Contact

321 Reed McDonald Building
Ph: 979-845-7048

Mailing Address:
Department of Chemistry Texas A&M University
P.O. Box 30012
College Station, TX 77843-3012

Shipping Address:
Department of Chemistry
Texas A&M University
580 Ross Street
MS3255 TAMU
College Station, TX 77843-3255

People

Prof. John A. Gladysz -- Research Personnel -- Office Personnel

Prof. John A. Gladysz
Distinguished Professor
Dow Chair in Chemical Invention


Office: 318 Reed McDonald
gladysz@mail.chem.tamu.edu
Ph: (979) 845-1399
Fax: (979) 845-5629

Assistant: Amy Day
amy.day@mail.chem.tamu.edu
(979) 845-7048

 

PROFESSIONAL

Professional Positions

  • Assistant Professor, University of California, Los Angeles, 1974-1982
  • Associate Professor, University of Utah, 1982-1985
  • Professor, University of Utah, 1985-1998
  • Professor Ordinarius (Chair, Organic Chemistry), Friedrich-Alexander-Universitt Erlangen-Nrnberg (Germany), 1998-2008
  • Distinguished Professor and Dow Chair in Chemical Invention, Texas A&M University, 2008

Consulting

  • Gas Research Institute, Panel Member; New Directions, Chicago, Illinois,
    Basic Research on Coal Gasification,1979-1980
  • G.D. Searle & Company, Consultant on Pharmaceutical Synthesis, Chicago,
    Illinois, High Pressure/Organometallic Methods,1980-1981
  • Procter & Gamble Company, Consultant for Corporate Technology
    Cincinnati, Ohio,Division, Miami Valley Laboratory, 1983-1985
  • Monsanto Corporation, Consultant for Polymer Products, Springfield
    Massachusetts Division, 1984-1986
  • Union Camp Corporation, Consultant for Terpene Products, Princeton,
    New Jersey Division, 1988-1989
  • Exxon Research & Engineering, Consultant for Corporate Research           
    Annandale, New Jersey, Laboratories, 1993-1998
  • Kimberly Clark Corporation, Consultant for New Technologies
    Roswell, Georgia Division, 1997-1998
  • 3M Corporation, Consultant for Fluorocarbon Products, Minneapolis
    Minnesota Division, 1998-1999
  • Rhodia (Rhône-Poulenc) Corporation, Consultant for Catalysis Division
    Lyon (Saint-Fons), France, 1999-2001
  • Total/Fina/Elf,Consultant for Polyolefin Division, Paris, France                       Seneffe,Belgium, 2002-2005
  • Edwards Nanoscience, Consultant for Oxidation Technologies           
    Houston, Texas, 2009-2011
  • Terrabon, Inc., Consultant for Biofuels Processing, Bryan, Texas, 2011-2012

Professional Service

  • Editor-in-Chief, Organometallics, 2010-2014
  • Associate Editor, Chemical Reviews, 1984-present
  • Co-PI, NSF Organometallic Workshop, 1991-1993
  • Member, NIH Medicinal Chemistry (A) Study Section, 1995-1999
  • Chair, Organometallic Chemistry Gordon Conference, 1996 (1995)
  • International Advisory Board Member, Encyclopedia of Catalysis (Wiley; I. Horvath, Ed.), 1999-2003

Advisory Boards

Professional Awards and Honors

  • Alfred P. Sloan Foundation Fellow, 1980-1984
  • Camille and Henry Dreyfus Teacher-Scholar, 1980-1985
  • Arthur C. Cope Scholar Award, 1988
  • University of Utah Distinguished Research Award, 1992
  • American Chemical Society Award in Organometallic Chemistry, 1994
  • von Humboldt Foundation Research Award for Senior Scientists, 1995-1996
  • Who's Who in the World, 2002-
  • Lady Davis Professorship, Technion - Israel Institut of Technology, 2003-2004
  • Fellow, American Association for the Advancement of Science, 2004
  • International Fluorous Technologies Award, 2007

Professional Societies and Organizations

  • American Chemical Society, 1970-
  • The Chemical Society, 1974-
  • American Association for the Advancement of Science, 1975-
  • Gesellschaft Deutscher Chemiker, 1997-
  • Phi Beta Delta (Honor Society for International Scholars, 2009-)
 
PERSONAL
  • Family Details [link under construction]
  • Wife - Dr. Janet Bluemel [link]
  • Mother - Margean A. Gladysz [link]
  • Father - Edward M. Gladysz [link under construction]
  • Crow's Nest Ranch
  • Directions [pdf]
  • House [link under construction]
  • Animals [link under construction]
  • Agriculture [link under construction]
  • Oil well [link under construction]
  • depth schematic, July 2010 [pdf]
  • drilling team, July 2010 [pdf]

Biographical Sketch

John A. Gladysz is a native of the Kalamazoo, Michigan area, and obtained his B. S. degree from the University of Michigan (1971) and his Ph. D degree from Stanford University (1974) with E. E. van Tamelen. He subsequently held appointments at UCLA (Assistant Professor, 1974-1982), the University of Utah (Associate Professor and Professor, 1982-1998), the Chair of Organic Chemistry at the University of Erlangen-Nuremberg in Germany, where he succeeded Paul von Ragu Schleyer, and is currently Distinguished Professor and DOW Chair at Texas A&M University. He is a fellow of the Alfred P. Sloan Foundation (1980-1984) and a Camille and Henry Dreyfus Teacher-Scholar Grant recipient (1980-1985). He received an Arthur C. Cope Scholar Award in 1988, the University of Utah Distinguished Research Award in 1992, the ACS Award in Organometallic Chemistry in 1994, and a von Humboldt Foundation Research Award for Senior Scientists in 1995. From June 1984 through July 2010, he served as the Associate Editor of Chemical Reviews. He then succeeded Dietmar Seyferth as the Editor in Chief of Organometallics.

Prof. Gladysz has authored over 400 papers and patents, and his research spans a wide range of problems in the general areas of synthetic and mechanistic organometallic chemistry, and catalysis.

On the personal side, he enjoys runing (5+ miles 4-5 times per week), all types of literature, and a good red wine. He is married to Janet Blümel, a Professor of Chemistry at Texas A&M University who specializes in inorganic chemistry, supported catalysts, and solid state NMR spectroscopy.

Personal/Family Biography [Link]

Publications


(PDF links are under construction)

1970   |   1980   |   1990   |   2000 |   2010 |bottom of list

   

1. "Nonenzymatic Nitrogen Fixation by an Iron-Molybdenum Model for Nitrogenase", van Tamelen, E. E.; Gladysz, J. A.; Miller, J. S. J. Am. Chem. Soc. 1973, 95, 1347-1348. [PDF]

   

2. "Biological and Abiological Nitrogen Fixation by Molybdenum-Bound N2/4Fe-4S Cluster Systems", van Tamelen, E. E.; Gladysz, J. A.; Brûlet, C. R. J. Am. Chem. Soc. 1974, 96, 3020-3021. [PDF]

   

3. "Direct Conversion of Aldehydes, Esters, and 1,2-Oxides to Alkanes with Carbon Skeleton Preservation", van Tamelen, E. E.; Gladysz, J. A. J. Am. Chem. Soc. 1974, 96, 5290-5291. [PDF]

   

4. "I. Titanocene Induced Reductive Deligandations of Organic Compounds; II. Iron-Molybdenum Models for Nitrogenase", Gladysz, J. A. Diss. Abstr. Int. B. 1974, 35, 2654.

   

5. "Thione Complexes of Group VIB Pentacarbonyls", Gladysz, J. A.; Avakian, R. W. Syn. React. Inorg. Metal-Org. Chem. 1975, 5, 247-255. [Link]

   

6. "Deoxygenation of Epoxides by Metal Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. J. Org. Chem. 1976, 41, 3647-3648. [PDF]

   

7. "5,6-Dehydro[3.3]Paracyclophane: Bridged Benzobarrelene Formation by Intramolecular Trapping of a Novel Aryne", Longone, D. T.; Gladysz, J. A. Tetrahedron Lett. 1976, 17, 4559-4562. [PDF]

   

8. "Deoxygenation of Nitro and Nitroso Arenes via Chromium Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. Tetrahedron Lett. 1977, 18, 521-524. [PDF]

   

9. "A Convenient Preparation of Transition Metal Monoanions by Trialkylborohydride Cleav­age of Metal Carbonyl Dimers; Observation and Reactions of a Bimetallic Manganese-For­myl Intermediate", Gladysz, J. A.; Williams, G. M.; Tam, W; Johnson, D. L. J. Organomet. Chem. 1977, 140, C1-C6. [PDF]

   

10. "A Convenient Synthesis of [3.3]Paracyclophane", Longone, D. T.; Kusefoglu, S. H.; Glad­ysz, J. A. J. Org. Chem. 1977, 42, 2787-2788. [PDF]

   

11. "Cyclotrimerization of Cyclic Diynes via Metal Atom Cocondensation; Revised Structure for the Reported 'Percyclophane-4'", Gladysz, J. A.; Fulcher, J. G.; Lee, S. J.; Bocarsly, A. B. Tetrahedron Lett. 1977, 18, 3421-3424. [PDF]

   

12. "High Pressure Cycloadditions of Pyrones; Synthesis of Highly Functionalized Six-Memb­ered Rings by Inhibitions of Carbon Dioxide Loss", Gladysz, J. A.; Lee, S. J.; Tomasello, J. A. V.; Yu, Y. S. J. Org. Chem. 1977, 42, 4170-4172. [PDF]

   

13. "Transition Metal Formyl Complexes: Synthesis by Trialkylborohydride Attack on Metal Carbonyl Acyls", Gladysz, J. A.; Selover, J. C. Tetrahedron Lett. 1978, 19, 319-322. [PDF]

   

14. "A Convenient One-Flask Synthesis of Dialkyl Selenides and Diselenides via Lithium Tri­ethylborohydride Reduction of Sex", Gladysz, J. A.; Hornby, J. L.; Garbe, J. E. J. Org. Chem. 1978, 43, 1204. [PDF]

   

15. "Binuclear and Mixed Metal Formyl Complexes; Isolation, Characterization, and Chemist­ry", Gladysz, J. A.; Tam, W. J. Am. Chem. Soc. 1978, 100, 2545-2547. [PDF]

   

16. "Ligand Wrapping Around Chromium: Reactions of Diphenylmethane, 1,4-Diphenylbutane, Benzyl Ether, and Benzyl Sulfide with Chromium Atoms", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Tetrahedron Lett. 1978, 19, 1725-1728. [PDF]

   

17. "A One-Flask Preparation of Analytically Pure K2Fe(CO)4", Gladysz, J. A.; Tam, W. J. Org. Chem. 1978, 43, 2279-2280. [PDF]

   

18.       "Ene Reactions of ß-Pinene at Room Temperature and 40 Kbar Pressure", Gladysz, J. A.; Yu, Y. S. J. Chem. Soc., Chem. Commun. 1978, 599-600. [PDF]

   

19.       "Hydride Transfer Reactions of Anionic Formyl Complexes: A Mechanistic Test", Gladysz, J. A.; Merrifield, J. H. Inorg. Chim. Acta 1978, 30, L317-L318.

   

20.       "Introduction of Sulfur into Organic Molecules via Lithium Triethylborohydride Reduction of S8", Gladysz, J. A.; Wong, V. K.; Jick, B. S. J. Chem. Soc., Chem. Commun. 1978, 838-839. [PDF]

   

21.       "Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkyl­borohydride Attack on Metal Carbonyl Compounds", Gladysz, J. A. in Fundamental Research in Homogeneous Catalysis, Vol. 2, Plenum, New York, 1978, pp. 101-116.

   

22.       "a-Silyloxy and a-Hydroxy Manganese Alkyls; Generation Via a New Five-membered Metallocycle", Gladysz, J. A.; Selover, J. C.; Strouse, C. E. J. Am. Chem. Soc. 1978, 100, 6766-6768. [PDF]

   

23.       "29 Si NMR Spectra of Transition Metal Silanes by the Selective Population Transfer Method", Li, S.; Johnson, D. L.; Gladysz, J. A.; Servis, K. L. J. Organomet. Chem. 1979, 166, 317-321. [PDF]

   

24.       "The Synthesis of Metal Carbonyl Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; A Convenient One-flask Preparation of Metal Alkyls, Metal Acyls, and Mixed Metal Compounds", Gladysz, J. A.; Williams, G. M.; Tam, W.; Johnson, D. L.; Parker, D. L.; Selover, J. C. Inorg. Chem. 1979, 18, 553-558. [PDF]

   

25.       "Neutral Metal Formyl Complexes; Generation, Reactivity, and Models for Fischer-Tropsch Catalyst Intermediates", Tam, W.; Wong, W. K.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 1589-1591. [PDF]

   

26.       "Trialkylborohydrides: Applications in Organometallic Syntheses", Gladysz, J. A. Aldrichi­mica Acta 1979, 12, 13-1 8.

   

27.       "Reactions of Organocyclopropanes and Spirocycles with Metal Atoms", Gladysz, J. A.; Fulcher, J. G.; Ugolick, R. C.; Hanlan, A. J. L.; Bocarsly, A. B. J. Am. Chem. Soc. 1979, 101, 3388-3390. [PDF]

   

28.       "Simplified in situ Syntheses of Anhydrous HMn(CO)5", Gladysz, J. A.; Tam, W.; Will­iams, G. M.; Johnson, D. L.; Parker, D. W. Inorg. Chem. 1979, 18, 1163-1165. [PDF]

   

29.       "X-Ray Crystal Structure and Chemical Transformations of the Neutral Metal Formyl (η5-C5H5)Re(PPh3)(NO)(CHO)", Wong, W.-K; Tam, W.; Strouse, C. E.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1979, 530-531. [PDF]

   

30.       "Squeezing the Transition State", Gladysz, J. A. CHEMTECH 1979, 9, 372-377.

