mit ω-dimethylaminoalkylsubstitutierten Ethylenediamin-liganden: Bifunktionale Wasserstoffbrückenbindungsdonor-Katalysatoren für hochgradig enantioselektive Michael Additionen", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., 2016, 128, 4429-4433. DOI: 10.1002/ange.201511314. [Abstract][PDF]

433. "A Phase Based Approach to Insulated Molecular Wires: Diplatinum Octatetraynediyl Complexes Bearing Fluorous Trialkylphosphine Ligands", Clough, M. C.; Fiedler, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2016, 812, 34-42. DOI:10.1016/j.jorganchem.2015.09.020. (invited contribution, special issue dedicated to Jack Lewis) [Abstract] [PDF]

432. "An Analogue of Grubbs' Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis", Balogh, J.; Hlil, A. R.; Su, H.-L.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. ChemCatChem. 2016, 8, 125-128. DOI: 10.1002/cctc.201500913 [Abstract] [PDF]

431. "Synthesis of a Series of ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands for use in Enantioselective Catalysis", Ghosh, S. K.; Ganzmann, C.; Gladysz, J. A. Tetrahedron: Asymmetry 2015, 26, 1273-1280. DOI:10.1016/j.tetasy.2015.09.012 [Abstract] [PDF]

430. "Phase Transfer Activation of Transition Metal Catalysts", Tuba, R.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Chem. Eur. J. 2015, 21, 15894-15906. DOI:10.1002/chem.201502403. [Abstract] [PDF]

429. "Substitution and Catalytic Chemistry of Gyroscope Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands", Estrada, A. L.; Jia, T.; Bhuvanesh, N.; Blümel, J.; Gladysz, J. A. Eur. J. Inorg. Chem.. 2015 2015 5318-5321. DOI:10.1002/ejic.201500953 [Abstract] [PDF]

428. "Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands", Xi, Z.; Bazzi, H.S.; Gladysz, J. A. J. Am. Chem. Soc. 2015, 137, 10930-10933. DOI:10.1021/jacs.5b06562 [Abstract] [PDF]

427. "Steric Control of the in/out Sense of Bridgehead Substituents in Macrobicyclic Compounds: Isolation of New "Crossed Chain" Variants of in/out Isomers", Stollenz, M.; Taher, D.; Bhuvanesh, N.; Reibenspies, J. H.; Baranová, Z.; Gladysz, J. A. Chem. Commun. 2015, 51, 16053-16056. DOI: 10.1039/c5cc05620a. [Abstract] [PDF]

426. "Phase and Redox Shifted Four Iron/Four Sulfur Clusters; Fluorous Analogs of Metalloensyme Cofactors", Zhang, C.-P.; Xi, Z.; Mueller, K. M.; Holliday, B. J.; Bazzi, H. S.; Gladysz, J. A. Dalton Trans. 2015, 44, 19615-19624. DOI:10.1039/C5DT01959A [Abstract] [PDF]

425. "Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3", Lang, G. M.; Skaper, D.; Shima, T.; Otto, M.; Wang, L.; Gladysz, J. A. Aust. J. Chem. 2015, 68, 1342-1351. DOI: 10.1071/CH15178. (invited contribution, issue commemorating the 2014 RACI National Congress) [Abstract] [PDF]

424. "Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis", Lewis, K. G.; Ghosh, S. K.; Bhuvanesh, N.; Gladysz, J. A. ACS Cent. Sci., 2015, 1, 50-56. DOI:10.1021/acscentsci.5b00035. [Abstract] [PDF]

423. "Fluorous Chemistry Meets Green Chemistry: A Concise Primer", Mukherjee, T.; Gladysz, J. A. Aldrichimica Acta, 2015, 48, 25-28. [PDF]

422. "An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2-Substituted Benzimidazoles", Gladysz, J. A.; Safaei, H. R.; Nouri, S. Helv. Chim. Acta 2014, 97, 1539-1545. DOI: 10.1002/hlca.201400033. [Abstract] [PDF]

421. "Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles", Baranová, Z.; Amini, H.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6746-6749. DOI:10.1021/om501026u. [Abstract][PDF]

420. "Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces", Hilliard, C. R.; Kharel, S.; Cluff, K. J.; Bhuvanesh, N.; Gladysz, J. A.; Blümel, J. Chem. Eur. J. 2014, 20, 17292-17295. DOI: 10.1002/chem.201404880. [Abstract][PDF]

419. "Liquid/Solid Phase Transfer Activation of Grubbs-Type Alkene Metathesis Catalysts; Application of Silver Salts of Sulfonated Polystyrene", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Catal. Sci. Technol. 2014, 4, 4178-4182. DOI:10.1039/c4cy01021c. [Abstract][PDF]

418. "Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions", Mukherjee, T.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6723-6737. DOI:10.1021/om­500705s. [Abstract][PDF]

417. "Metal Templated Hydrogen Bond Donors as 'Organocatalysts' for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes", Scherer, A.; Mukherjee, T.; Hampel, F.; Gladysz, J. A. Organometallics 2014, 33, 6709-6722. DOI:10.1021/om500704u. [Abstract][PDF]

416. "Synthesis, Photovoltaic Perfomances, and TD-DFT Modeling of Push-Pull Diacetylide Platinum Complexes in TiO2 Based Dye-Sensitized Solar Cells", Gauthier, S.; Caro, B.; Robin-Le Guen, F.; Bhuvanesh, N.; Gladysz, J. A.; Wojcik, L.; Le Poul, N.; Planchat, A.; Pellegrin, Y.; Blart, E.; Jacquemin, D.; Odobel, F. Dalton Trans. 2014, 43, 11233-11242. DOI:10.1039/C4DT00301B [Abstract][PDF]

415. "Organometallics Roundtable 2013-2014", Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaï, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. Organometallics 2014, 33, 1505-1527. DOI: 10.1021/om500253z. [Abstract][PDF]

414. "Photophysics of Platinum Tetrayne Oligomers: Delocalization of Triplet Exciton", Li, Y.; Winkel, R. W.; Weisbach, N.; Gladysz, J. A.; Schanze, K. S. J. Phys. Chem. A. 2014, 115, 10333-10339. DOI: 10.1021/jp5021388. [Abstract][PDF]

413. "Highly Active Families of Catalysts for the Ring Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimida­zole", Thomas, C.; Gladysz, J. A. ACS Catalysis 2014, 4, 1134-1138. DOI: 10.1021/cs500134z. ("ACS Editor's Choice" article for 14 March 2014: [Link]) [Abstract][PDF]

412. "Gyroscope Like Molecules Consisting of PdX2/PtX2 Rotators Within Three-Spoke Di­bridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Nawara-Hultzsch, A. J.; Stollenz, M.; Barbasiewicz, M.; Szafert, S.; Lis, T.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Chem. Eur. J. 2014, 20, 4617-4637. DOI: 10.1002/chem.201304419 [Abstract][PDF]

411. "Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladium Catalyzed Suzuki Cross-Coupling Reactions", Sierra Castro, D.; Bhuvanesh, N.; Reibenspeis, J. H.; Gladysz, J. A.; Klahn, A. H. J. Organomet. Chem. 2014, 749, 416-420. DOI: 10.1016/j.jorganchem.2013.10.029. [Abstract][PDF]

 

410. "Multifold Ring Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities", Fiedler, T.; Gladysz, J. A. in Olefin Metathesis – Theory and Practice, Grela, K., Ed.; John Wiley & Sons, Hoboken, New Jersey, 2014, 311-328. ISBN: 978-1-118-20794-9.

409. "A Metal-capped Conjugated Polyyne Threaded Through a Phenanthroline-based Macrocycle. Probing Beyond the Mechanical Bond to Interactions in Interlocked Molecular Ar­chitectures", Sahnoune, H.; Baranová, Z.; Bhuvanesh, N.; Gladysz, J. A.; Halet, J.-F. Organometallics, 2013, 32, 6360-6367. DOI: 10.1021om400709q. [Abstract][PDF]

 

408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Guerrero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u. [Abstract][PDF]

 

407. "Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Level Detection and In-Situ Monitoring of Absorption", Chen, L. D.; Lai, C.-Z.; Granda, L. P.; Fierke, M. A.; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P. Anal. Chem. 2013, 85, 7471-7477. DOI: 10.1021/ac401424j. [Abstract][PDF]

 

406. "Toward Permetalated Alkyne/Azide 3+2 or 'Click' Cycloadducts", Clough, M. C.; Zeits, P. D. Bhuvanesh, N.; Gladysz, J. A. Organometallics 2012, 31, 5231-5234. DOI: 10.1021/om300542a. [Abstract][PDF]

 

405. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluorous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g. [Abstract][PDF]

 

404. "Ring opening metathesis polymerization of an η4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments", Zeits, P. D.; Fiedler, T.; Gladysz, J. A. Chem. Commun. 2012, 48, 7925-7927. DOI: 10.1039/C2CC32150E. [Abstract][PDF]

 

403. "A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated polyyne", Weisbach, N.; Baranová, Z.; Gauthier, S.; Reibenspies, J. H.; Gladysz, J. A. Chem. Commun. 2012, 48, 7562-7564. DOI: 10.1039/C2CC33321J. [Abstract][PDF]

 

402. "Structural, Physical, and Chemical Properties of Fluorous Compounds", Gladysz, J. A.; Jurisch, M. Top. Curr. Chem. 2012, 308, 1-24. [PDF]

 

401. "Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands", Zeits, P. D.; Rachiero, G. P.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2012, 31, 2854-2877. [Abstract][PDF]

400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Abstract][PDF]

 

399. "Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts", Hilliard, C. R.; Gladysz, J. A.; Blümel, J. Dalton. Trans. 2012, 41, 1742-1754. DOI: 10.1039/c1dt11863c. [Abstract][PDF]

398. "Organometallics Roundtable 2011", Gladysz, J. A.; Ball, Z. T.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Man­ners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam, V. W.-W. Organometallics 2012, 31, 1-18. DOI: 10.1021/om201234x. [Abstract][PDF]

 

397. "Potentiometric Sensors Based on Fluorous Membranes Doped with Highly Selective Ionophores for Carbonate", Chen, L. D.; Mandal, D.; Pozzi, G.; Gladysz, J. A.; Bühlmann, P. J. Am. Chem. Soc. 2011, 133, 20869-20877. DOI: 10.1021/ja207680e. [Abstract][PDF]

 

396. "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines that can turn themselves Inside-Out", Stollenz, M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2011, 30, 6510-6513. DOI: 10.1021/om200924g. [Abstract][PDF]

 

395. "Analogs of Grubbs' Second Generation Catalyst with Hydrophilic Phosphine Ligands: Phase Transfer Activation of Ring Closing Alkene Metathesis", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Org. Lett. 2011, 13, 6188-6191. DOI: 10.1021/ol202548q. [Abstract][PDF]

 

394. (a) "Dibridgehead Diphosphines that Turn Themselves Inside-Out", Stollenz, M.; Barba­siewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Glad­ysz, J. A. Angew. Chem., Int. Ed. 2011, 50, 6647-6651. DOI: 10.1002/ange.201100893. [Abstract][PDF

(b) "Dreifach-verbrückte Diphosphine mit von innen nach außen invertierender Konfigur­ation", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem. 2011, 123, 6777-6781. DOI: 10.1002/ange.201100893. [Abstract][PDF]

 

393. "Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization", Kirillov, E.; Marquet, N.; Bader, M.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics, 2011, 30, 263-272. DOI: 10.1021/om100897j. [Abstract][PDF]

 

392. "The Future of Organometallic Chemistry", Gladysz, J. A. Organometallics 2011, 30, 1-4. DOI: 10.1021/om1011215. [Abstract][PDF]

 

391. "Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes", Lai, C.-Z.; Fierke, M. A.; Corrêa da Costa, R.; Gladysz, J. A.; Stein, A.; Bühlmann, P. Anal. Chem. 2010, 82, 7634-7640. DOI: 10.1021/ac1013767. [Abstract][PDF]

 

390. "New C1-Symmetric Ph2C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Polypropylene Polymerization: Synthetic Approach via Activated Fulvenes" Kirillov, E.; Marquet, N.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2010, 29, 5073-5082. (invited article, issue in honor of Dietmar Seyferth) DOI: 10.1021/om100289y. [Abstract][PDF]

 

389. "Thermomorphic Fluorous Phosphines as Organocatalysts for Michael Addition Reac­tions", Gimbert, C.; Vallribera, A.; Gladysz, J. A.; Jurisch, M. Tetrahedron Lett. 2010, 51, 4662-4665. DOI: 10.1016/j.tetlet.2010.06.136. [Abstract][PDF]

 

388. "Square Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH2)4CH=CH2 Substituents; Two- and Three-Fold Intramolecular Ring Closing Metatheses", Han, J.; Deng, C.; Fang, R.; Zhao, D.; Wang, L.; Gladysz, J. A. Organometallics 2010, 29, 3231-3234. DOI: 10.1021/om100536g. [Abstract][PDF]

 

387. "Towards Multistranded Molecular Wires: Syntheses, Structures, and Reactivities of Tetraplatinum bis(Polyynediyl) Complexes with Pt-Cx-Pt-(P(CH2)3P)2-Pt-Cx-Pt-(P(CH2)3­P)2 Cores (x = 4, 6, 8)", Owen, G. R.; Gauthier, S.; Weisbach, N.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Dalton Trans. 2010, 5260-5271. DOI: 10.1039/c002041a. [Abstract][PDF]

 

386. "Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes", Chen, L. D.; Mandal, D.; Gladysz, J. A.; Bühlmann, P. New. J. Chem. 2010, 34, 1867-1874. DOI: 10.1039/B9NJ00696F. [Abstract][PDF]

 

385. "Molecular Wires in Single Molecule Junctions: Charge Transport and Vibrational Exci­tations", Ballmann, S.; Hieringer, W.; Secker, D.; Zheng, Q.; Gladysz, J. A.; Görling, A.; Weber, H. B. ChemPhysChem 2010, 11, 2256-2260. DOI: 10.1002/cphc.200900974. [Abstract][PDF]

 

384. "Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3", Nawara-Hultzsch, A. J.; Skopek, K.; Shima, T.; Barbasiewicz, M.; Hess, G. D.; Skaper, D.; Gladysz, J. A. Z. Naturforsch. B.. 2010, 65, 414-424. (invited article, issue in honor of Rolf Saalfrank) DOI: 10.1515/ZNB-2010-0327 [Abstract] [PDF]

383. "Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents", Mandal, D.; Gladysz, J. A. Tetrahedron 2010, 66, 1070-1077. DOI: 10.1016/j.tet.2009.11.012. [Abstract][PDF]

 

382. "Syntheses and Structural Analyses of Chiral Rhenium Containing Amines of the Formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR') (n = 0, 1)", Seidel, S. N.; Prommesberger, M.; Eichenseher, S.; Meyer, O. Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2010, 363, 533-548. (invited article, issue in honor of Paul Pregosin) DOI:10.1016/j.ica.2009.03.047. [Abstract][PDF]

 

381. "The Experimental Assay of Catalyst Recovery: General Concepts", Gladysz, J. A. in Re­coverable and Recyclable Catalysts, Benanglia, M. Ed; Wiley-Blackwell, Oxford, England, 2009, pp. 1-22. ISBN: 978-0470681954.

 

380. "Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies", Gladysz, J. A. in Handbook of Green Chemistry, Anastas, P.; Crabtree, R. H. Eds; Volume 1: Homogeneous Catalysis; Crabtree, R. H. Volume Ed; Wiley/VCH, Weinheim, 2009, 17-38. ISBN: 9783527324965 3527324968.

