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All Publications -- Publications by Area

Publications by Area


Fluorous   |   Gyroscopes   |   Molecular Wires   |   Werner Complexes



Fluorous

205.     "Are Teflon Ponytails the Coming Fashion for Catalysts?", Gladysz, J. A. Science 1994, 266, 55-56. DOI: 10.1126/science.266.5182.55. [Abstract][PDF]

230.     (a) "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroboration", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1610-1612. DOI: 10.1002/anie.19971091509. [Abstract][PDF]

            (b) "Übergangsmetallkatalyse in fluorhaltigen Medien: Anwendung eines neuen Immobil­isierungsprinzips auf die Rh-katalysierte Hydroborieirung", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1682-1684. DOI: 10.1002/ange.19971091509. [Abstract][PDF]

231.     (a) "Synthesis, Structure, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2; Altered Reactivity in Fluorocarbons, and Implications for Catalysis", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612-1615. DOI: 10.1002/anie.199716121. [Abstract][PDF]

            (b) "Synthese, Struktur, und oxidative Additionen eines fluorhaltigen Analogons des Vaska-Komplexes, trans-[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2] – Reaktivitätsänderung in Fluor­kohlenwasserstoffen und Auswirkungen auf die Katalyse", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1685-1687. DOI: 10.1002/ange.19971091510. [Abstract][PDF]

237.     "Organometallic Reactivity Patterns in Fluorocarbons, and Implications for Catalysis; Synthesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2", Guillevic, M.-A.; Rocaboy, C.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Organometallics 1998, 17, 707-717. DOI: 10.1021/om9710834. [Abstract][PDF]

239.     "Transition Metal Catalysis in Fluorous Media: Application of a New Immobilization Principle to Rhodium Catalyzed Hydrogenation of Alkenes", Rutherford, D.; Juliette, J. J. J.; Rocaboy, C.; Horváth, I. T.; Gladysz, J. A. Catalysis Today 1998, 42, 381-388. (invited article, phase separable homogeneous catalysis thematic issue) DOI: 10.1016/S0920-5861(98)00120-5. [Abstract][PDF]

241.     "Additions of PH3 to Monosubstituted Alkenes of the Formula H2C=CH(CH2)x(CF2)yCF3; Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkyl Phosphines with Modulated Electronic Properties and Fluorous Phase Affinities", Alvey, L. J.; Rutherford, D.; Juliette, J. J. J.; Gladysz, J. A., J. Org. Chem. 1998, 63, 6302-6308. DOI: 10.1021/jo980692y. [Abstract][PDF]

243.     "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobiliza­tion Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes", Juliette, J. J. J.; Rutherford, D.; Horváth, I. T.; Gladysz, J. A. J. Am. Chem. Soc. 1999, 121, 2696-2704. DOI: 10.1021/ja982955b. [Abstract][PDF]

245.     "Chemistry in Fluorous Media: A User's Guide to Practical Considerations in the Applica­tion of Fluorous Catalysts and Reagents", Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587-605. (invited article, 33rd ICCC thematic issue) DOI: 10.1016/S0010-8545(99)00102-2. [Abstract][PDF]

247.     "Synthesis, Properties, and Reactions of Enantiomerically Pure, Chiral Fluorous Phosphines of the Formula (menthyl)P(CH2CH2(CF2)n-1CF3)2 (n = 6, 8)", Klose, A.; Gladysz, J. A. Tetrahedron–Asymmetry 1999, 10, 2665-2674. DOI: 10.1016/SO957-4166(99)00272-4. [Abstract][PDF]

249.     "Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones", Dinh, L. V.; Gladysz, J. A. Tetrahedron Lett. 1999, 40, 8995-8998. DOI: 10.1016SO040-4039(99)01924-3. [Abstract][PDF]