   

31.       "Electrophile Induced Disproportionation of the Neutral For (η5-C5H5)Re(PPh3)(NO)(CHO); Generation of Cationic Rhenium Carbenes of the Formula [(η5-C5H5)Re(NO)(PPh3)(CHX)]+ (X = H, OCH3, OH)", Wong, W.-K; Tam, W.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 5440-5442. [PDF]

   

32.       "New Methodology for the Introduction of Sulfur into Organic Molecules; Synthesis of An­hydrous Li2S, Li2S2 and LiSR Species by Lithium Triethylborohydride Reduction of Elemental Sulfur and Disulfides", Gladysz, J. A.; Wong, V. K.; Jick, B. S. Tetrahedron 1979, 35, 2329-2335. [PDF]

   

33.       "Reactions of Benzaldehyde with Trialkylsilyl Metal Carbonyl Complexes", Johnson, D. L.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 6433-6435. [PDF]

   

34.       "Substitution Mechanisms at Metal Carbonyl Centers; Conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an Anionic Acyl Intermediate", Parker, D. W.; Marsi, M. M.; Glad­ysz, J. A. J. Organomet. Chem. 1980, 194, C1-C4. [PDF]

   

35.       "Deoxygenation and Desulfurization of Organic Compounds via Transition Metal Atom Co­condensation", Togashi, S.; Fulcher, J. C.; Cho, B.-R.; Hasegawa, M.; Gladysz, J. A. J. Org. Chem. 1980, 45, 3044-3053. [PDF]

   

36.       "Unprecedented Regiospecificity and Stereospecificity in Reactions of Ph3C+PF6- with Rhenium Alkyls of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2R)", Kiel, W. A.; Lin, G.-Y.; Gladysz, J. A. J. Am. Chem. Soc. 1980, 102, 3299-3301. [PDF]

   

37.       "Chemistry via Metal Atom Cocondensation: Isomerization and Complexation Reactions of Organocyclopropanes and Spirocycles", Hanlan, A. J. L.; Ugolick, R. C.; Fulcher, J. G.; To­gashi, S.; Bocarsly, A. B.; Gladysz, J. A. Inorg. Chem. 1980, 19, 1543-1551. [PDF]

   

38.       "Stereospecific and Chemospecific Interconversions of the Rhenium Alkylidene [(η5-C5H5)­Re(NO)(PPh3)(CHC6H5)]+ PF6- and the Alkylrhenium (η5-C5H5)Re(NO)(PPh3(CH(OCH3)­C6H5)", Constable, A. G.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, C21-C24. [PDF]

   

39.       "New Methods for Metal-Carbon Bond Formation: Reactions of (CO)5MnSi(CH3)3 with Cyc­lic Ethers", Brinkman, K. C.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1980, 1260-1261. [PDF]

   

40.       "Preparation and Properties of (η5-C5H5)2ZrCl[Si(CH3)3] and (η5-C5H5)2Zr[Si(CH3)3]2: Tri­methylsilyl Group Transfer from Mercury to Zirconium", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, 263-268. [PDF]

   

41.       "Preparation and Alkylation Reactions of K+[(CO)4FeSi(CH3)]-; Reductive Elimination of Tetramethylsilane and Benzyl Trimethylsilane from Isolable (CO)4FeRSi(CH3)3 Complexes", Blakeney, A. J.; Gladysz, J. A. Inorg. Chim. Acta 1981, 53, L25-L27.

   

42.       "Mononuclear Anionic Formyl Complexes; Synthesis and Properties", Selover, J. C.; Marsi, M.; Parker, D. W.; Gladysz, J. A. J. Organomet. Chem. 1981, 206, 317-329. [PDF]

   

43.       "Nickel and Palladium Complexes in the Synthesis of Macrocyclic Compounds", Halweg, K. M.; Gladysz, J. A. The Strem Chemiker 1981, 9, 7-14.

   

44.       "Electrophile Induced Disproportionation of the Neutral Formyl (η5-C5H5)Re(NO)(PPh3)­(CHO); Isolation and Properties of the Rhenium Methylidene [(η5-C5H5)Re(NO)(PPh3)(CH2)]+ PF6-", Gladysz, J. A.; Kiel, W. A.; Lin, G.-Y.; Wong, W.-K.; Tam, W. ACS Symposium Series 1981, 152, 147-164. [PDF]

   

45.       "New Deoxygenative Transformations: Reactions of (CO)4Fe[Si(CH3)3]2 with Acyclic Ethers", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1981, 210, 303-312. [PDF]

   

46.       "Reactions of (CO)5MnSi(CH3)3 with Organic Carbonyl Compounds", Johnson, D. L.; Gladysz, J. A. Inorg. Chem. 1981, 20, 2508-2515. [PDF]

   

47.       "Exploratory Organometal-Sulfur Chemistry: Syntheses and Unusual Properties of Rhenium -CH2SR, -CH2S+RR' and =CHSR]+ Complexes", McCormick, F. B.; Gladysz, J. A. J. Or­ganomet. Chem. 1981, 218, C57-C61. [PDF]

   

48.       "Three Rational Syntheses of New Stable Metal a-Hydroxyalkyl Complexes", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1981, 103, 5608-5609. [PDF]

   

49.       "Synthesis of Iron Carbonyl Trimethylsilanes; Preparations and Interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+ [(CO)4FeSi(CH3)3]-, and trans-[Fe(CO)4Si(CH3)3]2", Blakeney, A. J.; Johnson, D. L.; Donovan, P. W.; Gladysz, J. A. Inorg. Chem. 1981, 20, 4415-4419. [PDF]

   

50.       "Synthesis and Electrophile Induced Disproportionation of the Neutral Formyl (η5-C5H5)Re­(NO)(PPh3)CHO)", Tam, W.; Lin, G.-Y.; Wong, W.-K.; Kiel, W. A.; Wong, V. K.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 141-152. [PDF]

   

51.       "A New Organometallic Photoreaction: Interconversion of Metal-Alkylidene Geometric Isomers", McCormick, F. B.; Kiel, W. A.; Gladysz, J. A. Organometallics 1982, 1, 405-408. [PDF]

   

52.       "Organic Transformations via Metal Silane Reagents: Syntheses of Vinyl Ethers from Dimethyl Ketals and (CO)5MnSi(CH3)3", Marsi, M.; Gladysz, J. A. Tetrahedron Lett. 1982, 23, 631-634. [PDF]

   

53.       "Syntheses of Kinetically Unstable Neutral Formyl Complexes via Li(C2H5)3BH and 'Transformylation' Reactions of Metal Carbonyl Cations", Tam, W.; Lin, G.-Y.; Gladysz, J. A. Organometallics 1982, 1, 525-529. [PDF]

   

54.       "Transition Metal Formyl Complexes", Gladysz, J. A. Adv. Organomet. Chem. 1982, 23, 1-38. [PDF]

   

55.       "Substituent Effects upon Alkyl Migration to Coordinated CO: Syntheses and Carbonylation Studies of (CO)5MnCH2I and (CO)5MnCH2OSi(CH3)3", Brinkman, K. C.; Vaughn, G. D.; Gladysz, J. A. Organometallics 1982, 1, 1056-1060. [PDF]

   

56.       "Synthesis and Properties of [(η5-C5H5)Re­(NO)(PPh3)(=CHC6H5)]+ PF6-: A Benzylidene Complex that is Formed by a Stereospecific a-Hydride Abstraction, Exists as Two Geometric Isomers, and Undergoes Stereospecific Nucleophilic Attack", Kiel, W. A.; Lin, G.-Y.; Constable, A. G.; McCormick, F. B.; Strouse, C. E.; Eisenstein, O.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4865-4878. [PDF]

   

57.       "Synthesis, Optical Resolution, and Absolute Configuration of Pseudotetrahedral Organo­rhenium Complexes (η5-C5H5)Re­(NO)(PPh3)(X)", Merrifield, J. H.; Strouse, C. E.; Gladysz, J. A. Organometallics 1982, 1, 1204-1211. [PDF]

   

58.       "Syntheses and Reactions of Rhenium Vinylidene and Acetylide Complexes; Unprecedent­ed Chirality Transfer through a C-C Triple Bond", Wong, A.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4948-4950. [PDF]

   

59.       "Reactions of Ketals and Acetals with (CO)5MnSi(CH3)3; A New Vinyl Ether Synthesis", Marsi, M.; Gladysz, J. A. Organometallics 1982, 1, 1467-1473. [PDF]

   

60.       "Synthesis, Chemical Properties, and X-ray Crystal Structures of Rhenium Formaldehyde and Thioformaldehyde Complexes", Buhro, W. E.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A.; McCormick, F. B.; Etter, M. C. J. Am. Chem. Soc. 1983, 105, 1056-1058. [PDF]

   

61.       "Bimetallic Anionic Formyl Complexes; Synthesis and Properties", Tam, W.; Marsi, M.; Gladysz, J. A. Inorg. Chem. 1983, 22, 1413-1421. [PDF]

   

62.       "Synthesis and Decarboxylation Mechanism of the Chiral Rhenium Formate (η5-C5H5)Re­(NO)(PPh3)(OCHO)", Merrifield, J. H.; Gladysz, J. A. Organometallics 1983, 2, 782-784. [PDF]

   

63.       "Regiospecific and Stereospecific Reactions of Ph3C+ PF6- with Rhenium Alkyls (η5-C5H5)Re(NO)(PPh3)(R); a vs ß Hydride Abstraction", Kiel, W. A.; Lin, G.-Y.; Bodner, G. S.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 4958-4972. [PDF]

   

64.       "Syntheses, Properties and X-ray Crystal Structures of Stable Methylidene Complexes of the Formula [(η5-C5H5)Re­(NO)(L)(=CH2)]+ PF6-", Patton, A. T.; Strouse, C. E.; Knobler, C. B.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5804-5811. [PDF]

   

65.       " Mechanism of Coupling of =CH2 to H2C=CH2 at a Homogeneous (η5-C5H5)Re(NO)(PPh3)+ Center; Remarkable Enantiomer Self-Recognition", Merrifield, J. H.; Lin, G.-Y.; Kiel, W. A.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5811-5819. [PDF]

   

66.       "Synthesis and Chemistry of Chiral Vinyl Rhenium Complexes (η5-C5H5)Re­(NO)(PPh3)­(CH=CHR). Stereoselective Reactions with Electrophiles and a Spontaneous Alkylidene to Olefin Rearrangement", Hatton, W. G.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 6157-6158. [PDF]

   

67.       "Atomos de Metales de Transicion en la Sintesis y la Catalisis Organica", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Rev. Soc. Quim. Mex. 1983, 27, 146-148.

   

68.       "A New Route to Metal Alkylidene Complexes; Synthesis of Ylide Adducts (CO)4FeCH­(R)P+Ar3 from Aldehydes, Triarylphosphines, and (CO)4FeSi(CH3)2CH2CH2Si(CH3)2", Nakazawa, H.; Johnson, D. L.; Gladysz, J. A. Organometallics 1983, 2, 1846-1851. [PDF]

   

69.       "Synthesis and Chemistry of Chiral Rhenium Acyls (η5-C5H5)Re­(NO)(PPh3)(COR)", Buhro, W. E.; Wong, A.; Merrifield, J. H.; Lin, G.-Y.; Constable, A. G.; Gladysz, J. A. Organo­metallics 1983, 2, 1852-1859. [PDF]

   

70.       "Reactions of (CO)5MnSi(CH3)3 and CO with Aldehydes and Cyclic Ethers; Syntheses of Functionalized Pentacarbonyl Manganese Acyls and Homologated Organic Compounds", Brinkman, K. C.; Gladysz, J. A. Organometallics 1984, 3, 147-155.[PDF]

   

71.       (a) "Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese. Synthesis of Ylide Complexes (CO)4MnCR(OSiMe3)PPh2 and a New Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1984, 23, 245-246. [PDF]

            (b) "Reaktionen von Diphenyl(trimethylsilyl)phosphan mit Alkyl(pentacarbonyl)mangan; Synthese der Ylidkomplexe (CO)4MnCR(OSiMe3)PPh2 unter Beteiligung einer CO-Ein­schiebung", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem. 1984, 96, 230-231.

   

72.       "Reaction of Benzylrhenium Complexes (η5-C5H5)Re­(NO)(L)(CH2Ar) with Ph3C+PF6-; Analysis of the Re-Ca Rotamers Involved in a-Hydride Abstraction", Kiel, W. A.; Buhro, W. E.; Gladysz, J. A. Organometallics 1984, 3, 879-886. [PDF]

   

73.       "Alkylation and Acylation of the Iron Carbonyl Anion [(CO)4FeSi(CH3)3]-. Evidence for 1,3-Silatropic Shifts from Iron to Acyl Oxygen", Brinkman, K. C.; Blakeney, A. J.; Krone-Schmidt, W.; Gladysz, J. A. Organometallics 1984, 3, 1325-1332. [PDF]

   

74.       "New Synthetic Chemistry of Transition Metal Trialkylsilane Complexes", Gladysz, J. A. Acc. Chem. Res. 1984, 17, 326-332. [PDF]

   

75.       "Reactions of Phosphorus Electrophiles with [(η5-C5Me5)Fe(CO)2]-: Spectroscopic Evid­ence for a Phosphinidene Complex", Nakazawa, H.; Buhro, W. E.; Bertrand, G.; Gladysz, J. A. Inorg. Chem. 1984, 23, 3431-3433.[PDF]

   

76.       "Hydrogen Bonding in Organometallic Ligands and Possible Implications for CO/H2 Chem­istry: First Carbonylation of an Isolable Metal a-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. Organometallics 1984, 3, 1596-1598. [PDF]

   

77.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds, 1. Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Gladysz, J. A. J. Am. Chem. Soc. 1984, 106, 7636-7637. [PDF]

   

78.       "Cleavage of Rhenium-Methyl Bond of(η5-C5H5)Re­(NO)(PPh3)(CH3) by Protic and Halo­gen Electrophiles; Stereochemistry at Rhenium", Merrifield, J. H.; Fernández, J. M.; Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1984, 23, 4022-4029. [PDF]

 

79.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds. Reactions of the Hydride Complex (η5-C5H5)Re(NO)(PPh3)(H) with n-Butyl-lithium-Tetramethylethyl­enediamine", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1985, 283-284. [PDF]

   

80.       "Electrochemical Oxidation of Rhenium Alkyl Complexes [Re(η5-C5H5)(NO)(PPh3)R]; Implications for the Mechanism of Hydride Abstraction by Ph3C+ PF6-", Asaro, M. F.; Bod­ner, G. S.; Gladysz, J. A.; Cooper, S. R.; Cooper N. J. Organometallics 1985, 4, 1020-1024. [PDF]

 

81.       "Synthesis, Conformation, and Reactivity of the Rhenium Phosphide Complex (η5-C5H5)Re­(NO)(PPh3)(PPh2). The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 3346-3348. [PDF]

   

82.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds, III. The First Carbon-Carbon Bond-Forming Reaction of an η1-Formyl Ligand", Heah, P. C.; Gladysz, J. A. J. Mol. Cat. 1985, 31, 207-209. [Link]

 

83.       "Reactions of Cyanomethyl Complex (η5-C5H5)Re­(NO)(PPh3)(CH2CN) with n-BuLi/ TMEDA; Generation, Stereospecific Alkylation, and Basicity of a Transition Metal Substi­tuted Carbanion", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 4103-4104. [PDF]

   

84.       "Reactions of Chiral a-Methoxyvinyl Rhenium Complexes (η5-C5H5)Re­(NO)(PPh3)(C­(OCH3)=CHR) with Alkyl Halides; Efficient 1,3-Asymmetric Induction", Smith, D. E.; Gladysz, J. A. Organometallics 1985, 4, 1480-1481. [PDF]

   

85.       "Reactions of (CO)5MnSi(CH3)3 with a-Bromocarbonyl and Related Organic Compounds; Facile Reductive Silylation", Marsi, M.; Brinkman, K. C.; Lisensky, C. A.; Vaughn, G. D.; Gladysz, J. A. J. Org. Chem. 1985, 50, 3396-3401. [PDF]

   

86.       "Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal PhosphideComplexes (η5-C5H5)Re­(NO)(PPh3)(PRR')", Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1985, 24, 3505-3507. [PDF]

 

87.       "Reactions of Organorhenium Complexes (η5-C5H5)Re­(NO)(PPh3)(CH2R) with Ph3C+ PF6-; Analysis of the Energetics of a-Hydride Abstraction", Georgiou, S.; Gladysz, J. A. Tetrahedron 1986, 42, 1109-1116. [PDF]

   

88.       "Deprotonation and Anionic Rearrangements of Organometallic Compounds. V. Kinetic vs Thermodynamic Deprotonation in Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Patton, A. T.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1185-1195. [PDF]

   

89.       "Synthesis and Reactivity of Metal a-Hydroxyalkyl Complexes; Generation of (CO)5MCH­(C6H5)OH (M = Mn, Re)", Selover, J. C.; Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1455-1462. [PDF]

   

90.       "Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium a-Hydroxyalkyl Complexes of the Formula (CO)4MP(C6H5)2)(o-C6H4CHOH)", Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1462-1473. [PDF]

   

91.       "Synthesis and Reactivity of Metallacyclic Manganese a-Hydroxyalkyl Complexes Con­taining Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms; First Carbonylation of an Isolable a-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1473-1480. [PDF]

   

92.       "Synthesis and Reactivity of Metallacyclic Manganese a-(Silyloxy)alkyl Complexes (CO)4­MnC(R)(OSi(CH3)3)P(C6H5)2; A New Thermodynamic Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Organometallics 1986, 5, 936-942. [PDF]

   

93.       "Synthesis, Structure, and Reactivity of the Formaldehyde Complex [(η5-C5H5)Re­(NO)(PPh3)(η2-H2C=O)]+ PF6-", Buhro, W. E.; Georgiou, S.; Fernández, J. M.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A. Organometallics 1986, 5, 956-965. [PDF]

   

94.       "Generation and Reactions of Chiral, Pyramidal, Transition Metal Lewis Acids of the Form­ula [(η5-C5H5)Re­(NO)(PPh3)]+ X-", Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1986, 25, 2672-2674.

