Gladysz Research Group

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321 Reed McDonald Building
Ph: 979-845-7048

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Department of Chemistry Texas A&M University
P.O. Box 30012
College Station, TX 77843-3012

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Texas A&M University
580 Ross Street
MS3255 TAMU
College Station, TX 77843-3255

Publications By Newest -- Publications by Area

Publications

1970 | 1980 | 1990 | 2000 | 2010 |bottom of list

1. "Nonenzymatic Nitrogen Fixation by an Iron-Molybdenum Model for Nitrogenase", van Tamelen, E. E.; Gladysz, J. A.; Miller, J. S. J. Am. Chem. Soc. 1973, 95, 1347-1348. DOI: 10.1021/ja00785a063. [Abstract] [PDF]
2. "Biological and Abiological Nitrogen Fixation by Molybdenum-Bound N₂/4Fe-4S Cluster Systems", van Tamelen, E. E.; Gladysz, J. A.; Brûlet, C. R. J. Am. Chem. Soc. 1974, 96, 3020-3021. DOI: 10.1021/ja00816a074. [Abstract] [PDF]
3. "Direct Conversion of Aldehydes, Esters, and 1,2-Oxides to Alkanes with Carbon Skeleton Preservation", van Tamelen, E. E.; Gladysz, J. A. J. Am. Chem. Soc. 1974, 96, 5290-5291. DOI: 10.1021/ja00823a065. [Abstract][PDF]
4. "I. Titanocene Induced Reductive Deligandations of Organic Compounds; II. Iron-Molybdenum Models for Nitrogenase", Gladysz, J. A. Diss. Abstr. Int. B. 1974, 35, 2654.
5. "Thione Complexes of Group VIB Pentacarbonyls", Gladysz, J. A.; Avakian, R. W. Syn. React. Inorg. Metal-Org. Chem. 1975, 5, 247-255. DOI: 10.1080/00945717508057315. [Abstract]
6. "Deoxygenation of Epoxides by Metal Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. J. Org. Chem. 1976, 41, 3647-3648. DOI: 10.1021/jo01303a023. [Abstract][PDF]
7. "5,6-Dehydro[3.3]Paracyclophane: Bridged Benzobarrelene Formation by Intramolecular Trapping of a Novel Aryne", Longone, D. T.; Gladysz, J. A. Tetrahedron Lett. 1976, 17, 4559-4562. DOI: 10.1016/SO040-4039(00)93931-5. [Abstract][PDF]
8. "Deoxygenation of Nitro and Nitroso Arenes via Chromium Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. Tetrahedron Lett. 1977, 18, 521-524. DOI: 10.1016/SO040-4039(01)92683-8. [Abstract][PDF]
9. "A Convenient Preparation of Transition Metal Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; Observation and Reactions of a Bimetallic Manganese-Formyl Intermediate", Gladysz, J. A.; Williams, G. M.; Tam, W; Johnson, D. L. J. Organomet. Chem. 1977, 140, C1-C6. DOI: 10.1016/SO022-328X(00)84402-2. [Abstract][PDF]
10. "A Convenient Synthesis of [3.3]Paracyclophane", Longone, D. T.; Kusefoglu, S. H.; Gladysz, J. A. J. Org. Chem. 1977, 42, 2787-2788. DOI: 10.1021/jo00436a033. [Abstract][PDF]
11. "Cyclotrimerization of Cyclic Diynes via Metal Atom Cocondensation; Revised Structure for the Reported 'Percyclophane-4'", Gladysz, J. A.; Fulcher, J. G.; Lee, S. J.; Bocarsly, A. B. Tetrahedron Lett. 1977, 18, 3421-3424. DOI: 10.1016/SO040-4039(01)83256-1. [Abstract][PDF]
12. "High Pressure Cycloadditions of Pyrones; Synthesis of Highly Functionalized Six-Membered Rings by Inhibitions of Carbon Dioxide Loss", Gladysz, J. A.; Lee, S. J.; Tomasello, J. A. V.; Yu, Y. S. J. Org. Chem. 1977, 42, 4170-4172. DOI: 10.1021/jo00445a050. [Abstract][PDF]
13. "Transition Metal Formyl Complexes: Synthesis by Trialkylborohydride Attack on Metal Carbonyl Acyls", Gladysz, J. A.; Selover, J. C. Tetrahedron Lett. 1978, 19, 319-322. DOI: 10.1016/SO040-4039(01)85114-5. [Abstract][PDF]
14. "A Convenient One-Flask Synthesis of Dialkyl Selenides and Diselenides via Lithium Triethylborohydride Reduction of Se_x", Gladysz, J. A.; Hornby, J. L.; Garbe, J. E. J. Org. Chem. 1978, 43, 1204-1208. DOI: 10.1021/jo00400a040. [Abstract][PDF]
15. "Binuclear and Mixed Metal Formyl Complexes; Isolation, Characterization, and Chemistry", Gladysz, J. A.; Tam, W. J. Am. Chem. Soc. 1978, 100, 2545-2547. DOI: 10.1021/ ja00476a046. [Abstract][PDF]
16. "Ligand Wrapping Around Chromium: Reactions of Diphenylmethane, 1,4-Diphenylbutane, Benzyl Ether, and Benzyl Sulfide with Chromium Atoms", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Tetrahedron Lett. 1978, 19, 1725-1728. DOI: 10.1016/SO040-4039(78)80027-6. [Abstract][PDF]
17. "A One-Flask Preparation of Analytically Pure K₂Fe(CO)₄", Gladysz, J. A.; Tam, W. J. Org. Chem. 1978, 43, 2279-2280. DOI: 10.1021/jo00405a041. [Abstract][PDF]
18. "Ene Reactions of β-Pinene at Room Temperature and 40 kbar Pressure", Gladysz, J. A.; Yu, Y. S. J. Chem. Soc., Chem. Commun. 1978, 599-600. DOI: 10.1039/C39780000599. [Abstract][PDF]
19. "Hydride Transfer Reactions of Anionic Formyl Complexes: A Mechanistic Test", Gladysz, J. A.; Merrifield, J. H. Inorg. Chim. Acta 1978, 30, L317-L318. DOI:10.1016/S0020-1693(00)88992-6. [Abstract][PDF]
20. "Introduction of Sulfur into Organic Molecules via Lithium Triethylborohydride Reduction of S₈", Gladysz, J. A.; Wong, V. K.; Jick, B. S. J. Chem. Soc., Chem. Commun. 1978, 838-839. DOI: 10.1039/C39780000838. [Abstract][PDF]
21. "Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds", Gladysz, J. A. in Fundamental Research in Homogeneous Catalysis, Vol. 2, Plenum, New York, 1978, pp. 101-115. (invited article, proceedings of international workshop on homogeneous catalysis)
22. "α-Silyloxy and α-Hydroxy Manganese Alkyls; Generation Via a New Five-membered Metallocycle", Gladysz, J. A.; Selover, J. C.; Strouse, C. E. J. Am. Chem. Soc. 1978, 100, 6766-6768. DOI: 10.1021/ja00489a044. [Abstract][PDF]
23. "²⁹Si NMR Spectra of Transition Metal Silanes by the Selective Population Transfer Method", Li, S.; Johnson, D. L.; Gladysz, J. A.; Servis, K. L. J. Organomet. Chem. 1979, 166, 317-321. DOI:10.1016/S0022-328X(00)82549-8. [Abstract][PDF]
24. "The Synthesis of Metal Carbonyl Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; A Convenient One-flask Preparation of Metal Alkyls, Metal Acyls, and Mixed Metal Compounds", Gladysz, J. A.; Williams, G. M.; Tam, W.; Johnson, D. L.; Parker, D. L.; Selover, J. C. Inorg. Chem. 1979, 18, 553-558. DOI: 10.1021/ic50193a006. [Abstract][PDF]
25. "Neutral Metal Formyl Complexes; Generation, Reactivity, and Models for Fischer-Tropsch Catalyst Intermediates", Tam, W.; Wong, W. K.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 1589-1591. DOI: 10.1021/ja00500a037. [Abstract][PDF]
26. "Trialkylborohydrides: Applications in Organometallic Syntheses", Gladysz, J. A. Aldrichimica Acta 1979, 12, 13-18. [Link]
27. "Reactions of Organocyclopropanes and Spirocycles with Metal Atoms", Gladysz, J. A.; Fulcher, J. G.; Ugolick, R. C.; Hanlan, A. J. L.; Bocarsly, A. B. J. Am. Chem. Soc. 1979, 101, 3388-3390. DOI: 10.1021/ja00506a048. [Abstract][PDF]
28. "Simplified in situ Syntheses of Anhydrous HMn(CO)₅", Gladysz, J. A.; Tam, W.; Williams, G. M.; Johnson, D. L.; Parker, D. W. Inorg. Chem. 1979, 18, 1163-1165. DOI: 10.1021/ic50194a05. [Abstract][PDF]
29. "X-Ray Crystal Structure and Chemical Transformations of the Neutral Metal Formyl (η-C₅H₅)Re(PPh₃)(NO)(CHO)", Wong, W.-K; Tam, W.; Strouse, C. E.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1979, 530-531. DOI: 10.1039/C39790000530. [Abstract][PDF]
30. "Squeezing the Transition State", Gladysz, J. A. CHEMTECH 1979, 9, 372-377.