253.     "Strategy and Design in Fluorous Phase Immobilization: A Systematic Study of the Effect of "Pony Tails" (CH2)3(CF2)n-1CF3 Upon the Partition Coefficients of Benzenoid Compounds", Rocaboy, C.; Rutherford, D.; Bennett, B. L.; Gladysz, J. A. J. Phys. Org. Chem. 2000, 13, 596-603. (invited article, organic reactivity (ESOR 7) thematic issue). DOI: 10.1002/1099-1395(200010)13. [Abstract][PDF]

255.     "Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Second, and Tertiary Aliphatic Amines NH3-x((CH2)m(CF2)7CF3)x (m = 3-5; x = 1-3); Fine Tuning of Basicities and Fluorous Phase Affinities", Rocaboy, C.; Bauer, W.; Gladysz, J. A. Eur. J. Org. Chem. 2000, 2621-2628. DOI: 10.1002/1099-0690(200007)2000:14. [Abstract][PDF]

256.     "Synthesis and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Tri­alkylphosphines: Precision Tuning of Electronic Properties, Including Insulation of the Per­fluoroalkyl Group", Alvey, L. J.; Meier, R.; Soós, T.; Bernatis, P.; Gladysz, J. A. Eur. J. Inorg. Chem. 2000, 1975-1983. DOI: 10.1002/1099-0682(200009)2000:9<1975::AID-EJIC1975>3.0.CO;2-M. [Abstract][PDF]

259.     "Tails and Steeds versus Heads and Beads: The Case for Fluorous Phase Methodology in Combinatorial and Parallel Synthesis", Rocaboy, C.; Gladysz, J. A. Actualité Chimique 2000, 47-50 (September).

267.     "Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C6H4(CH2)3(CF2)n-1CF3)3 (n = 6, 8, 10)", Soós, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. Organometallics 2001, 20, 3079-3086. DOI: 10.1021/om010193e. [Abstract][PDF]

272.     "Fluorous Catalysis Without Fluorous Solvents: A Friendlier Catalyst Recovery/Recycling Protocol Based upon Thermorphic Properties and Liquid/Solid Phase Separation", Wende, M.; Meier, R.; Gladysz, J. A. J. Am. Chem. Soc. 2001, 123, 11490-11491. DOI: 10.1021/ja011444d. [Abstract][PDF]

273.     "Recoverable Catalysts: Ultimate Goals, Criteria of Evaluation, and the Green Chemistry In­terface", Gladysz, J. A. Pure Appl. Chem. 2001, 73, 1319-1324. (invited article, CHEMRAWN XIV thematic issue) DOI:10.1351/ pac200173081319. [Abstract][PDF]

277.     "How to Insulate a Reactive Site from a Perfluoroalkyl Group: Photoelectron Spectroscopy, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH2)m(CF2)7CF3)3", Jiao, H.; Le Stang, S.; Soós, T.; Meier, R.; Kowski, K.; Rademacher, P.; Jaf­arpour, L.; Hamard, J.-B.; Nolan, S. P.; Gladysz, J. A. J. Am. Chem. Soc. 2002, 124, 1516-1523. DOI: 10.1021/ja011877g. [Abstract][PDF]

278.     "New Perfluorocarbon System for Multilayer Growth of Anchorage Dependent Mammalian Cells", Rappaport, C.; Rensch, Y.; Abbasi, M.; Kempe, M.; Rocaboy, C. Gladysz, J. A.; Trujillo, E. M. BioTechniques 2002, 32, 142-151. ISSN: 0736-6205. [PDF]

280.     "Fluorous Chemistry: From Biphasic Catalysis to a Parallel Chemical Universe and Bey­ond", Gladysz, J. A.; Curran, D. P. Tetrahedron 2002, 58, 3823-3825. DOI: 10.1016SO040-4020(02)00222-3. [Abstract][PDF]

281.     "Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Pre­cursors to Highly Active Catalysts for the Suzuki Coupling", Rocaboy, C.; Gladysz, J. A. Tetrahedron 2002, 58, 4007-4014. (invited article, fluorous chemistry thematic issue) DOI: 10.1016SO04020(02)00275-2. [Abstract][PDF]

