The Gladysz Research Group

Fluorous   |   Gyroscopes   |   Molecular Wires   |   Werner Complexes

271.     "Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Con­struction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands", Ruwwe, J.; Martín-Alvarez, J. M.; Horn, C. R.; Bauer, E. B.; Szafert, S.; Lis, T.; Hampel, F.; Cagle, P. C.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 3931-3950. DOI: 10.1002/1521-3765(20010917)7:18. [Abstract][PDF]

282.     (a) "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. DOI: 10.1021/ja0716103. [Abstract][PDF]

(b) "Von sp³-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte mole­kulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957. DOI: 10.1002/1521-3757(20020603)114:11<1951::AID-ANGE1951>3.0.CO;2-Z. [Abstract][PDF]

288.     "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η⁵-C₅Me₅)Re(NO)(PR₃)(C≡CC≡C­C≡CC≡C)(R₃P)(ON)Re(η⁵-C₅Me₅)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. DOI: 10.1021/om020676y. [Abstract][PDF]

303.     "Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres", Bauer, E. B.; Gladysz, J. A. in Handbook of Metathesis, Grubbs, R. H. Ed.; Wiley/VCH, New York, 2003, Vol 2, pp 403-431. DOI: 10.1002/9783527619481.ch26. [Abstract][PDF]

305.     "Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Sub­stitution on the Efficiencies of Macrocyclizations that join trans Positions of Square-Planar Platinum Complexes", Bauer, E. B.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 5567-5580. DOI: 10.1021/om034121u. [Abstract][PDF]

312. "Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Di­phosphine Ligands", Shima, T.; Bauer, E. B.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2004, 1012-1028. DOI: 10.1039/b400156g. [Abstract][PDF]

314.     "Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten- and Molybdenum-Catalyzed Syntheses of Novel Metallamacrocycles", Bauer, E. B.; Hampel, F.; Glaydsz, J. A. Adv. Synth. Catal. 2004, 346, 812-822. DOI: 10.1002/ adsc.200404026. [Abstract][PDF]

319.     (a) "Molecular Gyroscopes: {Fe(CO)₃} and {Fe(CO)₂(NO)}⁺ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. DOI: 10.1002/anie.200460534. [Abstract][PDF]

(b) "Molekulare Gyroskope: {Fe(CO)₃}- und {Fe(CO)₂(NO)}⁺-Rotatoren in einem Stator aus drei Speichen; Einfache Synthese durch Alken-Metathese", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2004, 116, 5653-5656. DOI: 10.1002/ange.200460534. [Abstract][PDF]

338. "Gyroscope-Like Molecules Consisting of PdX₂/PtX₂ Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetallation", Nawara, A. J.; Shima, T.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2006, 128, 4962-4963. DOI: 10.1021/ja061044w. [Abstract][PDF]

340. "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link in a Series of Square-Planar Platinum Complexes", Lewanzik, N.; Oeser, T.; Blümel, J.; Gladysz, J. A. J. Mol. Catal. A. 2006, 254, 20-28. (invited article, 16th International Symposium on Olefin Metathsis thematic issue) DOI: 10.1016/j.molcata.2005.10.047. [Abstract][PDF]

342. (a) "Giant" Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25-27 Membered Macrocycles", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 2006, 45, 4372-4375. DOI: 10.1002/anie.200601191. [Abstract][PDF]

(b) "Gyroskop-Giganten": Dipolare Cl-Rh-CO-Roatoren, umgeben von Startoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2006, 118, 4479-4482. DOI: 10.1002/ange.200601191. [Abstract][PDF]

348. "Gyroscope-Like Molecules Consisting of Three-Spoke Stators that Enclose "Switchable" Neutral Dipolar Rhodium Rotators; Reversible Cycling between Faster and Slower Spinning Rh(CO)I and Rh(CO)₂I Species" Wang, L.; Shima, T.; Hampel, F.; Gladysz, J. A. Chem. Commun. 2006, 4075-4077. DOI: 10.1039/b606728j. [Abstract][PDF]

355. "Gyroscopes and the Chemical Literature: 1852-2002" Skopek, K.; Hershberger, M. C.; Gladysz, J. A. Coord. Chem. 2007, Coord. Chem. Rev. 2007, 251, 1723-1733. (invited article, 37th ICCC thematic issue) DOI:10.1016/j.ccr.2006.12.015 [Abstract][PDF]

358. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices:  Directed Syntheses of Wirelike Pt(C≡C)_nPt Moieties That Are Spanned by Two P(CH₂)_mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alva­rez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. DOI: 10.1021/ja071612n. [Abstract][PDF]

360. "Octahedral Gyroscope-Like Molecules with M(CO)₃(X) Rotators Encased in Three-Spoked Diphosphine Stators:  Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities", Hess, G. D.; Hampel, F.; Gladysz, J. A. Organometallics 2007, 26, 5129-5131. DOI: 10.1021/om700625u. [Abstract][PDF]

361. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Wire-Like Pt(C≡C)_nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]

365. "Syntheses of Gyroscope-Like Molecules via Three-Fold Ring Closing Metatheses of bis­(Phosphine) Complexes trans-L_yM(P((CH₂)_nCH=CH₂)₃)₂, and Extensions to bis(Phosphite) Complexes trans-Fe(CO)₃(P(O(CH₂)_nCH=CH₂)₃)₂", Skopek, K.; Gladysz, J. A. J. Organomet. Chem. 2008, 693, 857-866. (invited article, "Frontiers in Organometallic Chemistry" thematic issue) DOI: 10.1016/J.JORGANCHEM.2007.11.001. [Abstract][PDF]

370. "Three-Fold Intramolecular Ring-Closing Metatheses Involving Square Planar Platinum Complexes with cis Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute Like Complexes", Skopek, K.; Barbasiewicz, M.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2008, 47, 3474-3476. DOI: 10.1021/ic702391m. [Abstract][PDF]

384. "Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Nawara-Hultzsch, A. J.; Skopek, K.; Shima, T.; Barbasiewicz, M.; Hess, G. D.; Skaper, D.; Gladysz, J. A. Z. Naturforsch. B.. 2010, 65, 414-424. (invited article, issue in honor of Rolf Saalfrank) DOI: 10.1515/ZNB-2010-0327 [Abstract] [PDF]

388. "Square Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH=CH₂ Substituents; Two- and Three-Fold Intramolecular Ring Closing Metatheses", Han, J.; Deng, C.; Fang, R.; Zhao, D.; Wang, L.; Gladysz, J. A. Organometallics 2010, 29, 3231-3234. DOI: 10.1021/om100536g. [Abstract][PDF]

394. (a) "Dibridgehead Diphosphines that Turn Themselves Inside-Out", Stollenz, M.; Barba­siewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Glad­ysz, J. A. Angew. Chem., Int. Ed. 2011, 50, 6647-6651. DOI: 10.1002/ange.201100893. [Abstract][PDF] 

(b) "Dreifach-verbrückte Diphosphine mit von innen nach außen invertierender Konfigur­ation", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem. 2011, 123, 6777-6781. DOI: 10.1002/ange.201100893. [Abstract][PDF]

396. "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines that can turn themselves Inside-Out", Stollenz, M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2011, 30, 6510-6513. DOI: 10.1021/om200924g. [Abstract][PDF]

401. "Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands", Zeits, P. D.; Rachiero, G. P.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2012, 31, 2854-2877. [Abstract][PDF]

404. "Ring opening metathesis polymerization of an η⁴-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments", Zeits, P. D.; Fiedler, T.; Gladysz, J. A. Chem. Commun. 2012, 48, 7925-7927. DOI: 10.1039/C2CC32150E. [Abstract][PDF]

405. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluorous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g. [Abstract][PDF]

410. "Multifold Ring Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities", Fiedler, T.; Gladysz, J. A. in Olefin Metathesis – Theory and Practice, Grela, K., Ed.; John Wiley & Sons, Hoboken, New Jersey, 2014, 311-328. ISBN: 978-1-118-20794-9.

412. "Gyroscope Like Molecules Consisting of PdX₂/PtX₂ Rotators Within Three-Spoke Di­bridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Nawara-Hultzsch, A. J.; Stollenz, M.; Barbasiewicz, M.; Szafert, S.; Lis, T.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Chem. Eur. J. 2014, 20, 4617-4637. DOI: 10.1002/chem.201304419 [Abstract][PDF]

425. "Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Lang, G. M.; Skaper, D.; Shima, T.; Otto, M.; Wang, L.; Gladysz, J. A. Aust. J. Chem. 2015, 68, 1342-1351. DOI: 10.1071/CH15178. (invited contribution, issue commemorating the 2014 RACI National Congress) [Abstract] [PDF]