31. "Electrophile Induced Disproportionation of the Neutral For (η-C₅H₅)Re(NO)(PPh₃)(CHO); Generation of Cationic Rhenium Carbenes of the Formula [(η-C₅H₅)Re(NO)(PPh₃)(CHX)]⁺ (X = H, OCH₃, OH)", Wong, W.-K; Tam, W.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 5440-5442. DOI: 10.1021/ja00512a069. [Abstract][PDF]
32. "New Methodology for the Introduction of Sulfur into Organic Molecules; Synthesis of Anhydrous Li₂S, Li₂S₂ and LiSR Species by Lithium Triethylborohydride Reduction of Elemental Sulfur and Disulfides", Gladysz, J. A.; Wong, V. K.; Jick, B. S. Tetrahedron 1979, 35, 2329-2335. DOI: 10.1016SO040-4020(01)93746-9. [Abstract][PDF]
33. "Reactions of Benzaldehyde with Trialkylsilyl Metal Carbonyl Complexes", Johnson, D. L.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 6433-6435. DOI: 10.1021/ja00515a048. [Abstract][PDF]
34. "Substitution Mechanisms at Metal Carbonyl Centers; Conversion of Ph₃P(CO)₄ReBr to Ph₃P(CO)₄ReCH₃ via an Anionic Acyl Intermediate", Parker, D. W.; Marsi, M. M.; Gladysz, J. A. J. Organomet. Chem. 1980, 194, C1-C4. DOI:10.1016/S0022-328X(00)90345-0. [Abstract][PDF]
35. "Deoxygenation and Desulfurization of Organic Compounds via Transition Metal Atom Cocondensation", Togashi, S.; Fulcher, J. C.; Cho, B.-R.; Hasegawa, M.; Gladysz, J. A. J. Org. Chem. 1980, 45, 3044-3053. DOI: 10.1021/jo01303a023. [Abstract][PDF]
36. "Unprecedented Regiospecificity and Stereospecificity in Reactions of Ph₃C⁺PF₆^- with Rhenium Alkyls of the Formula (η-C₅H₅)Re(NO)(PPh₃)(CH₂R)", Kiel, W. A.; Lin, G.-Y.; Gladysz, J. A. J. Am. Chem. Soc. 1980, 102, 3299-3301. DOI: 10.1021/ja00529a092. [Abstract][PDF]
37. "Chemistry via Metal Atom Cocondensation: Isomerization and Complexation Reactions of Organocyclopropanes and Spirocycles", Hanlan, A. J. L.; Ugolick, R. C.; Fulcher, J. G.; Togashi, S.; Bocarsly, A. B.; Gladysz, J. A. Inorg. Chem. 1980, 19, 1543-1551. DOI: 10.1021/ic50208a023. [Abstract][PDF]
38. "Stereospecific and Chemospecific Interconversions of the Rhenium Alkylidene [(η-C₅H₅)Re(NO)(PPh₃)(CHC₆H₅)]⁺ PF₆^- and the Alkylrhenium (η-C₅H₅)Re(NO)(PPh₃)(CH(OCH₃)C₆H₅)", Constable, A. G.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, C21-C24. DOI:10.1016/S0022-328X(00)81394-7. [Abstract][PDF]
39. "New Methods for Metal-Carbon Bond Formation: Reactions of (CO)₅MnSi(CH₃)₃ with Cyclic Ethers", Brinkman, K. C.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1980, 1260-1261. DOI: 10.1039/C39800001260. [Abstract][PDF]
40. "Preparation and Properties of (η-C₅H₅)₂ZrCl[Si(CH₃)₃] and (η-C₅H₅)₂Zr[Si(CH₃)₃]₂: Trimethylsilyl Group Transfer from Mercury to Zirconium", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, 263-268. DOI:10.1016/S0022-328X(00)92674-3. [Abstract][PDF]
41. "Preparation and Alkylation Reactions of K⁺[(CO)₄FeSi(CH₃)]^-; Reductive Elimination of Tetramethylsilane and Benzyl Trimethylsilane from Isolable (CO)₄FeRSi(CH₃)₃ Complexes", Blakeney, A. J.; Gladysz, J. A. Inorg. Chim. Acta 1981, 53, L25-L27. DOI:10.1016/S0020-1693(00)84730-1. [Abstract][PDF]
42. "Mononuclear Anionic Formyl Complexes; Synthesis and Properties", Selover, J. C.; Marsi, M.; Parker, D. W.; Gladysz, J. A. J. Organomet. Chem. 1981, 206, 317-329. DOI:10.1016/S0022-328X(00)83029-6. [Abstract][PDF]
43. "Nickel and Palladium Complexes in the Synthesis of Macrocyclic Compounds", Halweg, K. M.; Gladysz, J. A. The Strem Chemiker 1981, 9, 7-14.
44. "Electrophile Induced Disproportionation of the Neutral Formyl (η-C₅H₅)Re(NO)(PPh₃)(CHO); Isolation and Properties of the Rhenium Methylidene [(η-C₅H₅)Re(NO)(PPh₃)(CH₂)]⁺ PF₆^-, Gladysz, J. A.; Kiel, W. A.; Lin, G.-Y.; Wong, W.-K.; Tam, W. ACS Symposium Series 1981, 152, 147-164. DOI: 10.1021/bk-1981-0152.ch010. [Abstract]
45. "New Deoxygenative Transformations: Reactions of (CO)₄Fe[Si(CH₃)₃]₂ with Acyclic Ethers", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1981, 210, 303-312. DOI:10.1016/S0022-328X(00)80889-X. [Abstract][PDF]
46. "Reactions of (CO)₅MnSi(CH₃)₃ with Organic Carbonyl Compounds", Johnson, D. L.; Gladysz, J. A. Inorg. Chem. 1981, 20, 2508-2515. DOI: 10.1021/ic50222a028. [Abstract][PDF]
47. "Exploratory Organometal-Sulfur Chemistry: Syntheses and Unusual Properties of Rhenium -CH₂SR, -CH₂S⁺RR' and =CHSR]⁺ Complexes", McCormick, F. B.; Gladysz, J. A. J. Organomet. Chem. 1981, 218, C57-C61. DOI:10.1016/S0022-328X(00)81018-9. [Abstract][PDF]
48. "Three Rational Syntheses of New Stable Metal α-Hydroxyalkyl Complexes", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1981, 103, 5608-5609. DOI: 10.1021/ja00408a073. [Abstract][PDF]
49. "Synthesis of Iron Carbonyl Trimethylsilanes; Preparations and Interconversions of cis-(CO)₄Fe[Si(CH₃)₃]₂, M⁺ [(CO)₄FeSi(CH₃)₃]^-, and trans-[Fe(CO)₄Si(CH₃)₃]₂", Blakeney, A. J.; Johnson, D. L.; Donovan, P. W.; Gladysz, J. A. Inorg. Chem. 1981, 20, 4415-4419. DOI: 10.1021/ic50226a076. [Abstract][PDF]
50. "Synthesis and Electrophile Induced Disproportionation of the Neutral Formyl (η-C₅H₅)Re(NO)(PPh₃)CHO)", Tam, W.; Lin, G.-Y.; Wong, W.-K.; Kiel, W. A.; Wong, V. K.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 141-152. DOI: 10.1021/ja00365a027. [Abstract][PDF]
51. "A New Organometallic Photoreaction: Interconversion of Metal-Alkylidene Geometric Isomers", McCormick, F. B.; Kiel, W. A.; Gladysz, J. A. Organometallics 1982, 1, 405-408. DOI: 10.1021/om00062a033. [Abstract][PDF]
52. "Organic Transformations via Metal Silane Reagents: Syntheses of Vinyl Ethers from Dimethyl Ketals and (CO)₅MnSi(CH₃)₃", Marsi, M.; Gladysz, J. A. Tetrahedron Lett. 1982, 23, 631-634. DOI: 10.1016/SO040-4039(00)86908-7. [Abstract][PDF]
53. "Syntheses of Kinetically Unstable Neutral Formyl Complexes via Li(C₂H₅)₃BH and 'Transformylation' Reactions of Metal Carbonyl Cations", Tam, W.; Lin, G.-Y.; Gladysz, J. A. Organometallics 1982, 1, 525-529. DOI: 10.1021/om00063a022. [Abstract][PDF]
54. "Transition Metal Formyl Complexes", Gladysz, J. A. Adv. Organomet. Chem. 1982, 20, 1-38. DOI:10.1016/S0065-3055(08)60519-5. [Abstract]
55. "Substituent Effects upon Alkyl Migration to Coordinated CO: Syntheses and Carbonylation Studies of (CO)₅MnCH₂I and (CO)₅MnCH₂OSi(CH₃)₃", Brinkman, K. C.; Vaughn, G. D.; Gladysz, J. A. Organometallics 1982, 1, 1056-1060. DOI: 10.1021/om00068a010. [Abstract][PDF]
56. "Synthesis and Properties of [(η-C₅H₅)Re(NO)(PPh₃)(=CHC₆H₅)]⁺ PF₆^-: A Benzylidene Complex that is Formed by a Stereospecific α-Hydride Abstraction, Exists as Two Geometric Isomers, and Undergoes Stereospecific Nucleophilic Attack", Kiel, W. A.; Lin, G.-Y.; Constable, A. G.; McCormick, F. B.; Strouse, C. E.; Eisenstein, O.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4865-4878. DOI: 10.1021/ja00382a021. [Abstract][PDF]
57. "Synthesis, Optical Resolution, and Absolute Configuration of Pseudotetrahedral Organorhenium Complexes (η-C₅H₅)Re(NO)(PPh₃)(X)", Merrifield, J. H.; Strouse, C. E.; Gladysz, J. A. Organometallics 1982, 1, 1204-1211. DOI: 10.1021/om00069a018. [Abstract][PDF]
58. "Syntheses and Reactions of Rhenium Vinylidene and Acetylide Complexes; Unprecedented Chirality Transfer through a C≡C Triple Bond", Wong, A.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4948-4950. DOI: 10.1021/ja00382a036. [Abstract][PDF]
59. "Reactions of Ketals and Acetals with (CO)₅MnSi(CH₃)₃; A New Vinyl Ether Synthesis", Marsi, M.; Gladysz, J. A. Organometallics 1982, 1, 1467-1473. DOI: 10.1021/om00071a012. [Abstract][PDF]
60. "Synthesis, Chemical Properties, and X-ray Crystal Structures of Rhenium Formaldehyde and Thioformaldehyde Complexes", Buhro, W. E.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A.; McCormick, F. B.; Etter, M. C. J. Am. Chem. Soc. 1983, 105, 1056-1058. DOI: 10.1021/ja00342a070. [Abstract][PDF]
61. "Bimetallic Anionic Formyl Complexes; Synthesis and Properties", Tam, W.; Marsi, M.; Gladysz, J. A. Inorg. Chem. 1983, 22, 1413-1421. DOI: 10.1021/ic00152a001. [Abstract][PDF]
62. "Synthesis and Decarboxylation Mechanism of the Chiral Rhenium Formate (η-C₅H₅)Re(NO)(PPh₃)(OCHO)", Merrifield, J. H.; Gladysz, J. A. Organometallics 1983, 2, 782-784. DOI: 10.1021/om00078a022. [Abstract][PDF]
63. "Regiospecific and Stereospecific Reactions of Ph₃C⁺ PF₆^- with Rhenium Alkyls (η-C₅H₅)Re(NO)(PPh₃)(R); α vs β Hydride Abstraction", Kiel, W. A.; Lin, G.-Y.; Bodner, G. S.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 4958-4972. DOI: 10.1021/ja00353a020. [Abstract][PDF]
64. "Syntheses, Properties and X-ray Crystal Structures of Stable Methylidene Complexes of the Formula [(η-C₅Me₅)Re(NO)(L)(=CH₂)]⁺ PF₆^-", Patton, A. T.; Strouse, C. E.; Knobler, C. B.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5804-5811. DOI: 10.1021/ja00356a018. [Abstract][PDF]
65. " Mechanism of Coupling of =CH₂ to H₂C=CH₂ at a Homogeneous (η-C₅H₅)Re(NO)(PPh₃)⁺ Center; Remarkable Enantiomer Self-Recognition", Merrifield, J. H.; Lin, G.-Y.; Kiel, W. A.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5811-5819. DOI: 10.1021/ja00356a019. [Abstract][PDF]
66. "Synthesis and Chemistry of Chiral Vinyl Rhenium Complexes (η-C₅H₅)Re(NO)(PPh₃)(CH=CHR). Stereoselective Reactions with Electrophiles and a Spontaneous Alkylidene to Olefin Rearrangement", Hatton, W. G.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 6157-6158. DOI: 10.1021/ja00356a018. [Abstract][PDF]
67. "Atomos de Metales de Transicion en la Sintesis y la Catalisis Organica", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Rev. Soc. Quim. Mex. 1983, 27, 146-148.