 

379. "'Click' Chemistry in Metal Coordination Spheres: Copper(I) Catalyzed 3+2 Cycloaddi­tions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol3P)2Pt(C≡C)nH (n = 2-6)", Gauthier, S.; Weisbach, N.; Gladysz, J. A Organometallics 2009, 28, 5597-5599. DOI: 10.1021/om900680q. [Abstract][PDF]

 

378. "Synthesis and Reactivity of Fluorous and non-Fluorous Aryl and Alkyl Iodine(III) Dichlorides: New Chlorinating Reagents that are Easily Recycled using Biphasic Protocols", Podgoršek, A.; Jurisch, M.; Stavber, S.; Zupan, M.; Iskra, J.; Gladysz, J. A. J. Org. Chem. 2009, 74, 3133-3140. DOI: 10.1021/jo900233h. [Abstract][PDF]

 

377. "Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes", Kuhn, H.; Hampel, F.; Gladysz, J. A. Organometallics 2009, 28, 4979-4987. DOI: 10.1021/om9005017. [Abstract][PDF]

 

376. "Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Proctocols Involving Precipitation, Teflon® Tape and Gore-Rastex® Fiber", Seidel, F. O.; Gladysz, J. A. Adv. Synth. Catal. 2008, 350, 2443-2449. DOI: 10.1002/adsc.200800403. [Abstract][PDF]

 

375. "Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains", Samoc, M.; Dalton, G. T.; Gladysz, J. A.; Zheng, Q.; Yelkov, Y.; Ågren, H.; Norman, P.; Humphrey, M. G. Inorg. Chem. 2008, 47, 9946-9957. DOI: 10.1021/ic801145c. [Abstract][PDF]

 

374. "Ionic Transformations in Extremely Nonpolar Fluorous Media: Easily Recoverable Phase Transfer Catalysts for Halide Substitution Reactions", Mandal, D.; Jurisch, M.; Consorti, C. S.; Gladysz, J. A. Chem. Asian J. 2008, 3, 1772-1782. DOI: 10.1002/asia.200800138. [Abstract][PDF]

 

373. "Syntheses, Structures, and Electronic Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C6F5)(R3P)2Pt, (p-tol)(R3P)2Pt, and (Ph3P)Au End-Groups", de Quadras, L.; Shelton, A. H.; Kuhn, H.; Hampel, F.; Schanze, K. S.; Gladysz, J. A. Organometallics 2008, 27, 4979-4991. DOI: 10.1021/om800493x. [Abstract][PDF]

 

372. "Phase Transfer of Enantiopure Werner Cations into Organic Solvents; An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis", Ganzmann, C.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 5397-5400. DOI: 10.1002/chem.200800226. [Abstract][PDF]

 

371. "Synthesis and Reactivity of New Heterodinuclear Iron/Rhenium Cx Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C≡C)n(η2-dppe)Fe(η5-C5Me5) (n = 3, 4); Redox Properties and a Dicobalt Hexacarbonyl Adduct", Szafert, S.; Paul, F.; Meyer, W. E.; Gladysz, J. A.; Lapinte, C. C. R. Chimie 2008, 11, 693-701. (invited article, Gecom-Concoord thematic issue) DOI:10.1016/j.crci.2007.10.009. [Abstract][PDF]

370. "Three-Fold Intramolecular Ring-Closing Metatheses Involving Square Planar Platinum Complexes with cis Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute Like Complexes", Skopek, K.; Barbasiewicz, M.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2008, 47, 3474-3476. DOI: 10.1021/ic702391m. [Abstract][PDF]

 

369. "En Route to Diplatinum Polyynediyl Complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold Tales, Including End-Group Strategies", Stahl, J.; Bohling, J. C.; Peters, T. B.; de Quadras, L.; Gladysz, J. A. Pure Appl. Chem. 2008, 80, 459-474. (invited article, ISNA-12 thematic issue) DOI: 10.1351/pac200880030459. [Abstract][PDF]

368. "Synthesis of Fluorous Sulfur/Carbon/Sulfur Pincer Ligands and Palladium Complexes; New Catalyst Precursors for the Heck Reaction", Corrêa da Costa, R.; Jurisch, M.; Gladysz, J. A. Inorg. Chim. Acta 2008, 361, 3205-3214. (invited article, issue in honor of Robert Angelici) DOI: 10.1016/j.ica.2007.11.016. [Abstract][PDF]

367. "Coordination-Driven Self Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp3 Carbon Chains: Towards Endgroup-Endgroup Interactions", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 73-87. DOI: 10.1002/ chem.200701268. [Abstract][PDF]

366. "Thermomorphic Fluorous Palladacycles", Gladysz, J. A. in Palladacycles, Dupont, J.; Pfeffer, M. Eds; Wiley/VCH, Weinheim, 2008, 341-359. DOI:10.1002/ 9783527623211.ch14. [Abstract][PDF]

365. "Syntheses of Gyroscope-Like Molecules via Three-Fold Ring Closing Metatheses of bis­(Phosphine) Complexes trans-LyM(P((CH2)nCH=CH2)3)2, and Extensions to bis(Phosphite) Complexes trans-Fe(CO)3(P(O(CH2)nCH=CH2)3)2", Skopek, K.; Gladysz, J. A. J. Organomet. Chem. 2008, 693, 857-866. (invited article, "Frontiers in Organometallic Chemistry" thematic issue) DOI: 10.1016/J.JORGANCHEM.2007.11.001. [Abstract][PDF]

364. "Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains", Farley, R.; Zheng, Q.; Gladysz, J. A.; Schanze, K. S. Inorg. Chem. 2008, 47, 2955-2963. DOI: 10.1021/ic701220t. [Abstract][PDF]

363. "Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity", Boswell, P. G.; Szíjjáró, C.; Jurisch, M.; Gladysz, J. A.; Rábai, J.; Bühlmann, P. Anal. Chem. 2008, 80, 2084-2090. DOI: 10.1021/ac702161c. [Abstract][PDF]

 

362. "Chiral Phosphorus Donor Ligands Containing Monocyclopentadienyl Metal Fragments", Castillo, D. A.; Gladysz, J. A. in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Börner, A. Ed; Wiley/VCH, Weinheim, 2008, 408-437. DOI: 10.1002/chin.200942263.

 

361. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Wire-Like Pt(C≡C)nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]

 

360. "Octahedral Gyroscope-Like Molecules with M(CO)3(X) Rotators Encased in Three-Spoked Diphosphine Stators:  Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities", Hess, G. D.; Hampel, F.; Gladysz, J. A. Organometallics 2007, 26, 5129-5131. DOI: 10.1021/om700625u. [Abstract][PDF]

359. "Ionic Chemistry in Extremely Nonpolar Fluorous Media: Phase Transfer Catalysis of Halide Substitution Reactions", Consorti, C. S.; Jurisch, M.; Gladysz, J. A. Org. Lett. 2007, 9, 2309-2312. DOI: 10.1021/ol0706354. [Abstract][PDF]

358. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices:  Directed Syntheses of Wirelike Pt(C≡C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alva­rez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. DOI: 10.1021/ja071612n. [Abstract][PDF]

357. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Coordination-Driven Self Assembly of Wirelike Pt(C≡C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages", Stahl, J.; Mohr, W.; de Quadras, L.; Peters, T. B.; Bohling, J. C.; Martín-Alvarez, J. M.; Owen, G. R.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8282-8295. DOI: 10.1021/ja0716103. [Abstract][PDF]

356. "Temperature Controlled Catalyst Recycling: New Protocols based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid-Liquid Phase Separations", Tesevic, V.; Gladysz, J. A. Topics in Organometallic Chemistry 2008, 23, 67-89. (published on the web in 2006) DOI: 10.1007/3418_043. [Abstract][PDF]

355. "Gyroscopes and the Chemical Literature: 1852-2002" Skopek, K.; Hershberger, M. C.; Gladysz, J. A. Coord. Chem. 2007, Coord. Chem. Rev. 2007, 251, 1723-1733. (invited article, 37th ICCC thematic issue) DOI:10.1016/j.ccr.2006.12.015 [Abstract][PDF]

354. "Monophosphine and Diphosphine Ligands for Diplatinum Polyyendiyl Complexes: Efficient Syntheses of New Functionality-Containing Systems and Model Compounds", de Quadras, L.; Stahl,J.; Zhuravlev, F.; Gladysz, J. A. J. Organomet. Chem. 2007, 692, 1859-1870. DOI: 10.1016/J.JORGANCHEM.2006.12.023. [Abstract][PDF]

353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", Corrêa da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. (invited article, olefin metathesis thematic issue) DOI: 10.1002 /adsc.200600461. [Abstract][PDF]

352. "Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2PAr2)", Seidel, F.; Gladysz, J. A. Synlett 2007, 6, 986-988. DOI: 10.1055/s-2007-973859. [Abstract][PDF]

351. "Crystal Structure of an Unusual bis(fluorous phosphine) Ruthenium(III) Complex Derived from a Fluorous Grubbs' Catalyst", Corrêa da Costa, R.; Hampel, F.; Gladysz, J. A. Polyhedron 2007, 26, 581-588. DOI: 10.1016/j.poly.206.08.015. [Abstract][PDF]

350. "Update 1 of: Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2006, 106, PR1–PR33. (inaugural "Perennial Review") DOI: 10.1021/cr030041o. [Abstract][PDF]

349. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Complexes Derived From P(CH2)5P Backbones", Consorti, C. S.; Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2006, 359, 4874-4884. DOI: 10.1016/j.ica.2006.07.092. [Abstract][PDF]

348. "Gyroscope-Like Molecules Consisting of Three-Spoke Stators that Enclose "Switchable" Neutral Dipolar Rhodium Rotators; Reversible Cycling between Faster and Slower Spinning Rh(CO)I and Rh(CO)2I Species" Wang, L.; Shima, T.; Hampel, F.; Gladysz, J. A. Chem. Commun. 2006, 4075-4077. DOI: 10.1039/b606728j. [Abstract][PDF]

347. "Fluorous to the Core", Gladysz, J. A. Science 2006, 313, 1249-1250. DOI: 10.1126/ science.1131944. [Abstract][PDF]

346. "A Promising New Catalyst Family for Enantioselective [3+2] Cycloadditions of Allenes and Imines: Chiral Phosphines with a Transition Metal–CH2–P: Linkage" Scherer, A.; Gladysz, J. A. Tetrahedron Lett. 2006, 47, 6335-6337. DOI: 10.1016/j.tetlet.2006.07.005. [Abstract][PDF]

345. "Oxidation of Secondary Alcohols to Ketones Using Easily Recyclable bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Tesevic, V.; Gladysz, J. A.; J. Org. Chem. 2006, 71, 7433-7440. DOI: 10.1021/jo0612067. [Abstract][PDF]

344. "A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Bohling, J. C.; Peters, T. B.; Frisch, A. C.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 6486-6505. DOI: 10.1002/chem.200600615. [Abstract][PDF]

 

343. "Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Pony­tails; New Candidates for Phase Transfer Catalysts and Ionic Liquids", Emnet, C.; Weber, K. M.; Vidal, J. A.; Consorti, C. S.; Stuart, A. M. Gladysz, J. A. Adv. Synth. Catal. 2006, 348, 1625-1634. (invited article, "multiphase catalysis, green solvents, and immobilization" issue) DOI: 10.1002/adsc.200606138. [Abstract][PDF]

342. (a) "Giant" Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25-27 Membered Macrocycles", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 2006, 45, 4372-4375. DOI: 10.1002/anie.200601191. [Abstract][PDF]

(b) "Gyroskop-Giganten": Dipolare Cl-Rh-CO-Roatoren, umgeben von Startoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2006, 118, 4479-4482. DOI: 10.1002/ange.200601191. [Abstract][PDF]

341. "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies", Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 5267-5281. DOI: 10.1002/chem.200501540. [Abstract][PDF]

340. "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link in a Series of Square-Planar Platinum Complexes", Lewanzik, N.; Oeser, T.; Blümel, J.; Gladysz, J. A. J. Mol. Catal. A. 2006, 254, 20-28. (invited article, 16th International Symposium on Olefin Metathsis thematic issue) DOI: 10.1016/j.molcata.2005.10.047. [Abstract][PDF]

339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", Corrêa da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. DOI: 10.1039/B602428A. [Abstract][PDF]

 

338. "Gyroscope-Like Molecules Consisting of PdX2/PtX2 Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetallation", Nawara, A. J.; Shima, T.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2006, 128, 4962-4963. DOI: 10.1021/ja061044w. [Abstract][PDF]

337. "π Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts", Dinh, L. V.; Consorti, C. S.; Emnet, C.; Gladysz, J. A. Organometallics 2006, 25, 1245-1251. DOI: 10.1021/om050950z. [Abstract][PDF]

336. "Wire-Like PtC≡CC≡CC≡CC≡CPt Moieties Surrounded by Double-Helical 'Insulation': New Motifs Featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P Linkages", de Quadras, L.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2006, 2929-2933. DOI: 10.1039/b604465b. [Abstract][PDF]

335. "'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails: Syntheses from Polybromocyclopentadienyl Complexes, Phase Properties, and Electronic Effects", Dinh, L. V.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 7211-7222. DOI: 10.1002/chem.200500595. [Abstract][PDF]

334. "An Easily Accessed Class of Recyclable Hypervalent Iodide Reagents for Functional Group Oxidations: bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Tesevic, V.; Gladysz, J. A. Green Chem. 2005, 7, 833-836. DOI: 10.1039/b511951k. [Abstract][PDF]

333. "Fluorous Solvents: Physical Properties", Gladysz, J. A.; Emnet, C. in Green Reaction Med­ia in Organic Synthesis, Mikami, K. Ed.; Blackwell, Oxford, UK, 2005, pp 62-80 (Ch 3.2). ISBN: 978-1-4051-3402-6. DOI: 10.1002/9780470988770.ch3 [Abstract][PDF]

332. "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions", Friedlein, F. K.; Hampel, F.; Gladysz, J. A. Organometallics, 2005, 24, 4103-4105. DOI: 10.1021/om0504708. [Abstract][PDF]

331. "Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives", Emnet, C.; Tuba, R.; Gladysz, J. A. Adv. Synth. Catal., 2005, 347, 1819-1826. DOI: 10.1002/adsc.200505145. [Abstract][PDF]

 

330. "A Synthetic Breakthrough into an Unanticipated Stability Regime: Readily Isolable Complexes in which C16-C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Gladysz, J. A. J. Am. Chem. Soc. 2005, 127, 10508-10509. DOI: 10.1021/ja0534598. [Abstract][PDF]

329. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Ligands and Metal Complexes", Tuba, R.; Tesevic, V.; Dinh, L. V.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2005, 13, 2275-2283. DOI: 10.1039/B502309B [Abstract][PDF]

328.     "Synthesis and Reactivity of 1,2- and 1,3-Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis" Kromm, K.; Eichenseher, S.; Prommesberg­er, M.; Hampel, F.; Gladysz, J. A. Eur. J. Inorg. Chem. 2005, 2983-2998. DOI: 10.1002/ejic.200500254. [Abstract][PDF]

 

327.     (a) "'Catalyst-on-a-Tape' – Teflon: A New Delivery and Recovery Method for Homogene­ous Fluorous Catalysts", Dinh, L. V.; Gladysz, J. A. Angew. Chem., Int. Ed. 2005, 44, 4095-4097. DOI: 10.1002/anie.200500237. [Abstract][PDF]

(b) "'Katalysatoren am laufenden Band' – Teflon: Eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren", Dinh, L. V.; Gladysz, J. A. Angew. Chem., 2005, 26 4164-4167. DOI: 10.1002/ange.200500237. [Abstract][PDF]

 

326.     "Theoretical Study on the Spin State Energy Splittings and Local Spin in Cationic [Re]-Cn-[Re] Complexes", Herrmann, C.; Neugebauer, J.; Gladysz, J. A.; Reiher, M. Inorg. Chem. 2005, 44, 6174-6182. DOI: 10.1021/ic050240l. [Abstract][PDF]

 

325.     "Efficient Syntheses of Fluorous Primary Phosphines that do not Require PH3", Emnet, C.; Gladysz, J. A. Synthesis 2005, 1012-1018. DOI: 10.1055/s-2005-861815. [Abstract][PDF]

 

324.     "Generation and Reactions of Ruthenium Phosphido Complexes [(η5-C5H5)Ru(PR'3)2(PR2)]: Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions", Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416. DOI: 10.1002/chem.200400925. [Abstract][PDF]

 

323.     "Monophasic and Biphasic Hydrosilylations of Enones and Ketones using a Fluorous Rhodium Catalyst that is Easily Recycled under Fluorous/Organic Liquid/Liquid Biphase Condi­tions", Dinh, L. V.; Gladysz, J. A. New. J. Chem. 2005, 29, 173-181. DOI: 10.1039/B415344H [Abstract][PDF]

322.     "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems", Eichenseher, S.; Dela­croix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 245-255. DOI: 10.1021/om0492956. [Abstract][PDF]

321.     "Syntheses and Structures of Missing Links among Polybromocyclopentadienyl Rhenium and Manganese Tricarbonyl Complexes" , Dinh, L. V.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2005, 690, 493-503. DOI: 10.1016/J.JORGANCHEM.2004.09.072. [Abstract][PDF]

320.     "Electronic Structure and Chain Length Effects in Diplatinum Polyynediyl Complexes trans, trans-[(X)(R3P)2Pt(C≡C)nPt(PR3)2(X)]: A Computational Investigation", Zhuravlev, F.; Gladysz, J. A. Chem. Eur. J. 2004, 10, 6510-6522. DOI: 10.1002/chem.200400643. [Abstract][PDF]

 

319.     (a) "Molecular Gyroscopes: {Fe(CO)3} and {Fe(CO)2(NO)}+ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. DOI: 10.1002/anie.200460534. [Abstract][PDF]