284.     "Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Re­action; Evidence for a Palladium Nanoparticle Pathway", Rocaboy, C.; Gladysz, J. A. Org. Lett. 2002, 4, 1993-1996. DOI: 10.1021/ol025790r. [Abstract][PDF]

287.     "Syntheses and Reactivities of Disubstituted and Trisubstituted Fluorous Pyridines with High Fluorous Phase Affinities: Solid State, Liquid Crystal, and Ionic Liquid Phase Proper­ties", Rocaboy, C.; Hampel, F.; Gladysz, J. A. J. Org. Chem. 2002, 67, 6863-6870. DOI: 10.1021/jo011173p. [Abstract][PDF]

 

292.     "Convenient Syntheses of Fluorous Aryl Iodides and Hypervalent Iodine Compounds: ArI­(L)n Reagents that are Recoverable by Simple Liquid/Liquid Biphase Workups, and Applications in Oxidations of Hydroquinones", Rocaboy, C.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 88-95. DOI: 10.1002/chem.200390034. [Abstract][PDF]

 

294.     "Thermomorphic Fluorous Imine and Thioether Palladacycles as Precursors for Highly Active Heck and Suzuki Catalysts; Evidence for Palladium Nanoparticle Pathways", Roca­boy, C.; Gladysz, J. A. New J. Chem. 2003, 27, 39-49. DOI: 10.1039/b208545n. [Abstract][PDF]

 

296.     "Convenient Syntheses of Fluorous Phenols of the Formula HOC6H5-n((CH2)3(CF2)7CF3)n (n = 1,2) and the Corresponding Triarylphosphites", Le Stang, S.; Meier, R.; Rocaboy, C.; Gladysz, J. A. J. Fluorine Chem. 2003, 119, 141-149. DOI:10.1016/S0022-1139(02)00242-7. [Abstract][PDF]

 

298.     "Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A "Greener" Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation", Wende, M.; Gladysz, J. A. J. Am. Chem. Soc. 2003, 125, 5861-5872. DOI: 10.1021/ja029241s. [Abstract][PDF]

304.     "Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties ("Split Pony Tails")", Wende, M.; Seidel, F.; Gladysz, J. A. J. Fluorine Chem. 2003, 124, 45-54. DOI: 10.1016/S0022-1139(03)00171-4. [Abstract][PDF]

306.     "Fluorous Chemistry: Scope and Definition", Horváth, I. T.; Curran, D. P.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 1-4. DOI: 10.1002/3527603905.ch1. [Abstract]

307.     "Fluorous Solvents and Related Media", Gladysz, J. A.; Emnet, C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 11-23. DOI: 10.1002/3527603905.ch3. [Abstract]

308.     "Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation", Gladysz, J. A.; Corrêa da Costa, R. C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 24-40. DOI: 10.1002/3527603905.ch4. [Abstract]

309.     "Ponytails: Structural and Electronic Considerations", Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Wein­heim, 2004, pp. 41-55. DOI: 10.1002/3527603905.ch5. [Abstract]

310.     "Partition Coefficients involving Fluorous Solvents", Gladysz, J. A.; Emnet, C.; Rábai, J. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wil­ey/VCH, Weinheim, 2004, pp. 56-100. DOI: 10.1002/3527603905.ch6. [Abstract]

311.     "9H, 9H, 10H, 11H, 11H-Perfluoro-11-nonadecyl Iodide. Free Radical Chain Reactions of Fluorous Primary Alkyl Iodides", Wende, M.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 464-465. DOI: 10.1021/op050147g. [Abstract]

 

313.     "Convenient Syntheses of 'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Com­plexes with Three to Five Ponytails", Dinh, L. V.; Gladysz, J. A. Chem. Commun. 2004, 998-999. DOI: 10.1039/b401540a. [Abstract][PDF]

 