68. "A New Route to Metal Alkylidene Complexes; Synthesis of Ylide Adducts (CO)₄Fe^-CH(R)P⁺Ar₃ from Aldehydes, Triarylphosphines, and (CO)₄FeSi(CH₃)₂CH₂CH₂Si(CH₃)₂", Nakazawa, H.; Johnson, D. L.; Gladysz, J. A. Organometallics 1983, 2, 1846-1851. DOI: 10.1021/om50006a025. [Abstract][PDF]
69. "Synthesis and Chemistry of Chiral Rhenium Acyls (η-C₅H₅)Re(NO)(PPh₃)(COR)", Buhro, W. E.; Wong, A.; Merrifield, J. H.; Lin, G.-Y.; Constable, A. G.; Gladysz, J. A. Organometallics 1983, 2, 1852-1859. DOI: 10.1021/om50006a026. [Abstract][PDF]
70. "Reactions of (CO)₅MnSi(CH₃)₃ and CO with Aldehydes and Cyclic Ethers; Syntheses of Functionalized Pentacarbonyl Manganese Acyls and Homologated Organic Compounds", Brinkman, K. C.; Gladysz, J. A. Organometallics 1984, 3, 147-155. DOI: 10.1021/om00079a026. [Abstract][PDF]
71. (a) "Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese. Synthesis of Ylide Complexes (CO)₄MnCR(OSiMe₃)PPh₂ and a New Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1984, 23, 245-246. DOI: 10.1002/ange.1984096031. [Abstract][PDF] (b) "Reaktionen von Diphenyl(trimethylsilyl)phosphan mit Alkyl(pentacarbonyl)mangan; Synthese der Ylidkomplexe (CO)₄MnCR(OSiMe₃)PPh₂ unter Beteiligung einer CO-Einschiebung", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem. 1984, 96, 230-231. DOI: 10.1002/ange.19840960316. [Abstract][PDF]
72. "Reaction of Benzylrhenium Complexes (η-C₅H₅)Re(NO)(L)(CH₂Ar) with Ph₃C⁺PF₆^-; Analysis of the Re-C_α Rotamers Involved in α-Hydride Abstraction", Kiel, W. A.; Buhro, W. E.; Gladysz, J. A. Organometallics 1984, 3, 879-886. DOI: 10.1021/om00084a010. [Abstract][PDF]
73. "Alkylation and Acylation of the Iron Carbonyl Anion [(CO)₄FeSi(CH₃)₃]^-. Evidence for 1,3-Silatropic Shifts from Iron to Acyl Oxygen", Brinkman, K. C.; Blakeney, A. J.; Krone-Schmidt, W.; Gladysz, J. A. Organometallics 1984, 3, 1325-1332. DOI: 10.1021/ om00087a001. [Abstract][PDF]
74. "New Synthetic Chemistry of Transition Metal Trialkylsilane Complexes", Gladysz, J. A. Acc. Chem. Res. 1984, 17, 326-332. DOI: 10.1021/ar00105a005. [Abstract][PDF]
75. "Reactions of Phosphorus Electrophiles with [(η⁵-C₅Me₅)Fe(CO)₂]^-: Spectroscopic Evidence for a Phosphinidene Complex", Nakazawa, H.; Buhro, W. E.; Bertrand, G.; Gladysz, J. A. Inorg. Chem. 1984, 23, 3431-3433. DOI: 10.1021/ic00190a001. [Abstract][PDF]
76. "Hydrogen Bonding in Organometallic Ligands and Possible Implications for CO/H₂ Chemistry: First Carbonylation of an Isolable Metal α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. Organometallics 1984, 3, 1596-1598. DOI: 10.1021/om00088a028. [Abstract][PDF]
77. "Deprotonation and Anionic Rearrangements of Organometallic Compounds, 1. Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Gladysz, J. A. J. Am. Chem. Soc. 1984, 106, 7636-7637. DOI: 10.1021/ja00336a062. [Abstract][PDF]
78. "Cleavage of Rhenium-Methyl Bond of (η-C₅H₅)Re(NO)(PPh₃)(CH₃) by Protic and Halogen Electrophiles; Stereochemistry at Rhenium", Merrifield, J. H.; Fernández, J. M.; Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1984, 23, 4022-4029. DOI: 10.1021/ic00192a036. [Abstract][PDF]
79. "Deprotonation and Anionic Rearrangements of Organometallic Compounds. Reactions of the Hydride Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(H) with n-Butyl-lithium-Tetramethylethylenediamine", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1985, 283-284. DOI: 10.1039/C39850000283. [Abstract][PDF]
80. "Electrochemical Oxidation of Rhenium Alkyl Complexes [Re(η⁵-C₅H₅)(NO)(PPh₃)R]; Implications for the Mechanism of Hydride Abstraction by Ph₃C⁺PF₆^-", Asaro, M. F.; Bodner, G. S.; Gladysz, J. A.; Cooper, S. R.; Cooper N. J. Organometallics 1985, 4, 1020-1024. DOI: 10.1021/om00125a010. [Abstract][PDF]
81. "Synthesis, Conformation, and Reactivity of the Rhenium Phosphide Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(PPh₂). The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 3346-3348. DOI: 10.1021/ja00297a050. [Abstract][PDF]
82. "Deprotonation and Anionic Rearrangements of Organometallic Compounds, III. The First Carbon-Carbon Bond-Forming Reaction of an η¹-Formyl Ligand", Heah, P. C.; Gladysz, J. A. J. Mol. Cat. 1985, 31, 207-209. DOI:10.1016/0304-5102(85)85062-8. [Abstract][PDF]
83. "Reactions of Cyanomethyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂CN) with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of a Transition Metal Substituted Carbanion", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 4103-4104. DOI: 10.1021/ja00299a071. [Abstract][PDF]
84. "Reactions of Chiral α-Methoxyvinyl Rhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(C(OCH₃)=CHR) with Alkyl Halides; Efficient 1,3-Asymmetric Induction", Smith, D. E.; Gladysz, J. A. Organometallics 1985, 4, 1480-1481. DOI: 10.1021/om00127a039. [Abstract][PDF]
85. "Reactions of (CO)₅MnSi(CH₃)₃ with α-Bromocarbonyl and Related Organic Compounds; Facile Reductive Silylation", Marsi, M.; Brinkman, K. C.; Lisensky, C. A.; Vaughn, G. D.; Gladysz, J. A. J. Org. Chem. 1985, 50, 3396-3401. DOI: 10.1021/jo00218a030. [Abstract][PDF]
86. "Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PRR')", Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1985, 24, 3505-3507. DOI: 10.1021/ic00216a005. [Abstract][PDF]
87. "Reactions of Organorhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂R) with Ph₃C⁺PF₆^-; Analysis of the Energetics of α-Hydride Abstraction", Georgiou, S.; Gladysz, J. A. Tetrahedron 1986, 42, 1109-1116. DOI: 10.1016/SO040-4020(01)87514-1. [Abstract][PDF]
88. "Deprotonation and Anionic Rearrangements of Organometallic Compounds. V. Kinetic vs Thermodynamic Deprotonation in Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Patton, A. T.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1185-1195. DOI: 10.1021/ja00266a012. [Abstract][PDF]
89. "Synthesis and Reactivity of Metal α-Hydroxyalkyl Complexes; Generation of (CO)₅MCH(C₆H₅)OH (M = Mn, Re)", Selover, J. C.; Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1455-1462. DOI: 10.1021/ja00267a015. [Abstract][PDF]
90. "Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium α-Hydroxyalkyl Complexes of the Formula (CO)₄MP(C₆H₅)₂)(o-C₆H₄CHOH)", Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1462-1473. DOI: 10.1021/ja00267a016. [Abstract][PDF]
91. "Synthesis and Reactivity of Metallacyclic Manganese α-Hydroxyalkyl Complexes Containing Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms; First Carbonylation of an Isolable α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1473-1480. DOI: 10.1021/ja00267a017. [Abstract][PDF]
92. " Synthesis and Reactivity of Metallacyclic Manganese α-(Silyloxy)alkyl Complexes (CO)₄MnC(R)(OSi(CH₃)₃)P(C₆H₅)₂; A New Thermodynamic Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Organometallics 1986, 5, 936-942. DOI: 10.1021/om00136a016. [Abstract][PDF]
93. "Synthesis, Structure, and Reactivity of the Formaldehyde Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-H₂C=O)]⁺PF₆^-", Buhro, W. E.; Georgiou, S.; Fernández, J. M.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A. Organometallics 1986, 5, 956-965. DOI: 10.1021/om00136a020. [Abstract][PDF]
94. "Generation and Reactions of Chiral, Pyramidal, Transition Metal Lewis Acids of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺X^-", Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1986, 25, 2672-2674. DOI: 10.1021/ic00236a00. [Abstract][PDF]
95. "Reaction of Ylide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂PAr₃)]⁺PF₆^- with n-Butyl-lithium-Tetramethylethylenediamine: Generation and Stereospecific Alkylation of a Transition-Metal-Substituted-Wittig Reagent", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1986, 1154-1156. DOI: 10.1039/C39860001154. [Abstract][PDF]
96. "Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂)]_nS⁺(CH₃)_3-n (n = 1,2,3)", McCormick, F. B.; Gleason, W. B.; Zhao, X.; Heah, P. C.; Gladysz, J. A. Organometallics 1986, 5, 1778-1785. DOI: 10.1021/om00140a004. [Abstract][PDF]
97. "A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-RCH=O)]⁺PF₆^-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 8268-8270. DOI: 10.1021/ja00286a030. [Abstract][PDF]
98. "Novel Electron Impact-Induced Hydrogen Rearrangements in the Mass Spectra of Organorhenium Hydrides and Alkyls", Crocco, G. L.; Sharp, T. L.; Gladysz J. A. Int. J. Mass. Spectrum. Ion. Phys. 1986, 73, 181-185. DOI:10.1016/0168-1176(86)80019-2. [Abstract][PDF]
99. "New Mechanistic Probes of Hydride Abstraction from Rhenium Alkyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R) by Ph₃C⁺PF₆^-; Evidence for Initial Electron Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 1757-1764. DOI: 10.1021/ja00240a027. [Abstract][PDF]
100. "Synthesis, Structure, and Reactivity of the Thioformaldehyde Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-H₂C=S)]⁺PF₆^-", Buhro, W. E.; Etter, M. C.; Georgiou, S.; Gladysz, J. A.; McCormick, F. B. Organometallics 1987, 6, 1150-1156. DOI: 10.1021/om00149a003. [Abstract][PDF]
101. "A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups; Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R)", O'Connor, E. J.; Kobayashi, M.; Floss, H. G.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 4837-4844. DOI: 10.1021/ja00250a014. [Abstract][PDF]
102. "Electrochemical Oxidation of Rhenium Alkyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(R): Evidence for One-Electron Charge Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. Organometallics 1987, 6, 1628-1633. DOI: 10.1021/om00151a006. [Abstract][PDF]
103. "Synthesis, Structure, and Reactivity of Transition Metal/Main Group Metal Bridging Carboxylate Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CO₂ML_n) (M = Li, K, Ge, Sn, Pb)", Senn, D. R.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Inorg. Chem. 1987, 26, 2737-2739. DOI: 10.1021/ic00264a001. [Abstract][PDF]
104. (a) "A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon A Chiral Rhenium Template Containing Two Phosphido Substituents", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1987, 26, 910-912. DOI: 10.1002/anie.198709101. [Abstract][PDF] (b) "Ein neuartiger heterodinuclearer Katalysator für die asymmetrische Hydrierung ein Bisphosphido-Ligand mit einem stereogenen Rheniumzentrum", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem. 1987, 99, 921-922. DOI: 10.1002/ange.19870990914. [Abstract][PDF]
105. "Crystallographic and Theoretical Analyses of the Structures of Rhenium Formyl and Acyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(COR)", Bodner, G. S.; Patton, A. T.; Smith, D. E.; Georgiou, S.; Tam, W.; Wong, W.-K.; Strouse, C. E.; Gladysz, J. A. Organometallics 1987, 6, 1954-1961. DOI: 10.1021/om00152a021. [Abstract][PDF]