(b) "Molekulare Gyroskope: {Fe(CO)3}- und {Fe(CO)2(NO)}+-Rotatoren in einem Stator aus drei Speichen; Einfache Synthese durch Alken-Metathese", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2004, 116, 5653-5656. DOI: 10.1002/ange.200460534. [Abstract][PDF]

 

318. "Transition-Metal-Based Fluorous Catalysts", Corrêa da Costa, R. ; Gladysz, J. A. in Transition Metals for Organic Synthesis, 2nd ed, Beller, M.; Bolm, C. Eds.; Wiley/VCH, Weinheim, 2004, 527-543. DOI: 10.1002/9783527619405.ch6b. [Abstract]

 

317.     "Longitudinally Extended Molecular Wires based upon PtC≡CC≡CC≡CC≡C Repeat Units; Iterative Syntheses of Functionalized Linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt Assemblies", Zheng, Q.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5896-5899. DOI: 10.1021/om049353n. [Abstract][PDF]

316.     "Syntheses and Structures of Tetraplatinum bis(Polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains", Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893-5895. DOI: 10.1021/om049354f. [Abstract][PDF]

 

315.     "Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, In which the sp Carbon Chains are shielded by sp3 Carbon Chains", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889-5892. DOI: 10.1021/om0493558. [Abstract][PDF]

 

314.     "Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten- and Molybdenum-Catalyzed Syntheses of Novel Metallamacrocycles", Bauer, E. B.; Hampel, F.; Glaydsz, J. A. Adv. Synth. Catal. 2004, 346, 812-822. DOI: 10.1002/ adsc.200404026. [Abstract][PDF]

 

313.     "Convenient Syntheses of 'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Com­plexes with Three to Five Ponytails", Dinh, L. V.; Gladysz, J. A. Chem. Commun. 2004, 998-999. DOI: 10.1039/b401540a. [Abstract][PDF]

 

312. "Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Di­phosphine Ligands", Shima, T.; Bauer, E. B.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2004, 1012-1028. DOI: 10.1039/b400156g. [Abstract][PDF]

 

311.     "9H, 9H, 10H, 11H, 11H-Perfluoro-11-nonadecyl Iodide. Free Radical Chain Reactions of Fluorous Primary Alkyl Iodides", Wende, M.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 464-465. DOI: 10.1021/op050147g. [Abstract]

310.     "Partition Coefficients involving Fluorous Solvents", Gladysz, J. A.; Emnet, C.; Rábai, J. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 56-100. DOI: 10.1002/3527603905.ch6. [Abstract]

309.     "Ponytails: Structural and Electronic Considerations", Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Wein­heim, 2004, pp. 41-55. DOI: 10.1002/3527603905.ch5. [Abstract]

308.     "Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation", Gladysz, J. A.; Corrêa da Costa, R. C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 24-40. DOI: 10.1002/3527603905.ch4. [Abstract]

307.     "Fluorous Solvents and Related Media", Gladysz, J. A.; Emnet, C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 11-23. DOI: 10.1002/3527603905.ch3. [Abstract]

306.     "Fluorous Chemistry: Scope and Definition", Horváth, I. T.; Curran, D. P.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 1-4. DOI: 10.1002/3527603905.ch1. [Abstract]

 

305.     "Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Sub­stitution on the Efficiencies of Macrocyclizations that join trans Positions of Square-Planar Platinum Complexes", Bauer, E. B.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 5567-5580. DOI: 10.1021/om034121u. [Abstract][PDF]

304.     "Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties ("Split Pony Tails")", Wende, M.; Seidel, F.; Gladysz, J. A. J. Fluorine Chem. 2003, 124, 45-54. DOI: 10.1016/S0022-1139(03)00171-4. [Abstract][PDF]

303.     "Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres", Bauer, E. B.; Gladysz, J. A. in Handbook of Metathesis, Grubbs, R. H. Ed.; Wiley/VCH, New York, 2003, Vol 2, pp 403-431. DOI: 10.1002/9783527619481.ch26. [Abstract][PDF]

 

302.     "Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2003, 103, 4175-4205. DOI: 10.1021/cr030041o. [Abstract][PDF]

 

301.     "Tungsten-Catalyzed Alkyne Metatheses in Transition Metal Coordination Spheres: Versatile New Synthesis of Metallamacrocycles", Bauer, E. B.; Szafert, S.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 2184-2186. DOI: 10.1021/om030195u. [Abstract][PDF]

 

 

300.     "Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M']n+: Computational Analyses of the Effect of the Metal", Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; La­pinte, C. J. Am. Chem. Soc. 2003, 125, 9511-9522. DOI: 10.1021/ja034619n. [Abstract][PDF]

299. "Convenient and Convergent Syntheses of Long-Chain α,ω-Dibromides and Diphosphines of the Formula X(CH2)nX (n = 18-32)", Mohr, W.; Horn, C. R.; Stahl, J.; Gladysz, J. A. Synthesis 2003, 1279-1285. DOI: 10.1055/s-2003-39414. [Abstract][PDF]

298.     "Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A "Greener" Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation", Wende, M.; Gladysz, J. A. J. Am. Chem. Soc. 2003, 125, 5861-5872. DOI: 10.1021/ja029241s. [Abstract][PDF]

297. "Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear bis(1,3-Butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)­dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)]", Horn, C. R.; Gladysz, J. A. Eur. J. Inorg. Chem. 2003, 9, 2211-2218. (feature article). DOI: 10.1002/ejic.200300043. [Abstract][PDF]

 

296.     "Convenient Syntheses of Fluorous Phenols of the Formula HOC6H5-n((CH2)3(CF2)7CF3)n (n = 1,2) and the Corresponding Triarylphosphites", Le Stang, S.; Meier, R.; Rocaboy, C.; Gladysz, J. A. J. Fluorine Chem. 2003, 119, 141-149. DOI:10.1016/S0022-1139(02)00242-7. [Abstract][PDF]

 

295.     "Synthesis, Structure, and Reactivity of sp Carbon Chains with bis(phosphine) Pentafluorophenylplatinum Endgroups: Butadiynediyl (C4) through Hexadecaoctaynediyl (C16) Bridges, and Beyond", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324-3340. DOI: 10.1002/chem.200204741. [Abstract][PDF]

 

294.     "Thermomorphic Fluorous Imine and Thioether Palladacycles as Precursors for Highly Active Heck and Suzuki Catalysts; Evidence for Palladium Nanoparticle Pathways", Roca­boy, C.; Gladysz, J. A. New J. Chem. 2003, 27, 39-49. DOI: 10.1039/b208545n. [Abstract][PDF]

 

293. "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age", Delacroix, O.; Gladysz, J. A. Chem. Comm­un. 2003, 665-675 (feature article). DOI: 10.1002/chin.200325223. [Abstract][PDF]

 

292.     "Convenient Syntheses of Fluorous Aryl Iodides and Hypervalent Iodine Compounds: ArI­(L)n Reagents that are Recoverable by Simple Liquid/Liquid Biphase Workups, and Applications in Oxidations of Hydroquinones", Rocaboy, C.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 88-95. DOI: 10.1002/chem.200390034. [Abstract][PDF]

 

291.     "How do the Electronic Structures of Low-Symmetry Metal-Hydride and -Alkyl Complexes Compare? Photoelectron Spectroscopy and Computational Studies of (η5-C5R5)Re(NO)(L)R' [L = CO, P(C6H5)3; R, R' = H, CH3)]", Lichtenberger, D. L.; Gruhn, N. E.; Rai-Chaud­huri, A.; Renshaw, S. K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, I. Organometallics 2002, 21, 5494-5504. DOI: 10.1021/om020793t. [Abstract][PDF]

290.     "Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Sukuki Cross-Couplings", Giner Planas, J.; Gladysz, J. A. Inorg. Chem. 2002, 41, 6947-6949. DOI: 10.1021/ic020589y. [Abstract][PDF]

289.     "Facile and Selective Carbonylation of Methane in Superacids", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Adv. Synth. Catal. 2002, 344, 1059-1062. DOI: 10.1002/1615-4169(200212)344:10<1059::AID-ADSC1059>3.0.CO;2-O. [Abstract][PDF]

 

288.     "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η5-C5Me5)Re(NO)(PR3)(C≡CC≡C­C≡CC≡C)(R3P)(ON)Re(η5-C5Me5)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. DOI: 10.1021/om020676y. [Abstract][PDF]

287.     "Syntheses and Reactivities of Disubstituted and Trisubstituted Fluorous Pyridines with High Fluorous Phase Affinities: Solid State, Liquid Crystal, and Ionic Liquid Phase Proper­ties", Rocaboy, C.; Hampel, F.; Gladysz, J. A. J. Org. Chem. 2002, 67, 6863-6870. DOI: 10.1021/jo011173p. [Abstract][PDF]

 

286.     "Chelating Diphosphines that Contain a Rhenium Stereocenter in the Backbone: Applica­tions in Rhodium-Catalyzed Enantioselective Ketone Hydrosilylations and Alkene Hydro­genations", Kromm, K.; Osburn, P. L.; Gladysz, J. A. Organometallics 2002, 21, 4275-4280. DOI: 10.1021/om020432d. [Abstract][PDF]

285.     "A New Family of Chelating Diphosphines with Transition Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System", Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2002, 21, 4264-4274. DOI: 10.1021/om020431l. [Abstract][PDF]

284.     "Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Re­action; Evidence for a Palladium Nanoparticle Pathway", Rocaboy, C.; Gladysz, J. A. Org. Lett. 2002, 4, 1993-1996. DOI: 10.1021/ol025790r. [Abstract][PDF]

283.     "New Approaches to High-Activity Transition Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catal­yzed Suzuki Cross-Couplings", Eichenseher, S.; Kromm, K.; Delacroix, O.; Gladysz, J. A., Chem. Commun. 2002, 1046-1047. DOI: 10.1021/om0492956. [Abstract][PDF]

282.     (a) "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. DOI: 10.1021/ja0716103. [Abstract][PDF]

(b) "Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte mole­kulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957. DOI: 10.1002/1521-3757(20020603)114:11<1951::AID-ANGE1951>3.0.CO;2-Z. [Abstract][PDF]

281.     "Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Pre­cursors to Highly Active Catalysts for the Suzuki Coupling", Rocaboy, C.; Gladysz, J. A. Tetrahedron 2002, 58, 4007-4014. (invited article, fluorous chemistry thematic issue) DOI: 10.1016SO04020(02)00275-2. [Abstract][PDF]

280.     "Fluorous Chemistry: From Biphasic Catalysis to a Parallel Chemical Universe and Bey­ond", Gladysz, J. A.; Curran, D. P. Tetrahedron 2002, 58, 3823-3825. DOI: 10.1016SO040-4020(02)00222-3. [Abstract][PDF]

279.     "Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphos­phines that Contain a Rhenium Stereocenter in the Backbone", Kromm, K.; Hampel, F.; Gladysz, J. A. Helv. Chim. Acta 2002, 85, 1778-1789. DOI: 10.1002/1522-2675(200206)85:6. [Abstract][PDF]

278.     "New Perfluorocarbon System for Multilayer Growth of Anchorage Dependent Mammalian Cells", Rappaport, C.; Rensch, Y.; Abbasi, M.; Kempe, M.; Rocaboy, C. Gladysz, J. A.; Trujillo, E. M. BioTechniques 2002, 32, 142-151. ISSN: 0736-6205. [PDF]

277.     "How to Insulate a Reactive Site from a Perfluoroalkyl Group: Photoelectron Spectroscopy, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH2)m(CF2)7CF3)3", Jiao, H.; Le Stang, S.; Soós, T.; Meier, R.; Kowski, K.; Rademacher, P.; Jaf­arpour, L.; Hamard, J.-B.; Nolan, S. P.; Gladysz, J. A. J. Am. Chem. Soc. 2002, 124, 1516-1523. DOI: 10.1021/ja011877g. [Abstract][PDF]

276.     "An Unexpected Insertion of Acetone into the Silicon-Carbon Terminus of an sp Carbon Chain: Syntheses and Structures of Model Monoplatinum Hexatriynyl and Octatetraynyl Complexes", Mohr, W.; Peters, T. B.; Bohling, J. C.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Comptes Rendus Chemie 2002, 5, 111-118. (invited article, Gecom-Concoord thematic issue) DOI: 10.1016/S1631-0748(02)01351-6. [Abstract][PDF]

275.     "Vibrational Progressions in the Valence Ionizations of Transition Metal Hydrides: Evaluation of Metal-Hydride Bonding and Vibrations in (η5-C5R5)Re(NO)(CO)(H) [R = H, CH3]", Lichtenberger, D. L.; Gruhn, N.; Rai-Chaudhuri, A.; Renshaw, K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, A. J. Am. Chem. Soc. 2002, 124, 1417-1423. DOI: 10.1021/ja0120227. [Abstract][PDF]

274.     "Syntheses and Structures of Monoplatinum Model Complexes for Diplatinum Polyynediyl Adducts LnPt(C≡C)zPtLn", Peters, T. B.; Zheng, Q.; Stahl, J.; Bohling, J. C.; Arif, A. M.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2002, 641, 53-61. (invited article, interactions of π systems with metals thematic issue) DOI: 10.1016/ S0022-328X(01)01311-0. [Abstract][PDF]

273.     "Recoverable Catalysts: Ultimate Goals, Criteria of Evaluation, and the Green Chemistry In­terface", Gladysz, J. A. Pure Appl. Chem. 2001, 73, 1319-1324. (invited article, CHEMRAWN XIV thematic issue) DOI:10.1351/ pac200173081319. [Abstract][PDF]

272.     "Fluorous Catalysis Without Fluorous Solvents: A Friendlier Catalyst Recovery/Recycling Protocol Based upon Thermorphic Properties and Liquid/Solid Phase Separation", Wende, M.; Meier, R.; Gladysz, J. A. J. Am. Chem. Soc. 2001, 123, 11490-11491. DOI: 10.1021/ja011444d. [Abstract][PDF]

271.     "Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Con­struction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands", Ruwwe, J.; Martín-Alvarez, J. M.; Horn, C. R.; Bauer, E. B.; Szafert, S.; Lis, T.; Hampel, F.; Cagle, P. C.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 3931-3950. DOI: 10.1002/1521-3765(20010917)7:18. [Abstract][PDF]

270.     "Bent and Stretched but not yet to the Breaking Point: C8-C16 sp Carbon Chains the Span two Platinum Atoms, and the First Structurally Characterized 1,3,5,7,9,11,13,15-Octayne", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2001, 40, 3263-3264. DOI: 10.1021/ic010309z. [Abstract][PDF]

269.     "Structures and Energies of 10-Azatriquinacene and Its Hydrogenation Products: A Comput­ational Study", Jiao, H.; Halet, J.-F.; Gladysz, J. A. J. Org. Chem. 2001, 66, 3902-3905. DOI: 10.1021/jo001800v. [Abstract][PDF]

268.     "A New Family of Chiral Chelating Diamines with Transition Metal Stereocenters: Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted Diamine (η5-C5H5)Re(NO)(PPh3)(CH2N(CH3)CH2CH2(H3C)NCH2)(Ph3P)(ON)Re(η5-C5H5)", Alvey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; Lis, T.; Gladysz, J. A. Organometallics 2001, 20, 3087-3096. DOI: 10.1021/om010153a. [Abstract][PDF]

267.     "Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n = 6, 8, 10)", Soós, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. Organometallics 2001, 20, 3079-3086. DOI: 10.1021/om010193e. [Abstract][PDF]

266.     "Synthesis, Structure, and Interconversion of Chiral Rhenium Oxygen- and Sulfur-Bound Sulfoxide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(OS(Me)R)]+ X-; Diastereoselective Oxidations of Coordinated Methyl Alkyl Sulfides", Otto, M.; Boone, B. J.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 2001, 1218-1229. DOI: 10.1039/b009533h. [Abstract][PDF]

265.     "Metal-Metal Interactions Across Bridging Elemental Carbon Chains: A Computational Study of Odd-Carbon Complexes", Jiao, H.; Gladysz, J. A. New J. Chem. 2001, 25, 551-562. DOI: 10.1039/b008786f. [Abstract][PDF]

264.     "Synthesis and Oxidation of Dirhenium C4, C6, and C8 Complexes of the Formula (η5-C5Me5)Re(NO)(PR3)(C≡C)n(R3P)(ON)Re(η5-C5Me5) (R = 4-C6H4R', c-C6H11): In Search of Dications and Radical Cations with Enhanced Stabilities", Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115-1127. DOI: 10.1021/om000961m. [Abstract][PDF]

263.     "A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of 'Chiral-at-Rhenium' Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations", Kromm, K.; Zwick, B. D.; Meyer, O.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 2015-2027. DOI: 10.1002/1521-3765(20010504)7:9. [Abstract][PDF]

262.     "New Chiral Cyclopentadienyl Rhenium Lewis Acids Featuring Fluorinated Triaryl Phos­phines and Enhanced Acceptor Abilities - An Unusual Carbon-Fluorine Bond Activation in a Metal Coordination Sphere", Mohr, W.; Stark, G. A.; Jiao, H.; Gladysz, J. A. Eur. J. Inorg. Chem. 2001, 925-933. DOI:10.1002/1099-0682(200104)2001:4<925::AID-EJIC925>3.0.CO;2-N. [Abstract][PDF]

261.     "Surface Reactivity Studies of Bimetallic Complexes (η5-C5Me5)Re(NO)(PPh3)(C≡C)n(Ph3P)(ON)Re(η5-C5Me5) (n = 2, 4, 6): Candidates for Molecular Wires", Schennach, R.; Naugle, D. G.; Cocke, D.; Dembinski, R.; Gladysz, J. A. Vacuum 2000, 56, 115-121. DOI:10.1016/S0042-207X(99)00178-5. [Abstract][PDF]

260.     "Olefin Metatheses in Metal Coordination Spheres: Novel trans-Spanning Bidentate and Facially-Spanning Tridentate Macrocyclic Phosphine Complexes", Bauer, E. B.; Ruwwe, J.; Martín-Alvarez, J. M.; Peters, T. B.; Bohling, J. C.; Hampel, F. A.; Szafert, S.; Lis, T.; Gladysz, J. A. Chem. Commun. 2000, 2261-2262. DOI: 10.1039/b007405p. [Abstract][PDF]

259.     "Tails and Steeds versus Heads and Beads: The Case for Fluorous Phase Methodology in Combinatorial and Parallel Synthesis", Rocaboy, C.; Gladysz, J. A. Actualité Chimique 2000, 47-50 (September).