318. "Transition-Metal-Based Fluorous Catalysts", Corrêa da Costa, R. ; Gladysz, J. A. in Transition Metals for Organic Synthesis, 2nd ed, Beller, M.; Bolm, C. Eds.; Wiley/VCH, Weinheim, 2004, 527-543. DOI: 10.1002/9783527619405.ch6b. [Abstract]

 

323.     "Monophasic and Biphasic Hydrosilylations of Enones and Ketones using a Fluorous Rhodium Catalyst that is Easily Recycled under Fluorous/Organic Liquid/Liquid Biphase Condi­tions", Dinh, L. V.; Gladysz, J. A. New. J. Chem. 2005, 29, 173-181. DOI: 10.1039/B415344H [Abstract][PDF]

325.     "Efficient Syntheses of Fluorous Primary Phosphines that do not Require PH3", Emnet, C.; Gladysz, J. A. Synthesis 2005, 1012-1018. DOI: 10.1055/s-2005-861815. [Abstract][PDF]

 

327.     (a) "'Catalyst-on-a-Tape' – Teflon: A New Delivery and Recovery Method for Homogene­ous Fluorous Catalysts", Dinh, L. V.; Gladysz, J. A. Angew. Chem., Int. Ed. 2005, 44, 4095-4097. DOI: 10.1002/anie.200500237. [Abstract][PDF]

(b) "'Katalysatoren am laufenden Band' – Teflon: Eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren", Dinh, L. V.; Gladysz, J. A. Angew. Chem., 2005, 26 4164-4167. DOI: 10.1002/ange.200500237. [Abstract][PDF]

 

329. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Ligands and Metal Complexes", Tuba, R.; Tesevic, V.; Dinh, L. V.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2005, 13, 2275-2283. DOI: 10.1039/B502309B [Abstract][PDF]

331. "Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives", Emnet, C.; Tuba, R.; Gladysz, J. A. Adv. Synth. Catal., 2005, 347, 1819-1826. DOI: 10.1002/adsc.200505145. [Abstract][PDF]

 

333. "Fluorous Solvents: Physical Properties", Gladysz, J. A.; Emnet, C. in Green Reaction Med­ia in Organic Synthesis, Mikami, K. Ed.; Blackwell, Oxford, UK, 2005, pp 62-80 (Ch 3.2). ISBN: 978-1-4051-3402-6. DOI: 10.1002/9780470988770.ch3 [Abstract][PDF]

334. "An Easily Accessed Class of Recyclable Hypervalent Iodide Reagents for Functional Group Oxidations: bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Tesevic, V.; Gladysz, J. A. Green Chem. 2005, 7, 833-836. DOI: 10.1039/b511951k. [Abstract][PDF]

335. "'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails: Syntheses from Polybromocyclopentadienyl Complexes, Phase Properties, and Electronic Effects", Dinh, L. V.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 7211-7222. DOI: 10.1002/chem.200500595. [Abstract][PDF]

337. "π Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts", Dinh, L. V.; Consorti, C. S.; Emnet, C.; Gladysz, J. A. Organometallics 2006, 25, 1245-1251. DOI: 10.1021/om050950z. [Abstract][PDF]

339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", Corrêa da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. DOI: 10.1039/B602428A. [Abstract][PDF]

 

343. "Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Pony­tails; New Candidates for Phase Transfer Catalysts and Ionic Liquids", Emnet, C.; Weber, K. M.; Vidal, J. A.; Consorti, C. S.; Stuart, A. M. Gladysz, J. A. Adv. Synth. Catal. 2006, 348, 1625-1634. (invited article, "multiphase catalysis, green solvents, and immobilization" issue) DOI: 10.1002/adsc.200606138. [Abstract][PDF]

345. "Oxidation of Secondary Alcohols to Ketones Using Easily Recyclable bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF3(CF2)n-1I(OCOCF3)2", Tesevic, V.; Gladysz, J. A.; J. Org. Chem. 2006, 71, 7433-7440. DOI: 10.1021/jo0612067. [Abstract][PDF]