106. "A New Method for the Activation of Metal-Bound Methyl Groups. Oxidative Disproportionation to Coordinated Ethylene and Methane", Tilset, M.; Bodner, G. S.; Senn, D. R.; Gladysz, J. A.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 7551-7553. DOI: 10.1021/ ja00258a062. [Abstract][PDF]
107. "A General Class of Stable Alkyl Halide Complexes; Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(IR)]⁺BF₄^-", Winter, C. H.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7560-7561. DOI: 10.1021/ja00258a067. [Abstract][PDF]
108. "Synthesis, Structure, and Alkylation of Chiral Vinyl Rhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(CX=CHR) (X = H, OCH₃). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium To Carbon", Bodner, G. S.; Smith, D. E.; Hatton, W. G.; Heah, P. C.; Georgiou, S.; Rheingold, A. L.; Geib, S. J.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7688-7705. DOI: 10.1021/ja00259a018. [Abstract][PDF]
109. "The Selective Activation of One Ketone Enantioface via σ-Binding to a Chiral Metal Template: Synthesis and Reactivity of Rhenium Ketone Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-RR'C=O)]⁺PF₆^-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1988, 37-39. DOI: 10.1039/C39880000037. [Abstract][PDF]
110. "Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands", Crocco, G. L.; Gladysz, J. A. Chem. Ber. 1988, 121, 375-377. DOI: 10.1002/cber.19881210227. [Abstract][PDF]
111. "Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PR₂): The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439. DOI: 10.1021/ja00216a015. [Abstract][PDF]
112. "Aldehyde and Ketone Ligands in Organometallic Complexes and Catalysis", Huang, Y.-H.; Gladysz, J. A. J. Chem. Ed. 1988, 65, 298-303. DOI: 10.1021/ed065p298. [Abstract][PDF]
113. "Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]", Bodner, G. S.; Fernández, J. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 4082-4084. DOI: 10.1021/ ja00220a082. [Abstract][PDF]
114. "Synthesis and Reactivity of Functionalized Rhenium Germyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(GePh₂X); Dynamic Equilibria with Germylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GePh₂)]⁺ X^-", Lee, K. E.; Gladysz, J. A. Polyhedron 1988, 7, 2209-2211. DOI: 10.1016/S0277-5387(00)81805-7. [Abstract][PDF]
115. "Synthesis, Structure, and Reactions of Chiral Rhenium Vinylidene and Acetylide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(X)]ⁿ⁺; Vinylidene Complexes that are Formed by Stereospecific C_β Electrophilic Attack, Exist as Two Re=C=C Geometric Isomers, and Undergo Stereospecific Nucleophilic C_α Attack", Senn, D. R.; Wong, A.; Patton, A. T.; Marsi, M.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6096-6109. DOI: 10.1021/ja00226a026. [Abstract][PDF]
116. "Divergent Kinetic and Thermodynamic Acidity in Organotransition-Metal Hydride Complexes; Synthesis, Structure, and Reactivity of the Rhenium Anion Li⁺ [(η⁵-C₅H₅)Re(NO)(PPh₃)]^-", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6110-6118. DOI: 10.1021/ja00226a027. [Abstract][PDF]
117. "Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(SiR₂X). Anionic Rearrangements Leading to the New Disilametallacycle ((η⁵-C₅H₅)Re(NO)(PPh₃)Si(CH₃)₂)", Crocco, G. L.; Young, C. S.; Lee, K. E.; Gladysz, J. A. Organometallics 1988, 7, 2158-2162. DOI: 10.1021/om00100a012. [Abstract][PDF]
118. "Generation of the Dichloromethane Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClCH₂Cl)]⁺ BF₄^-, and its Conversion to the Oxidative Addition Product (η⁵-C₅H₅)Re(NO)(PPh₃)Cl)(CH₂Cl)]⁺ BF₄^-", Winter, C. H.; Gladysz, J. A. J. Organomet. Chem. 1988, 354, C33-C36. DOI:10.1016/0022-328X(88)80664-8. [Abstract][PDF]
119. "Synthetic Approaches to the Chiral, Pyramidal, Transition Metal Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ X^-; Generation, Characterization, and Reactions of a Dichloromethane Adduct", Fernández, J. M.; Gladysz, J. A. Organometallics 1989, 8, 207-219. DOI: 10.1021/om00103a027. [Abstract][PDF]
120. "Synthesis, Structure, and Reactivity of Bridging Halide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]₂X⁺ BF₄^-; Preferential Binding of One Enantiomer of Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) by the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Winter, C. H.; Arif, A. M.; Gladysz, J. A. Organometallics 1989, 8, 219-225. DOI: 10.1021/om00103a028. [Abstract][PDF]
121. "Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ by K(s-C₄H₉)₃BH; Synthesis of Optically Active Secondary Alcohols and Derivatives", Dalton, D. M.; Gladysz, J. A. J. Organomet. Chem. 1989, 370, C17-C21. DOI:10.1016/0022-328X(89)87307-3. [Abstract][PDF]
122. "Synthesis, Structure and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(IR)]⁺ BF₄^-", Winter, C. H.; Veal, W. R.; Garner, C. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1989, 111, 4766-4776. DOI: 10.1021/ja00195a033. [Abstract][PDF]
123. "The Role of Virtual Halogen d Orbitals in the Stability and Reactivity of Rhenium Alkyl-Halide Complexes of the Form [(η⁵-C₅H₅)Re(NO)(PPh₃)(XR)]⁺", Czech, P. T.; Gladysz, J. A.; Fenske, R. F. Organometallics 1989, 8, 1806-1810. DOI: 10.1021/om00109a038. [Abstract][PDF]
124. "Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae [(η⁵-C₅H₅)Re(NO)(PPh₃)(η2-O=CHR)]⁺ BF₄^-; A New Synthesis of Optically Active Cyanohydrin Derivatives", Garner, C. M.; Fernández, J. M.; Gladysz, J. A. Tetrahedron Lett. 1989, 30, 3931-3934. DOI: 10.1016/SO040-4039(00)99278-6. [Abstract][PDF]
125. "Synthesis and Reactivity of Functionalized Rhenium Phosphido Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PXX'). An Unusual CCl₄ 1,3-Addition Leading to an Exo-Substituted η⁴-Cyclopentadiene Complex", Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1989, 28, 3837-3845. DOI: 10.1021/ic00319a018. [Abstract][PDF]
126. "Synthesis and Structure of Chiral Rhenium Allyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂C(R')=CHR)", Bodner, G. S.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Organometallics 1989, 8, 2399-2404. DOI: 10.1021/om00112a022. [Abstract][PDF]
127. "Tetracarbonyl{[2-(diphenylphosphino)phenyl]hydroxymethyl-C,P}manganese", Vaughn, G. D.; Gladysz, J. A. Inorg. Synth. 1989, 26, 169-171. DOI: 10.1002/9780470132579.ch30. [Abstract][PDF]
128. "Optical Resolution and Absolute Configuration of the Chiral Pentamethylcyclopentadienyl Rhenium Carbonyl Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CO)]⁺ BF₄^-", Huang, Y.-H.; Niedercorn, F.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 383, 213-225. DOI: 10.1016/0022-328X(90)85133-J. [Abstract][PDF]
129. "Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(OR₂)]⁺ X^-", Agbossou, S. K.; Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 476-480. DOI: 10.1021/ic00328a027. [Abstract][PDF]
130. "Synthesis and Structure of σ-Pyridine, Quinoline, and Isoquinoline Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(NC_xH_y)]⁺ CF₃SO₃^-", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 384, C29-C32. DOI: 10.1016/0022328X(90)87079-S. [Abstract][PDF]
131. "Synthesis, Structure, and Reactivity of the Chiral Rhenium Phenyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(C₆H₅)", Agbossou, S. K.; Bodner, G. S.; Patton, A. T.; Gladysz, J. A. Organometallics 1990, 9, 1184-1191. DOI: 10.1021/om00118a046. [Abstract][PDF]
132. "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ X^-", Bodner, G. S.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organometallics 1990, 9, 1191-1205. DOI: 10.1021/om00118a047. [Abstract][PDF]
133. "Isomerization of Diastereomeric Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺; the Alkene Enantioface Bound to the Metal can "Flip" Without Alkene Dissociation", Peng, T.-S.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1990, 902-903. DOI: 10.1039/C39900000902. [Abstract][PDF]
134. "Synthesis and Reactivity of Chiral Rhenium Amine and Amide Complexes of the Formulas [(η⁵-C₅H₅)Re(NO)(PPh₃)(NHRR')]⁺ TfO^- and (η⁵-C₅H₅)Re(NO)(PPh₃)(NRR')", Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1349-1351. DOI: 10.1021/om00118a083. [Abstract][PDF]
135. "Mechanism of Equilibration of Diastereomeric Rhenium Amide Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(NHCHRR'); Rhenium vs Carbon Epimerization", Dewey, M. A.; Gladysz, J. A. Organometallics 1990, 9, 1351-1353. DOI: 10.1021/om00118a084. [Abstract][PDF]
136. "Selective Binding of One Aldehyde Enantioface by a Chiral Transition Metal Lewis Acid: Synthesis, Structure and Reactivity of Rhenium Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHR)]⁺ X^-", Garner, C. M.; Quirós Méndez, N.; Kowalczyk, J. J.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 5146-5160. DOI: 10.1021/ja00169a024. [Abstract][PDF]
137. "Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ROH)]⁺ BF₄^-", Agbossou, S. K.; Smith, W. W.; Gladysz, J. A. Chem. Ber. 1990, 123, 1293-1299. DOI: 10.1002/cber.19901230612. [Abstract][PDF]
138. "Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions to Chiral Monosubstituted Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Gladysz, J. A. Tetrahedron Lett. 1990, 31, 4417-4420. DOI: 10.1016/SO040-4039(00)97636-6. [Abstract][PDF]
139. "Synthesis, Structure, and Reactivity of the Nitrosyl Ligand/Lewis Acid Adduct (η⁵-C₅H₅)Re(NO·BCl₃)(PPh₃)(SiMe₂Cl)", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 2885-2887. DOI: 10.1021/ic00341a005. [Abstract][PDF]
140. "Reactions of Cyanomethyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂CN) and Ylide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂P(p-tol)₃)]⁺ PF₆^- with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of Transition-Metal-Substituted Carbanions and Ylides", Crocco, G. L.; Lee, K. E.; Gladysz, J. A. Organometallics 1990, 9, 2819-2831. DOI: 10.1021/om00160a034. [Abstract][PDF]
141. "Generation and Reactivity of the Chiral Rhenium Chlorobenzene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClC₆H₅)]⁺ BF₄^-: An Improved Functional Equivalent of the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ BF₄^-", Kowalczyk, J. J.; Agbossou, S. K.; Gladysz, J. A. J. Organomet. Chem. 1990, 397, 333-346. DOI: 10.1016/0022-328X(90)85333-T. [Abstract][PDF]
142. "A New Carbon-Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^- by the Base t-BuO^- K⁺", Peng, T.-S.; Gladysz, J. A. Organometallics 1990, 9, 2884-2886. DOI: 10.1021/om00161a016. [Abstract][PDF]
143. "Selective Activation of One Methyl Ketone Enantioface via σ-Binding to a Chiral Transition Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-O=C(CH₃)R]⁺ X^-", Dalton, D. M.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 9198-9212. DOI: 10.1021/ja00181a024. [Abstract][PDF]