258.     "Synthesis, Crystal Structure, and Reactions of the Seventeen-Valence-Electron Rhenium Methyl Complex [(η5-C5Me5)Re(NO)(P(4-C6H4CH3)3)(CH3)]·+ (B(3,5-C6H3(CF3)2)4-: Experimental and Computational Bonding Comparisons with Eighteen-Electron Methyl and Methylidene Complexes", Le Bras, J.; Jiao, H.; Meyer, W. E.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 54-66. DOI: 10.1016/S0022-328X(00)00531-3- [Abstract][PDF]

257.    "Synthesis and Oxidation of Chiral Rhenium Phosphine Methyl Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(CH3): In Search of Radical Cations with Enhanced Kinetic Stabilities", Meyer, W. E.; Amoroso, A. J.; Jaeger, M.; Le Bras, J.; Wong W.-T.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 44-53. DOI: 10.1016/S0022-328X(00)00528-3. [Abstract][PDF]

256.     "Synthesis and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Tri­alkylphosphines: Precision Tuning of Electronic Properties, Including Insulation of the Per­fluoroalkyl Group", Alvey, L. J.; Meier, R.; Soós, T.; Bernatis, P.; Gladysz, J. A. Eur. J. Inorg. Chem. 2000, 1975-1983. DOI: 10.1002/1099-0682(200009)2000:9<1975::AID-EJIC1975>3.0.CO;2-M. [Abstract][PDF]

255.     "Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Second, and Tertiary Aliphatic Amines NH3-x((CH2)m(CF2)7CF3)x (m = 3-5; x = 1-3); Fine Tuning of Basicities and Fluorous Phase Affinities", Rocaboy, C.; Bauer, W.; Gladysz, J. A. Eur. J. Org. Chem. 2000, 2621-2628. DOI: 10.1002/1099-0690(200007)2000:14. [Abstract][PDF]

254.     "A 'Conjugal' Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C4 Species", Paul, F.; Meyer, W. E.; Toupet, L.; Jiao, H.; Gladysz, J. A.; Lapinte, C. J. Am. Chem. Soc. 2000, 122, 9405-9414. DOI: 10.1021/ja0011055. [Abstract][PDF]

253.     "Strategy and Design in Fluorous Phase Immobilization: A Systematic Study of the Effect of "Pony Tails" (CH2)3(CF2)n-1CF3 Upon the Partition Coefficients of Benzenoid Compounds", Rocaboy, C.; Rutherford, D.; Bennett, B. L.; Gladysz, J. A. J. Phys. Org. Chem. 2000, 13, 596-603. (invited article, organic reactivity (ESOR 7) thematic issue). DOI: 10.1002/1099-1395(200010)13. [Abstract][PDF]

252.     " Synthesis and Properties of Chiral Rhenium Pentatetraenylidene Complexes of the Formula [(η5-C5Me5)Re(NO)(PPh3)(=C=C=C=C=CAr2)]+BF4- (CAr2 = 9-fluorenylidene)", Szafert, S.; Haquette, P.; Falloon, S. B.; Gladysz, J. A. J. Organomet. Chem. 2000, 604, 52-58. DOI:10.1016/S0022-328X(00)00201-1. [Abstract][PDF]

251. "Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C6-C20 Polyynediyl Chains that Span Two Redox-Active (η5-C5Me5)Re(NO)(PPh3) Endgroups", Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810-822. DOI: 10.1021/ja992747z. [Abstract][PDF]

250.     "A New Route to Heterobimetallic C3 Complexes via C≡C Metatheses of 1,3-Diynyl Ligands: Synthesis and Structure of (η5-C5Me5)Re(NO)(PPh3)(C≡CC≡)W(O-t-Bu)3", Dembinski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438-5440. DOI: 10.1021/om990766b. [Abstract][PDF]

249.     "Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones", Dinh, L. V.; Gladysz, J. A. Tetrahedron Lett. 1999, 40, 8995-8998. DOI: 10.1016SO040-4039(99)01924-3. [Abstract][PDF]

248.     "Wire-Like sp Carbon Chains that Span Two Platinum Atoms: Synthesis and Crystal Structures of Building Blocks of the Formula trans-(p-tolyl)(Ph3P)2Pt(C≡C)nSiMe3", Bohling, J. C.; Peters, T. B.; Arif, A. M.; Hampel, F.; Gladysz, J. A., in Coordination Chemistry at the Turn of the Century; Ondrejoviç, G.; Sirota, A. Eds.; Slovak Technical University Press: Bratislava, Slovokia, 1999; pp. 47-52.

247.     "Synthesis, Properties, and Reactions of Enantiomerically Pure, Chiral Fluorous Phosphines of the Formula (menthyl)P(CH2CH2(CF2)n-1CF3)2 (n = 6, 8)", Klose, A.; Gladysz, J. A. Tetrahedron–Asymmetry 1999, 10, 2665-2674. DOI: 10.1016/SO957-4166(99)00272-4. [Abstract][PDF]

246.     "C8 and C12 sp Carbon Chains that Span Two Platinum Atoms; The First Structurally Characterized 1,3,5,7,9,11-hexayne", Peters, T. B.; Bohling, J. C.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 3261-3263. DOI: 10.1021/om990448c. [Abstract][PDF]

245.     "Chemistry in Fluorous Media: A User's Guide to Practical Considerations in the Applica­tion of Fluorous Catalysts and Reagents", Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587-605. (invited article, 33rd ICCC thematic issue) DOI: 10.1016/S0010-8545(99)00102-2. [Abstract][PDF]

244.     "Appreciably Bent sp Carbon Chains: Synthesis, Structure, and Protonation of Organometallic 1,3,5-Triynes and 1,3,5,7-Tetraynes of the Formula (η5-C5Me5)Re(NO)(PPh3)((C≡C)n-p-C6H4Me)", Dembinski, R.; Lis, T.; Szafert, S.; Mayne, C. L.; Bartik, T.; Gladysz, J. A. J. Organomet. Chem. 1999, 578, 229-246. DOI:10.1016/S0022-328X(98)01128-0. [Abstract][PDF]

243.     "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobiliza­tion Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes", Juliette, J. J. J.; Rutherford, D.; Horváth, I. T.; Gladysz, J. A. J. Am. Chem. Soc. 1999, 121, 2696-2704. DOI: 10.1021/ja982955b. [Abstract][PDF]

242.     "Olefin Metatheses in Metal Coordination Spehres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds", Martin-Alvarez, J. M.; Hampel, F.; Arif, A. M.; Glad­ysz, J. A. Organometallics 1999, 18, 955-957. DOI: 10.1021/om9808920. [Abstract][PDF]

241.     "Additions of PH3 to Monosubstituted Alkenes of the Formula H2C=CH(CH2)x(CF2)yCF3; Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkyl Phosphines with Modulated Electronic Properties and Fluorous Phase Affinities", Alvey, L. J.; Rutherford, D.; Juliette, J. J. J.; Gladysz, J. A., J. Org. Chem. 1998, 63, 6302-6308. DOI: 10.1021/jo980692y. [Abstract][PDF]

240.     "New Forms of Coordinated Carbon: Wire-Like Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer", Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071-11081. DOI: 10.1021/ja981927q. [Abstract][PDF]

239.     "Transition Metal Catalysis in Fluorous Media: Application of a New Immobilization Principle to Rhodium Catalyzed Hydrogenation of Alkenes", Rutherford, D.; Juliette, J. J. J.; Rocaboy, C.; Horváth, I. T.; Gladysz, J. A. Catalysis Today 1998, 42, 381-388. (invited article, phase separable homogeneous catalysis thematic issue) DOI: 10.1016/S0920-5861(98)00120-5. [Abstract][PDF]

238.     "Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries more Distorted than Planar Tetracoordinate", Falloon, S. B.; Szafert, S.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1998, 4, 1033-1042. DOI:10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P. [Abstract][PDF]

237.     "Organometallic Reactivity Patterns in Fluorocarbons, and Implications for Catalysis; Synthesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2", Guillevic, M.-A.; Rocaboy, C.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Organometallics 1998, 17, 707-717. DOI: 10.1021/om9710834. [Abstract][PDF]

236.     "Additions of Carbon Nucleophiles to Acyclic Imine Complexes of the Chiral Rhenium Le­wis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Controlling Factors in 1,3-Asymmetric Induction and Syntheses of Non-Racemic Organic Amines", Stark, G. A.; Gladysz, J. A. Inorg. Chim. Acta 1998, 269, 167-180. (invited article, issue in honor of Wolfgang Beck) DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]

235.     "Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η5-C5H5)Re(NO)(PPh3)]+: Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6", Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 6032-6034. DOI: 10.1021/om970792e. [Abstract][PDF]

234.     "Synthesis and Crystallographic Characterization of the 'Sometimes-Chiral' Dirhenium Polyoxotungstate Salt {(η5-C5H5)Re(NO)(PPh3)(CO)]+}2[W6O19]2-, Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1997, 134, 793-799. ISSN: 0037-8968.

233.     "Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η5-C5R5)Re(NO)(PPh3)CN(Ph3P)(ON)Re(η5-C5R5)]+TfO- (R, R' = H, Me)", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2909-2918. DOI: 10.1021/om970167+. [Abstract][PDF]

232.     "Synthesis and Crystal Structure of the Conjugated Tetrayne (η5-C5H5)Re(NO)(PPh3)(C≡CC≡CC≡CC≡CSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp Carbon Wires", Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. New J. Chem. 1997, 21, 739-750. (invited article, 13th summer school in coordination chemistry thematic issue)

231.     (a) "Synthesis, Structure, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2; Altered Reactivity in Fluorocarbons, and Implications for Catalysis", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612-1615. DOI: 10.1002/anie.199716121. [Abstract][PDF]

            (b) "Synthese, Struktur, und oxidative Additionen eines fluorhaltigen Analogons des Vaska-Komplexes, trans-[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2] – Reaktivitätsänderung in Fluor­kohlenwasserstoffen und Auswirkungen auf die Katalyse", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1685-1687. DOI: 10.1002/ange.19971091510. [Abstract][PDF]

230.     (a) "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroboration", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1610-1612. DOI: 10.1002/anie.19971091509. [Abstract][PDF]

            (b) "Übergangsmetallkatalyse in fluorhaltigen Medien: Anwendung eines neuen Immobil­isierungsprinzips auf die Rh-katalysierte Hydroborieirung", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1682-1684. DOI: 10.1002/ange.19971091509. [Abstract][PDF]

229.     "Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C≡CC(OMe)=)Mm(CO)n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in which a C3 Chain Links two Metals and Spans a Third", Falloon, S. B.; Weng, W.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2008-2015. DOI: 10.1021/om970055i. [Abstract][PDF]

228.     "Spectroscopic Observation of the Formyl Cation in a Condensed Phase", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Science 1997, 276. 776-779. DOI: 10.1126/science.276.5313.776. [Abstract][PDF]

227.     (a) "Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities", Gladysz, J. A.; Boone, B. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 551-583. DOI: 10.1002/anie.199705501. [Abstract][PDF]

            (b) "Chirale Erkennung in π-Komplexen von Alkenen, Aldehyden und Ketonen mit Über­gangsmetall-Lewis-Säuren; Entwicklung eines allgemeinen Modells für enantiofacialle Komplexierungsselektivitäten", Gladysz, J. A.; Boone, B. J. Angew. Chem. 1997, 109, 566-602. DOI: 10.1002/ange.19971090604. [Abstract][PDF]

226.     "Methods for Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Carbon Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)10(H)", Falloon, S. B.; Arif, A. M.; Gladysz, J. A. Chem. Commun. 1997, 629-630. DOI: 10.1039/a607884b. [Abstract][PDF]

225.     "Consanguineous Families of Coordinated Carbon: A ReC4Re Assembly that is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC≡CC≡CRe and +Re=C=C=C=C=Re+ Adducts and a Radical Cation in which Charge is Delocalized Be­tween Rhenium Termini", Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, A. J.; Arif, A. M.; Böhme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788. DOI: 10.1021/ja9631817. [Abstract][PDF]

224.     "Configurational Equilibria in Amido and Lithioamido Complexes of Formulas (η5-C5H5)Re(NO)(PAr3)(NHCHRR') and (η5-C5H5)Re(NO)(PAr3)(NLiR"): Epimerization Occurs at Rhenium via Phosphine Dissociation", Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organo­metallics 1996, 15, 4798-4807. DOI: 10.1021/om960662q. [Abstract][PDF]

223.     "Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids: Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements to Give Thiolate Complexes with New Carbon Stereocenters", Bell, P. T.; Cagle, P. C.; Vichard, D.; Gladysz, J. A. Organometallics 1996, 15, 4695-4701. DOI: 10.1021/om960541q. [Abstract][PDF]

222.     "A Search for π/σ Equilibria in Chiral Rhenium Imine Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(N(H)=C(CF3)X)]+ TfO-; Investigation of Electronic Effects Upon the Binding Mode", Stark, G. A.; Gladysz, J. A. Inorg. Chem. < 1996, 35, 5509-5513. DOI: 10.1021/ic960302v. [Abstract][PDF]

221.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrange­ments of Ylides Derived from Di(allyl), Di(propargyl), and Di(benzyl) Sulfide Complexes; Control of Carbon Configuration by an Easily Resolved and Recycled Rhenium Auxiliary", Meyer, O.; Cagle, P. C.; Weickhardt, K.; Vichard, D.; Gladysz, J. A. Pure Appl. Chemistry 1996, 68, 79-88. (invited article, 8th OMCOS symposium thematic issue) DOI: 10.1351/pac199668010079. [Abstract][PDF]

220.     "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Seyler, J. W.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118, 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]

219.     (a) "A Step-Growth Approach to Metal-Capped One-Dimensional Carbon Allotropes; Syntheses of C12, C16, and C20 μ-Polyynendiyl Complexes", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 414-417. DOI: 10.1002/anie.19961080415. [Abstract][PDF]

            (b) "Schrittweises Kettenwachstum eindimensionaler Kohlenstoffallotrope mit terminalen Metallgruppen; Synthese von C12-, C16-, und C20-μ-Polyindiylkomplexen", Bartik, T.; Bart­ik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem. 1996, 108, 467-469. DOI: 10.1002/ange.19961080415. [Abstract][PDF]

218.     "Reactions of t-BuOK and Di(Benzyl), Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Highly Diastereoselective or Chemoselective [2,3] Sigmatropic Rearrangements", Cagle, P. C.; Meyer, O.; Vichard, D.; Weickhardt, K; Arif, A. M.; Gladysz, J. A. Organometallics 1996, 15, 194-204. DOI: 10.1021/om950701i. [Abstract][PDF]

217.     "Synthesis, Structure and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M' and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (η5-C5Me5)Re(NO)(PPh3)(C≡CLi) and (η5-C5Me5)Re(NO)(PPh3)(C≡CC≡CLi)", Weng, W.; Bartik, T. ; Brady, M.; Bartik, B.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11922-11931. DOI: 10.1021/ja953523t. [Abstract][PDF]

216.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Rearrangements of Yl­ides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Con­figuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Meyer, O.; Weickhardt, K.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11730-11744. DOI: 10.1021/ja00152a014. [Abstract][PDF]

215.     "Crystal Structures of Diastereomeric Styrene Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+; Effect of Ligating Enantioface upon Bonding and Conformation", Sanau, M.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1995, 503, 235-241. DOI: 10.1016/0022-328X(95)05565-7. [Abstract][PDF]

214.     "Synthesis, Structure, and Reactivity of Chiral Rhenium N-Pyrrolyl Complexes [(η5-C5H5)Re(NO)(PPh3)(NCR=CR'CH=CH)]; Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon-Ligated Species", Johnson, T. J.; Alvey, L. J.; Brady, M.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1995, 1, 294-302. DOI: 10.1002/chem.19950010506. [Abstract][PDF]

213.     "Nucleophilic Additions to the Chiral Rhenium Alkene Complexes [Re(η5-C5H5)(NO)(PPh3)(H2C=CHR)]BF4 (R = H, Me, CH2CH2Me, Ph or CH2Ph): Regio-, Diastereo-, and Enantioselectivities", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1995, 1857-1865. DOI: 10.1039/DT9950001857. [Abstract][PDF]

212.     "Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline and Quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary; Enantioselective Syntheses of Alkyl, Dialkyl, and Trialkyl Hydroisoquinoline Derivatives", Stark, G. A.; Dewey, M. A.; Richter-Addo, G. B.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. in Stereoselective Reactions of Metal-Activated Molecules; Werner, H.; Sundermeyer, J. Eds.; Vieweg-Verlag: Braunschweig, Germany, 1995; pp. 51-71. ISBN: 3-528-06664-4, 9783528066642.