   

95.       "Reaction of Ylide Complex [(η5-C5H5)Re(NO)(PPh3)(CH2PAr3)]+ PF6- with n-Butyl-lithium-Tetramethylethylenediamine: Generation and Stereospecific Alkylation of a Transition-Metal-Substituted-Wittig Reagent", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1986, 1154-1156. [PDF]

   

96.       "Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts [(η5-C5H5)Re­(NO)(PPh3)(CH2)]nS+(CH3)3-n (n = 1,2,3)", McCormick, F. B.; Gleason, W. B.; Zhao, X.; Heah, P. C.; Gladysz, J. A. Organometallics 1986, 5, 1778-1785. [PDF]

   

97.       "A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes [(η5-C5H5)Re­(NO)(PPh3)(η2-RCH=O)]+ PF6-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 8268-8270. [PDF]

   

98.       "Novel Electron Impact-Induced Hydrogen Rearrangements in the Mass Spectra of Organo­rhenium Hydrides and Alkyls", Crocco, G. L.; Sharp, T. L.; Gladysz J. A. Int. J. Mass. Spec­trum. Ion. Phys. 1986, 73, 181-185. [PDF]

   

99.       "New Mechanistic Probes of Hydride Abstraction from Rhenium Alkyl Complexes (η5-C5H5)Re­(NO)(PPh3)(R) by Ph3C+ PF6-; Evidence for Initial Electron Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 1757-1764. [PDF]

   

100.     "Synthesis, Structure, and Reactivity of the Thioformaldehyde Complex [(η5-C5H5)Re­(NO)(PPh3)(η2-H2C=S)]+ PF6-", Buhro, W. E.; Etter, M. C.; Georgiou, S.; Gladysz, J. A.; McCormick, F. B. Organometallics 1987, 6, 1150-1156. [PDF]

   

101.     "A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups; Stereoche­mistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η5-C5H5)Re­(NO)(PPh3)(R)", O'Connor, E. J.; Kobayashi, M.; Floss, H. G.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 4837-4844. [PDF]

   

102.     "Electrochemical Oxidation of Rhenium Alkyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(R): Evidence for One Electron Charge Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. Organometallics 1987, 6, 1628-1633. [PDF]

   

103.     "Synthesis, Structure, and Reactivity of Transition Metal/Main Group Metal Bridging Carb­oxylate Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb)", Senn, D. R.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Inorg. Chem. 1987, 26, 2737-2739. [PDF]

   

104.     (a) "A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon A Chiral Rhenium Template Containing Two Phosphido Substituents", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1987, 26, 910-912. [PDF]

            (b) "Ein neuartiger heterodinuclearer Katalysator für die asymmetrische Hydrierung ein Bis­phosphido-Ligand mit einem stereogenen Rheniumzentrum", Zwick, B. D.; Arif, A. M.; Pat­ton, A. T.; Gladysz, J. A. Angew. Chem. 1987, 99, 921-922.

   

105.     "Crystallographic and Theoretical Analyses of the Structures of Rhenium Formyl and Acyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(COR)", Bodner, G. S.; Patton, A. T.; Smith, D. E.; Georgiou, S.; Tam, W.; Wong, W.- K.; Strouse, C. E.; Gladysz, J. A. Organ­ometallics 1987, 6, 1954-1961. [PDF]

   

106.     "A New Method for the Activation of Metal-Bound Methyl Groups; Oxidative Dispropor­tionation to Coordinated Ethylene and Methane", Tilset, M.; Bodner, G. S.; Senn, D. R.; Gladysz, J. A.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 7551-7553. [PDF]

   

107.     "A General Class of Stable Alkyl Halide Complexes; Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(IR)]+ BF4-", Winter, C. H.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7560-7561. [PDF]

   

108.     "Synthesis, Structure, and Alkylation of Chiral Vinyl Rhenium Complexes (η5-C5H5)Re­(NO)(PPh3)(CX=CHR) (X = H, OCH3). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium To Carbon", Bodner, G. S.; Smith, D. E.; Hatton, W. G.; Heah, P. C.; Geor­giou, S.; Rheingold, A. L.; Geib, S. J.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7688-7705. [PDF]

   

109.     "The Selective Activation of One Ketone Enantioface via s-Binding to a Chiral Metal Template: Synthesis and Reactivity of Rhenium Ketone Complexes [(η5-C5H5)Re­(NO)(PPh3)(η1-RR'C=O)]+ PF6-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1988, 37-39. [PDF]

   

110.     "Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η5-C5H5)Re­(NO)(PPh3)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands", Crocco, G. L.; Gladysz, J. A. Chem. Ber. 1988, 121, 375-377. [PDF]

   

111.     "Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphide Complexes (η5-C5H5)Re­(NO)(PPh3)(PR2): The "Gauche Effect" in Transition Metal Chemistry", Buh­ro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439. [PDF]

   

112.     "Aldehyde and Ketone Ligands in Organometallic Complexes and Catalysis", Huang, Y.-H.; Gladysz, J. A. J. Chem. Ed. 1988, 65, 298-303. [PDF]

   

113.     "Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]", Bodner, G. S.; Fernández, J. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 4082-4084. [PDF]

   

114.     "Synthesis and Reactivity of Functionalized Rhenium Germyl Complexes (η5-C5H5)Re­(NO)(PPh3)(GePh2X); Dynamic Equilibria with Germylene Complex [(η5-C5H5)Re­(NO)(PPh3)(=GePh2)]+ X-", Lee, K. E.; Gladysz, J. A. Polyhedron 1988, 7, 2209-2211. [PDF]

   

115.     "Synthesis, Structure, and Reactions of Chiral Rhenium Vinylidene and Acetylide Complex­es of the Formula [(η5-C5H5)Re­(NO)(PPh3)(X)]n+; Vinylidene Complexes that are Formed by Stereospecific Cß Electrophilic Attack, Exist as Two Re=C=C Geometric Isomers, and Undergo Stereospecific Nucleophilic Ca Attack", Senn, D. R.; Wong, A.; Patton, A. T.; Marsi, M.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6096-6109. [PDF]

   

116.     "Divergent Kinetic and Thermodynamic Acidity in Organotransition-Metal Hydride Com­plexes; Synthesis, Structure, and Reactivity of the Rhenium Anion Li+ [(η5-C5H5)Re­(NO)(PPh3)]-", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6110-6118. [PDF]

   

117.     "Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η5-C5H5)Re­(NO)(PPh3)(SiR2X). Anionic Rearrangements Leading to the New Disilametallacycle ((η5-C5H4Si)Re(NO)(PPh3)Si(CH3)2)", Crocco, G. L.; Young, C. S.; Lee, K. E.; Gladysz, J. A. Organometallics 1988, 7, 2158-2162. [PDF]

   

118.     "Generation of the Dichloromethane Complex [(η5-C5H5)Re­(NO)(PPh3)(ClCH2Cl)]+ BF4-, and its Conversion to the Oxidative Addition Product [(η5-C5H5)Re­(NO)(PPh3)(Cl)(CH2­Cl)]+ BF4-", Winter, C. H.; Gladysz, J. A. J. Organomet. Chem. 1988, 354, C33-C36. [PDF]

   

119.     "Synthetic Approaches to the Chiral, Pyramidal, Transition Metal Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+ X-; Generation, Characterization, and Reactions of a Dichloromethane Ad­duct", Fernández, J. M.; Gladysz, J. A. Organometallics 1989, 8, 207-219. [PDF]

   

120.     "Synthesis, Structure, and Reactivity of Bridging Halide Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)]2X+ BF4-; Preferential Binding of One Enantiomer of Halide Com­plexes (η5-C5H5)Re­(NO)(PPh3)(X) by the Chiral Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+", Winter, C. H.; Arif, A. M.; Gladysz, J. A. Organometallics 1989, 8, 219-225. [PDF]

   

121.     "Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+ by K(s-C4H9)3BH; Synthesis of Optically Active Secondary Alcohols and Derivatives", Dalton, D. M.; Gladysz, J. A. J. Organomet. Chem. 1989, 370, C17-C21. [PDF]

   

122.     "Synthesis, Structure and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the For­mula [(η5-C5H5)Re(NO)(PPh3)(IR)]+ BF4-", Winter, C. H.; Veal, W. R.; Garner, C. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1989, 111, 4766-4776. [PDF]

   

123.     "The Role of Virtual Halogen d Orbitals in the Stability and Reactivity of Rhenium Alkyl-Halide Complexes of the Form [(η5-C5H5)Re­(NO)(PPh3)(XR)]+", Czech, P. T.; Gladysz, J. A.; Fenske, R. F. Organometallics 1989, 8, 1806-1810. [PDF]

   

124.     "Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae [(η5-C5H5)Re­(NO)(PPh3)(η2-O=CHR)]+ BF4-; A New Synthesis of Optically Active Cyanohydrin Derivatives", Garner, C. M.; Fernández, J. M.; Gladysz, J. A. Tetrahed­ron Lett. 1989, 30, 3931-3934. [PDF]

   

125.     "Synthesis and Reactivity of Functionalized Rhenium Phosphido Complexes (η5-C5H5)Re­(NO)(PPh3)(PXX'). An Unusual CCl4 1,3-Addition Leading to an Exo-Substituted η4-Cyclopentadiene Complex", Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1989, 28, 3837-3845. [PDF]

   

126.     "Synthesis and Structure of Chiral Rhenium Allyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(CH2C(R')=CHR)", Bodner, G. S.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Organometallics 1989, 8, 2399-2404. [PDF]

   

127.     "Tetracarbonyl{[2-(diphenylphosphino) phenyl]hydroxymethyl-C,P}manganese", Vaughn, G. D.; Gladysz, J. A. Inorg. Synth. 1989, 26, 169-171. [PDF]

   

128.     "Optical Resolution and Absolute Configuration of the Chiral Pentamethylcyclopentadienyl Rhenium Carbonyl Complex [(η5-C5H5)Re­(NO)(PPh3)(CO)]+ BF4-", Huang, Y.-H.; Nied­ercorn, F.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 383, 213-225. [PDF]

   

129.     "Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(OR2)]+ X-", Agbossou, S. K.; Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 476-480. [PDF]

   

130.     "Synthesis and Structure of s-Pyridine, Quinoline, and Isoquinoline Complexes of the For­mula [(η5-C5H5)Re­(NO)(PPh3)(NCxHy)]+ CF3SO3-", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 384, C29-C32. [PDF]

   

131.     "Synthesis, Structure, and Reactivity of the Chiral Rhenium Phenyl Complex (η5-C5H5)Re­(NO)(PPh3)(C6H5)", Agbossou, S. K.; Bodner, G. S.; Patton, A. T.; Gladysz, J. A. Organ­ometallics 1990, 9, 1184-1191. [PDF]

   

132.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkene Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+ X-", Bodner, G. S.; Peng, T.-S.; Arif, A. M.; Glad­ysz, J. A. Organometallics 1990, 9, 1191-1205. [PDF]

   

133.     "Isomerization of Diastereomeric Alkene Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+; the Alkene Enantioface Bound to the Metal can "Flip" Without Alkene Dissociation", Peng, T.-S.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1990, 902-903. [Link]

   

134.     "Synthesis and Reactivity of Chiral Rhenium Amine and Amide Complexes of the Formulas [(η5-C5H5)Re­(NO)(PPh3)(NHRR')]+ TfO- and (η5-C5H5)Re­(NO)(PPh3)(NRR')", Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1349-1351. [PDF]

   

135.     "Mechanism of Equilibration of Diastereomeric Rhenium Amide Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(NHCHRR'); Rhenium vs Carbon Epimerization", Dewey, M. A.; Gladysz, J. A. Organometallics 1990, 9, 1351-1353. [PDF]

   

136.     "Selective Binding of One Aldehyde Enantioface by a Chiral Transition Metal Lewis Acid: Synthesis, Structure and Reactivity of Rhenium Aldehyde Complexes [(η5-C5H5)Re­(NO)(PPh3)(η2-O=CHR)]+ X-", Garner, C. M.; Quirós Méndez, N.; Kowalczyk, J. J.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 5146-5160. [PDF]

   

137.     "Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(ROH)]+ BF4-", Agbossou, S. K.; Smith, W. W.; Gladysz, J. A. Chem. Ber. 1990, 123, 1293-1299. [PDF]

   

138.     "Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions to Chiral Mo­nosubstituted Alkene Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Gladysz, J. A. Tetrahedron Lett. 1990, 31, 4417-4420. [PDF]

   

139.     "Synthesis, Structure, and Reactivity of the Nitrosyl Ligand/Lewis Acid Adduct (η5-C5H5)Re­(NO.BCl3)(PPh3)(SiMe2Cl)", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 2885-2887. [PDF]

   

140.     "Reactions of Cyanomethyl Complex (η5-C5H5)Re­(NO)(PPh3)(CH2CN) and Ylide Com­plex [(η5-C5H5)Re­(NO)(PPh3)(CH2P(p-tol)3)]+ PF6- with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of Transition-Metal-Substituted Carbanions and Ylides", Crocco, G. L.; Lee, K. E.; Gladysz, J. A. Organometallics 1990, 9, 2819-2831. [PDF]

   

141.     "Generation and Reactivity of the Chiral Rhenium Chlorobenzene Complex [(η5-C5H5)Re­(NO)(PPh3)(ClC6H5)]+ BF4-: An Improved Functional Equivalent of the Chiral Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+ BF4-", Kowalczyk, J. J.; Agbossou, S. K.; Gladysz, J. A. J. Organomet. Chem. 1990, 397, 333-346. [PDF]

   

142.     "A New Carbon-Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+ BF4- by the Base t-BuO- K+", Peng, T.-S.; Gladysz, J. A. Organometallics 1990, 9, 2884-2886. [PDF]

   

143.          "Selective Activation of One Methyl Ketone Enantioface via s-Binding to a Chiral Transition Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes [(η5-C5H5)Re­(NO)(PPh3)(η1-O=C(CH3)R]+ X-", Dalton, D. M.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 9198-9212. [PDF]

   

144.     (a) "π/s Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Aromatic Aldehyde Complexes [(η5-C5H5)Re­(NO)(PPh3)(O=CHAr)]+ X-", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1473-1474. [PDF]

            (b) "π/s-Gleichgewichte in Metall-Komplexen organischer Carbonylverbindungen; Syn­these und Struktur chiraler Rhenium-Komplexe [(η5-C5H5)Re­(NO)(PPh3)(O=CHAr)]X", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1990, 102, 1507-1509.