347. "Fluorous to the Core", Gladysz, J. A. Science 2006, 313, 1249-1250. DOI: 10.1126/ science.1131944. [Abstract][PDF]

349. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Complexes Derived From P(CH2)5P Backbones", Consorti, C. S.; Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2006, 359, 4874-4884. DOI: 10.1016/j.ica.2006.07.092. [Abstract][PDF]

351. "Crystal Structure of an Unusual bis(fluorous phosphine) Ruthenium(III) Complex Derived from a Fluorous Grubbs' Catalyst", Corrêa da Costa, R.; Hampel, F.; Gladysz, J. A. Polyhedron 2007, 26, 581-588. DOI: 10.1016/j.poly.206.08.015. [Abstract][PDF]

353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", Corrêa da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. (invited article, olefin metathesis thematic issue) DOI: 10.1002 /adsc.200600461. [Abstract][PDF]

356. "Temperature Controlled Catalyst Recycling: New Protocols based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid-Liquid Phase Separations", Tesevic, V.; Gladysz, J. A. Topics in Organometallic Chemistry 2008, 23, 67-89. (published on the web in 2006) DOI: 10.1007/3418_043. [Abstract][PDF]

359. "Ionic Chemistry in Extremely Nonpolar Fluorous Media: Phase Transfer Catalysis of Halide Substitution Reactions", Consorti, C. S.; Jurisch, M.; Gladysz, J. A. Org. Lett. 2007, 9, 2309-2312. DOI: 10.1021/ol0706354. [Abstract][PDF]

361. "sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Wire-Like Pt(C≡C)nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]

 

363. "Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity", Boswell, P. G.; Szíjjáró, C.; Jurisch, M.; Gladysz, J. A.; Rábai, J.; Bühlmann, P. Anal. Chem. 2008, 80, 2084-2090. DOI: 10.1021/ac702161c. [Abstract][PDF]

 

366. "Thermomorphic Fluorous Palladacycles", Gladysz, J. A. in Palladacycles, Dupont, J.; Pfeffer, M. Eds; Wiley/VCH, Weinheim, 2008, 341-359. DOI:10.1002/ 9783527623211.ch14. [Abstract][PDF]

368. "Synthesis of Fluorous Sulfur/Carbon/Sulfur Pincer Ligands and Palladium Complexes; New Catalyst Precursors for the Heck Reaction", Corrêa da Costa, R.; Jurisch, M.; Gladysz, J. A. Inorg. Chim. Acta 2008, 361, 3205-3214. (invited article, issue in honor of Robert Angelici) DOI: 10.1016/j.ica.2007.11.016. [Abstract][PDF]

374. "Ionic Transformations in Extremely Nonpolar Fluorous Media: Easily Recoverable Phase Transfer Catalysts for Halide Substitution Reactions", Mandal, D.; Jurisch, M.; Consorti, C. S.; Gladysz, J. A. Chem. Asian J. 2008, 3, 1772-1782. DOI: 10.1002/asia.200800138. [Abstract][PDF]

 

376. "Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Proctocols Involving Precipitation, Teflon® Tape and Gore-Rastex® Fiber", Seidel, F. O.; Gladysz, J. A. Adv. Synth. Catal. 2008, 350, 2443-2449. DOI: 10.1002/adsc.200800403. [Abstract][PDF]

 

378. "Synthesis and Reactivity of Fluorous and non-Fluorous Aryl and Alkyl Iodine(III) Dichlorides: New Chlorinating Reagents that are Easily Recycled using Biphasic Protocols", Podgoršek, A.; Jurisch, M.; Stavber, S.; Zupan, M.; Iskra, J.; Gladysz, J. A. J. Org. Chem. 2009, 74, 3133-3140. DOI: 10.1021/jo900233h. [Abstract][PDF]

 

380. "Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies", Gladysz, J. A. in Handbook of Green Chemistry, Anastas, P.; Crabtree, R. H. Eds; Volume 1: Homogeneous Catalysis; Crabtree, R. H. Volume Ed; Wiley/VCH, Weinheim, 2009, 17-38. ISBN: 9783527324965 3527324968.