211.     "A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprot­onation of a Chiral Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon", Meyer, O.; Arif, A. M.; Gladysz, J. A. Org­anometallics 1995, 14, 1844-1849. DOI: 10.1021/om00004a043. [Abstract][PDF]

210.     "Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+; Enantioselective Syntheses of 3-Substituted Cycloalkanones", Wang, Y.; Gladysz, J. A. J. Org. Chem. 1995, 60, 903-909. DOI: 10.1021/jo00109a022. [Abstract][PDF]

209.     "Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(=CHR)]+ PF6-; A Versatile and Highly Stereoselective Route to Alkene Complexes", Wang, Y.; Gladysz, J. A. Chem. Ber. 1995, 128, 213-220. DOI: 10.1002/cber.19951280303. [Abstract][PDF]

208.     "A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of Chiral Cationic Rhenium Alkene Complexes [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Gladysz, J. A. Organometallics 1995, 14, 898-911. DOI: 10.1021/om00002a041. [Abstract][PDF]

207.     "Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula ((η5-C5Me5)Re(NO)(PPh3)(C≡CX); Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C4H3 and C4H4 Species", Weng, W.; Bartik, T.; Johnson, M. T.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 889-897. DOI: 10.1021/om00002a041. [Abstract][PDF]

206.     "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]

205.     "Are Teflon Ponytails the Coming Fashion for Catalysts?", Gladysz, J. A. Science 1994, 266, 55-56. DOI: 10.1126/science.266.5182.55. [Abstract][PDF]

204.     "Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 4523-4530. DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]

203.     "New Families of Coordinated Carbon: Oxidative Coupling and Cross-coupling of a Transition Metal Butadiynyl Complex to Bimetallic M-C≡CC≡CC≡CC≡C-M and M-C≡CC≡CC≡C-M Adducts", M. Brady; W. Weng; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 2655-2656. DOI: 10.1021/ja9631817. [Abstract][PDF]

202.     "Synthesis, Structure and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+; Diastereoselective Electrophilic Additions", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 3182-3193. DOI: 10.1021/om00020a035. [Abstract][PDF]

201.     "Syntheses of Cyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ by Hydride Ion Abstraction from Amido Complexes", Cantrell, W. R. Jr.; Richter-Addo, G. B.; Gladysz, J. A. J. Organomet. Chem. 1994, 472, 195-204. DOI: 10.1016/0022-328X(94)80206-8. [Abstract][PDF]

200.     (a) "Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumu­lenic C5 Chain that Mediates Charge Transfer Between Rhenium and Manganese Termini", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1994, 33, 2199-2202. DOI: 10.1002/anie.199421991. [Abstract][PDF]

            (b) "Auf dem Weg zur Verknüpfung einzelner Metalle durch "eindimensionale Kohlenstoff­drähte": Ladungstransfer zwischen terminalen Rhenium- und Manganzentren über ein C5-Cumulen", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem. 1994, 106, 2269-2272. DOI: 10.1002/ange.19941062112. [Abstract][PDF]

 

199.     "Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+", Wang, Y.; Arif, A. M.; Gladysz, J. A. Organ­ometallics 1994, 13, 2164-2169. DOI: 10.1021/om00018a008. [Abstract][PDF]

198.     "Generation and Reactivity of Substitution-Labile Dichloromethane and Chlorobenzene Adducts of the Chiral Pentamethylcyclopentadienyl Rhenium Lewis Acid [(η5-C5Me5)Re(NO)(PPh3)]+", Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534-2542. DOI: 10.1021/ic00090a011. [Abstract][PDF]

197.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3]-Sigmatropic Rearrange­ments of Ylides of Di(allyl) and Di(propargyl) Sulfonium Salts. Control of Carbon Config­uration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1994, 116, 3655-3656. DOI: 10.1021/ja00087a084. [Abstract][PDF]

196.     "Syntheses and Structures of Unsymmetrically 1,1-and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+: Enantioface Binding Selectivities and Conformational Equilibria", Peng, T.-S.; Pu, J.; Gladysz, J. A. Organometallics 1994, 13, 929-940. DOI: 10.1021/om00015a029. [Abstract][PDF]

195.     "Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(GeMe2X); Equilibria Involving the Dimethylgermylene Complex [(η5-C5H5)Re(NO)(PPh3)(=GeMe2)]+ TfO-", Lee, K. E.; Gladysz, J. A. Phosphorus, Sulfur, Silicon, and the Related Elements 1994, 87, 113-123. DOI: 10.1080/10426509408037445. [Abstract]

194.     "New Strategies for Enantioselective Syntheses of 1-Alkyl and 1,4-Dialkyl 1,2,3,4-Tetrahy­droisoquinolines: Diastereoselective Additions of Nucleophiles and Electrophiles to Iso­quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Richter-Addo, G. B.; Knight, A. D.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 11863-11873. DOI: 10.1021/ja00078a026. [Abstract][PDF]

193.     "Pyrrolyl-N and Pyrrolyl-C Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+: Synthesis, Protonation, and Rearrangement Chemistry", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4728-4730. DOI: 10.1021/om00036a006. [Abstract][PDF]

192.     "Synthesis, Structure, and Reactivity of η2-1,3-Diene and Enyne Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+; Ozonolysis Within a Metal Coordination Sphere", Peng, T.-S.; Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4535-4544. DOI: 10.1021/om00035a044. [Abstract][PDF]

191.     "Synthesis, Structure and Reactivity of Chiral Rhenium Imine and Methyleneamido Complexes of the Formulas [(η5-C5H5)Re(NO)(PPh3)(η1-N(R")=C(R)R')]+ TfO- and (η5-C5H5)Re(NO)(PPh3)N=C(R)R')", Knight, D. A.; Dewey, M. A.; Stark, G. A.; Bennett, B. K.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4523-4534. DOI: 10.1021/om00035a043. [Abstract][PDF]

190.     "Reactions of Rhenium Cyclopentadienyl and Indenyl Dichloromethane Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+ BF4- with Ketones; Substitution Rates and Mechanism", Dewey, M. A.; Zhou, Y.; Liu, Y.; Gladysz, J. A. Organometallics 1993, 12, 3924-3932. DOI: 10.1021/om00034a027. [Abstract][PDF]

189.     "Synthesis and Reactivity of Chiral Rhenium Indenyl Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(X)]n+", Zhou, Y.; Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 3918-3923. DOI: 10.1021/om00034a026. [Abstract][PDF]

188.     "An Isolable Organometallic Cation Radical in which a C4 Chain Conducts Charge Between Two Chiral and Configurationally Stable Rhenium Termini", Seyler, J. W.; Weng, W.; Zhou, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 3802-3804. DOI: 10.1021/om00034a008. [Abstract][PDF]

187.     "New Families of Coordinated Carbon: Oxidative Coupling of an Ethynyl Complex to Isolable and Crystallographically Characterized MC≡CC≡CM and M=C=C=C=C=M Assemblies", Zhou, Y.; Seyler, J. W.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 8509-8510. DOI: 10.1021/ja00071a095. [Abstract][PDF]

186.     "Synthesis and Structure of Complexes of α,β-Unsaturated Carbonyl Compounds and the Chiral Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+; Divergent Kinetic and Thermodynamic C=O/C=C and C=O/C-C Binding Selectivities", Wang, Y.; Agbossou, F.; Dalton, D. M.; Liu, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2699-2713. DOI: 10.1021/om00031a045. [Abstract][PDF]

185.     "Synthesis, structure, and dynamic behavior of symmetrical cis- and trans- alkene complexes of the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+: binding selectivities and isomerization processes", Pu, J.; Peng, T.-S.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2686-2698. DOI: 10.1021/om00031a044. [Abstract][PDF]

184.     "Optical Rotation Measurements of Organometallic Compounds: Caveats and Recommend­ed Procedures", Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 2390-2392. DOI: 10.1021/om00030a061. [Abstract][PDF]

183.     (a) "A New Form of Coordinated Carbon: A C3 Chain That is Anchored by a Transition Metal on Each End and Spanned by a Third", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 891-892. DOI: 10.1002/anie.199308911. [Abstract][PDF]

(b) "Ein neuer Kohlenstoffligand; eine durch ein Re-Atom überdachte Re-C3Re-Kette", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1993, 105, 937-938. DOI: 10.1002/ange.19931050632. [Abstract][PDF]

182.     "A New Form of Coordinated Carbon: An Unsupported C3 Chain Spanning Two Different Transition Metals", Weng, W.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 3824-3825. DOI: 10.1021/ja00062a078. [Abstract][PDF]

181.     "Synthesis and Reactivity of Bimetallic Bridging Haloalkyl Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)X(CH2)xM(CO)5]+BF4- (X = I, Br, Cl; M = Re, Mn; x = 1,4)", Zhou, Y.; Gladysz, J. A. Organometallics 1993, 12, 1073-1078. DOI: 10.1021/om00028a023. [Abstract][PDF]

180.     "Synthesis, Structure, and Spectroscopic Properties of Chiral Rhenium Aromatic Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(O=CHAr)]+X-: Equilibria between π and σ Aldehyde Bonding Modes", Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 2323-2334. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]

179.     "Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+", Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1993, 450, 157-164. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]

178.     "Reactions of Rhenium Halide Complexes (η5-C5H5)Re(NO)(PPh3)(X) and Organocopper Nucleophiles; New Routes to Racemic and Optically Active Hydrocarbyl Complexes (η5-C5H5)Re(NO)(PPh3)(R)", Ramsden, J. A.; Peng, T.-S.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1992, 129, 625-631. ISSN:0037-8968.

177.     "Deprotonation of Rhenium Terminal Acetylide Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(C≡CH): Generation and Reactivity of Rhenium/Lithium C2 Complexes", Ramsden, J. A.; Weng, W.; Gladysz, J. A. Organometallics 1992, 11, 3635-3645. DOI: 10.1021/om00059a029. [Abstract][PDF]

176.     "Activation of Organic Carbonyl Compounds by Lewis Acids: Relative Reactivities of σ and π Adducts towards Nucleophiles, and Implications for Enantioselective Addition Reac­tions", Klein, D. P.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 8710-8711. DOI: 10.1021/ja00048a060. [Abstract][PDF]

175.     "Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+", Roger, C.; Peng, T.-S.; Gladysz, J. A. J. Organomet. Chem. 1992, 439, 163-175. DOI: 10.1016/0022-328X(92)80227-O. [Abstract][PDF]

174.     "Synthesis, Structure, and Reactivity of Allene Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+", Pu, J.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organomet­allics 1992, 11, 3232-3241. DOI: 10.1021/om00046a020. [Abstract][PDF]

173.     "Synthesis and Structure of σ-Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1992, 47, 1175-1184. ISSN: 0932-0776. [PDF]

172.     "A Versatile New Route to Carbon Complexes of the Formula LnMC≡CM'L'n': Deprotonation and Metalation of the Terminal Acetylide Complex (η5-C5Me5)Re(NO)(PPh3)(C≡CH)", Ramsden, J. A.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 5890-5891. DOI: 10.1021/ja00040a079. [Abstract][PDF]

 

171.     "Synthesis, Structure, Dynamic Behavior, and Reactivity of Chiral Rhenium Primary Phos­phine and Phosphido Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(PRH2)]+ X- and ((η5-C5H5)Re(NO)(PPh3)(PRH)", Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673-2685. DOI: 10.1021/om00043a061. [Abstract][PDF]

170.     "Cyclopentadienyl Rhenium Complexes", Agbossou, F.; O'Connor, E. J.; Garner, C. M.; Quirós Méndez, N.; Fernández, J. M.; Patton, A. T.; Ramsden, J. A.; Gladysz, J. A. Inorg. Synth. 1992, 29, 211-225. DOI: 10.1016/j.organchem.2007.11.024. [Abstract][PDF]

 

169.     "Mechanism of Equilibration of Diastereomeric Chiral Rhenium Alkene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+BF4. the Metal Traverses between Alkene Enantiofaces without Dissociation", Peng, T.-S.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 4174-4181. DOI: 10.1021/ja00037a020. [Abstract][PDF]

168.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(NRR')", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824. DOI: 10.1002/cber.19921250410. [Abstract][PDF]

167.     "Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition Metal Lewis Acid; Equilibration of Diastereomeric (Cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Helv. Chim. Acta 1992, 75, 442-456. DOI: 10.1002/hlca.19920750204. [Abstract][PDF]

 

166.     "Synthesis and Reactivity of Chiral Metal Fluoride and Water Complexes Derived from the Rhenium Fragment [(η5-C5H5)Re(NO)(PPh3)]+", Agbossou, S. K.; Roger, C.; Igau, A.; Gladysz, J. A. Inorg. Chem. 1992, 31, 419-424. DOI: 10.1016/S0277-5387(00)860544. [Abstract][PDF]

165.     "Epimerization of Secondary Alcohols by New Homogeneous, Low Oxidation State Metal Catalysts: Carbon-Hydrogen Bond Activation in Rhenium Alkoxide Complexes (η5-C5H5)Re(NO)(PPh3)(OCHRR')", Saura-Llamas, I.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 2136-2144. DOI: 10.1021/ja00032a030. [Abstract][PDF]

164.     "Synthesis, Structure, and Reactivity of (Pentamethylcyclopentadienyl)Rhenium Aldehyde Complexes [(η5-C5Me5)Re(NO)(PPh3)(η2-O=CHR)]+BF4-: Highly Diastereoselective Deuteride Additions", Agbossou, F.; Ramsden, J. A.; Huang, Y.-H.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 693-701. DOI: 10.1021/om00038a029. [Abstract][PDF]

163.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Carboxylic and Carbonic Acid Ester Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(η1-O=C(X)X')]+X''-", Saura-Llamas, I.; Dalton, D. M.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 683-693. DOI: 10.1021/om00038a028. [Abstract][PDF]

162.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Amine Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(NRR'R")]+TfO-", Dewey, M. A.; Knight, D. A.; Klein, D. P.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1991, 30, 4995-5002. DOI: 10.1021/ic00026a026. [Abstract][PDF]

161.     "Synthesis and Chemistry of Secondary Alkyl Iodide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(ICHRR')]+BF4-", Igau, A.; Gladysz, J. A. Polyhedron 1991, 10, 1903-1909. DOI: 10.1016/S0277-2387(00)86054-4. [Abstract][PDF]

160.     "A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives: Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(O=CRR')]+BF4-", Dalton, D. M.; Garner, C. M.; Fernández, J. M.; Gladysz, J. A. J. Org. Chem. 1991, 56, 6823-6829. DOI: 10.1021/jo00024a023. [Abstract][PDF]

159.     "Mechanism of Isomerization of Alkylidene Complexes [(η5-C5H5)Re(NO)(PPh3)(=CH­CHR'R'')]+X- to Alkene Complexes [(η5-C5H5)Re(NO)(PPh3)(H2C=CR'R'')]+X-: An Organometallic Wagner-Meerwein-Type Rearrangement", Roger, C.; Bodner, G. S.; Hatton, W. G.; Gladysz, J. A. Organometallics 1991, 10, 3266-3274. DOI: 10.1021/om00055a051. [Abstract][PDF]