144. (a) "π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Aromatic Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]⁺ X^-", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1473-1474. DOI: 10.1002/anie.199014731. [Abstract][PDF] (b) "π/σ-Gleichgewichte in Metall-Komplexen organischer Carbonylverbindungen; Synthese und Struktur chiraler Rhenium-Komplexe [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]X", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1990, 102, 1507-1509. DOI: 10.1002/ange.19901021245. [Abstract][PDF]
145. (a) "Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHAr)]BF₄", Quirós Méndez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1475-1476. DOI: 10.1002/anie.199014751. [Abstract][PDF] (b) "Thermodynamisch kontrollierte enantiofaciale Selektivität bei der Bindung von Aldehyden an chirale Metall-Komplexfragmente, der Mechanismus der Interkonversion diastereomerer π-Aldehyd-Komplexe [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHAr)]BF₄", Quirós Méndez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem. 1990, 102, 1509-1511. DOI: 10.1002/ange.19901021246. [Abstract][PDF]
146. "Synthesis, Structure, and Reactivity of Functionalized Germyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(GePh₂X); Equilibria Involving the Germylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GePh₂)]⁺ TfO^-", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 751-760. DOI: 10.1021/om00049a040. [Abstract][PDF]
147. "Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(SiMe₂X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base-Free Silylene Complexes", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 309-320 (1991). ISSN 0009-2940. [Abstract][PDF]
148. "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkyne Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(RC≡CR')]⁺ BF₄^-", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079-1088. DOI: 10.1021/om00050a045. [Abstract][PDF]
149. "Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH=CH(CH₂)_n-2)]⁺ BF₄^-; Facile Vinylic Deprotonation of a Coordinated Alkene", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 729-742. DOI: 10.1002/cber.19911240410. [Abstract][PDF]
150. "Delocalized Electronic Interactions in Chiral Cyclopentadienyl Rhenium Halide Complexes. The Valence Photoelectron Spectra of the Formula CpRe(NO)(L)X", Lichtenberger, D. L.; Rai-Chaudhuri, A. R.; Seidel, M. J.; Gladysz, J. A.; Agbossou, S. K.; Igau, A.; Winter, C. H. Organometallics 1991, 10, 1355-1364. DOI: 10.1021/om00051a028. [Abstract][PDF]
151. "Synthesis and Structure of the Rhenium Phenylamido Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(NHPh); An Unprecedented Pyramidal Amido Ligand", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 712-714. DOI: 10.1039/C399¬10000712. [Abstract][PDF]
152. "Facile Separations of Enantiomers of Chiral Organometallic Compounds with A Bakerbond Chiralcel HPLC Column", Ramsden, J. A.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 1631-1633. DOI: 10.1021/om00051a066. [Abstract][PDF]
153. "π/σ Equilibria in rhenium ketone complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CRR')]⁺X^-; a marked electronic effect upon the binding mode", Klein, D. P.; Dalton, D. M.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1991, 412, C7-C10. DOI:10.1016/0022-328X(91)86066-Y. [Abstract][PDF]
154. "Synthesis, Structure, and Dynamic Behavior of Rhenium Sulfide and Sulfoxide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(L)(XRR')]⁺ X'^- (X = S, SO)", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 2199-2209. DOI: 10.1021/om00053a024. [Abstract][PDF]
155. "Reactions of the Neohexyl Iodide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ICH₂CH₂C(CH₃)₃)]⁺BF₄^- and Nucleophiles: Stereochemistry of Carbon-Iodine Bond Cleavage in Highly Accelerated S_N2 Reactions", Igau, A.; Gladysz, J. A. Organometallics 1991, 10, 2327-2334. DOI: 10.1021/om00053a040. [Abstract][PDF]
156. "Reactions of the Terminal Rhenium Acetylide Complex Re(η⁵-C₅H₅)(NO)(PPh₃)(C≡CH) and Butyllithium; Generation, Alkylation, and Stannylation of Lithiocarbide Complexes of the Formula Re(η⁵-C₅H₅)(NO)(PPh₃)(C≡CLi) (X = H, Li)", Ramsden, J. A.; Agbossou, F.; Senn, D. R.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 1360-1362. ISSN 0022-4936. [Abstract][PDF]
157. "A New Catalyst for the Epimerization of Secondary Alcohols: Carbon-Hydrogen Bond Activation in the Rhenium Alkoxide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(OCHRR')", Saura-Llamas, I.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 2533-2535. DOI: 10.1021/om00054a003. [Abstract][PDF]
158. "Synthesis and Characterization of Chiral Rhenium σ-Ketone Complexes. Binding Properties of Symmetrical Ketones and Alkylcyclohexanones", Dalton, D. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1991, 2741-2747. ISSN 0300-9246. [Abstract][PDF]
159. "Mechanism of Isomerization of Alkylidene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(=CHCHR'R'')]⁺X^- to Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CR'R'')]⁺X^-: An Organometallic Wagner-Meerwein-Type Rearrangement", Roger, C.; Bodner, G. S.; Hatton, W. G.; Gladysz, J. A. Organometallics 1991, 10, 3266-3274. DOI: 10.1021/om00055a051. [Abstract][PDF]
160. "A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives: Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CRR')]⁺BF₄^-", Dalton, D. M.; Garner, C. M.; Fernández, J. M.; Gladysz, J. A. J. Org. Chem. 1991, 56, 6823-6829. DOI: 10.1021/jo00024a023. [Abstract][PDF]
161. "Synthesis and Chemistry of Secondary Alkyl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ICHRR')]⁺BF₄^-", Igau, A.; Gladysz, J. A. Polyhedron 1991, 10, 1903-1909. DOI: 10.1016/S0277-2387(00)86054-4. [Abstract][PDF]
162. "Synthesis, Structure, and Reactivity of Chiral Rhenium Amine Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(NRR'R")]⁺TfO^-", Dewey, M. A.; Knight, D. A.; Klein, D. P.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1991, 30, 4995-5002. DOI: 10.1021/ic00026a026. [Abstract][PDF]
163. "Synthesis, Structure, and Reactivity of Chiral Rhenium Carboxylic and Carbonic Acid Ester Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-O=C(X)X')]⁺X''^-", Saura-Llamas, I.; Dalton, D. M.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 683-693. DOI: 10.1021/om00038a028. [Abstract][PDF]
164. "Synthesis, Structure, and Reactivity of (Pentamethylcyclopentadienyl)Rhenium Aldehyde Complexes [(η⁵-C₅Me₅)Re(NO)(PPh₃)(η²-O=CHR)]⁺BF₄^-: Highly Diastereoselective Deuteride Additions", Agbossou, F.; Ramsden, J. A.; Huang, Y.-H.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 693-701. DOI: 10.1021/om00038a029. [Abstract][PDF]
165. "Epimerization of Secondary Alcohols by New Homogeneous, Low Oxidation State Metal Catalysts: Carbon-Hydrogen Bond Activation in Rhenium Alkoxide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(OCHRR')", Saura-Llamas, I.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 2136-2144. DOI: 10.1021/ja00032a030. [Abstract][PDF]
166. "Synthesis and Reactivity of Chiral Metal Fluoride and Water Complexes Derived from the Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Agbossou, S. K.; Roger, C.; Igau, A.; Gladysz, J. A. Inorg. Chem. 1992, 31, 419-424. DOI: 10.1016/S0277-5387(00)860544. [Abstract][PDF]
167. "Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition Metal Lewis Acid; Equilibration of Diastereomeric (Cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Helv. Chim. Acta 1992, 75, 442-456. DOI: 10.1002/hlca.19920750204. [Abstract][PDF]
168. "Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(NRR')", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824. DOI: 10.1002/cber.19921250410. [Abstract][PDF]
169. "Mechanism of Equilibration of Diastereomeric Chiral Rhenium Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺BF₄^–. the Metal Traverses between Alkene Enantiofaces without Dissociation", Peng, T.-S.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 4174-4181. DOI: 10.1021/ja00037a020. [Abstract][PDF]
170. "Cyclopentadienyl Rhenium Complexes", Agbossou, F.; O'Connor, E. J.; Garner, C. M.; Quirós Méndez, N.; Fernández, J. M.; Patton, A. T.; Ramsden, J. A.; Gladysz, J. A. Inorg. Synth. 1992, 29, 211-225. DOI: 10.1016/j.organchem.2007.11.024. [Abstract][PDF]
171. "Synthesis, Structure, Dynamic Behavior, and Reactivity of Chiral Rhenium Primary Phosphine and Phosphido Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(PRH₂)]⁺ X^- and ((η⁵-C₅H₅)Re(NO)(PPh₃)(PRH)", Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673-2685. DOI: 10.1021/om00043a061. [Abstract][PDF]
172. "A Versatile New Route to Carbon Complexes of the Formula L_nMC≡CM'L'_n': Deprotonation and Metalation of the Terminal Acetylide Complex (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CH)", Ramsden, J. A.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 5890-5891. DOI: 10.1021/ja00040a079. [Abstract][PDF]
173. "Synthesis and Structure of σ-Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ and Aromatic Nitrogen Heterocycles", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1992, 47, 1175-1184. ISSN: 0932-0776. [PDF]
174. "Synthesis, Structure, and Reactivity of Allene Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Pu, J.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 3232-3241. DOI: 10.1021/om00046a020. [Abstract][PDF]
175. "Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Roger, C.; Peng, T.-S.; Gladysz, J. A. J. Organomet. Chem. 1992, 439, 163-175. DOI: 10.1016/0022-328X(92)80227-O. [Abstract][PDF]
176. "Activation of Organic Carbonyl Compounds by Lewis Acids: Relative Reactivities of σ and π Adducts towards Nucleophiles, and Implications for Enantioselective Addition Reactions", Klein, D. P.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 8710-8711. DOI: 10.1021/ja00048a060. [Abstract][PDF]
177. "Deprotonation of Rhenium Terminal Acetylide Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(C≡CH): Generation and Reactivity of Rhenium/Lithium C₂ Complexes", Ramsden, J. A.; Weng, W.; Gladysz, J. A. Organometallics 1992, 11, 3635-3645. DOI: 10.1021/om00059a029. [Abstract][PDF]
178. "Reactions of Rhenium Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) and Organocopper Nucleophiles; New Routes to Racemic and Optically Active Hydrocarbyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R)", Ramsden, J. A.; Peng, T.-S.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1992, 129, 625-631. ISSN:0037-8968.