 

381. "The Experimental Assay of Catalyst Recovery: General Concepts", Gladysz, J. A. in Re­coverable and Recyclable Catalysts, Benanglia, M. Ed; Wiley-Blackwell, Oxford, England, 2009, pp. 1-22. ISBN: 978-0470681954.

 

383. "Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents", Mandal, D.; Gladysz, J. A. Tetrahedron 2010, 66, 1070-1077. DOI: 10.1016/j.tet.2009.11.012. [Abstract][PDF]

 

386. "Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes", Chen, L. D.; Mandal, D.; Gladysz, J. A.; Bühlmann, P. New. J. Chem. 2010, 34, 1867-1874. DOI: 10.1039/B9NJ00696F. [Abstract][PDF]

 

389. "Thermomorphic Fluorous Phosphines as Organocatalysts for Michael Addition Reac­tions", Gimbert, C.; Vallribera, A.; Gladysz, J. A.; Jurisch, M. Tetrahedron Lett. 2010, 51, 4662-4665. DOI: 10.1016/j.tetlet.2010.06.136. [Abstract][PDF]

 

391. "Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes", Lai, C.-Z.; Fierke, M. A.; Corrêa da Costa, R.; Gladysz, J. A.; Stein, A.; Bühlmann, P. Anal. Chem. 2010, 82, 7634-7640. DOI: 10.1021/ac1013767. [Abstract][PDF]

 

397. "Potentiometric Sensors Based on Fluorous Membranes Doped with Highly Selective Ionophores for Carbonate", Chen, L. D.; Mandal, D.; Pozzi, G.; Gladysz, J. A.; Bühlmann, P. J. Am. Chem. Soc. 2011, 133, 20869-20877. DOI: 10.1021/ja207680e. [Abstract][PDF]

 

400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Abstract][PDF]

 

402. "Structural, Physical, and Chemical Properties of Fluorous Compounds", Gladysz, J. A.; Jurisch, M. Top. Curr. Chem. 2012, 308, 1-24. [PDF]

 

405. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluorous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g. [Abstract][PDF]

 

407. "Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Level Detection and In-Situ Monitoring of Absorption", Chen, L. D.; Lai, C.-Z.; Granda, L. P.; Fierke, M. A.; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P. Anal. Chem. 2013, 85, 7471-7477. DOI: 10.1021/ac401424j. [Abstract][PDF]

 

408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Guerrero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u. [Abstract][PDF]

 

423. "Fluorous Chemistry Meets Green Chemistry: A Concise Primer", Mukherjee, T.; Gladysz, J. A. Aldrichimica Acta, 2015, 48, 25-28. [PDF]

426. "Phase and Redox Shifted Four Iron/Four Sulfur Clusters; Fluorous Analogs of Metalloensyme Cofactors", Zhang, C.-P.; Xi, Z.; Mueller, K. M.; Holliday, B. J.; Bazzi, H. S.; Gladysz, J. A. Dalton Trans. 2015, 44, 19615-19624. DOI:10.1039/C5DT01959A [Abstract] [PDF]

428. "Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands", Xi, Z.; Bazzi, H.S.; Gladysz, J. A. J. Am. Chem. Soc. 2015, 137, 10930-10933. DOI:10.1021/jacs.5b06562 [Abstract] [PDF]

430. "Phase Transfer Activation of Transition Metal Catalysts", Tuba, R.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Chem. Eur. J. 2015, 21, 15894-15906. DOI:10.1002/chem.201502403. [Abstract] [PDF]

432. "An Analogue of Grubbs' Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis", Balogh, J.; Hlil, A. R.; Su, H.-L.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. ChemCatChem. 2016, 8, 125-128. DOI: 10.1002/cctc.201500913 [Abstract] [PDF]