 

145.     (a) "Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes [(η5-C5H5)Re­(NO)(PPh3)(η2-O=CHAr)]+ BF4-", Quirós Méndez, N.; Mayne, C. L.; Glad­ysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1475-1476. [PDF]

            (b) "Thermodynamisch kontrollierte enantiofaciale Selektivität bei der Bindung von Alde­hyden an chirale Metall-Komplexfragmente, der Mechanismus der Interkonversion diaster­eomerer π-Aldehyd-Komplexe [(η5-C5H5)Re­(NO)(PPh3)(η2-O=CHAr)]BF4", Quirós Mén­dez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem. 1990, 102, 1509-1511.

   

146.     "Synthesis, Structure, and Reactivity of Functionalized Germyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(GePh2X); Equilibria Involving the Germylene Complex [(η5-C5H5)Re­(NO)(PPh3)(=GePh2)]+ TfO-", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Organometal­lics 1991, 10, 751-760. [Link]

   

147.     "Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(SiMe2X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base-Free Silylene Complexes", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 309-320 (1991). [PDF]

   

148.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkyne Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(RC-CR')]+ BF4-", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079-1088. [PDF]

   

149.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the For­mula [(η5-C5H5)Re­(NO)(PPh3)(CH=CH(CH2)n-2)]+ BF4-; Facile Vinylic Deprotonation of a Coordinated Alkene", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 729-742. [PDF]

   

150.     "Delocalized Electronic Interactions in Chiral Cyclopentadienyl Rhenium Halide Complexes. The Valence Photoelectron Spectra of the Formula CpRe(NO)(L)X", Lichten­berger, D. L.; Rai-Chaudhuri, A. R.; Seidel, M. J.; Gladysz, J. A.; Agbossou, S. K.; Igau, A.; Winter, C. H. Organometallics 1991, 10, 1355-1364. [PDF]

   

151.     "Synthesis and Structure of the Rhenium Phenylamido Complex (η5-C5H5)Re(NO)(PPh3)(NHPh); An Unprecedented Pyramidal Amido Ligand", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 712-714. [PDF]

   

152.     "Facile Separations of Enantiomers of Chiral Organometallic Compounds with A Baker­bond Chiralcel HPLC Column", Ramsden, J. A.; Garner, C. M.; Gladysz, J. A. Organomet­allics 1991, 10, 1631-1633. [PDF]

   

153.     "π/s Equilibria in Rhenium Ketone Complexes [(η5-C5H5)Re­(NO)(PPh3)(O=CRR')]+ X-; A Marked Electronic Effect Upon the Binding Mode", Klein, D. P.; Dalton, D. M.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1991, 412, C7-C10. [PDF]

   

154.     "Synthesis, Structure, and Dynamic Behavior of Rhenium Sulfide and Sulfoxide Complexes of the Formula [(η5-C5H5)Re­(NO)(L)(XRR')]+ X'- (X = S, SO)", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 2199-2209. [PDF]

   

155.    "Reactions of the Neohexyl Iodide Complex [(η5-C5H5)Re­(NO)(PPh3)(ICH2CH2C­(CH3)3)]+ BF4- and Nucleophiles; Stereochemistry of Carbon-Iodine Bond Cleavage in Highly Accelerated SN2 Reactions", Igau, A.; Gladysz, J. A. Organometallics 1991, 10, 2327-2334. [PDF]

   

156.     "Reactions of the Terminal Rhenium Acetylide Complex Re(η5-C5H5)(NO)(PPh3)(C-CH) and Butyllithium; Generation, Alkylation, and Stannylation of Lithiocarbide Complexes of the Formula Re(η5-C5H5)(NO)(PPh3)(C-CLi) (X = H, Li)", Ramsden, J. A.; Agbossou, F.; Senn, D. R.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 1360-1362. [Link]

   

157.     "A New Catalyst for the Epimerization of Secondary Alcohols; Carbon-Hydrogen Bond Ac­tivation in the Rhenium Alkoxide Complexes (η5-C5H5)Re­(NO)(PPh3)(OCHRR')", Saura-Llamas, I.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 2533-2535. [PDF]

   

158.     "Synthesis and Characterization of Chiral Rhenium s-Ketone Complexes. Binding Proper­ties of Symmetrical Ketones and Alkylcyclohexanones", Dalton, D. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1991, 2741-2747.

   

159.     "Mechanism of Isomerization of Alkylidene Complexes [(η5-C5H5)Re­(NO)(PPh3)(=CH­CHRR')]+ X- to Alkene Complexes [(η5-C5H5)Re­(NO)(PPh3)(H2C=CRR')]+ X-: An Organometallic Wagner-Meerwein-Type Rearrangement", Roger, C.; Bodner, G. S.; Hatton, W. G.; Gladysz, J. A. Organometallics 1991, 10, 3266-3274. [PDF]

   

160.     "A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives; Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(O=CRR')]+ BF4-", Dalton, D. M.; Garner, C. M.; Fernández, J. M.; Gladysz, J. A. J. Org. Chem. 1991, 56, 6823-6829. [PDF]

   

161.     "Synthesis and Chemistry of Secondary Alkyl Iodide Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(ICHRR')]+ BF4-", Igau, A.; Gladysz, J. A. Polyhedron 1991, 10, 1903-1909. [PDF]

   

162.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Amine Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(NRR'R")]+ TfO-", Dewey, M. A.; Knight, D. A.; Klein, D. P.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1991, 30, 4995-5002. [PDF]

   

163.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Carboxylic and Carbonic Acid Ester Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(η1-O=C(X)X')]+ X-", Saura-Llamas, I.; Dalton, D. M.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 683-693. [PDF]

   

164.     "Synthesis, Structure, and Reactivity of (Pentamethylcyclopentadienyl)Rhenium Aldehyde Complexes [(η5-C5Me5)Re­(NO)(PPh3)(η2-O=CHR)]+ BF4-: Highly Diastereoselective Deuteride Additions", Agbossou, F.; Ramsden, J. A.; Huang, Y.-H.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 693-701. [PDF]

   

165.     "Epimerization of Secondary Alcohols by New Homogeneous, Low Oxidation State Metal Catalysts: Carbon-Hydrogen Bond Activation in Rhenium Alkoxide Complexes (η5-C5H5)Re­(NO)(PPh3)(OCHRR')", Saura-Llamas, I.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 2136-2144. [PDF]

   

166.     "Synthesis and Reactivity of Chiral Metal Fluoride and Water Complexes Derived from the Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+", Agbossou, S. K.; Roger, C.; Igau, A.; Gladysz, J. A. Inorg. Chem. 1992, 31, 419-424. [Link]

 

167.     "Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition Metal Lewis Acid; Equilibration of Diastereomeric (Cyclo­pentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Helv. Chim. Acta 1992, 75, 442-456. [PDF]

   

168.     "Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(NRR')", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824. [PDF]

   

169.            "Mechanism of Equilibration of Diastereomeric Chiral Rhenium Alkene Complexes of the Formula [(h5-C5H5)Re(NO)(PPh3)(H2C=CHR)]+ BF4–. the Metal Traverses between Alkene Enantiofaces without Dissociation", Peng, T.-S.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 4174-4181. [PDF]

 

170.     "Cyclopentadienyl Rhenium Complexes", Agbossou, F.; O'Connor, E. J.; Garner, C. M.; Quirós Méndez, N.; Fernández, J. M.; Patton, A. T.; Ramsden, J. A.; Gladysz, J. A. Inorg. Synth. 1992, 29, 211-225. [PDF]

   

171.     "Synthesis, Structure, Dynamic Behavior, and Reactivity of Chiral Rhenium Primary Phos­phine and Phosphido Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(PRH2)]+ X- and ((η5-C5H5)Re­(NO)(PPh3)(PRH)", Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673-2685. [Link]

 

172.     "A Versatile New Route to Carbon Complexes of the Formula LnMC-CM'L'n': Deprotonation and Metalation of the Terminal Acetylide Complex (η5-C5H5)Re­(NO)(PPh3)(C-CH)", Ramsden, J. A.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 5890-5891. [PDF]

   

173.     "Synthesis and Structure of  s -Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1992, 47, 1175-1184.

   

174.     "Synthesis, Structure, and Reactivity of Allene Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+", Pu, J.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organomet­allics 1992, 11, 3232-3241. [PDF]

   

175.     "Synthesis and Reactivity of Bridging Bis(alkyl) and Bis(alkylidene) Complexes Derived From the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+", Roger, C.; Peng, T.-S.; Gladysz, J. A. J. Organomet. Chem. 1992, 439, 163-175. [PDF]

   

176.     "Activation of Organic Carbonyl Compounds by Lewis Acids: Relative Reactivities of s and π Adducts Towards Nucleophiles, and Implications for Enantioselective Addition Reac­tions", Klein, D. P.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 8710-8711. [PDF]

   

177.     "Deprotonation of Rhenium Terminal Acetylide Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(C-CH): Generation and Reactivity of Rhenium/Lithium C2 Complexes", Ramsden, J. A.; Weng, W.; Gladysz, J. A. Organometallics 1992, 11, 3635-3645. [PDF]

   

178.     "Reactions of Rhenium Halide Complexes (η5-C5H5)Re­(NO)(PPh3)(X) and Organocopper Nucleophiles; New Routes to Racemic and Optically Active Hydrocarbyl Complexes (η5-C5H5)Re­(NO)(PPh3)(R)", Ramsden, J. A.; Peng, T.-S.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1992, 129, 625-631. [Link]

   

179.     "Structures of Propionaldehyde, Butyraldehyde, and Pivalaldehyde Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+", Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1993, 450, 157-164. [PDF]

   

180.     "Synthesis, Structure, and Spectroscopic Properties of Chiral Rhenium Aromatic Aldehyde Complexes [(η5-C5H5)Re­(NO)(PPh3)(O=CHAr)]+ X-: Equilibria between π and s Alde­hyde Bonding Modes", Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 2323-2334. [PDF]

   

181.     "Synthesis and Reactivity of Bimetallic Bridging Haloalkyl Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)X(CH2)xM(CO)5]+ BF4- (X = I, Br, Cl; M = Re, Mn; x = 1,4)", Zhou, Y.; Gladysz, J. A. Organometallics 1993, 12, 1073-1078. [PDF]

   

182.     "A New Form of Coordinated Carbon: An Unsupported C3 Chain Spanning Two Different Transition Metals", Weng, W.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 3824-3825. [PDF]

   

183.     (a) "A New Form of Coordinated Carbon: A C3 Chain That is Anchored by a Transition Metal on Each End and Spanned by a Third", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 891-892. [PDF]

             (b) "Ein neuer Kohlenstoffligand; eine durch ein Re-Atom überdachte Re-C3Re-Kette", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1993, 105, 937-938. [PDF]

   

184.     "Optical Rotation Measurements of Organometallic Compounds: Caveats and Recommend­ed Procedures", Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 2390-2392. [PDF]

   

185.     "Synthesis, Structure, and Dynamic Behavior of Symmetrical cis and trans Alkene Com­plexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+: Binding Selectivities and Isomerization Processes", Pu, J.; Peng, T.-S.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2686-2698. [PDF]

   

186.     "Synthesis and Structure of Complexes of a,ß-Unsaturated Carbonyl Compounds and the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+; Divergent Kinetic and Thermodyn­amic C=O/C=C and C=O/C-C Binding Selectivities", Wang, Y.; Agbossou, F.; Dalton, D. M.; Liu, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2699-2713. [PDF]

   

187.     "New Families of Coordinated Carbon: Oxidative Coupling of an Ethynyl Complex to Iso­lable and Crystallographically Characterized MC-CC-CM and M=C=C=C=C=M Assemb­lies", Zhou, Y.; Seyler, J. W.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 8509-8510. [PDF]

   

188.     "An Isolable Organometallic Cation Radical in which a C4 Chain Conducts Charge Between Two Chiral and Configurationally Stable Rhenium Termini", Seyler, J. W.; Weng, W.; Zhou, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 3802-3804. [PDF]

   

189.     "Synthesis and Reactivity of Chiral Rhenium Indenyl Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(X)]n+", Zhou, Y.; Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 3918-3923. [PDF]

   

190.     "Reactions of Rhenium Cyclopentadienyl and Indenyl Dichloromethane Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(ClCH2Cl)]+ BF4- with Ketones; Substitution Rates and Mechanism", Dewey, M. A.; Zhou, Y.; Liu, Y.; Gladysz, J. A. Organometallics 1993, 12, 3924-3932. [PDF]

   

191.     "Synthesis, Structure and Reactivity of Chiral Rhenium Imine and Methyleneamido Com­plexes of the Formulas [(η5-C5H5)Re­(NO)(PPh3))(η1-N(R")=C(R)R')]+ TfO- and (η5-C5H5)Re­(NO)(PPh3)N=C(R)R')", Knight, D. A.; Dewey, M. A.; Stark, G. A.; Bennett, B. K.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4523-4534. [PDF]

   

192.     "Synthesis, Structure, and Reactivity of η2-1,3-Diene and Enyne Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+; Ozonolysis Within a Metal Coordination Sphere", Peng, T.-S.; Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4535-4544. [PDF]

   

193.     "Pyrrolyl-N and Pyrrolyl-C Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3))]+: Synthesis, Protonation, and Rearrangement Chemistry", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4728-4730. [PDF]

   

194.     "New Strategies for Enantioselective Syntheses of 1-Alkyl and 1,4-Dialkyl 1,2,3,4-Tetrahy­droisoquinolines: Diastereoselective Additions of Nucleophiles and Electrophiles to Iso­quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Richter-Addo, G. B.; Knight, A. D.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 11863-11873. [PDF]

   

195.     "Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(GeMe2X); Equilibria Involving the Dimethylgermylene Complex [(η5-C5H5)Re­(NO)(PPh3)(=GeMe2)]+ TfO-", Lee, K. E.; Gladysz, J. A. Phosphorus, Sulfur, Silicon, and the Related Elements 1994, 87, 113-123. [PDF]

   

196.     "Syntheses and Structures of Unsymmetrically 1,1-and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+: Enantioface Binding Selec­tivities and Conformational Equilibria", Peng, T.-S.; Pu, J.; Gladysz, J. A. Organometallics 1994, 13, 929-940. [PDF]

   

197.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3]-Sigmatropic Rearrange­ments of Ylides of Di(allyl) and Di(propargyl) Sulfonium Salts. Control of Carbon Config­uration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1994, 116, 3655-3656. [PDF]

   

198.     "Generation and Reactivity of Substitution-Labile Dichloromethane and Chlorobenzene Ad­ducts of the Chiral Pentamethylcyclopentadienyl Rhenium Lewis Acid [(η5-C5Me5)Re­(NO)(PPh3)]+", Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534-2542. [PDF]

   

199.     "Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhe­nium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+", Wang, Y.; Arif, A. M.; Gladysz, J. A. Organ­ometallics 1994, 13, 2164-2169. [PDF]

 

200.     (a) "Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumu­lenic C5 Chain that Mediates Charge Transfer Between Rhenium and Manganese Termini", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1994, 33, 2199-2202. [PDF]

            (b) "Auf dem Weg zur Verknüpfung einzelner Metalle durch "eindimensionale Kohlenstoff­drähte": Ladungstransfer zwischen terminalen Rhenium- und Manganzentren über ein C5-Cumulen", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem. 1994, 106, 2269-2272.