179. "Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1993, 450, 157-164. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]
180. "Synthesis, Structure, and Spectroscopic Properties of Chiral Rhenium Aromatic Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]⁺X^-: Equilibria between π and σ Aldehyde Bonding Modes", Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 2323-2334. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]
181. "Synthesis and Reactivity of Bimetallic Bridging Haloalkyl Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)X(CH₂)_xM(CO)₅]⁺BF₄^- (X = I, Br, Cl; M = Re, Mn; x = 1,4)", Zhou, Y.; Gladysz, J. A. Organometallics 1993, 12, 1073-1078. DOI: 10.1021/om00028a023. [Abstract][PDF]
182. "A New Form of Coordinated Carbon: An Unsupported C₃ Chain Spanning Two Different Transition Metals", Weng, W.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 3824-3825. DOI: 10.1021/ja00062a078. [Abstract][PDF]
183. (a) "A New Form of Coordinated Carbon: A C₃ Chain That is Anchored by a Transition Metal on Each End and Spanned by a Third", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 891-892. DOI: 10.1002/anie.199308911. [Abstract][PDF] (b) "Ein neuer Kohlenstoffligand; eine durch ein Re-Atom überdachte Re-C₃Re-Kette", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1993, 105, 937-938. DOI: 10.1002/ange.19931050632. [Abstract][PDF]
184. "Optical Rotation Measurements of Organometallic Compounds: Caveats and Recommended Procedures", Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 2390-2392. DOI: 10.1021/om00030a061. [Abstract][PDF]
185. "Synthesis, structure, and dynamic behavior of symmetrical cis- and trans- alkene complexes of the chiral rhenium Lewis acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: binding selectivities and isomerization processes", Pu, J.; Peng, T.-S.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2686-2698. DOI: 10.1021/om00031a044. [Abstract][PDF]
186. "Synthesis and Structure of Complexes of α,β-Unsaturated Carbonyl Compounds and the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Divergent Kinetic and Thermodynamic C=O/C=C and C=O/C-C Binding Selectivities", Wang, Y.; Agbossou, F.; Dalton, D. M.; Liu, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2699-2713. DOI: 10.1021/om00031a045. [Abstract][PDF]
187. "New Families of Coordinated Carbon: Oxidative Coupling of an Ethynyl Complex to Isolable and Crystallographically Characterized MC≡CC≡CM and M=C=C=C=C=M Assemblies", Zhou, Y.; Seyler, J. W.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 8509-8510. DOI: 10.1021/ja00071a095. [Abstract][PDF]
188. "An Isolable Organometallic Cation Radical in which a C₄ Chain Conducts Charge Between Two Chiral and Configurationally Stable Rhenium Termini", Seyler, J. W.; Weng, W.; Zhou, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 3802-3804. DOI: 10.1021/om00034a008. [Abstract][PDF]
189. "Synthesis and Reactivity of Chiral Rhenium Indenyl Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(X)]ⁿ⁺", Zhou, Y.; Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 3918-3923. DOI: 10.1021/om00034a026. [Abstract][PDF]
190. "Reactions of Rhenium Cyclopentadienyl and Indenyl Dichloromethane Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClCH₂Cl)]⁺ BF₄^- with Ketones; Substitution Rates and Mechanism", Dewey, M. A.; Zhou, Y.; Liu, Y.; Gladysz, J. A. Organometallics 1993, 12, 3924-3932. DOI: 10.1021/om00034a027. [Abstract][PDF]
191. "Synthesis, Structure and Reactivity of Chiral Rhenium Imine and Methyleneamido Complexes of the Formulas [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-N(R")=C(R)R')]⁺ TfO^- and (η⁵-C₅H₅)Re(NO)(PPh₃)N=C(R)R')", Knight, D. A.; Dewey, M. A.; Stark, G. A.; Bennett, B. K.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4523-4534. DOI: 10.1021/om00035a043. [Abstract][PDF]
192. "Synthesis, Structure, and Reactivity of η²-1,3-Diene and Enyne Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Ozonolysis Within a Metal Coordination Sphere", Peng, T.-S.; Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4535-4544. DOI: 10.1021/om00035a044. [Abstract][PDF]
193. "Pyrrolyl-N and Pyrrolyl-C Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Synthesis, Protonation, and Rearrangement Chemistry", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4728-4730. DOI: 10.1021/om00036a006. [Abstract][PDF]
194. "New Strategies for Enantioselective Syntheses of 1-Alkyl and 1,4-Dialkyl 1,2,3,4-Tetrahydroisoquinolines: Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Richter-Addo, G. B.; Knight, A. D.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 11863-11873. DOI: 10.1021/ja00078a026. [Abstract][PDF]
195. "Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(GeMe₂X); Equilibria Involving the Dimethylgermylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GeMe₂)]⁺ TfO^-", Lee, K. E.; Gladysz, J. A. Phosphorus, Sulfur, Silicon, and the Related Elements 1994, 87, 113-123. DOI: 10.1080/10426509408037445. [Abstract]
196. "Syntheses and Structures of Unsymmetrically 1,1-and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Enantioface Binding Selectivities and Conformational Equilibria", Peng, T.-S.; Pu, J.; Gladysz, J. A. Organometallics 1994, 13, 929-940. DOI: 10.1021/om00015a029. [Abstract][PDF]
197. "Enantioselective Syntheses of Organosulfur Compounds via [2,3]-Sigmatropic Rearrangements of Ylides of Di(allyl) and Di(propargyl) Sulfonium Salts. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1994, 116, 3655-3656. DOI: 10.1021/ja00087a084. [Abstract][PDF]
198. "Generation and Reactivity of Substitution-Labile Dichloromethane and Chlorobenzene Adducts of the Chiral Pentamethylcyclopentadienyl Rhenium Lewis Acid [(η⁵-C₅Me₅)Re(NO)(PPh₃)]⁺", Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534-2542. DOI: 10.1021/ic00090a011. [Abstract][PDF]
199. "Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 2164-2169. DOI: 10.1021/om00018a008. [Abstract][PDF]
200. (a) "Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumulenic C₅ Chain that Mediates Charge Transfer Between Rhenium and Manganese Termini", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1994, 33, 2199-2202. DOI: 10.1002/anie.199421991. [Abstract][PDF] (b) "Auf dem Weg zur Verknüpfung einzelner Metalle durch "eindimensionale Kohlenstoffdrähte": Ladungstransfer zwischen terminalen Rhenium- und Manganzentren über ein C₅-Cumulen", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem. 1994, 106, 2269-2272. DOI: 10.1002/ange.19941062112. [Abstract][PDF]
201. "Syntheses of Cyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ by Hydride Ion Abstraction from Amido Complexes", Cantrell, W. R. Jr.; Richter-Addo, G. B.; Gladysz, J. A. J. Organomet. Chem. 1994, 472, 195-204. DOI: 10.1016/0022-328X(94)80206-8. [Abstract][PDF]
202. "Synthesis, Structure and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Diastereoselective Electrophilic Additions", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 3182-3193. DOI: 10.1021/om00020a035. [Abstract][PDF]
203. "New Families of Coordinated Carbon: Oxidative Coupling and Cross-coupling of a Transition Metal Butadiynyl Complex to Bimetallic M-C≡CC≡CC≡CC≡C-M and M-C≡CC≡CC≡C-M Adducts", M. Brady; W. Weng; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 2655-2656. DOI: 10.1021/ja9631817. [Abstract][PDF]
204. "Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 4523-4530. DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]
205. "Are Teflon Ponytails the Coming Fashion for Catalysts?", Gladysz, J. A. Science 1994, 266, 55-56. DOI: 10.1126/science.266.5182.55. [Abstract][PDF]
206. "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]
207. "Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C₂Li Complexes of the Formula ((η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CX); Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C₄H₃ and C₄H₄ Species", Weng, W.; Bartik, T.; Johnson, M. T.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 889-897. DOI: 10.1021/om00002a041. [Abstract][PDF]
208. "A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of Chiral Cationic Rhenium Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Gladysz, J. A. Organometallics 1995, 14, 898-911. DOI: 10.1021/om00002a041. [Abstract][PDF]
209. "Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(=CHR)]⁺ PF₆^-; A Versatile and Highly Stereoselective Route to Alkene Complexes", Wang, Y.; Gladysz, J. A. Chem. Ber. 1995, 128, 213-220. DOI: 10.1002/cber.19951280303. [Abstract][PDF]
210. "Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Enantioselective Syntheses of 3-Substituted Cycloalkanones", Wang, Y.; Gladysz, J. A. J. Org. Chem. 1995, 60, 903-909. DOI: 10.1021/jo00109a022. [Abstract][PDF]
211. "A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprotonation of a Chiral Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon", Meyer, O.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 1844-1849. DOI: 10.1021/om00004a043. [Abstract][PDF]
212. "Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline and Quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary; Enantioselective Syntheses of Alkyl, Dialkyl, and Trialkyl Hydroisoquinoline Derivatives", Stark, G. A.; Dewey, M. A.; Richter-Addo, G. B.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. in Stereoselective Reactions of Metal-Activated Molecules; Werner, H.; Sundermeyer, J. Eds.; Vieweg-Verlag: Braunschweig, Germany, 1995; pp. 51-71. ISBN: 3-528-06664-4, 9783528066642.