158.     "Synthesis and Characterization of Chiral Rhenium σ-Ketone Complexes. Binding Properties of Symmetrical Ketones and Alkylcyclohexanones", Dalton, D. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1991, 2741-2747. ISSN 0300-9246. [Abstract][PDF]

157.     "A New Catalyst for the Epimerization of Secondary Alcohols: Carbon-Hydrogen Bond Activation in the Rhenium Alkoxide Complexes (η5-C5H5)Re(NO)(PPh3)(OCHRR')", Saura-Llamas, I.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 2533-2535. DOI: 10.1021/om00054a003. [Abstract][PDF]

156.     "Reactions of the Terminal Rhenium Acetylide Complex Re(η5-C5H5)(NO)(PPh3)(C≡CH) and Butyllithium; Generation, Alkylation, and Stannylation of Lithiocarbide Complexes of the Formula Re(η5-C5H5)(NO)(PPh3)(C≡CLi) (X = H, Li)", Ramsden, J. A.; Agbossou, F.; Senn, D. R.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 1360-1362. ISSN 0022-4936. [Abstract][PDF]

155.    "Reactions of the Neohexyl Iodide Complex [(η5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and Nucleophiles: Stereochemistry of Carbon-Iodine Bond Cleavage in Highly Accelerated SN2 Reactions", Igau, A.; Gladysz, J. A. Organometallics 1991, 10, 2327-2334. DOI: 10.1021/om00053a040. [Abstract][PDF]

154.     "Synthesis, Structure, and Dynamic Behavior of Rhenium Sulfide and Sulfoxide Complexes of the Formula [(η5-C5H5)Re(NO)(L)(XRR')]+ X'- (X = S, SO)", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 2199-2209. DOI: 10.1021/om00053a024. [Abstract][PDF]

153.     "π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(O=CRR')]+X-; a marked electronic effect upon the binding mode", Klein, D. P.; Dalton, D. M.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1991, 412, C7-C10. DOI:10.1016/0022-328X(91)86066-Y. [Abstract][PDF]

152.     "Facile Separations of Enantiomers of Chiral Organometallic Compounds with A Baker­bond Chiralcel HPLC Column", Ramsden, J. A.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 1631-1633. DOI: 10.1021/om00051a066. [Abstract][PDF]

151.     "Synthesis and Structure of the Rhenium Phenylamido Complex (η5-C5H5)Re(NO)(PPh3)(NHPh); An Unprecedented Pyramidal Amido Ligand", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 712-714. DOI: 10.1039/C399¬10000712. [Abstract][PDF]

150.     "Delocalized Electronic Interactions in Chiral Cyclopentadienyl Rhenium Halide Complexes. The Valence Photoelectron Spectra of the Formula CpRe(NO)(L)X", Lichten­berger, D. L.; Rai-Chaudhuri, A. R.; Seidel, M. J.; Gladysz, J. A.; Agbossou, S. K.; Igau, A.; Winter, C. H. Organometallics 1991, 10, 1355-1364. DOI: 10.1021/om00051a028. [Abstract][PDF]

149.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(CH=CH(CH2)n-2)]+ BF4-; Facile Vinylic Deprotonation of a Coordinated Alkene", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 729-742. DOI: 10.1002/cber.19911240410. [Abstract][PDF]

148.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkyne Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(RC≡CR')]+ BF4-", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079-1088. DOI: 10.1021/om00050a045. [Abstract][PDF]

147.     "Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(SiMe2X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base-Free Silylene Complexes", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 309-320 (1991). ISSN 0009-2940. [Abstract][PDF]

146.     "Synthesis, Structure, and Reactivity of Functionalized Germyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(GePh2X); Equilibria Involving the Germylene Complex [(η5-C5H5)Re(NO)(PPh3)(=GePh2)]+ TfO-", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 751-760. DOI: 10.1021/om00049a040. [Abstract][PDF]

145.     (a) "Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(η2-O=CHAr)]BF4", Quirós Méndez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1475-1476. DOI: 10.1002/anie.199014751. [Abstract][PDF]

            (b) "Thermodynamisch kontrollierte enantiofaciale Selektivität bei der Bindung von Aldehyden an chirale Metall-Komplexfragmente, der Mechanismus der Interkonversion diastereomerer π-Aldehyd-Komplexe [(η5-C5H5)Re(NO)(PPh3)(η2-O=CHAr)]BF4", Quirós Mén­dez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem. 1990, 102, 1509-1511. DOI: 10.1002/ange.19901021246. [Abstract][PDF]

 

144.     (a) "π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Aromatic Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(O=CHAr)]+ X-", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1473-1474. DOI: 10.1002/anie.199014731. [Abstract][PDF]

            (b) "π/σ-Gleichgewichte in Metall-Komplexen organischer Carbonylverbindungen; Synthese und Struktur chiraler Rhenium-Komplexe [(η5-C5H5)Re(NO)(PPh3)(O=CHAr)]X", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1990, 102, 1507-1509. DOI: 10.1002/ange.19901021245. [Abstract][PDF]

143.          "Selective Activation of One Methyl Ketone Enantioface via σ-Binding to a Chiral Transition Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes [(η5-C5H5)Re(NO)(PPh3)(η1-O=C(CH3)R]+ X-", Dalton, D. M.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 9198-9212. DOI: 10.1021/ja00181a024. [Abstract][PDF]

142.     "A New Carbon-Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ BF4- by the Base t-BuO- K+", Peng, T.-S.; Gladysz, J. A. Organometallics 1990, 9, 2884-2886. DOI: 10.1021/om00161a016. [Abstract][PDF]

141.     "Generation and Reactivity of the Chiral Rhenium Chlorobenzene Complex [(η5-C5H5)Re(NO)(PPh3)(ClC6H5)]+ BF4-: An Improved Functional Equivalent of the Chiral Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ BF4-", Kowalczyk, J. J.; Agbossou, S. K.; Gladysz, J. A. J. Organomet. Chem. 1990, 397, 333-346. DOI: 10.1016/0022-328X(90)85333-T. [Abstract][PDF]

140.     "Reactions of Cyanomethyl Complex (η5-C5H5)Re(NO)(PPh3)(CH2CN) and Ylide Complex [(η5-C5H5)Re(NO)(PPh3)(CH2P(p-tol)3)]+ PF6- with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of Transition-Metal-Substituted Carbanions and Ylides", Crocco, G. L.; Lee, K. E.; Gladysz, J. A. Organometallics 1990, 9, 2819-2831. DOI: 10.1021/om00160a034. [Abstract][PDF]

139.     "Synthesis, Structure, and Reactivity of the Nitrosyl Ligand/Lewis Acid Adduct (η5-C5H5)Re(NO·BCl3)(PPh3)(SiMe2Cl)", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 2885-2887. DOI: 10.1021/ic00341a005. [Abstract][PDF]

138.     "Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions to Chiral Mo­nosubstituted Alkene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Gladysz, J. A. Tetrahedron Lett. 1990, 31, 4417-4420. DOI: 10.1016/SO040-4039(00)97636-6. [Abstract][PDF]

137.     "Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(ROH)]+ BF4-", Agbossou, S. K.; Smith, W. W.; Gladysz, J. A. Chem. Ber. 1990, 123, 1293-1299. DOI: 10.1002/cber.19901230612. [Abstract][PDF]

136.     "Selective Binding of One Aldehyde Enantioface by a Chiral Transition Metal Lewis Acid: Synthesis, Structure and Reactivity of Rhenium Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(η2-O=CHR)]+ X-", Garner, C. M.; Quirós Méndez, N.; Kowalczyk, J. J.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 5146-5160. DOI: 10.1021/ja00169a024. [Abstract][PDF]

135.     "Mechanism of Equilibration of Diastereomeric Rhenium Amide Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(NHCHRR'); Rhenium vs Carbon Epimerization", Dewey, M. A.; Gladysz, J. A. Organometallics 1990, 9, 1351-1353. DOI: 10.1021/om00118a084. [Abstract][PDF]

134.     "Synthesis and Reactivity of Chiral Rhenium Amine and Amide Complexes of the Formulas [(η5-C5H5)Re(NO)(PPh3)(NHRR')]+ TfO- and (η5-C5H5)Re(NO)(PPh3)(NRR')", Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1349-1351. DOI: 10.1021/om00118a083. [Abstract][PDF]

133.     "Isomerization of Diastereomeric Alkene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+; the Alkene Enantioface Bound to the Metal can "Flip" Without Alkene Dissociation", Peng, T.-S.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1990, 902-903. DOI: 10.1039/C39900000902. [Abstract][PDF]

132.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ X-", Bodner, G. S.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organometallics 1990, 9, 1191-1205. DOI: 10.1021/om00118a047. [Abstract][PDF]

131.     "Synthesis, Structure, and Reactivity of the Chiral Rhenium Phenyl Complex (η5-C5H5)Re(NO)(PPh3)(C6H5)", Agbossou, S. K.; Bodner, G. S.; Patton, A. T.; Gladysz, J. A. Organ­ometallics 1990, 9, 1184-1191. DOI: 10.1021/om00118a046. [Abstract][PDF]

130.     "Synthesis and Structure of σ-Pyridine, Quinoline, and Isoquinoline Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(NCxHy)]+ CF3SO3-", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 384, C29-C32. DOI: 10.1016/0022328X(90)87079-S. [Abstract][PDF]

129.     "Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(OR2)]+ X-", Agbossou, S. K.; Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 476-480. DOI: 10.1021/ic00328a027. [Abstract][PDF]

128.     "Optical Resolution and Absolute Configuration of the Chiral Pentamethylcyclopentadienyl Rhenium Carbonyl Complex [(η5-C5H5)Re(NO)(PPh3)(CO)]+ BF4-", Huang, Y.-H.; Niedercorn, F.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 383, 213-225. DOI: 10.1016/0022-328X(90)85133-J. [Abstract][PDF]

127.     "Tetracarbonyl{[2-(diphenylphosphino)phenyl]hydroxymethyl-C,P}manganese", Vaughn, G. D.; Gladysz, J. A. Inorg. Synth. 1989, 26, 169-171. DOI: 10.1002/9780470132579.ch30. [Abstract][PDF]

126.     "Synthesis and Structure of Chiral Rhenium Allyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2C(R')=CHR)", Bodner, G. S.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Organometallics 1989, 8, 2399-2404. DOI: 10.1021/om00112a022. [Abstract][PDF]

125.     "Synthesis and Reactivity of Functionalized Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PXX'). An Unusual CCl4 1,3-Addition Leading to an Exo-Substituted η4-Cyclopentadiene Complex", Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1989, 28, 3837-3845. DOI: 10.1021/ic00319a018. [Abstract][PDF]

124.     "Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae [(η5-C5H5)Re(NO)(PPh3)(η2-O=CHR)]+ BF4-; A New Synthesis of Optically Active Cyanohydrin Derivatives", Garner, C. M.; Fernández, J. M.; Gladysz, J. A. Tetrahedron Lett. 1989, 30, 3931-3934. DOI: 10.1016/SO040-4039(00)99278-6. [Abstract][PDF]

123.     "The Role of Virtual Halogen d Orbitals in the Stability and Reactivity of Rhenium Alkyl-Halide Complexes of the Form [(η5-C5H5)Re(NO)(PPh3)(XR)]+", Czech, P. T.; Gladysz, J. A.; Fenske, R. F. Organometallics 1989, 8, 1806-1810. DOI: 10.1021/om00109a038. [Abstract][PDF]

122.     "Synthesis, Structure and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(IR)]+ BF4-", Winter, C. H.; Veal, W. R.; Garner, C. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1989, 111, 4766-4776. DOI: 10.1021/ja00195a033. [Abstract][PDF]

121.     "Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ by K(s-C4H9)3BH; Synthesis of Optically Active Secondary Alcohols and Derivatives", Dalton, D. M.; Gladysz, J. A. J. Organomet. Chem. 1989, 370, C17-C21. DOI:10.1016/0022-328X(89)87307-3. [Abstract][PDF]

120.     "Synthesis, Structure, and Reactivity of Bridging Halide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)]2X+ BF4-; Preferential Binding of One Enantiomer of Halide Complexes (η5-C5H5)Re(NO)(PPh3)(X) by the Chiral Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+", Winter, C. H.; Arif, A. M.; Gladysz, J. A. Organometallics 1989, 8, 219-225. DOI: 10.1021/om00103a028. [Abstract][PDF]

119.     "Synthetic Approaches to the Chiral, Pyramidal, Transition Metal Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ X-; Generation, Characterization, and Reactions of a Dichloromethane Adduct", Fernández, J. M.; Gladysz, J. A. Organometallics 1989, 8, 207-219. DOI: 10.1021/om00103a027. [Abstract][PDF]

118.     "Generation of the Dichloromethane Complex [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+ BF4-, and its Conversion to the Oxidative Addition Product (η5-C5H5)Re(NO)(PPh3)Cl)(CH2­Cl)]+ BF4-", Winter, C. H.; Gladysz, J. A. J. Organomet. Chem. 1988, 354, C33-C36. DOI:10.1016/0022-328X(88)80664-8. [Abstract][PDF]

117.     "Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic Rearrangements Leading to the New Disilametallacycle ((η5-C5H5)Re(NO)(PPh3)Si(CH3)2)", Crocco, G. L.; Young, C. S.; Lee, K. E.; Gladysz, J. A. Organometallics 1988, 7, 2158-2162. DOI: 10.1021/om00100a012. [Abstract][PDF]

116.     "Divergent Kinetic and Thermodynamic Acidity in Organotransition-Metal Hydride Complexes; Synthesis, Structure, and Reactivity of the Rhenium Anion Li+ [(η5-C5H5)Re(NO)(PPh3)]-", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6110-6118. DOI: 10.1021/ja00226a027. [Abstract][PDF]

115.     "Synthesis, Structure, and Reactions of Chiral Rhenium Vinylidene and Acetylide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(X)]n+; Vinylidene Complexes that are Formed by Stereospecific Cβ Electrophilic Attack, Exist as Two Re=C=C Geometric Isomers, and Undergo Stereospecific Nucleophilic Cα Attack", Senn, D. R.; Wong, A.; Patton, A. T.; Marsi, M.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6096-6109. DOI: 10.1021/ja00226a026. [Abstract][PDF]

114.     "Synthesis and Reactivity of Functionalized Rhenium Germyl Complexes (η5-C5H5)Re(NO)(PPh3)(GePh2X); Dynamic Equilibria with Germylene Complex [(η5-C5H5)Re(NO)(PPh3)(=GePh2)]+ X-", Lee, K. E.; Gladysz, J. A. Polyhedron 1988, 7, 2209-2211. DOI: 10.1016/S0277-5387(00)81805-7. [Abstract][PDF]

113.     "Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]", Bodner, G. S.; Fernández, J. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 4082-4084. DOI: 10.1021/ ja00220a082. [Abstract][PDF]

112.     "Aldehyde and Ketone Ligands in Organometallic Complexes and Catalysis", Huang, Y.-H.; Gladysz, J. A. J. Chem. Ed. 1988, 65, 298-303. DOI: 10.1021/ed065p298. [Abstract][PDF]

111.     "Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PR2): The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439. DOI: 10.1021/ja00216a015. [Abstract][PDF]

110.     "Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η5-C5H5)Re(NO)(PPh3)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands", Crocco, G. L.; Gladysz, J. A. Chem. Ber. 1988, 121, 375-377. DOI: 10.1002/cber.19881210227. [Abstract][PDF]

109.     "The Selective Activation of One Ketone Enantioface via σ-Binding to a Chiral Metal Template: Synthesis and Reactivity of Rhenium Ketone Complexes [(η5-C5H5)Re(NO)(PPh3)(η1-RR'C=O)]+PF6-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1988, 37-39. DOI: 10.1039/C39880000037. [Abstract][PDF]

108.     "Synthesis, Structure, and Alkylation of Chiral Vinyl Rhenium Complexes (η5-C5H5)Re(NO)(PPh3)(CX=CHR) (X = H, OCH3). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium To Carbon", Bodner, G. S.; Smith, D. E.; Hatton, W. G.; Heah, P. C.; Georgiou, S.; Rheingold, A. L.; Geib, S. J.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7688-7705. DOI: 10.1021/ja00259a018. [Abstract][PDF]

107.     "A General Class of Stable Alkyl Halide Complexes; Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(IR)]+BF4-", Winter, C. H.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7560-7561. DOI: 10.1021/ja00258a067. [Abstract][PDF]

106.     "A New Method for the Activation of Metal-Bound Methyl Groups. Oxidative Disproportionation to Coordinated Ethylene and Methane", Tilset, M.; Bodner, G. S.; Senn, D. R.; Gladysz, J. A.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 7551-7553. DOI: 10.1021/ ja00258a062. [Abstract][PDF]