   

201.     "Syntheses of Cyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(v5-C₅H5)Re­(NO)(PPh3)]+ by Hydride Ion Abstraction from Amido Complexes", Cantrell, W. R. Jr.; Richter-Addo, G. B.; Gladysz, J. A. J. Organomet. Chem. 1994, 472, 195-204. [PDF]

   

202.     "Synthesis, Structure and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+; Diastereoselective Electrophilic Additions", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 3182-3193. [PDF]

   

203.     "New Families of Coordinated Carbon: Oxidative Coupling and Cross-coupling of a Transi­tion Metal Butadiynyl Complex to Bimetallic M-Cº-CC-CC-CC-C-M and M-C-CC-C­C-C-M Adducts", M. Brady; W. Weng; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 2655-2656. [PDF]

   

204.     "Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 4523-4530. [PDF]

   

205.     "Are Teflon Ponytails the Coming Fashion for Catalysts?", Gladysz, J. A. Science 1994, 266, 55-56. [PDF]

   

206.     "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 279-281. [PDF]

   

207.     "Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula ((η5-C5H5)Re­(NO)(PPh3)(C-CX); Synthesis, Structure, and Reactivity of Unusu­al 1,3-Dimetalated Cyclic C4H3 and C4H4 Species", Weng, W.; Bartik, T.; Johnson, M. T.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 889-897. [PDF]

   

208.     "A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vi­nylic Deprotonation of Chiral Cationic Rhenium Alkene Complexes [(η5-C5H5)Re­(NO)(PPh3)(H2C=CHR)]+ BF4-", Peng, T.-S.; Gladysz, J. A. Organometallics 1995, 14, 898-911. [PDF]

   

209.     "Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formu­la (η5-C5H5)Re­(NO)(PPh3)(=CHR)]+ PF6-; A Versatile and Highly Stereoselective Route to Alkene Complexes", Wang, Y.; Gladysz, J. A. Chem. Ber. 1995, 128, 213-220. [PDF]

   

210.     "Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rheni­um Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+; Enantioselective Syntheses of 3-Substituted Cycloalkanones", Wang, Y.; Gladysz, J. A. J. Org. Chem. 1995, 60, 903-909. [PDF]

   

211.     "A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprot­onation of a Chiral Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon", Meyer, O.; Arif, A. M.; Gladysz, J. A. Org­anometallics 1995, 14, 1844-1849. [PDF]

   

212.     "Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline and Quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary; Enantioselective Syntheses of Alkyl, Dialkyl, and Trialkyl Hydroisoquinoline Derivatives", Stark, G. A.; Dewey, M. A.; Richter-Addo, G. B.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. in Stereoselective Reactions of Metal-Activated Molecules; Werner, H.; Sundermeyer, J. Eds.; Vieweg-Verlag: Braunschweig, Germany, 1995; pp. 51-71. [PDF]

   

213.     "Nucleophilic Additions to the Chiral Rhenium Alkene Complexes [Re(η5-C5H5)(NO)(PPh3)(H2C=CHR)]BF4 (R = H, Me, CH2CH2Me, Ph or CH2Ph): Regio-, Diastereo-, and Enantioselectivities", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1995, 1857-1865. [PDF]

   

214.     "Synthesis, Structure, and Reactivity of Chiral Rhenium N-Pyrrolyl Complexes [(η5-C5H5)Re­(NO)(PPh3)(NCR=CR'CH=CH)]; Regiochemistry of Electrophilic Addition and Unprec­edented Rearrangements to Carbon-Ligated Species", Johnson, T. J.; Alvey, L. J.; Brady, M.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1995, 1, 294-302. [PDF]

   

215.     "Crystal Structures of Diastereomeric Styrene Complexes of the Chiral Rhenium Fragment [(η5-C5H5)Re­(NO)(PPh3)]+; Effect of Ligating Enantioface upon Bonding and Conforma­tion", Sanau, M.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1995, 503, 235-241. [PDF]

   

216.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Rearrangements of Yl­ides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Con­figuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Meyer, O.; Weickhardt, K.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11730-11744. [PDF]

   

217.     "Synthesis, Structure and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M' and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (η5-C5H5)Re­(NO)(PPh3)(C-CLi) and (η5-C5H5)Re­(NO)(PPh3)(C-CC-CLi)", Weng, W.; Bartik, T. ; Brady, M.; Bartik, B.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11922-11931.

   

218.     "Reactions of t-BuOK and Di(Benzyl), Benzyl Allyl, and Allyl b-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re­(NO)(PPh3)]+: Highly Diastereoselective or Chemoselective [2,3] Sigmatropic Rearrangements", Cagle, P. C.; Meyer, O.; Vichard, D.; Weickhardt, K; Arif, A. M.; Gladysz, J. A. Organometallics 1996, 15, 194-204. [PDF]

   

219.     (a) "A Step-Growth Approach to Metal-Capped One-Dimensional Carbon Allotropes; Syn­theses of C12, C16, and C20 m-Polyynendiyl Complexes", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 414-417. [PDF]

            (b) "Schrittweises Kettenwachstum eindimensionaler Kohlenstoffallotrope mit terminalen Metallgruppen; Synthese von C12-, C16-, und C20-m-Polyindiylkomplexen", Bartik, T.; Bart­ik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem. 1996, 108, 467-469. [PDF]

   

220.     "A Crystallographic Map of Chiral Recognition in p-Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correl­ate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Seyler, J. W.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118, 2411-2421. [PDF]

   

221.     "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrange­ments of Ylides Derived from Di(allyl), Di(propargyl), and Di(benzyl) Sulfide Complexes; Control of Carbon Configuration by an Easily Resolved and Recycled Rhenium Auxiliary", Meyer, O.; Cagle, P. C.; Weickhardt, K.; Vichard, D.; Gladysz, J. A. Pure Appl. Chemistry 1996, 68, 79-88.[PDF]

   

222.     "A Search for π/s Equilibria in Chiral Rhenium Imine Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(N(H)=C(CF3)X)]+ TfO-; Investigation of Electronic Effects Upon the Binding Mode", Stark, G. A.; Gladysz, J. A. Inorg. Chem. 1996, 35, 5509-5513. [PDF]

   

223.     "Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids: Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements to give Thiolate Complexes with New Carbon Stereocenters", Bell, P. T.; Cagle, P. C.; Vichard, D.; Gladysz, J. A. Organo­metallics 1996, 15, 4695-4701. [PDF]

   

224.     "Configurational Equilibria in Amido and Lithioamido Complexes of Formulas (η5-C5H5)Re­(NO)(PAr3)(NHCHRR') and (η5-C5H5)Re­(NO)(PAr3)(NLiR"): Epimerization Occurs at Rhenium via Phosphine Dissociation", Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organo­metallics 1996, 15, 4798-4807. [PDF]

   

225.     "Consanguineous Families of Coordinated Carbon: A ReC4Re Assembly that is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC-CC-ºCRe and +Re=C=C=C=C=Re+ Adducts and a Radical Cation in which Charge is Delocalized Be­tween Rhenium Termini", Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, A. J.; Arif, A. M.; Böhme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788. [PDF]

   

226.     "Methods for Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Carbon Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(CC)nOs3(CO)10(H)", Falloon, S. B.; Arif, A. M.; Gladysz, J. A. Chem. Commun. 1997, 629-630. [PDF]

   

227.     (a) "Chiral Recognition in p-Complexes of Alkenes, Aldehydes, and Ketones with Transi­tion Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectiv­ities", Gladysz, J. A.; Boone, B. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 551-583. [PDF]

            (b) "Chirale Erkennung in π-Komplexen von Alkenen, Aldehyden und Ketonen mit Über­gangsmetall-Lewis-Säuren; Entwicklung eines allgemeinen Modells für enantiofaciale Komplexierungsselektivitäten", Gladysz, J. A.; Boone, B. J. Angew. Chem. 1997, 109, 566-602.

   

228.     "Spectroscopic Observation of the Formyl Cation in a Condensed Phase", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Science 1997, 276. 776-779. [Link]

   

229.     "Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (η5-C5H5)Re­(NO)(PPh3)(C-CC(OMe)=)Mm(CO)n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in which a C3 Chain Links two Metals and Spans a Third", Falloon, S. B.; Weng, W.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2008-2015. [PDF]

   

230.     (a) "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroboration", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1610-1612. [PDF]

            (b) "Übergangsmetallkatalyse in fluorhaltigen Medien: Anwendung eines neuen Immobil­isierungsprinzips auf die Rh-katalysierte Hydroborieirung", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1682-1684.

   

231.     (a) "Synthesis, Structure, and Oxidative Additions of a Fluorous Analog of Vaska's Com­plex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2; Altered Reactivity in Fluorocarbons, and Implications for Catalysis", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612-1615. [PDF]

            (b) "Synthese, Struktur, und oxidative Additionen eines fluorhaltigen Analogons des Vaska-Komplexes, trans-[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2] – Reaktivitätsänderung in Fluor­kohlenwasserstoffen und Auswirkungen auf die Katalyse", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1685-1687. [PDF]

   

232.     "Synthesis and Crystal Structure of the Conjugated Tetrayne (η5-C5H5)Re­(NO)(PPh3)­(C-CC-CC-CC-CSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp Carbon Wires", Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. New J. Chem. 1997, 21, 739-750.

   

233.     "Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η5-C5R5)Re­(NO)(PPh3)CN(Ph3P)(ON)Re(η5-C5R5)]+ TfO- (R, R' = H, Me)", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2909-2918. [PDF]

   

234.     "Synthesis and Crystallographic Characterization of the 'Sometimes-Chiral' Dirhenium Polyoxotungstate Salt {(η5-C5H5)Re­(NO)(PPh3)(CO)]+}2 [W6O19]2-", Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1997, 134, 793-799.

   

235.     "Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η5-C5H5)Re­(NO)(PPh3)]+: Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6", Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 6032-6034. [PDF]

   

236.     "Additions of Carbon Nucleophiles to Acyclic Imine Complexes of the Chiral Rhenium Le­wis Acid [(η5-C5H5)Re­(NO)(PPh3)]+: Controlling Factors in 1,3-Asymmetric Induction and Syntheses of Non-Racemic Organic Amines", Stark, G. A.; Gladysz, J. A. Inorg. Chim. Acta 1998, 269, 167-180. [PDF]

   

237.     "Organometallic Reactivity Patterns in Fluorocarbons, and Implications for Catalysis; Syn­thesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analog of Vaska's Com­plex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2", Guillevic, M.-A.; Rocaboy, C.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Organometallics 1998, 17, 707-717. [PDF]

   

238.     "Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Re­activity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re­(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries more Distorted than Planar Tetracoordin­ate", Falloon, S. B.; Szafert, S.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1998, 4, 1033-1042. [PDF]

   

239.     "Transition Metal Catalysis in Fluorous Media: Application of a New Immobilization Principle to Rhodium Catalyzed Hydrogenation of Alkenes", Rutherford, D.; Juliette, J. J. J.; Rocaboy, C.; Horváth, I. T.; Gladysz, J. A. Catalysis Today 1998, 42, 381-388. [PDF]

   

240.     "New Forms of Coordinated Carbon: Wire-Like Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer", Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071-11081. [PDF]

   

241.     "Additions of PH3 to Monosubstituted Alkenes of the Formula H2C=CH(CH2)x(CF2)yCF3; Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkyl Phosphines with Modulated Electronic Properties and Fluorous Phase Affinities", Alvey, L. J.; Ruther­ford, D.; Juliette, J. J. J.; Gladysz, J. A., J. Org. Chem. 1998, 63, 6302-6308. [PDF)

   

242.     "Olefin Metatheses in Metal Coordination Spehres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds", Martin-Alvarez, J. M.; Hampel, F.; Arif, A. M.; Glad­ysz, J. A. Organometallics 1999, 18, 955-957. [PDF]

   

243.     "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobiliza­tion Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes", Juliette, J. J. J.; Rutherford, D.; Horváth, I. T.; Gladysz, J. A. J. Am. Chem. Soc. 1999, 121, 2696-2704. [PDF]

   

244.     "Appreciably Bent sp Carbon Chains: Synthesis, Structure, and Protonation of Organometal­lic 1,3,5-Triynes and 1,3,5,7-Tetraynes of the Formula (η5-C5H5)Re­(NO)(PPh3)((C-C)n-p-C6H4Me)", Dembinski, R.; Lis, T.; Szafert, S.; Mayne, C. L.; Bartik, T.; Gladysz, J. A. J. Organomet. Chem. 1999, 578, 229-246. [PDF]

   

245.     "Chemistry in Fluorous Media: A User's Guide to Practical Considerations in the Applica­tion of Fluorous Catalysts and Reagents", Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587-605. [PDF]

   

246.     "C8 and C12 sp Carbon Chains that Span Two Platinum Atoms; The First Structurally Char­acterized 1,3,5,7,9,11-hexayne", Peters, T. B.; Bohling, J. C.; Arif, A. M.; Gladysz, J. A. Or­ganometallics 1999, 18, 3261-3263. [PDF]

   

247.     "Synthesis, Properties, and Reactions of Enantiomerically Pure, Chiral Fluorous Phosphines of the Formula (menthyl)P(CH2CH2(CF2)n-1CF3)2 (n = 6, 8)", Klose, A.; Gladysz, J. A. Tetrahedron–Asymmetry 1999, 10, 2665-2674. [PDF]

   

248.     "Wire-Like sp Carbon Chains that Span Two Platinum Atoms: Synthesis and Crystal Struc­tures of Building Blocks of the Formula trans-(p-tolyl)(Ph3P)2Pt(C-C)nSiMe3", Bohling, J. C.; Peters, T. B.; Arif, A. M.; Hampel, F.; Gladysz, J. A., in Coordination Chemistry at the Turn of the Century; Ondrejoviç, G.; Sirota, A. Eds.; Slovak Technical University Press: Bratislava, Slovokia, 1999; pp. 47-52.