213. "Nucleophilic Additions to the Chiral Rhenium Alkene Complexes [Re(η⁵-C₅H₅)(NO)(PPh₃)(H₂C=CHR)]BF₄ (R = H, Me, CH₂CH₂Me, Ph or CH₂Ph): Regio-, Diastereo-, and Enantioselectivities", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1995, 1857-1865. DOI: 10.1039/DT9950001857. [Abstract][PDF]
214. "Synthesis, Structure, and Reactivity of Chiral Rhenium N-Pyrrolyl Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(NCR=CR'CH=CH)]; Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon-Ligated Species", Johnson, T. J.; Alvey, L. J.; Brady, M.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1995, 1, 294-302. DOI: 10.1002/chem.19950010506. [Abstract][PDF]
215. "Crystal Structures of Diastereomeric Styrene Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Effect of Ligating Enantioface upon Bonding and Conformation", Sanau, M.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1995, 503, 235-241. DOI: 10.1016/0022-328X(95)05565-7. [Abstract][PDF]
216. "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Rearrangements of Ylides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Meyer, O.; Weickhardt, K.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11730-11744. DOI: 10.1021/ja00152a014. [Abstract][PDF]
217. "Synthesis, Structure and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC₂M', MC₄M' and MC₄M'C₄M Linkages. Transmetalations of Lithiocarbon Complexes (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CLi) and (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC≡CLi)", Weng, W.; Bartik, T. ; Brady, M.; Bartik, B.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11922-11931. DOI: 10.1021/ja953523t. [Abstract][PDF]
218. "Reactions of t-BuOK and Di(Benzyl), Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Highly Diastereoselective or Chemoselective [2,3] Sigmatropic Rearrangements", Cagle, P. C.; Meyer, O.; Vichard, D.; Weickhardt, K; Arif, A. M.; Gladysz, J. A. Organometallics 1996, 15, 194-204. DOI: 10.1021/om950701i. [Abstract][PDF]
219. (a) "A Step-Growth Approach to Metal-Capped One-Dimensional Carbon Allotropes; Syntheses of C₁₂, C₁₆, and C₂₀ μ-Polyynendiyl Complexes", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 414-417. DOI: 10.1002/anie.19961080415. [Abstract][PDF] (b) "Schrittweises Kettenwachstum eindimensionaler Kohlenstoffallotrope mit terminalen Metallgruppen; Synthese von C₁₂-, C₁₆-, und C₂₀-μ-Polyindiylkomplexen", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem. 1996, 108, 467-469. DOI: 10.1002/ange.19961080415. [Abstract][PDF]
220. "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Seyler, J. W.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118, 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]
221. "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrangements of Ylides Derived from Di(allyl), Di(propargyl), and Di(benzyl) Sulfide Complexes; Control of Carbon Configuration by an Easily Resolved and Recycled Rhenium Auxiliary", Meyer, O.; Cagle, P. C.; Weickhardt, K.; Vichard, D.; Gladysz, J. A. Pure Appl. Chemistry 1996, 68, 79-88. (invited article, 8th OMCOS symposium thematic issue) DOI: 10.1351/pac199668010079. [Abstract][PDF]
222. "A Search for π/σ Equilibria in Chiral Rhenium Imine Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(N(H)=C(CF₃)X)]⁺ TfO^-; Investigation of Electronic Effects Upon the Binding Mode", Stark, G. A.; Gladysz, J. A. Inorg. Chem. < 1996, 35, 5509-5513. DOI: 10.1021/ic960302v. [Abstract][PDF]
223. "Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids: Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements to Give Thiolate Complexes with New Carbon Stereocenters", Bell, P. T.; Cagle, P. C.; Vichard, D.; Gladysz, J. A. Organometallics 1996, 15, 4695-4701. DOI: 10.1021/om960541q. [Abstract][PDF]
224. "Configurational Equilibria in Amido and Lithioamido Complexes of Formulas (η⁵-C₅H₅)Re(NO)(PAr₃)(NHCHRR') and (η⁵-C₅H₅)Re(NO)(PAr₃)(NLiR"): Epimerization Occurs at Rhenium via Phosphine Dissociation", Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798-4807. DOI: 10.1021/om960662q. [Abstract][PDF]
225. "Consanguineous Families of Coordinated Carbon: A ReC₄Re Assembly that is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC≡CC≡CRe and ⁺Re=C=C=C=C=Re⁺ Adducts and a Radical Cation in which Charge is Delocalized Between Rhenium Termini", Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, A. J.; Arif, A. M.; Böhme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788. DOI: 10.1021/ja9631817. [Abstract][PDF]
226. "Methods for Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Carbon Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(CC)_nOs₃(CO)₁₀(H)", Falloon, S. B.; Arif, A. M.; Gladysz, J. A. Chem. Commun. 1997, 629-630. DOI: 10.1039/a607884b. [Abstract][PDF]
227. (a) "Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities", Gladysz, J. A.; Boone, B. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 551-583. DOI: 10.1002/anie.199705501. [Abstract][PDF] (b) "Chirale Erkennung in π-Komplexen von Alkenen, Aldehyden und Ketonen mit Übergangsmetall-Lewis-Säuren; Entwicklung eines allgemeinen Modells für enantiofacialle Komplexierungsselektivitäten", Gladysz, J. A.; Boone, B. J. Angew. Chem. 1997, 109, 566-602. DOI: 10.1002/ange.19971090604. [Abstract][PDF]
228. "Spectroscopic Observation of the Formyl Cation in a Condensed Phase", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Science 1997, 276. 776-779. DOI: 10.1126/science.276.5313.776. [Abstract][PDF]
229. "Synthesis, Structure, and Reactivity of Polymetallic C₃OMe Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC(OMe)=)M_m(CO)_n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in which a C₃ Chain Links two Metals and Spans a Third", Falloon, S. B.; Weng, W.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2008-2015. DOI: 10.1021/om970055i. [Abstract][PDF]
230. (a) "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroboration", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1610-1612. DOI: 10.1002/anie.19971091509. [Abstract][PDF] (b) "Übergangsmetallkatalyse in fluorhaltigen Medien: Anwendung eines neuen Immobilisierungsprinzips auf die Rh-katalysierte Hydroborieirung", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1682-1684. DOI: 10.1002/ange.19971091509. [Abstract][PDF]
231. (a) "Synthesis, Structure, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH₂CH₂(CF₂)₅CF₃)₃]₂; Altered Reactivity in Fluorocarbons, and Implications for Catalysis", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612-1615. DOI: 10.1002/anie.199716121. [Abstract][PDF] (b) "Synthese, Struktur, und oxidative Additionen eines fluorhaltigen Analogons des Vaska-Komplexes, trans-[IrCl(CO){P[CH₂CH₂(CF₂)₅CF₃]₃}₂] – Reaktivitätsänderung in Fluorkohlenwasserstoffen und Auswirkungen auf die Katalyse", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1685-1687. DOI: 10.1002/ange.19971091510. [Abstract][PDF]
232. "Synthesis and Crystal Structure of the Conjugated Tetrayne (η⁵-C₅H₅)Re(NO)(PPh₃)(C≡CC≡CC≡CC≡CSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp Carbon Wires", Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. New J. Chem. 1997, 21, 739-750. (invited article, 13th summer school in coordination chemistry thematic issue)
233. "Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η⁵-C₅R₅)Re(NO)(PPh₃)CN(Ph₃P)(ON)Re(η⁵-C₅R₅)]⁺TfO^- (R, R' = H, Me)", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2909-2918. DOI: 10.1021/om970167+. [Abstract][PDF]
234. "Synthesis and Crystallographic Characterization of the 'Sometimes-Chiral' Dirhenium Polyoxotungstate Salt {(η⁵-C₅H₅)Re(NO)(PPh₃)(CO)]⁺}₂[W₆O₁₉]^2-, Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1997, 134, 793-799. ISSN: 0037-8968.