427. "Steric Control of the in/out Sense of Bridgehead Substituents in Macrobicyclic Compounds: Isolation of New "Crossed Chain" Variants of in/out Isomers", Stollenz, M.; Taher, D.; Bhuvanesh, N.; Reibenspies, J. H.; Baranová, Z.; Gladysz, J. A. Chem. Commun. 2015, 51, 16053-16056. DOI: 10.1039/c5cc05620a. [Abstract] [PDF]

429. "Substitution and Catalytic Chemistry of Gyroscope Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands", Estrada, A. L.; Jia, T.; Bhuvanesh, N.; Blümel, J.; Gladysz, J. A. Eur. J. Inorg. Chem.. 2015 2015 5318-5321. DOI:10.1002/ejic.201500953 [Abstract] [PDF]

435. "Gyroscope Like Molecules Consisting of Trigonal or Square Planar Osmium Rotators Within Three-Spoked Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Fiedler, T.; Bhuvanesh, N.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Dalton Trans. 2016, 45, 7131-7147. DOI:10.1039/c6dt00692b [Abstract] [PDF]

437. " Gyroscope Like Complexes based upon Dibridgehead Diphosphine Cages that are Accessed by Three Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)₃, Fe(CO)₂(NO)⁺ and Fe(CO)₃(H)⁺ Rotators", Lang, G. M.; Shima, T.; Wang, L.; Cluff, K. J.; Skopek, K.; Hampel, F.; Blümel, J.; Gladysz, J. A. J. Am. Chem. Soc. 2016, 138, 7649-7663. DOI:10.1021/jacs.6b03178 [Abstract] [PDF]

439. "Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR", Fiedler, T.; Chen, L.; Wagner, N. D.; Russell, D. R.; Gladysz, J. A. Organometallics 2016, 35, 2071-2075. DOI:10.1021/acs.organomet.6b00249 [Abstract] [PDF]

441. "Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Carbonyl Complexes based upon Dibridgehead Diarsine Cages", Lang, G. M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2016, 35, 2873-2889. DOI: 10.1021/acs.organomet.6b00447. [Abstract] [PDF]

443. "Mono- and Disubstitution Reactions of Gyroscope Like Complexes Derived from Cl-Pt-Cl Rotators within Cage Like Dibridgehead Diphosphine Ligands", Taher, D.; Nawara-Hultzsch, A. J.; Bhuvanesh, N.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2016, 821, 136-141. DOI: 10.1016/j.jorganchem.2016.03.022. (invited contribution, special issue dedicated to Heinrich Lang) [Abstract] [PDF]

446. "Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl₂ Species (M = Pt, Pd, Ni)", 2016, Kharel, S.; Joshi, H.; Bierschenk, S.; Stollenz, M.; Taher, D.; Bhuvanesh, N.; Gladysz, J. A. J. Am. Chem. Soc. 2017, 139, 2172-2175. DOI: 10.1021/jacs.6b12788. [Abstract] [PDF]

448. (a) "Gigging Benzene", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem., Int. Ed. 2017, 58, 5664-5666. DOI: 10.1002/anie.201702942. [Abstract] [PDF]

(b) "Vom Aufspießen des Benzols", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem. 2017, 129, 5756–5758. DOI: 10.1002/ange.201702942. [Abstract] [PDF]

339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", Corrêa da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. DOI: 10.1039/B602428A. [Abstract][PDF]

353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", Corrêa da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. (invited article, olefin metathesis thematic issue) DOI: 10.1002 /adsc.200600461. [Abstract][PDF]

395. "Analogs of Grubbs' Second Generation Catalyst with Hydrophilic Phosphine Ligands: Phase Transfer Activation of Ring Closing Alkene Metathesis", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Org. Lett. 2011, 13, 6188-6191. DOI: 10.1021/ol202548q. [Abstract][PDF]

400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Abstract][PDF]

419. "Liquid/Solid Phase Transfer Activation of Grubbs-Type Alkene Metathesis Catalysts; Application of Silver Salts of Sulfonated Polystyrene", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Catal. Sci. Technol. 2014, 4, 4178-4182. DOI:10.1039/c4cy01021c. [Abstract][PDF]

430. "Phase Transfer Activation of Transition Metal Catalysts", Tuba, R.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Chem. Eur. J. 2015, 21, 15894-15906. DOI:10.1002/chem.201502403. [Abstract] [PDF]

432. "An Analogue of Grubbs' Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis", Balogh, J.; Hlil, A. R.; Su, H.-L.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. ChemCatChem. 2016, 8, 125-128. DOI: 10.1002/cctc.201500913 [Abstract] [PDF]