105.     "Crystallographic and Theoretical Analyses of the Structures of Rhenium Formyl and Acyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(COR)", Bodner, G. S.; Patton, A. T.; Smith, D. E.; Georgiou, S.; Tam, W.; Wong, W.-K.; Strouse, C. E.; Gladysz, J. A. Organometallics 1987, 6, 1954-1961. DOI: 10.1021/om00152a021. [Abstract][PDF]

104.     (a) "A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon A Chiral Rhenium Template Containing Two Phosphido Substituents", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1987, 26, 910-912. DOI: 10.1002/anie.198709101. [Abstract][PDF]

            (b) "Ein neuartiger heterodinuclearer Katalysator für die asymmetrische Hydrierung ein Bis­phosphido-Ligand mit einem stereogenen Rheniumzentrum", Zwick, B. D.; Arif, A. M.; Pat­ton, A. T.; Gladysz, J. A. Angew. Chem. 1987, 99, 921-922. DOI: 10.1002/ange.19870990914. [Abstract][PDF]

103.     "Synthesis, Structure, and Reactivity of Transition Metal/Main Group Metal Bridging Carboxylate Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb)", Senn, D. R.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Inorg. Chem. 1987, 26, 2737-2739. DOI: 10.1021/ic00264a001. [Abstract][PDF]

102.     "Electrochemical Oxidation of Rhenium Alkyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(R): Evidence for One-Electron Charge Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. Organometallics 1987, 6, 1628-1633. DOI: 10.1021/om00151a006. [Abstract][PDF]

101.     "A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups; Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R)", O'Connor, E. J.; Kobayashi, M.; Floss, H. G.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 4837-4844. DOI: 10.1021/ja00250a014. [Abstract][PDF]

100.     "Synthesis, Structure, and Reactivity of the Thioformaldehyde Complex [(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)]+PF6-", Buhro, W. E.; Etter, M. C.; Georgiou, S.; Gladysz, J. A.; McCormick, F. B. Organometallics 1987, 6, 1150-1156. DOI: 10.1021/om00149a003. [Abstract][PDF]

99.       "New Mechanistic Probes of Hydride Abstraction from Rhenium Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R) by Ph3C+PF6-; Evidence for Initial Electron Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 1757-1764. DOI: 10.1021/ja00240a027. [Abstract][PDF]

98.       "Novel Electron Impact-Induced Hydrogen Rearrangements in the Mass Spectra of Organorhenium Hydrides and Alkyls", Crocco, G. L.; Sharp, T. L.; Gladysz J. A. Int. J. Mass. Spec­trum. Ion. Phys. 1986, 73, 181-185. DOI:10.1016/0168-1176(86)80019-2. [Abstract][PDF]

97.       "A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(η2-RCH=O)]+PF6-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 8268-8270. DOI: 10.1021/ja00286a030. [Abstract][PDF]

96.       "Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts [(η5-C5H5)Re(NO)(PPh3)(CH2)]nS+(CH3)3-n (n = 1,2,3)", McCormick, F. B.; Gleason, W. B.; Zhao, X.; Heah, P. C.; Gladysz, J. A. Organometallics 1986, 5, 1778-1785. DOI: 10.1021/om00140a004. [Abstract][PDF]

95.       "Reaction of Ylide Complex [(η5-C5H5)Re(NO)(PPh3)(CH2PAr3)]+PF6- with n-Butyl-lithium-Tetramethylethylenediamine: Generation and Stereospecific Alkylation of a Transition-Metal-Substituted-Wittig Reagent", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1986, 1154-1156. DOI: 10.1039/C39860001154. [Abstract][PDF]

94.       "Generation and Reactions of Chiral, Pyramidal, Transition Metal Lewis Acids of the Formula [(η5-C5H5)Re(NO)(PPh3)]+X-", Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1986, 25, 2672-2674. DOI: 10.1021/ic00236a00. [Abstract][PDF]

93.       "Synthesis, Structure, and Reactivity of the Formaldehyde Complex [(η5-C5H5)Re(NO)(PPh3)(η2-H2C=O)]+PF6-", Buhro, W. E.; Georgiou, S.; Fernández, J. M.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A. Organometallics 1986, 5, 956-965. DOI: 10.1021/om00136a020. [Abstract][PDF]

92.       " Synthesis and Reactivity of Metallacyclic Manganese α-(Silyloxy)alkyl Complexes (CO)4­MnC(R)(OSi(CH3)3)P(C6H5)2; A New Thermodynamic Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Organometallics 1986, 5, 936-942. DOI: 10.1021/om00136a016. [Abstract][PDF]

91.       "Synthesis and Reactivity of Metallacyclic Manganese α-Hydroxyalkyl Complexes Containing Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms; First Carbonylation of an Isolable α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1473-1480. DOI: 10.1021/ja00267a017. [Abstract][PDF]

90.       "Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium α-Hydroxyalkyl Complexes of the Formula (CO)4MP(C6H5)2)(o-C6H4CHOH)", Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1462-1473. DOI: 10.1021/ja00267a016. [Abstract][PDF]

89.       "Synthesis and Reactivity of Metal α-Hydroxyalkyl Complexes; Generation of (CO)5MCH­(C6H5)OH (M = Mn, Re)", Selover, J. C.; Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1455-1462. DOI: 10.1021/ja00267a015. [Abstract][PDF]

88.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds. V. Kinetic vs Thermodynamic Deprotonation in Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Patton, A. T.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1185-1195. DOI: 10.1021/ja00266a012. [Abstract][PDF]

87.       "Reactions of Organorhenium Complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+PF6-; Analysis of the Energetics of α-Hydride Abstraction", Georgiou, S.; Gladysz, J. A. Tetrahedron 1986, 42, 1109-1116. DOI: 10.1016/SO040-4020(01)87514-1. [Abstract][PDF]

 

86.       "Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η5-C5H5)Re(NO)(PPh3)(PRR')", Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1985, 24, 3505-3507. DOI: 10.1021/ic00216a005. [Abstract][PDF]

85.       "Reactions of (CO)5MnSi(CH3)3 with α-Bromocarbonyl and Related Organic Compounds; Facile Reductive Silylation", Marsi, M.; Brinkman, K. C.; Lisensky, C. A.; Vaughn, G. D.; Gladysz, J. A. J. Org. Chem. 1985, 50, 3396-3401. DOI: 10.1021/jo00218a030. [Abstract][PDF]

84.       "Reactions of Chiral α-Methoxyvinyl Rhenium Complexes (η5-C5H5)Re(NO)(PPh3)(C­(OCH3)=CHR) with Alkyl Halides; Efficient 1,3-Asymmetric Induction", Smith, D. E.; Gladysz, J. A. Organometallics 1985, 4, 1480-1481. DOI: 10.1021/om00127a039. [Abstract][PDF]

83.       "Reactions of Cyanomethyl Complex (η5-C5H5)Re(NO)(PPh3)(CH2CN) with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of a Transition Metal Substituted Carbanion", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 4103-4104. DOI: 10.1021/ja00299a071. [Abstract][PDF]

 

82.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds, III. The First Carbon-Carbon Bond-Forming Reaction of an η1-Formyl Ligand", Heah, P. C.; Gladysz, J. A. J. Mol. Cat. 1985, 31, 207-209. DOI:10.1016/0304-5102(85)85062-8. [Abstract][PDF]

81.       "Synthesis, Conformation, and Reactivity of the Rhenium Phosphide Complex (η5-C5H5)Re(NO)(PPh3)(PPh2). The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 3346-3348. DOI: 10.1021/ja00297a050. [Abstract][PDF]

 

80.       "Electrochemical Oxidation of Rhenium Alkyl Complexes [Re(η5-C5H5)(NO)(PPh3)R]; Implications for the Mechanism of Hydride Abstraction by Ph3C+PF6-", Asaro, M. F.; Bodner, G. S.; Gladysz, J. A.; Cooper, S. R.; Cooper N. J. Organometallics 1985, 4, 1020-1024. DOI: 10.1021/om00125a010. [Abstract][PDF]

79.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds. Reactions of the Hydride Complex (η5-C5H5)Re(NO)(PPh3)(H) with n-Butyl-lithium-Tetramethylethylenediamine", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1985, 283-284. DOI: 10.1039/C39850000283. [Abstract][PDF]

 

78.       "Cleavage of Rhenium-Methyl Bond of (η-C5H5)Re(NO)(PPh3)(CH3) by Protic and Halogen Electrophiles; Stereochemistry at Rhenium", Merrifield, J. H.; Fernández, J. M.; Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1984, 23, 4022-4029. DOI: 10.1021/ic00192a036. [Abstract][PDF]

77.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds, 1. Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Gladysz, J. A. J. Am. Chem. Soc. 1984, 106, 7636-7637. DOI: 10.1021/ja00336a062. [Abstract][PDF]

76.       "Hydrogen Bonding in Organometallic Ligands and Possible Implications for CO/H2 Chemistry: First Carbonylation of an Isolable Metal α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. Organometallics 1984, 3, 1596-1598. DOI: 10.1021/om00088a028. [Abstract][PDF]

75.       "Reactions of Phosphorus Electrophiles with [(η5-C5Me5)Fe(CO)2]-: Spectroscopic Evidence for a Phosphinidene Complex", Nakazawa, H.; Buhro, W. E.; Bertrand, G.; Gladysz, J. A. Inorg. Chem. 1984, 23, 3431-3433. DOI: 10.1021/ic00190a001. [Abstract][PDF]

74.       "New Synthetic Chemistry of Transition Metal Trialkylsilane Complexes", Gladysz, J. A. Acc. Chem. Res. 1984, 17, 326-332. DOI: 10.1021/ar00105a005. [Abstract][PDF]

73.       "Alkylation and Acylation of the Iron Carbonyl Anion [(CO)4FeSi(CH3)3]-. Evidence for 1,3-Silatropic Shifts from Iron to Acyl Oxygen", Brinkman, K. C.; Blakeney, A. J.; Krone-Schmidt, W.; Gladysz, J. A. Organometallics 1984, 3, 1325-1332. DOI: 10.1021/ om00087a001. [Abstract][PDF]

72.       "Reaction of Benzylrhenium Complexes (η-C5H5)Re(NO)(L)(CH2Ar) with Ph3C+PF6-; Analysis of the Re-Cα Rotamers Involved in α-Hydride Abstraction", Kiel, W. A.; Buhro, W. E.; Gladysz, J. A. Organometallics 1984, 3, 879-886. DOI: 10.1021/om00084a010. [Abstract][PDF]

71.       (a) "Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese. Synthesis of Ylide Complexes (CO)4MnCR(OSiMe3)PPh2 and a New Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1984, 23, 245-246. DOI: 10.1002/ange.1984096031. [Abstract][PDF]

(b) "Reaktionen von Diphenyl(trimethylsilyl)phosphan mit Alkyl(pentacarbonyl)mangan; Synthese der Ylidkomplexe (CO)4MnCR(OSiMe3)PPh2 unter Beteiligung einer CO-Einschiebung", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem. 1984, 96, 230-231. DOI: 10.1002/ange.19840960316. [Abstract][PDF]

70.       "Reactions of (CO)5MnSi(CH3)3 and CO with Aldehydes and Cyclic Ethers; Syntheses of Functionalized Pentacarbonyl Manganese Acyls and Homologated Organic Compounds", Brinkman, K. C.; Gladysz, J. A. Organometallics 1984, 3, 147-155. DOI: 10.1021/om00079a026. [Abstract][PDF]

69.       "Synthesis and Chemistry of Chiral Rhenium Acyls (η-C5H5)Re(NO)(PPh3)(COR)", Buhro, W. E.; Wong, A.; Merrifield, J. H.; Lin, G.-Y.; Constable, A. G.; Gladysz, J. A. Organometallics 1983, 2, 1852-1859. DOI: 10.1021/om50006a026. [Abstract][PDF]

68.       "A New Route to Metal Alkylidene Complexes; Synthesis of Ylide Adducts (CO)4Fe-CH(R)P+Ar3 from Aldehydes, Triarylphosphines, and (CO)4FeSi(CH3)2CH2CH2Si(CH3)2", Nakazawa, H.; Johnson, D. L.; Gladysz, J. A. Organometallics 1983, 2, 1846-1851. DOI: 10.1021/om50006a025. [Abstract][PDF]

67.       "Atomos de Metales de Transicion en la Sintesis y la Catalisis Organica", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Rev. Soc. Quim. Mex. 1983, 27, 146-148.

66.       "Synthesis and Chemistry of Chiral Vinyl Rhenium Complexes (η-C5H5)Re(NO)(PPh3)(CH=CHR). Stereoselective Reactions with Electrophiles and a Spontaneous Alkylidene to Olefin Rearrangement", Hatton, W. G.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 6157-6158. DOI: 10.1021/ja00356a018. [Abstract][PDF]

65.       " Mechanism of Coupling of =CH2 to H2C=CH2 at a Homogeneous (η-C5H5)Re(NO)(PPh3)+ Center; Remarkable Enantiomer Self-Recognition", Merrifield, J. H.; Lin, G.-Y.; Kiel, W. A.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5811-5819. DOI: 10.1021/ja00356a019. [Abstract][PDF]

64.       "Syntheses, Properties and X-ray Crystal Structures of Stable Methylidene Complexes of the Formula [(η-C5Me5)Re(NO)(L)(=CH2)]+ PF6-", Patton, A. T.; Strouse, C. E.; Knobler, C. B.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5804-5811. DOI: 10.1021/ja00356a018. [Abstract][PDF]

63.       "Regiospecific and Stereospecific Reactions of Ph3C+ PF6- with Rhenium Alkyls (η-C5H5)Re(NO)(PPh3)(R); α vs β Hydride Abstraction", Kiel, W. A.; Lin, G.-Y.; Bodner, G. S.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 4958-4972. DOI: 10.1021/ja00353a020. [Abstract][PDF]

62.       "Synthesis and Decarboxylation Mechanism of the Chiral Rhenium Formate (η-C5H5)Re(NO)(PPh3)(OCHO)", Merrifield, J. H.; Gladysz, J. A. Organometallics 1983, 2, 782-784. DOI: 10.1021/om00078a022. [Abstract][PDF]

61.       "Bimetallic Anionic Formyl Complexes; Synthesis and Properties", Tam, W.; Marsi, M.; Gladysz, J. A. Inorg. Chem. 1983, 22, 1413-1421. DOI: 10.1021/ic00152a001. [Abstract][PDF]

60.       "Synthesis, Chemical Properties, and X-ray Crystal Structures of Rhenium Formaldehyde and Thioformaldehyde Complexes", Buhro, W. E.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A.; McCormick, F. B.; Etter, M. C. J. Am. Chem. Soc. 1983, 105, 1056-1058. DOI: 10.1021/ja00342a070. [Abstract][PDF]

59.       "Reactions of Ketals and Acetals with (CO)5MnSi(CH3)3; A New Vinyl Ether Synthesis", Marsi, M.; Gladysz, J. A. Organometallics 1982, 1, 1467-1473. DOI: 10.1021/om00071a012. [Abstract][PDF]

58.       "Syntheses and Reactions of Rhenium Vinylidene and Acetylide Complexes; Unprecedented Chirality Transfer through a C≡C Triple Bond", Wong, A.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4948-4950. DOI: 10.1021/ja00382a036. [Abstract][PDF]

57.       "Synthesis, Optical Resolution, and Absolute Configuration of Pseudotetrahedral Organo­rhenium Complexes (η-C5H5)Re(NO)(PPh3)(X)", Merrifield, J. H.; Strouse, C. E.; Gladysz, J. A. Organometallics 1982, 1, 1204-1211. DOI: 10.1021/om00069a018. [Abstract][PDF]

56.       "Synthesis and Properties of [(η-C5H5)Re(NO)(PPh3)(=CHC6H5)]+ PF6-: A Benzylidene Complex that is Formed by a Stereospecific α-Hydride Abstraction, Exists as Two Geometric Isomers, and Undergoes Stereospecific Nucleophilic Attack", Kiel, W. A.; Lin, G.-Y.; Constable, A. G.; McCormick, F. B.; Strouse, C. E.; Eisenstein, O.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4865-4878. DOI: 10.1021/ja00382a021. [Abstract][PDF]

55.       "Substituent Effects upon Alkyl Migration to Coordinated CO: Syntheses and Carbonylation Studies of (CO)5MnCH2I and (CO)5MnCH2OSi(CH3)3", Brinkman, K. C.; Vaughn, G. D.; Gladysz, J. A. Organometallics 1982, 1, 1056-1060. DOI: 10.1021/om00068a010. [Abstract][PDF]