   

249.     "Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones", Dinh, L. V.; Gladysz, J. A. Tetrahedron Lett. 1999, 40, 8995-8998. [PDF]

   

250.     "A New Route to Heterobimetallic C3 Complexes via CºC Metatheses of 1,3-Diynyl Lig­ands: Synthesis and Structure of (η5-C5Me5)Re­(NO)(PPh3)(-CC-C)W(O-t-Bu)3", Dembin­ski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438-5440. [PDF]

   

251. "Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C6-C20 Polyynediyl Chains that Span Two Redox-Active (η5-C5Me5)Re­(NO)(PPh3) Endgroups", Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810-822. [PDF]

   

252.     " Synthesis and Properties of Chiral Rhenium Pentatetraenylidene Complexes of the Form­ula [(η5-C5Me5)Re­(NO)(PPh3)(=C=C=C=C=CAr2)]+ BF4- (CAr2 = 9-fluorenylidene)", Szafert, S.; Haquette, P.; Falloon, S. B.; Gladysz, J. Organomet. Chem.2000, 604, 52-58. [PDF]

   

253.     "Strategy and Design in Fluorous Phase Immobilization: A Systematic Study of the Effect of "Pony Tails" (CH2)3(CF2)n-1CF3 Upon the Partition Coefficients of Benzenoid Com­pounds", Rocaboy, C.; Rutherford, D.; Bennett, B. L.; Gladysz, J. A. J. Phys. Org. Chem. 2000, 13, 596-603. [PDF]

   

254.     "A 'Conjugal' Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C4 Species", Paul, F.; Meyer, W. E.; Toupet, L.; Jiao, H.; Gladysz, J. A.; Lapinte, C. J. Am. Chem. Soc. 2000, 122, 9405-9414. [PDF]

   

255.     "Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Second, and Tertiary Aliphatic Amines NH3-x((CH2)m(CF2)7CF3)x (m = 3-5; x = 1-3); Fine Tuning of Basicities and Fluorous Phase Affinities", Rocaboy, C.; Bauer, W.; Gladysz, J. A. Eur. J. Org. Chem. 2000, 2621-2628. [PDF]

   

256.     "Synthesis and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Tri­alkylphosphines: Precision Tuning of Electronic Properties, Including Insulation of the Per­fluoroalkyl Group", Alvey, L. J.; Meier, R.; Soós, T.; Bernatis, P.; Gladysz, J. A. Eur. J. Inorg. Chem. 2000, 1975-1983. [PDF]

   

257.    "Synthesis and Oxidation of Chiral Rhenium Phosphine Methyl Complexes of the Formula (η5-C5Me5)Re­(NO)(PPh3)(CH3): In Search of Radical Cations with Enhanced Kinetic Stab­ilities", Meyer, W. E.; Amoroso, A. J.; Jaeger, M.; Le Bras, J.; Wong W.-T.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 44-53. [PDF]

   

258.     "Synthesis, Crystal Structure, and Reactions of the Seventeen-Valence-Electron Rhenium Methyl Complex [(η5-C5Me5)Re­(NO)(P(4-C6H4CH3)3)(CH3)]·+ (B(3,5-C6H3(CF3)2)4-: Experimental and Computational Bonding Comparisons with Eighteen-Electron Methyl and Methylidene Complexes", Le Bras, J.; Jiao, H.; Meyer, W. E.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 54-66. [PDF]

   

259.     "Tails and Steeds versus Heads and Beads: The Case for Fluorous Phase Methodology in Combinatorial and Parallel Synthesis", Rocaboy, C.; Gladysz, J. A. Actualité Chimique 2000, 47-50 (September).

   

260.     "Olefin Metatheses in Metal Coordination Spheres: Novel trans-Spanning Bidentate and Facially-Spanning Tridentate Macrocyclic Phosphine Complexes", Bauer, E. B.; Ruwwe, J.; Martín-Alvarez, J. M.; Peters, T. B.; Bohling, J. C.; Hampel, F. A.; Szafert, S.; Lis, T.; Gladysz, J. A. Chem. Commun. 2000, 2261-2262. [PDF]

   

261.     "Surface Reactivity Studies of Bimetallic Complexes (η5-C5Me5)Re­(NO)(PPh3)(C-C)n(Ph3P)(ON)Re(η5-C5Me5) (n = 2, 4, 6): Candidates for Molecular Wires", Schennach, R.; Naugle, D. G.; Cocke, D.; Dembinski, R.; Gladysz, J. A. Vacuum 2000, 56, 115-121. [PDF]

   

262.     "New Chiral Cyclopentadienyl Rhenium Lewis Acids Featuring Fluorinated Triaryl Phos­phines and Enhanced Acceptor Abilities; An Unusual Carbon-Fluorine Bond Activation in a Metal Coordination Sphere", Mohr, W.; Stark, G. A.; Jiao, H.; Gladysz, J. A. Eur. J. Inorg. Chem. 2001, 925-933. [PDF]

   

263.     "A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of 'Chiral-at-Rhenium' Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations", Kromm, K.; Zwick, B. D.; Meyer, O.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 2015-2027. [PDF]

   

264.     "Synthesis and Oxidation of Dirhenium C4, C6, and C8 Complexes of the Formula (η5-C5Me5)Re­(NO)(PR3)(C-C)n(R3P)(ON)Re(η5-C5Me5) (R = 4-C6H4R', c-C6H11): In Search of Dications and Radical Cations with Enhanced Stabilities", Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115-1127. [PDF]

   

265.     "Metal-Metal Interactions Across Bridging Elemental Carbon Chains: A Computational Study of Odd-Carbon Complexes", Jiao, H.; Gladysz, J. A. New J. Chem. 2001, 25, 551-562. [PDF]

   

266.     "Synthesis, Structure, and Interconversion of Chiral Rhenium Oxygen- and Sulfur-Bound Sulfoxide Complexes of the Formula [(η5-C5H5)Re­(NO)(PPh3)(OS(Me)R)]+ X-; Diastereo­selective Oxidations of Coordinated Methyl Alkyl Sulfides", Otto, M.; Boone, B. J.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 2001, 1218-1229. [PDF]

   

267.     "Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n = 6, 8, 10)", Soós, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. Organometallics 2001, 20, 3079-3086. [PDF]

   

268.     "A New Family of Chiral Chelating Diamines with Transition Metal Stereocenters: Synthes­is, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted Diamine (η5-C5H5)Re­(NO)(PPh3)(CH2N(CH3)CH2CH2(H3C)NCH2)(Ph3P)(ON)Re(η5-C5H5)", Al­vey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; Lis, T.; Gladysz, J. A. Organometallics 2001, 20, 3087-3096. [PDF]

   

269.     "Structures and Energies of 10-Azatriquinacene and Its Hydrogenation Products: A Comput­ational Study", Jiao, H.; Halet, J.-F.; Gladysz, J. A. J. Org. Chem. 2001, 66, 3902-3905. [PDF]

   

270.     "Bent and Stretched but not yet to the Breaking Point: C8-C16 sp Carbon Chains the Span two Platinum Atoms, and the First Structurally Characterized 1,3,5,7,9,11,13,15-Octayne", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2001, 40, 3263-3264. [PDF]

   

271.     "Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Con­struction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands", Ruwwe, J.; Martín-Alvarez, J. M.; Horn, C. R.; Bauer, E. B.; Szafert, S.; Lis, T.; Hampel, F.; Cagle, P. C.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 3931-3950. [PDF]

   

272.     "Fluorous Catalysis Without Fluorous Solvents: A Friendlier Catalyst Recovery/Recycling Protocol Based upon Thermorphic Properties and Liquid/Solid Phase Separation", Wende, M.; Meier, R.; Gladysz, J. A. J. Am. Chem. Soc. 2001, 123, 11490-11491. [PDF]

   

273.     "Recoverable Catalysts: Ultimate Goals, Criteria of Evaluation, and the Green Chemistry In­terface", Gladysz, J. A. Pure Appl. Chem. 2001, 73, 1319-1324. [PDF]

   

274.     "Syntheses and Structures of Monoplatinum Model Complexes for Diplatinum Polyynediyl Adducts LnPt(C-C)zPtLn", Peters, T. B.; Zheng, Q.; Stahl, J.; Bohling, J. C.; Arif, A. M.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2002, 641, 53-61. [PDF]

   

275.     "Vibrational Progressions in the Valence Ionizations of Transition Metal Hydrides: Evalua­tion of Metal-Hydride Bonding and Vibrations in CpRe(NO)(CO)(H) [Cp = η5-C5H5, η5-C5(CH3)5)]", Lichtenberger, D. L.; Gruhn, N.; Rai-Chaudhuri, A.; Renshaw, K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, A. J. Am. Chem. Soc. 2002, 124, 1417-1423. [PDF]

   

276.     "An Unexpected Insertion of Acetone into the Silicon-Carbon Terminus of an sp Carbon Chain: Syntheses and Structures of Model Monoplatinum Hexatriynyl and Octatetraynyl Complexes", Mohr, W.; Peters, T. B.; Bohling, J. C.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Comptes Rendus Chemie 2002, 5, 111-118. [PDF]

   

277.     "How to Insulate a Reactive Site from a Perfluoroalkyl Group: PES, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH2)m(CF2)7CF3)3", Jiao, H.; Le Stang, S.; Soós, T.; Meier, R.; Kowski, K.; Rademacher, P.; Jaf­arpour, L.; Hamard, J.-B.; Nolan, S. P.; Gladysz, J. A. J. Am. Chem. Soc. 2002, 124, 1516-1523. [PDF]

   

278.     "New Perfluorocarbon System for Multilayer Growth of Anchorage Dependent Mammalian Cells", Rappaport, C.; Rensch, Y.; Abbasi, M.; Kempe, M.; Rocaboy, C. Gladysz, J. A.; Trujillo, E. M. BioTechniques 2002, 32, 142-151.

   

279.     "Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphos­phines that Contain a Rhenium Stereocenter in the Backbone", Kromm, K.; Hampel, F.; Gladysz, J. A. Helv. Chim. Acta 2002, 85, 1778-1789. [PDF]

   

280.     "Fluorous Chemistry: From Biphasic Catalysis to a Parallel Chemical Universe and Bey­ond", Gladysz, J. A.; Curran, D. P. Tetrahedron 2002, 58, 3823-3825. [PDF]

   

281.     "Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Pre­cursors to Highly Active Catalysts for the Suzuki Coupling", Rocaboy, C.; Gladysz, J. A. Tetrahedron 2002, 58, 4007-4014. [PDF]

   

282.     (a) "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. [PDF]

(b) "Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte mole­kulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957.

   

283.     "New Approaches to High-Activity Transition Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catal­yzed Suzuki Cross-Couplings", Eichenseher, S.; Kromm, K.; Delacroix, O.; Gladysz, J. A., Chem. Commun. 2002, 1046-1047.

   

284.     "Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Re­action; Evidence for a Palladium Nanoparticle Pathway", Rocaboy, C.; Gladysz, J. A. Org. Lett. 2002, 4, 1993-1996. [PDF]

   

285.     "A New Family of Chelating Diphosphines with Transition Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System", Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2002, 21, 4264-4274. [PDF]

   

286.     "Chelating Diphosphines that Contain a Rhenium Stereocenter in the Backbone: Applica­tions in Rhodium-Catalyzed Enantioselective Ketone Hydrosilylations and Alkene Hydro­genations", Kromm, K.; Osburn, P. L.; Gladysz, J. A. Organometallics 2002, 21, 4275-4280. [PDF]

 

287.     "Syntheses and Reactivities of Disubstituted and Trisubstituted Fluorous Pyridines with High Fluorous Phase Affinities: Solid State, Liquid Crystal, and Ionic Liquid Phase Proper­ties", Rocaboy, C.; Hampel, F.; Gladysz, J. A. J. Org. Chem. 2002, 67, 6863-6870. [PDF]

 

288.     "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η5-C5Me5)Re­(NO)(PR3)(C-CC-C­C-CC-C)(R3P)(ON)Re(η5-C5Me5)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. [PDF]

 

289.     "Facile and Selective Carbonylation of Methane in Superacids", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Adv. Synth. Catal. 2002, 344, 1059-1062. [PDF]

 

290.     "Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Sukuki Cross-Couplings", Giner Planas, J.; Gladysz, J. A. Inorg. Chem. 2002, 41, 6947-6949. [PDF]

 

291.     "How do the Electronic Structures of Low-Symmetry Metal-Hydride and -Alkyl Complexes Compare? Photoelectron Spectroscopy and Computational Studies of (η5-C5R5)Re­(NO)(L)­R' [L = CO, P(C6H5)3; R, R' = H, CH3)]", Lichtenberger, D. L.; Gruhn, N. E.; Rai-Chaud­huri, A.; Renshaw, S. K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, I. Organometallics 2002, 21, 5594-5504. [PDF]

 

292.     "Convenient Syntheses of Fluorous Aryl Iodides and Hypervalent Iodine Compounds: ArI­(L)n Reagents that are Recoverable by Simple Liquid/Liquid Biphase Workups, and Appli­cations in Oxidations of Hydroquinones", Rocaboy, C.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 88-95. [ [PDF]

 

 

293. "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age", Delacroix, O.; Gladysz, J. A. Chem. Comm­un. 2003, 665-675 (feature article). [PDF]

 

 

294.     "Thermomorphic Fluorous Imine and Thioether Palladacycles as Precursors for Highly Active Heck and Suzuki Catalysts; Evidence for Palladium Nanoparticle Pathways", Roca­boy, C.; Gladysz, J. A. New J. Chem. 2003, 27, 39-49. [PDF]

 

295.     "Synthesis, Structure, and Reactivity of sp Carbon Chains with bis(phosphine) Pentafluoro­phenylplatinum Endgroups: Butadiynediyl (C4) through Hexadecaoctaynediyl (C16) Bridges, and Beyond", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324-3340. [PDF]

 

296.     "Convenient Syntheses of Fluorous Phenols of the Formula HOC6H5-n((CH2)3(CF2)7CF3)n (n = 1,2) and the Corresponding Triarylphosphites", Le Stang, S.; Meier, R.; Rocaboy, C.; Gladysz, J. A. J. Fluorine Chem. 2003, 119, 141-149. [PDF]

 

297. "Syntheses of Dimetallamacrocycles via Intramolecular Oxidative Couplings of Dinuclear bis(1,3-Butadienyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)­dirhenium Complexes [(η5-C5Me5)Re­(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5­Me5)]", Horn, C. R.; Gladysz, J. A. Eur. J. Inorg. Chem. 2003, 9, 2211-2218. (feature article). [PDF]

 

298.     "Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A "Greener" Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation", Wende, M.; Gladysz, J. A. J. Am. Chem. Soc. 2003, 125, 5861-5872. [PDF]

 

299.     "Convenient and Convergent Syntheses of Long-Chain a,w-Dibromides and Diphosphines of the Formula X(CH2)nX (n = 18-32)", Mohr, W.; Horn, C. R.; Stahl, J.; Gladysz, J. A. Synthesis 2003, 1279-1285. [PDF]

 

300.     "Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M']n+: Computational Analyses of the Effect of the Metal", Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; La­pinte, C. J. Am. Chem. Soc. 2003, 125, 9511-9522. [PDF]

 

 

301.     "Tungsten-Catalyzed Alkyne Metatheses in Transition Metal Coordination Spheres: A Vers­atile New Synthesis of Metallamacrocycles", Bauer, E. B.; Szafert, S.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 2184-2186. [PDF]

 

302.     "Carbon in One Dimension: Structural Analysis of the Higher Polyynes", Szafert, S.; Glad­ysz, J. A. Chem. Rev. 2003, 103, 4175-4205. [PDF]

 

303.     "Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres", Bauer, E. B.; Gladysz, J. A. in Handbook of Metathesis, Grubbs, R. H. Ed.; Wiley/VCH, New York, 2003, Vol 2, pp 403-431. [PDF]

 

304.     "Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties ("Split Pony Tails")", Wende, M.; Seidel, F.; Gladysz, J. A. J. Fluorine Chem. 2003, 124, 45-54. [PDF]

 

305.     "Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Sub­stitution on the Efficiencies of Macrocyclizations that join trans Positions of Square-Planar Platinum Complexes", Bauer, E. B.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 5567-5580. [PDF]

 

306.     "Fluorous Chemistry: Scope and Definition", Horváth, I. T.; Curran, D. P.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 1-4. [Link]

307.     "Fluorous Solvents and Related Media", Gladysz, J. A.; Emnet, C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 11-23.