433. "A Phase Based Approach to Insulated Molecular Wires: Diplatinum Octatetraynediyl Complexes Bearing Fluorous Trialkylphosphine Ligands", Clough, M. C.; Fiedler, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2016, 812, 34-42. DOI:10.1016/j.jorganchem.2015.09.020. (invited contribution, special issue dedicated to Jack Lewis) [Abstract] [PDF]

440. " Convenient Protocols for Mizoroki-Heck Reactions of Aromatic Bromides and Polybromides with Fluorous Alkenes of the Formula H2C=CH(CF2)n–1CF3 (n = 8, 10)", Su, H.-L.; Balogh, J.; Al-Hashimi, M.; Seapy, D. G.; Bazzi, H. S.; Gladysz, J. A. Org. Biomol. Chem. 2016, 10058-10069. DOI:10.1039/c6ob01980c. [Abstract] [PDF]

452. "Syntheses, Structures, and Stabilities of Aliphatic and Aromatic Fluorous Iodine(I) and Iodine(III) Compounds; the Role of Iodine Atom Lewis Basicity", Mukherjee, T.; Biswas, S.; Ehnbom, A.; Ghosh, S.; El-Zoghbi, I.; Bhuvanesh, N.; Bazzi, H. S.; Gladysz, J. A. Beilstein J. Org. Chem. 2017, 13, 2486-2501. DOI: 10.3762/bjoc/13/246. (invited contribution, special issue on "Organo-fluorine Chemistry IV") [Abstract] [PDF]

454. "Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene) (PTFE); "Catalyst-on-a-Tape"", Dinh, L. V.; Jurisch, M.; Fiedler, T.; Gladysz, J. A. ACS Sustainable Chemistry & Engineering 2017, 5, 10875-10888. DOI: 10.1021/acssuschemeng.7b02770. [Abstract] [PDF]

456. "Cleaning of pH Selective Electrodes with Ionophore-Doped Fluorous Membranes in Na-OH Solution at 90 °C", Lugert-Thom, E. C.; Gladysz, J. A.; Rábai, J.; Buhlmann, P. Electroanalysis 2017, 29, in press DOI: 10.1002/elan.201700228. [Abstract] [PDF]





Patent Activity

E1.       Patent Memorandum, Exxon Research and Engineering Co., May 1995, "Minimal Step Procedures for the Preparation of (Perfluoroalkyl)alkyliodides and (Perfluoroalkyl)alkyl­anions – Key Precursors for the Synthesis of Polyperfluoroalkylated Phosphines and Phosphonium Salts", Gladysz, J. A.; Horváth, I.; Bernatis, P.; Gea, Y.

E2.       German Patent Application, February 2002, "Fluorige Katalysatoren oder Reagenzien mit temperaturabhängiger Löslichkeit" ("Fluorinated Catalysts or Reagents with Temperature Dependent Solubility"), Gladysz, J. A.; Wende, M.; Rocaboy, C.; Chemical Abstracts number 140:17732 (DE 102 12 424 A 1).

E3.       US and World Patent Application, April 2002, "Method and Apparatus for Multi-Layer Growth of Anchorage Dependent Cells", Rappaport, C.; Trujillo, E. Rensch, Y.; Abbasi, M.; Kempe, M.; Gladysz, J. A.; Rocaboy, C.; Chemical Abstracts number 137:2706 (US 2004/ 0023374 A1, WO 02/44341 A2, and WO 02/044341 A3).

E4.       US Patent Application, September 2002: "Recovery Method for Catalyst, Reagents, and Co-Products", Gladysz. J. A.; Wende, M. O.; Curran, D. P.; Chemical Abstracts number 141:90875 (US 2004/0127755 A1). Issued 25 January 2011 as US Patent No. 7,875,752.

E6.       US Patent Application, November 2005, "Methods, Processes, and Materials for Dispens­ing and Recovering Supported Fluorous Reaction Components", Gladysz, J. A.; Dinh, L. V.; Curran, D. P.; Chemical Abstracts number 144:432299 (S 2006/0094866 A1).