54.       "Transition Metal Formyl Complexes", Gladysz, J. A. Adv. Organomet. Chem. 1982, 20, 1-38. DOI:10.1016/S0065-3055(08)60519-5. [Abstract]

53.       "Syntheses of Kinetically Unstable Neutral Formyl Complexes via Li(C2H5)3BH and 'Transformylation' Reactions of Metal Carbonyl Cations", Tam, W.; Lin, G.-Y.; Gladysz, J. A. Organometallics 1982, 1, 525-529. DOI: 10.1021/om00063a022. [Abstract][PDF]

52.       "Organic Transformations via Metal Silane Reagents: Syntheses of Vinyl Ethers from Dimethyl Ketals and (CO)5MnSi(CH3)3", Marsi, M.; Gladysz, J. A. Tetrahedron Lett. 1982, 23, 631-634. DOI: 10.1016/SO040-4039(00)86908-7. [Abstract][PDF]

51.       "A New Organometallic Photoreaction: Interconversion of Metal-Alkylidene Geometric Isomers", McCormick, F. B.; Kiel, W. A.; Gladysz, J. A. Organometallics 1982, 1, 405-408. DOI: 10.1021/om00062a033. [Abstract][PDF]

50.       "Synthesis and Electrophile Induced Disproportionation of the Neutral Formyl (η-C5H5)Re(NO)(PPh3)CHO)", Tam, W.; Lin, G.-Y.; Wong, W.-K.; Kiel, W. A.; Wong, V. K.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 141-152. DOI: 10.1021/ja00365a027. [Abstract][PDF]

49.       "Synthesis of Iron Carbonyl Trimethylsilanes; Preparations and Interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+ [(CO)4FeSi(CH3)3]-, and trans-[Fe(CO)4Si(CH3)3]2", Blakeney, A. J.; Johnson, D. L.; Donovan, P. W.; Gladysz, J. A. Inorg. Chem. 1981, 20, 4415-4419. DOI: 10.1021/ic50226a076. [Abstract][PDF]

48.       "Three Rational Syntheses of New Stable Metal α-Hydroxyalkyl Complexes", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1981, 103, 5608-5609. DOI: 10.1021/ja00408a073. [Abstract][PDF]

47.       "Exploratory Organometal-Sulfur Chemistry: Syntheses and Unusual Properties of Rhenium -CH2SR, -CH2S+RR' and =CHSR]+ Complexes", McCormick, F. B.; Gladysz, J. A. J. Organomet. Chem. 1981, 218, C57-C61. DOI:10.1016/S0022-328X(00)81018-9. [Abstract][PDF]

46.       "Reactions of (CO)5MnSi(CH3)3 with Organic Carbonyl Compounds", Johnson, D. L.; Gladysz, J. A. Inorg. Chem. 1981, 20, 2508-2515. DOI: 10.1021/ic50222a028. [Abstract][PDF]

45.       "New Deoxygenative Transformations: Reactions of (CO)4Fe[Si(CH3)3]2 with Acyclic Ethers", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1981, 210, 303-312. DOI:10.1016/S0022-328X(00)80889-X. [Abstract][PDF]

44.       "Electrophile Induced Disproportionation of the Neutral Formyl (η-C5H5)Re(NO)(PPh3)(CHO); Isolation and Properties of the Rhenium Methylidene [(η-C5H5)Re(NO)(PPh3)(CH2)]+ PF6-, Gladysz, J. A.; Kiel, W. A.; Lin, G.-Y.; Wong, W.-K.; Tam, W. ACS Symposium Series 1981, 152, 147-164. DOI: 10.1021/bk-1981-0152.ch010. [Abstract]

43.       "Nickel and Palladium Complexes in the Synthesis of Macrocyclic Compounds", Halweg, K. M.; Gladysz, J. A. The Strem Chemiker 1981, 9, 7-14.

42.       "Mononuclear Anionic Formyl Complexes; Synthesis and Properties", Selover, J. C.; Marsi, M.; Parker, D. W.; Gladysz, J. A. J. Organomet. Chem. 1981, 206, 317-329. DOI:10.1016/S0022-328X(00)83029-6. [Abstract][PDF]

41.       "Preparation and Alkylation Reactions of K+[(CO)4FeSi(CH3)]-; Reductive Elimination of Tetramethylsilane and Benzyl Trimethylsilane from Isolable (CO)4FeRSi(CH3)3 Complexes", Blakeney, A. J.; Gladysz, J. A. Inorg. Chim. Acta 1981, 53, L25-L27. DOI:10.1016/S0020-1693(00)84730-1. [Abstract][PDF]

40.       "Preparation and Properties of (η-C5H5)2ZrCl[Si(CH3)3] and (η-C5H5)2Zr[Si(CH3)3]2: Trimethylsilyl Group Transfer from Mercury to Zirconium", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, 263-268. DOI:10.1016/S0022-328X(00)92674-3. [Abstract][PDF]

39.       "New Methods for Metal-Carbon Bond Formation: Reactions of (CO)5MnSi(CH3)3 with Cyclic Ethers", Brinkman, K. C.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1980, 1260-1261. DOI: 10.1039/C39800001260. [Abstract][PDF]

38.       "Stereospecific and Chemospecific Interconversions of the Rhenium Alkylidene [(η-C5H5)Re(NO)(PPh3)(CHC6H5)]+ PF6- and the Alkylrhenium (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5)", Constable, A. G.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, C21-C24. DOI:10.1016/S0022-328X(00)81394-7. [Abstract][PDF]

37.       "Chemistry via Metal Atom Cocondensation: Isomerization and Complexation Reactions of Organocyclopropanes and Spirocycles", Hanlan, A. J. L.; Ugolick, R. C.; Fulcher, J. G.; Togashi, S.; Bocarsly, A. B.; Gladysz, J. A. Inorg. Chem. 1980, 19, 1543-1551. DOI: 10.1021/ic50208a023. [Abstract][PDF]

36.       "Unprecedented Regiospecificity and Stereospecificity in Reactions of Ph3C+PF6- with Rhenium Alkyls of the Formula (η-C5H5)Re(NO)(PPh3)(CH2R)", Kiel, W. A.; Lin, G.-Y.; Gladysz, J. A. J. Am. Chem. Soc. 1980, 102, 3299-3301. DOI: 10.1021/ja00529a092. [Abstract][PDF]

35.       "Deoxygenation and Desulfurization of Organic Compounds via Transition Metal Atom Cocondensation", Togashi, S.; Fulcher, J. C.; Cho, B.-R.; Hasegawa, M.; Gladysz, J. A. J. Org. Chem. 1980, 45, 3044-3053. DOI: 10.1021/jo01303a023. [Abstract][PDF]

34.       "Substitution Mechanisms at Metal Carbonyl Centers; Conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an Anionic Acyl Intermediate", Parker, D. W.; Marsi, M. M.; Gladysz, J. A. J. Organomet. Chem. 1980, 194, C1-C4. DOI:10.1016/S0022-328X(00)90345-0. [Abstract][PDF]

33.       "Reactions of Benzaldehyde with Trialkylsilyl Metal Carbonyl Complexes", Johnson, D. L.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 6433-6435. DOI: 10.1021/ja00515a048. [Abstract][PDF]

32.       "New Methodology for the Introduction of Sulfur into Organic Molecules; Synthesis of Anhydrous Li2S, Li2S2 and LiSR Species by Lithium Triethylborohydride Reduction of Elemental Sulfur and Disulfides", Gladysz, J. A.; Wong, V. K.; Jick, B. S. Tetrahedron 1979, 35, 2329-2335. DOI: 10.1016SO040-4020(01)93746-9. [Abstract][PDF]

31.       "Electrophile Induced Disproportionation of the Neutral For (η-C5H5)Re(NO)(PPh3)(CHO); Generation of Cationic Rhenium Carbenes of the Formula [(η-C5H5)Re(NO)(PPh3)(CHX)]+ (X = H, OCH3, OH)", Wong, W.-K; Tam, W.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 5440-5442. DOI: 10.1021/ja00512a069. [Abstract][PDF]

30.       "Squeezing the Transition State", Gladysz, J. A. CHEMTECH 1979, 9, 372-377.

29.       "X-Ray Crystal Structure and Chemical Transformations of the Neutral Metal Formyl (η-C5H5)Re(PPh3)(NO)(CHO)", Wong, W.-K; Tam, W.; Strouse, C. E.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1979, 530-531. DOI: 10.1039/C39790000530. [Abstract][PDF]

28.       "Simplified in situ Syntheses of Anhydrous HMn(CO)5", Gladysz, J. A.; Tam, W.; Williams, G. M.; Johnson, D. L.; Parker, D. W. Inorg. Chem. 1979, 18, 1163-1165. DOI: 10.1021/ic50194a05. [Abstract][PDF]

27.       "Reactions of Organocyclopropanes and Spirocycles with Metal Atoms", Gladysz, J. A.; Fulcher, J. G.; Ugolick, R. C.; Hanlan, A. J. L.; Bocarsly, A. B. J. Am. Chem. Soc. 1979, 101, 3388-3390. DOI: 10.1021/ja00506a048. [Abstract][PDF]

26.       "Trialkylborohydrides: Applications in Organometallic Syntheses", Gladysz, J. A. Aldrichimica Acta 1979, 12, 13-18. [Link]

25.       "Neutral Metal Formyl Complexes; Generation, Reactivity, and Models for Fischer-Tropsch Catalyst Intermediates", Tam, W.; Wong, W. K.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 1589-1591. DOI: 10.1021/ja00500a037. [Abstract][PDF]

24.       "The Synthesis of Metal Carbonyl Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; A Convenient One-flask Preparation of Metal Alkyls, Metal Acyls, and Mixed Metal Compounds", Gladysz, J. A.; Williams, G. M.; Tam, W.; Johnson, D. L.; Parker, D. L.; Selover, J. C. Inorg. Chem. 1979, 18, 553-558. DOI: 10.1021/ic50193a006. [Abstract][PDF]

23.       "29Si NMR Spectra of Transition Metal Silanes by the Selective Population Transfer Method", Li, S.; Johnson, D. L.; Gladysz, J. A.; Servis, K. L. J. Organomet. Chem. 1979, 166, 317-321. DOI:10.1016/S0022-328X(00)82549-8. [Abstract][PDF]

22.       "α-Silyloxy and α-Hydroxy Manganese Alkyls; Generation Via a New Five-membered Metallocycle", Gladysz, J. A.; Selover, J. C.; Strouse, C. E. J. Am. Chem. Soc. 1978, 100, 6766-6768. DOI: 10.1021/ja00489a044. [Abstract][PDF]

21.       "Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds", Gladysz, J. A. in Fundamental Research in Homogeneous Catalysis, Vol. 2, Plenum, New York, 1978, pp. 101-115. (invited article, proceedings of international workshop on homogeneous catalysis)

20.       "Introduction of Sulfur into Organic Molecules via Lithium Triethylborohydride Reduction of S8", Gladysz, J. A.; Wong, V. K.; Jick, B. S. J. Chem. Soc., Chem. Commun. 1978, 838-839. DOI: 10.1039/C39780000838. [Abstract][PDF]

19.       "Hydride Transfer Reactions of Anionic Formyl Complexes: A Mechanistic Test", Gladysz, J. A.; Merrifield, J. H. Inorg. Chim. Acta 1978, 30, L317-L318. DOI:10.1016/S0020-1693(00)88992-6. [Abstract][PDF]

18.       "Ene Reactions of β-Pinene at Room Temperature and 40 kbar Pressure", Gladysz, J. A.; Yu, Y. S. J. Chem. Soc., Chem. Commun. 1978, 599-600. DOI: 10.1039/C39780000599. [Abstract][PDF]

17. "A One-Flask Preparation of Analytically Pure K2Fe(CO)4", Gladysz, J. A.; Tam, W. J. Org. Chem. 1978, 43, 2279-2280. DOI: 10.1021/jo00405a041. [Abstract][PDF]

16. "Ligand Wrapping Around Chromium: Reactions of Diphenylmethane, 1,4-Diphenylbutane, Benzyl Ether, and Benzyl Sulfide with Chromium Atoms", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Tetrahedron Lett. 1978, 19, 1725-1728. DOI: 10.1016/SO040-4039(78)80027-6. [Abstract][PDF]

15. "Binuclear and Mixed Metal Formyl Complexes; Isolation, Characterization, and Chemistry", Gladysz, J. A.; Tam, W. J. Am. Chem. Soc. 1978, 100, 2545-2547. DOI: 10.1021/ ja00476a046. [Abstract][PDF]

14. "A Convenient One-Flask Synthesis of Dialkyl Selenides and Diselenides via Lithium Triethylborohydride Reduction of Sex", Gladysz, J. A.; Hornby, J. L.; Garbe, J. E. J. Org. Chem. 1978, 43, 1204-1208. DOI: 10.1021/jo00400a040. [Abstract][PDF]

13. "Transition Metal Formyl Complexes: Synthesis by Trialkylborohydride Attack on Metal Carbonyl Acyls", Gladysz, J. A.; Selover, J. C. Tetrahedron Lett. 1978, 19, 319-322. DOI: 10.1016/SO040-4039(01)85114-5. [Abstract][PDF]

12. "High Pressure Cycloadditions of Pyrones; Synthesis of Highly Functionalized Six-Membered Rings by Inhibitions of Carbon Dioxide Loss", Gladysz, J. A.; Lee, S. J.; Tomasello, J. A. V.; Yu, Y. S. J. Org. Chem. 1977, 42, 4170-4172. DOI: 10.1021/jo00445a050. [Abstract][PDF]

11. "Cyclotrimerization of Cyclic Diynes via Metal Atom Cocondensation; Revised Structure for the Reported 'Percyclophane-4'", Gladysz, J. A.; Fulcher, J. G.; Lee, S. J.; Bocarsly, A. B. Tetrahedron Lett. 1977, 18, 3421-3424. DOI: 10.1016/SO040-4039(01)83256-1. [Abstract][PDF]

10. "A Convenient Synthesis of [3.3]Paracyclophane", Longone, D. T.; Kusefoglu, S. H.; Gladysz, J. A. J. Org. Chem. 1977, 42, 2787-2788. DOI: 10.1021/jo00436a033. [Abstract][PDF]

9. "A Convenient Preparation of Transition Metal Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; Observation and Reactions of a Bimetallic Manganese-Formyl Intermediate", Gladysz, J. A.; Williams, G. M.; Tam, W; Johnson, D. L. J. Organomet. Chem. 1977, 140, C1-C6. DOI: 10.1016/SO022-328X(00)84402-2. [Abstract][PDF]

8. "Deoxygenation of Nitro and Nitroso Arenes via Chromium Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. Tetrahedron Lett. 1977, 18, 521-524. DOI: 10.1016/SO040-4039(01)92683-8. [Abstract][PDF]

7. "5,6-Dehydro[3.3]Paracyclophane: Bridged Benzobarrelene Formation by Intramolecular Trapping of a Novel Aryne", Longone, D. T.; Gladysz, J. A. Tetrahedron Lett. 1976, 17, 4559-4562. DOI: 10.1016/SO040-4039(00)93931-5. [Abstract][PDF]

6. "Deoxygenation of Epoxides by Metal Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. J. Org. Chem. 1976, 41, 3647-3648. DOI: 10.1021/jo01303a023. [Abstract][PDF]

5. "Thione Complexes of Group VIB Pentacarbonyls", Gladysz, J. A.; Avakian, R. W. Syn. React. Inorg. Metal-Org. Chem. 1975, 5, 247-255. DOI: 10.1080/00945717508057315. [Abstract]

4. "I. Titanocene Induced Reductive Deligandations of Organic Compounds; II. Iron-Molybdenum Models for Nitrogenase", Gladysz, J. A. Diss. Abstr. Int. B. 1974, 35, 2654.

3. "Direct Conversion of Aldehydes, Esters, and 1,2-Oxides to Alkanes with Carbon Skeleton Preservation", van Tamelen, E. E.; Gladysz, J. A. J. Am. Chem. Soc. 1974, 96, 5290-5291. DOI: 10.1021/ja00823a065. [Abstract][PDF]

2. "Biological and Abiological Nitrogen Fixation by Molybdenum-Bound N2/4Fe-4S Cluster Systems", van Tamelen, E. E.; Gladysz, J. A.; Brûlet, C. R. J. Am. Chem. Soc. 1974, 96, 3020-3021. DOI: 10.1021/ja00816a074. [Abstract] [PDF]

1. "Nonenzymatic Nitrogen Fixation by an Iron-Molybdenum Model for Nitrogenase", van Tamelen, E. E.; Gladysz, J. A.; Miller, J. S. J. Am. Chem. Soc. 1973, 95, 1347-1348. DOI: 10.1021/ja00785a063. [Abstract] [PDF]