308.     "Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation", Gladysz, J. A.; da Costa, R. C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 24-40.

309.     "Pony Tails: Structural and Electronic Considerations", Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Wein­heim, 2004, pp. 41-55.

310.     "Partition Coefficients involving Fluorous Solvents", Gladysz, J. A.; Emnet, C.; Rábai, J. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 56-100.

311.     "9H, 9H, 10H, 11H, 11H-Perfluoro-11-nonadecyl Iodide. Free Radical Chain Reactions of Fluorous Primary Alkyl Iodides", Wende, M.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 464-465.

 

312. "Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join <em>trans</em>
Positions of Square-Planar Platinum Complexes to give Topologically Novel Di­phosphine Ligands", Shima, T.; Bauer, E. B.; Hampel, F.; Gladysz, J. A.; 2004, 1012-1018. [PDF]

 

313.     "Convenient Syntheses of 'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Com­plexes with Three to Five Ponytails", Dinh, L. V.; Gladysz, J. A. Chem. Commun. 2004, 998-999. [PDF]

 

314.     "Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten- and Molybdenum-Catalyzed Syntheses of Novel Metallamacrocycles", Bauer, E. B.; Hampel, F.; Glaydsz, J. A. Adv. Synth. Catal. 2004, 346, 812-822. [PDF]

 

315.     "Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, In which the sp Carbon Chains are shielded by sp3 Carbon Chains", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889-5892. [PDF]

316.     "Syntheses and Structures of Tetraplatinum bis(Polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains", Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893-5895. [PDF]

 

317.     "Longitudinally Extended Molecular Wires based upon PtC-CC-CC-CC-C Repeat Units; Iterative Syntheses of Functionalized Linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt As­semblies", Zheng, Q.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5896-5899. [PDF]

 

318.     "Transition-Metal-Based Fluorous Catalysts", da Costa, R. C.; Gladysz, J. A. in Transition Metals for Organic Synthesis, 2nd ed, Beller, M.; Bolm, C. Eds.; Wiley/VCH, Weinheim, 2004, 527-543.[Link]

 

 

319.     (a) "Molecular Gyroscopes: Fe(CO)3 and Fe(CO)2(NO)+ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. [PDF]

(b) "Molekulare Gyroskope: Fe(CO)3- und Fe(CO)2(NO)+-Rotatoren in einem Stator aus drei Speichen; Einfache Synthese durch Alken-Metathese", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2004, 116, 5653-5656.

 

 

320.     "Electronic Structure and Chain Length Effects in Diplatinum Polyynediyl Complexes trans, trans-(X)(R3P)2Pt(CC)nPt(PR3)2(X): A Computational Investigation", Zhuravlev, F.; Gladysz, J. A. Chem. Eur. J. 2004, 10, 6510-6522. [PDF]

 

321.     "Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes" , Dinh, L. V.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2005, 690, 493-503. [PDF]

 

322.     "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems", Eichenseher, S.; Dela­croix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 245-255. [PDF]

 

323.     "Monophasic and Biphasic Hydrosilylations of Enones and Ketones using a Fluorous Rhodium Catalyst that is Easily Recycled under Fluorous/Organic Liquid/Liquid Biphase Condi­tions", Dinh, L. V.; Gladysz, J. A. New. J. Chem. 2005, 29, 173-181. [PDF]

 

324.     "Generation and Reactions of Ruthenium Phosphido Complexes (η5-C5H5)Ru(PR'3)2(PR2): Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions", Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416. [PDF]

 

325.     "Efficient Syntheses of Fluorous Primary Phosphines that do not Require PH3", Emnet, C.; Gladysz, J. A. Synthesis 2005, 1012-1018. [PDF]

 

326.     "A Theoretical Study on Spin State Energy Splittings and Local Spin in Cationic [Re]-(C-C)n-[Re] Complexes", Herrmann, C.; Neugebauer, J.; Gladysz, J. A.; Reiher, M. Inorg. Chem. 2005, 44, 6174-6182. [PDF]

 

327.     (a) "'Catalyst-on-a-Tape' – Teflon: A New Delivery and Recovery Protocol for Homogene­ous Fluorous Catalysts", Dinh, L. V.; Gladysz, J. A. Angew. Chem., Int. Ed. 2005, 44, 4164-4167. [PDF]

(b) "'Katalysatoren am laufenden Band' – Teflon: Eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren", Dinh, L. V.; Gladysz, J. A. 4167.

 

328.     "Synthesis and Reactivity of 1,2- and 1,3-Diphosphines that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unpriv­ileged Ligands for Enantioselective Catalysis" Kromm, K.; Eichenseher, S.; Prommesberg­er, M.; Hampel, F.; Gladysz, J. A. Eur. J. Inorg. Chem. 2005, 2983-2998. [PDF]

 

329. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Li­gands and Metal Complexes", Tuba, R.; Tesevic, V.; Dinh, L. V.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2005, 2275-2283. [PDF]

 

330. "A Synthetic Breakthrough into an Unanticipated Stability Regime: Readily Isolable Com­plexes in which C16-C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Glad­ysz, J. A. J. Am. Chem. Soc. 2005, 127, 10508-10509. [PDF]

 

331. "Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Deriva­tives", Emnet, C.; Tuba, R.; Gladysz, J. A. Adv. Synth. Catal. 2005, 347, 1819-1826. [PDF]

 

332. "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions", Friedlein, F. K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 4103-4105. [PDF]

 

333. "Fluorous Solvents: Physical Properties", Gladysz, J. A.; Emnet, C. in Green Reaction Med­ia in Organic Synthesis, Mikami, K. Ed.; Blackwell, Oxford, UK, 2005, pp 62-80 (Ch 3.2). [PDF]

 

334. "An Easily Accessed Class of Recyclable Hypervalent Iodide Reagents for Functional Group Oxidations: bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Gladysz, J. A.; Tesevic, V. Green Chem. 2005, 7, 833-836. [PDF]

 

335. "'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails: Syntheses from Polybromocyclopentadienyl Complexes, Phase Properties, and Electronic Effects", Dinh, L. V.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 7211-7222. [PDF]

 

336. "Wire-Like PtC-CC-CC-CC-CPt Moieties Surrounded by Double-Helical 'Insulation': New Motifs Featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P Linkages", de Quadras, L.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2006, 2929-2933. [PDF]

 

337. "π Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts", Dinh, L. V.; Consorti, C. S.; Emnet, C.; Gladysz, J. A. Organometallics 2006, 25, 1245-1251. [PDF]

 

338. "Gyroscope-Like Molecules Consisting of PdX2/PtX2 Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetallation Reac-tions", Nawara, A. J.; Shima, T.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2006, 128, 4962-4963. [PDF]

 

339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. [PDF]

 

340. "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link in a Series of Square-Planar Platinum Complexes", Lewanzik, N.; Oeser, T.; Blümel, J.; Gladysz, J. A. J. Mol. Catal. A. 2006, 254, 20-28. [PDF]

 

341. "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies", Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 5267-5281. [PDF]

 

342. (a) "Giant" Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25-27 Membered Macrocycles; Syntheses, Structures, Dy­namic Properties, and Reactivity", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 2006, 45, 4372-4375. [PDF]

(b) "Gyroskop-Giganten": Dipolare Cl-Rh-CO-Roatoren, umgeben von Startoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2006, 118, 4479-4482.

 

343. "Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Pony­tails; New Candidates for Phase Transfer Catalysts and Ionic Liquids", Emnet, C.; Weber, K. M.; Vidal, J. A.; Consorti, C. S.; Stuart, A. M. Gladysz, J. A. Adv. Synth. Catal. 2006, 348, 1625-1634. [PDF]

 

344. "A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Bohling, J. C.; Peters, T. B.; Frisch, A. C.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 6486-6505. [PDF]

 

345. "Oxidation of Secondary Alcohols to Ketones Using Easily Recyclable bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Gladsz, J. A.; Tesevic, V. J. Org. Chem. 2006, 71, 7433-7440. [PDF]

 

346. "A Promising New Catalyst Family for Enantioselective Cycloadditions of Allenes and Imines: Chiral Phosphines with a Transition Metal–CH2–P: Linkage" Scherer, A.; Gladysz, J. A. Tetrahedron Lett. 2006, 47, 6335-6337. [PDF]

 

347. "Fluorous to the Core", Gladysz, J. A. Sience 2006, 313, 1249-1250. [Link]

 

348. "Gyroscope-Like Molecules Consisting of Three-Spoke Stators that Enclose "Switchable" Neutral Dipolar Rhodium Rotators; Reversible Cycling between Faster ans Slower Spinning Rh(CO)I and Rh(CO)2I Species" Wang, L.; Shima, T.; Hampel, F.; Gladysz, J. A. Chem. Commun. 2006, 4075-4077. [PDF]

 

349. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Complexes Derived From P(CH2)5P Backbones", Consorti, C. S.; Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2006, 359, 4874-4884. [PDF]

 

350. "Update 1 of: Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2006, 106, PR1–PR33. [PDF]

 

351. "Crystal structure of an unusual bis(fluorous phosphine) ruthenium(III)complex derived from a fluorous Grubbs' catalyst", da Costa, R.; Hampel, F.; Gladysz, J. A. Polyhedron 2007, 26, 581-588. [PDF]

 

352. "Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2PAr2)", Seidel, F.; Gladysz, J. A. Synlett 2007, 6, 986-988. [PDF]

 

353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. [PDF]

 

354. "Monophosphine and Diphosphine Ligands for Diplatinum Polyyendiyl Complexes: Efficient Synthesis of New Functionality-Containing Systems and Model Compounds", de Quadras, L.; Stahl,J.; Zhuravlev, F.; Gladysz, J. A. J. Organomet. Chem. 2007, 692, 1859-1870. [PDF]

 

355. "Gyroscopes and the Chemical Literature: 1852-2002" Skopek, K.; Hershberger, M. C.; Gladysz, J. A. Coord. Chem. 2007, Coord. Chem. Rev. 2007, 251, 1723-1733. [PDF]

 

356. "Temperature Controlled Catalyst Recycling: New Protocols based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid-Liquid Phase Separations", Gladysz, J. A.; Tesevic, V. Topics in Organometallic Chemistry 2008, 23, 67-89.

 

357. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Coordination-Driven Self Assembly of Wirelike Pt(C⋮C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages", Stahl, J.; Mohr, W.; de Quadras, L.; Peters, T. B.; Bohling, J. C.; Martín-Alvarez, J. M.; Owen, G. R.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8282-8295. [PDF]

 

358. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices:  Directed Syntheses of Wirelike Pt(C⋮C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alva­rez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. [PDF]

 

359. "Ionic Chemistry in Extremely Nonpolar Fluorous Media: Phase Transfer Catalysis of Halide Substitution Reactions", Consorti, C. S.; Jurisch, M.; Gladysz, J. A. Org. Lett. 2007, 9, 2309-2312. [PDF]

 

360. "Octahedral Gyroscope-Like Molecules with M(CO)3(X) Rotators Encased in Three-Spoked Diphosphine Stators:  Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities", Hess, G. D.; Hampel, F.; Gladysz, J. A. Orga­nometallics 2007, 26, 5129-5131. [PDF]

 

361. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Wire-Like Pt(C≡C)nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. [PDF]

 

362. "Chiral Phosphorus Donor Ligands Containing Monocyclopentadienyl Metal Fragments", Castillo, D. A.; Gladysz, J. A. in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Börner, A. Ed; Wiley/VCH, Weinheim, 2008, 408-437.

 

363. "Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity", Boswell, P. G.; Szíjjáró, C.; Jurisch, M.; Gladysz, J. A.; Rábai, J.; Bühlmann, P. Anal. Chem. 2008, 80, 2084-2090. [PDF]

 

364. "Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains", Farley, R.; Zheng, Q.; Gladysz, J. A.; Schanze, K. S. Inorg. Chem. 2008, 47, 2955-2963. [PDF]

 

365. "Syntheses of Gyroscope-Like Molecules via Three-Fold Ring Closing Metatheses of bis­(Phosphine) Complexes trans-LyM(P((CH2)nCH=CH2)3)2, and Extensions to bis(Phosphite) Complexes  trans-Fe(CO)3(P(O(CH2)nCH=CH2)3)2", Skopek, K.; Gladysz, J. A. J. Organ­omet. Chem. 2008, 693, 857-866. [PDF]

   

366. "Thermomorphic Fluorous Palladacycles", Gladysz, J. A. in Palladacycles, Dupont, J.; Pfeffer, M. Eds; Wiley/VCH, Weinheim, 2008, 341-359. [PDF]

 

367. "Coordination-Driven Self Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp3 Carbon Chains: Towards Endgroup-Endgroup Interactions", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 73-87. [PDF]

 

368. "Synthesis of Fluorous Sulfur/Carbon/Sulfur Pincer Ligands and Palladium Complexes; New Catalyst Precursors for the Heck Reaction", da Costa, R. C.; Jurisch, M.; Gladysz, J. A. Inorg. Chim. Acta 2008, 361, 3205-3214. [PDF]

   

369. "En Route to Diplatinum Polyynediyl Complexes trans,trans-(Ar)(R3P)2Pt(C≡C)nPt(PR3)2(Ar): Untold Tales, Including End-Group Strategies", Stahl, J.; Bohling, J. C.; Peters, T. B.; de Quadras, L.; Gladysz, J. A. Pure Appl. Chem. 2008, 80, 459-474. [PDF]

 

370. "Three-Fold Intramolecular Ring-Closing Metatheses Involving Square Planar Platinum Complexes with cis Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute Like Complexes", Skopik, K.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2008, 47, 3474-3476. [PDF]

 

371. "Synthesis and Reactivity of New Heterodinuclear Iron/Rhenium Cx Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C≡C)n2-dppe)Fe(η5-C5Me5) (n = 3, 4); Redox Properties and a Dicobalt Hexacarbonyl Adduct", Szafert, S.; Paul, F.; Meyer, W. E.; Gladysz, J. A.; Lapinte, C. Comptes Rendus Chimie 2008, 11, 693-701. [PDF]

 

372. "Phase Transfer of Enantiopure Werner Cations into Organic Solvents; An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis", Ganzmann, C.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 5397-5400. [PDF]

 

373. "Syntheses, Structures, and Electronic Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C6F5)(R3P)2Pt, (p-tol)(R3P)2Pt, and (Ph3P)Au End-Groups", de Quadras, L.; Shelton, A. H.; Kuhn, H.; Hampel, F.; Schanze, K. S.; Gladysz, J. A. Organometallics 2008, 27, 4979-4991. [PDF]

 

374. "Ionic Transformations in Extremely Nonpolar Fluorous Media: Easily Recoverable Phase Transfer Catalysts for Halide Substitution Reactions", Mandal, D.; Jurisch, M.; Consorti, C. S.; Gladysz, J. A. Chemistry – an Asian Journal 2008, 3, 1772-1782. [PDF]

 

375. "Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains", Samoc, M.; Humphrey, M. G.; Dalton, G. T.; Gladysz, J. A.; Zheng, Q.; Yelkov, Y.; Ågren, H.; Norman, P. Inorg. Chem. 2008, 47, 9946-9957. [PDF]

 

376. "Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Proctocols Involving Precipitation, Teflon® Tape and Gore-Tex® Fibers", Seidel, F. O.; Gladysz, J. A. Adv. Synth. Catal. 2008, 350, 2443-2449. [PDF]

 

377. "Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes", Kuhn, H.; Hampel, F.; Gladysz, J. A. Organometallics 2009, 28, 4979-4987. [PDF]

 

378. "Synthesis and Reactivity of Fluorous and non-Fluorous Aryl and Alkyl Iodine(III) Dichlor¬ides: New Chlorinating Reagents that are Easily Recycled using Biphasic Protocols", Podgoršek, A.; Jurisch, M.; Stavber, S.; Zupan, M.; Iskra, J.; Gladysz, J. A. J. Org. Chem. 2009, 74, 3133-3140. [PDF]

 

379. "'Click' Chemistry in Metal Coordination Spheres: Copper(I) Catalyzed 3+2 Cycloaddi­tions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol3P)2Pt­(CºC)nH (n = 2-6)", Gauthier, S.; Weisbach, N.; Gladysz, J. A Organometallics 2009, 28, 5597-5599. [PDF]

 

380. "Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies", Gladysz, J. A. in Handbook of Green Chemistry, Anastas, P.; Crabtree, R. H. Eds; Volume 1: Homoge¬neous Catalysis; Crabtree, R. H. Volume Ed; Wiley/VCH, Weinheim, 2009, 17-38.

 

381. "The Experimental Assay of Catalyst Recovery: General Concepts", Gladysz, J. A. in Re­coverable and Recyclable Catalysts, Benanglia, M. Ed; Wiley-Blackwell, Oxford, England, 2009, pp. 1-22.

 

382. "Syntheses and Structural Analyses of Chiral Rhenium Containing Amines of the Form­ula (h5-C5H5)Re(NO)(PPh3)((CH2)nNRR') (n = 0, 1)", Seidel, S. N.; Prommesberger, M.; Eichenseher, S.; Meyer, O. Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2010, 363, 533-548. (invited article, issue in honor of Paul Pregosin) [PDF]

 

383. "Syntheses of Fluorous Quaternary Ammonium Salts and their Application as Phase Transfer Catalysts for Halide Substitution Reactions in Extremely Nonpolar Fluorous Solvents", Mandal, D.; Gladysz, J. A. Tetrahedron 2010, 66, 1070-1077. [PDF]

   

384. "Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphos­phines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3", Nawara-Hultzsch, A. J.; Skopek, K.; Shima, T.; Barbasiewicz, M.; Hess, G. D.; Skaper, D.; Gladysz, J. A. Z. Naturforsch. B: Anorg. Chem., Org. Chem. 2010, 65, 414-424. (invited article, issue in honor of Rolf Saalfrank)

 

385. "Molecular Wires in Single Molecule Junctions: Charge Transport and Vibrational Exci­tations", Ballmann, S.; Hieringer, W.; Secker, D.; Zheng, Q.; Gladysz, J. A.; Görling, A.; Weber, H. B. ChemPhysChem 2010, 11, 2256-2260. [PDF]

 

386. "Chemical Stability and Application of a Fluorophilic Tetraalkylphosphonium Salt in Fluorous Membrane Anion-Selective Electrodes", Chen, L. D.; Mandel, D.; Gladysz, J. A.; Bühlmann, P. New. J. Chem. 2010, 34, 1867-1874. [PDF]

 

387. "Towards Multistranded Molecular Wires: Syntheses, Structures, and Reactivities of Tet­raplatinum bis(Polyynediyl) Complexes with Pt-Cx-Pt-(P(CH2)3P)2-Pt-Cx-Pt-(P(CH2)3­P)2 Cores (x = 4, 6, 8)", Owen, G. R.; Gauthier, S.; Weisbach, N.; Hampel, F.; Bhuvan­esh, N.; Gladysz, J. A. Dalton Trans. 2010, 5260-5271. [PDF]

 

388. "Square Planar Palladium Complexes with trans-Di- and Tribenzylphosphine Ligands Bearing O(CH2)4CH=CH2 Substituents; Two- and Three-Fold Intramolecular Ring Clos­ing Metatheses", Han, J.; Deng, C.; Wang, L.; Gladysz, J. A. Organometallics 2010, 29, 3231-3234. [PDF]

 

389. "Thermomorphic Fluorous Phosphines as Organocatalysts for Michael Addition Reac­tions", Gimbert, C.; Vallribera, A.; Gladysz, J. A.; Jurisch, M. Tetrahedron Lett. 2010, 51, 4662-4665. [PDF]

 

390. "C1-Symmetric Ph2C-Bridged ansa-Zirconocenes: Synthesis, Structure and Highly Iso­specific Polypropylene Polymerization", Kirillov, E.; Marquet, N.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpenter, J.-F. Organometallics 2010, 29, 5073-5082. (invited article, issue in honor of Dietmar Seyferth) [PDF]

 

391. "Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes", Lai, C.-Z.; Fierke, M. A.; da Costa, R. C.; Gladysz, J. A.; Stein, A.; Bühlmann, P. Anal. Chem. 2010, 82, 7634-7640. [PDF]

 

392. "The Future of Organometallic Chemistry", Gladysz, J. A. Organometallics 2011, 30, 1-4. [PDF]

 

   

393. "Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselect­ive Propylene Polymerization", Kirillov, E.; Marquet, N.; Bader, M.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2011, 30, 263-272. DOI: 10.1021/om100897j. [Link]

   

394. (a) "Dibridgehead Diphosphines that Turn Themselves Inside-Out", Stollenz, M.; Barba­siewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2011, 50, 6647-6651. DOI: 10.1002/ange.201100893. [Link

(b) "Dreifach-verbrückte Diphosphine mit von innen nach außen invertierender Konfigur­ation", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem. 2011, 123, 6777-6781. DOI: 10.1002/ange.201100893. [Link]

    395. "Analogs of Grubbs' Second Generation Catalyst with Hydrophilic Phosphine Ligands: Phase Transfer Activation of Ring Closing Alkene Metathesis", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Org. Lett. 2011, 13, 6188-6191. DOI: 10.1021/ol202548q. [Link]
    396. "Synthesis, Purification, and Characterization of Phosphine Oxides and their Hydrogen Peroxide Adducts", Hilliard, C. R.; Gladysz, J. A.; Bluemel, J. Dalton. Trans. 2011, in press.
    397. "Potentiometric Sensors Based on Fluorous Membranes with Highly Selective Iono­phores for CO32–", Chen, L. D.; Mandal, D.; Pozzi, G.; Gladysz, J. A.; Bühlmann, P. J. Am. Chem. Soc. 2011, 133, in press. [Link]
    398. "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphos­phines that can turn themselves Inside-Out", Stollenz, M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. submitted to Organometallics. [Link]
   

399. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Correa da Costa, R.; Bassi, H. S.; Gladysz, J. A. submitted to ACS Catalysis. [Link]

   

400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Link]

   

401. "Gyroscope-Like Platinum and Palladium Complexes with trans-Spanning Bis(Pyridine) Ligands", Zeits, P. D.; Rachiero, G. P.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Or­ganometallics 2012, 31, in press.

   

402. "Structural, Physical, and Chemical Properties of Fluorous Compounds", Gladysz, J. A.; Jurisch, M. Topics in Current Chemistry 2012, 308, 1-24.

   

403. "A New Type of Insulated Molecular Wire: a Rotaxane Derived from a Metal-Capped Conjugated Polyyne", Weisbach, N.; Baranová, Z.; Gauthier, S.; Reibenspies, J. H.; Gladysz, J. A. Chem. Commun. 2012, 48, 7562-7564. DOI: 10.1039/C2CC33321J.

   

404. "Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Lev­el Detection and In-Situ Monitoring of Absorption onto Sand", Chen, L. D.; Lai, C.-Z.; Granda, L. P.; Fierke, M.; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P. Environ. Sci. Technol. 2012, 46, in press.

   

405. "Ring Opening Metathesis Polymerization of an h4-Benzene Complex: A Direct Synthe­sis of a Polyacetylene with a Regular Pattern of π Bound Metal Fragments", Zeits, P. D.; Fiedler, T.; Gladysz, J. A. Chem. Commun. 2012, 48, 7925-7927. DOI: 10.1039/C2CC32 150E.

   

406. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluor­ous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g.

   

407. "Toward Permetalated Alkyne/Azide 3+2 or 'Click' Cycloadducts", Clough, M. C.; Zeits, P. D. Bhuvanesh, N.; Gladysz, J. A. Organometallics 2012, 31, 5231-5234. DOI: 10.1021/om300542a.

   

408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Relat­ed Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Gu­errero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u.

   

409. "A Metal-capped Conjugated Polyyne Threaded Through a Phenanthroline-based Macro­cycle. Probing Beyond the Mechanical Bond to Interactions in Interlocked Molecular Ar­chitectures", Sahnoune, H.; Baranová, Z.; Bhuvanesh, N.; Gladysz, J. A.; Halet, J.-F. Organometallics 2013, 32, 6360-6367. DOI: 10.1021om400709q.

   

410. "Multifold Ring Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities, Fiedler, T.; Gladysz, J. A. in Olefin Metathesis – Theory and Practice, Grela, K., Ed.; John Wiley & Sons, Hoboken, New Jersey, 2014, 311-328. ISBN: 978-1-118-20794-9.

   

411. "Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladi¬um Catalyzed Suzuki Cross-Coupling Reactions, Sierra Castro, D.; Bhuvanesh, N.; Rei¬benspeis, J. H.; Gladysz, J. A.; Klahn, A. H. J. Organomet. Chem. 2014, 749, 416-420. DOI: 10.1016/j.jorganchem.2013.10.029.

   

412. "Gyroscope Like Molecules Consisting of PdX2/PtX2 Rotators Within Three-Spoke Di­bridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dyn­amic Properties", Nawara-Hultzsch, A. J.; Stollenz, M.; Barbasiewicz, M.; Szafert, S.; Lis, T.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Chem. Eur. J. 2014, 20, 4617-4637. DOI: 10.1002/chem.201304419

   

413. "Highly Active Families of Catalysts for the Ring Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimida­zole", Thomas, C.; Gladysz, J. A. ACS Catalysis 2014, 4, 1134-1138. DOI: 10.1021/ cs500134z.
("ACS Editor's Choice" article for 14 March 2014: http://pubs.acs.org/editorschoice/)

   

414. "Photophysics of Platinum Tetrayne Oligomers: Delocalization of Triplet Exciton", Li, Y.; Winkel, R. W.; Weisbach, N.; Gladysz, J. A.; Schanze, K. S. J. Phys. Chem. A. 2014, 115, 10333-10339. DOI: 10.1021/jp5021388.

   

415. "Organometallics Roundtable 2013-2014", Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaï, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. Organometallics 2014, 33, 1505-1527. DOI: 10. 1021/om500253z.

   

416. "Synthesis, Photovoltaic Perfomances, and TD-DFT Modeling of Push-Pull Diacetylide Platinum Complexes in TiO2 Based Dye-Sensitized Solar Cells", Gauthier, S.; Caro, B.; Robin-Le Guen, F.; Bhuvanesh, N.; Gladysz, J. A.; Wojcik, L.; Le Poul, N.; Planchat, A.; Pellegrin, Y.; Blart, E.; Jacquemin, D.; Odobel, F. Dalton Trans. 2014, 53, 11233-11242. DOI: 10.1039/c4dt00301b. .

   

417. "Metal Templated Hydrogen Bond Donors as 'Organocatalysts' for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes", Scherer, A.; Mukherjee, T.; Hampel, F.; Glad­ysz, J. A. Organometallics 2014, 33, 6709-6722. DOI:10.1021/om500704u.

   

418. "Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions", Mukherjee, T.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6723-6737. DOI:10.1021/om­500705s.

   

419. "Liquid/Solid Phase Transfer Activation of Grubbs-Type Alkene Metathesis Catalysts; Application of Silver Salts of Sulfonated Polystyrene", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Catal. Sci. Technol. 2014, 4, 4178-4182. DOI:10.1039/c4cy01021c.

   

420. "Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces", Hilliard, C. R.; Kharel, S.; Cluff, K. J.; Bhuvanesh, N.; Gladysz, J. A.; Blümel, J. Chem. Eur. J. 2014, 20, 17292-17295. DOI: 10.1002/chem.201404880.

   

421. "Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Ex­panded Macrocycles", Baranová, Z.; Amini, H.; Bhuvanesh, N.; Gladysz, J. A. Organo­metallics 2014, 33, 6746-6749. DOI:10.1021/om501026u.

   

422. "An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthe­sis of 2-Substituted Benzimidazoles", Safaei, H. R.; Gladysz, J. A.; Nouri, S. Helv. Chim. Acta 2014, 97, 1539-1545. DOI: 10.1002/hlca.201400033.

   

423. "Fluorous Chemistry Meets Green Chemistry: A Concise Primer", Mukherjee, T.; Glad­ysz, J. A. Aldrichimica Acta, 2015, 48, in press.

   

424. "Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Av­ailable, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantiosel­ective Organic Synthesis", Lewis, K. G.; Ghosh, S. K.; Bhuvanesh, N.; Gladysz, J. A. ACS Central Science, 2015, 1, DOI:10.1021acscentsci5b00035.

   
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