235. "Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6", Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 6032-6034. DOI: 10.1021/om970792e. [Abstract][PDF]
236. "Additions of Carbon Nucleophiles to Acyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Controlling Factors in 1,3-Asymmetric Induction and Syntheses of Non-Racemic Organic Amines", Stark, G. A.; Gladysz, J. A. Inorg. Chim. Acta 1998, 269, 167-180. (invited article, issue in honor of Wolfgang Beck) DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]
237. "Organometallic Reactivity Patterns in Fluorocarbons, and Implications for Catalysis; Synthesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH₂CH₂(CF₂)₅CF₃)₃]₂", Guillevic, M.-A.; Rocaboy, C.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Organometallics 1998, 17, 707-717. DOI: 10.1021/om9710834. [Abstract][PDF]
238. "Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η⁵-C₅Me₅)Re(NO)(PPh₃)(CC)_nOs₃(CO)_y(X)_z]^m+, Including Carbon Geometries more Distorted than Planar Tetracoordinate", Falloon, S. B.; Szafert, S.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1998, 4, 1033-1042. DOI:10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P. [Abstract][PDF]
239. "Transition Metal Catalysis in Fluorous Media: Application of a New Immobilization Principle to Rhodium Catalyzed Hydrogenation of Alkenes", Rutherford, D.; Juliette, J. J. J.; Rocaboy, C.; Horváth, I. T.; Gladysz, J. A. Catalysis Today 1998, 42, 381-388. (invited article, phase separable homogeneous catalysis thematic issue) DOI: 10.1016/S0920-5861(98)00120-5. [Abstract][PDF]
240. "New Forms of Coordinated Carbon: Wire-Like Cumulenic C₃ and C₅ sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer", Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071-11081. DOI: 10.1021/ja981927q. [Abstract][PDF]
241. "Additions of PH₃ to Monosubstituted Alkenes of the Formula H₂C=CH(CH₂)_x(CF₂)_yCF₃; Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkyl Phosphines with Modulated Electronic Properties and Fluorous Phase Affinities", Alvey, L. J.; Rutherford, D.; Juliette, J. J. J.; Gladysz, J. A., J. Org. Chem. 1998, 63, 6302-6308. DOI: 10.1021/jo980692y. [Abstract][PDF]
242. "Olefin Metatheses in Metal Coordination Spehres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds", Martin-Alvarez, J. M.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 955-957. DOI: 10.1021/om9808920. [Abstract][PDF]
243. "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes", Juliette, J. J. J.; Rutherford, D.; Horváth, I. T.; Gladysz, J. A. J. Am. Chem. Soc. 1999, 121, 2696-2704. DOI: 10.1021/ja982955b. [Abstract][PDF]
244. "Appreciably Bent sp Carbon Chains: Synthesis, Structure, and Protonation of Organometallic 1,3,5-Triynes and 1,3,5,7-Tetraynes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)((C≡C)_n-p-C₆H₄Me)", Dembinski, R.; Lis, T.; Szafert, S.; Mayne, C. L.; Bartik, T.; Gladysz, J. A. J. Organomet. Chem. 1999, 578, 229-246. DOI:10.1016/S0022-328X(98)01128-0. [Abstract][PDF]
245. "Chemistry in Fluorous Media: A User's Guide to Practical Considerations in the Application of Fluorous Catalysts and Reagents", Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587-605. (invited article, 33rd ICCC thematic issue) DOI: 10.1016/S0010-8545(99)00102-2. [Abstract][PDF]
246. "C₈ and C₁₂ sp Carbon Chains that Span Two Platinum Atoms; The First Structurally Characterized 1,3,5,7,9,11-hexayne", Peters, T. B.; Bohling, J. C.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 3261-3263. DOI: 10.1021/om990448c. [Abstract][PDF]
247. "Synthesis, Properties, and Reactions of Enantiomerically Pure, Chiral Fluorous Phosphines of the Formula (menthyl)P(CH₂CH₂(CF₂)_n-1CF₃)₂ (n = 6, 8)", Klose, A.; Gladysz, J. A. Tetrahedron–Asymmetry 1999, 10, 2665-2674. DOI: 10.1016/SO957-4166(99)00272-4. [Abstract][PDF]
248. "Wire-Like sp Carbon Chains that Span Two Platinum Atoms: Synthesis and Crystal Structures of Building Blocks of the Formula trans-(p-tolyl)(Ph₃P)₂Pt(C≡C)_nSiMe₃", Bohling, J. C.; Peters, T. B.; Arif, A. M.; Hampel, F.; Gladysz, J. A., in Coordination Chemistry at the Turn of the Century; Ondrejoviç, G.; Sirota, A. Eds.; Slovak Technical University Press: Bratislava, Slovokia, 1999; pp. 47-52.
249. "Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones", Dinh, L. V.; Gladysz, J. A. Tetrahedron Lett. 1999, 40, 8995-8998. DOI: 10.1016SO040-4039(99)01924-3. [Abstract][PDF]
250. "A New Route to Heterobimetallic C₃ Complexes via C≡C Metatheses of 1,3-Diynyl Ligands: Synthesis and Structure of (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC≡)W(O-t-Bu)₃", Dembinski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438-5440. DOI: 10.1021/om990766b. [Abstract][PDF]
251. "Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C₆-C₂₀ Polyynediyl Chains that Span Two Redox-Active (η⁵-C₅Me₅)Re(NO)(PPh₃) Endgroups", Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810-822. DOI: 10.1021/ja992747z. [Abstract][PDF]
252. " Synthesis and Properties of Chiral Rhenium Pentatetraenylidene Complexes of the Formula [(η⁵-C₅Me₅)Re(NO)(PPh₃)(=C=C=C=C=CAr₂)]⁺BF₄^- (CAr₂ = 9-fluorenylidene)", Szafert, S.; Haquette, P.; Falloon, S. B.; Gladysz, J. A. J. Organomet. Chem. 2000, 604, 52-58. DOI:10.1016/S0022-328X(00)00201-1. [Abstract][PDF]
253. "Strategy and Design in Fluorous Phase Immobilization: A Systematic Study of the Effect of "Pony Tails" (CH₂)₃(CF₂)_n-1CF₃ Upon the Partition Coefficients of Benzenoid Compounds", Rocaboy, C.; Rutherford, D.; Bennett, B. L.; Gladysz, J. A. J. Phys. Org. Chem. 2000, 13, 596-603. (invited article, organic reactivity (ESOR 7) thematic issue). DOI: 10.1002/1099-1395(200010)13. [Abstract][PDF]
254. "A 'Conjugal' Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C₄ Species", Paul, F.; Meyer, W. E.; Toupet, L.; Jiao, H.; Gladysz, J. A.; Lapinte, C. J. Am. Chem. Soc. 2000, 122, 9405-9414. DOI: 10.1021/ja0011055. [Abstract][PDF]
255. "Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Second, and Tertiary Aliphatic Amines NH_3-x((CH₂)_m(CF₂)₇CF₃)_x (m = 3-5; x = 1-3); Fine Tuning of Basicities and Fluorous Phase Affinities", Rocaboy, C.; Bauer, W.; Gladysz, J. A. Eur. J. Org. Chem. 2000, 2621-2628. DOI: 10.1002/1099-0690(200007)2000:14. [Abstract][PDF]
256. "Synthesis and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Trialkylphosphines: Precision Tuning of Electronic Properties, Including Insulation of the Perfluoroalkyl Group", Alvey, L. J.; Meier, R.; Soós, T.; Bernatis, P.; Gladysz, J. A. Eur. J. Inorg. Chem. 2000, 1975-1983. DOI: 10.1002/1099-0682(200009)2000:9<1975::AID-EJIC1975>3.0.CO;2-M. [Abstract][PDF]
257. "Synthesis and Oxidation of Chiral Rhenium Phosphine Methyl Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(CH₃): In Search of Radical Cations with Enhanced Kinetic Stabilities", Meyer, W. E.; Amoroso, A. J.; Jaeger, M.; Le Bras, J.; Wong W.-T.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 44-53. DOI: 10.1016/S0022-328X(00)00528-3. [Abstract][PDF]
258. "Synthesis, Crystal Structure, and Reactions of the Seventeen-Valence-Electron Rhenium Methyl Complex [(η⁵-C₅Me₅)Re(NO)(P(4-C₆H₄CH₃)₃)(CH₃)]^·+ (B(3,5-C₆H₃(CF₃)₂)₄^-: Experimental and Computational Bonding Comparisons with Eighteen-Electron Methyl and Methylidene Complexes", Le Bras, J.; Jiao, H.; Meyer, W. E.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 54-66. DOI: 10.1016/S0022-328X(00)00531-3- [Abstract][PDF]
259. "Tails and Steeds versus Heads and Beads: The Case for Fluorous Phase Methodology in Combinatorial and Parallel Synthesis", Rocaboy, C.; Gladysz, J. A. Actualité Chimique 2000, 47-50 (September).
260. "Olefin Metatheses in Metal Coordination Spheres: Novel trans-Spanning Bidentate and Facially-Spanning Tridentate Macrocyclic Phosphine Complexes", Bauer, E. B.; Ruwwe, J.; Martín-Alvarez, J. M.; Peters, T. B.; Bohling, J. C.; Hampel, F. A.; Szafert, S.; Lis, T.; Gladysz, J. A. Chem. Commun. 2000, 2261-2262. DOI: 10.1039/b007405p. [Abstract][PDF]
261. "Surface Reactivity Studies of Bimetallic Complexes (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡C)_n(Ph₃P)(ON)Re(η₅-C₅Me₅) (n = 2, 4, 6): Candidates for Molecular Wires", Schennach, R.; Naugle, D. G.; Cocke, D.; Dembinski, R.; Gladysz, J. A. Vacuum 2000, 56, 115-121. DOI:10.1016/S0042-207X(99)00178-5. [Abstract][PDF]
262. "New Chiral Cyclopentadienyl Rhenium Lewis Acids Featuring Fluorinated Triaryl Phosphines and Enhanced Acceptor Abilities - An Unusual Carbon-Fluorine Bond Activation in a Metal Coordination Sphere", Mohr, W.; Stark, G. A.; Jiao, H.; Gladysz, J. A. Eur. J. Inorg. Chem. 2001, 925-933. DOI:10.1002/1099-0682(200104)2001:4<925::AID-EJIC925>3.0.CO;2-N. [Abstract][PDF]
263. "A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of 'Chiral-at-Rhenium' Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations", Kromm, K.; Zwick, B. D.; Meyer, O.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 2015-2027. DOI: 10.1002/1521-3765(20010504)7:9. [Abstract][PDF]
264. "Synthesis and Oxidation of Dirhenium C₄, C₆, and C₈ Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PR₃)(C≡C)_n(R₃P)(ON)Re(η⁵-C₅Me₅) (R = 4-C₆H₄R', c-C₆H₁₁): In Search of Dications and Radical Cations with Enhanced Stabilities", Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115-1127. DOI: 10.1021/om000961m. [Abstract][PDF]
265. "Metal-Metal Interactions Across Bridging Elemental Carbon Chains: A Computational Study of Odd-Carbon Complexes", Jiao, H.; Gladysz, J. A. New J. Chem. 2001, 25, 551-562. DOI: 10.1039/b008786f. [Abstract][PDF]
266. "Synthesis, Structure, and Interconversion of Chiral Rhenium Oxygen- and Sulfur-Bound Sulfoxide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(OS(Me)R)]⁺ X^-; Diastereoselective Oxidations of Coordinated Methyl Alkyl Sulfides", Otto, M.; Boone, B. J.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 2001, 1218-1229. DOI: 10.1039/b009533h. [Abstract][PDF]
267. "Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C₆H₄(CH₂)₃(CF₂)_n-1CF₃)₃ (n = 6, 8, 10)", Soós, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. Organometallics 2001, 20, 3079-3086. DOI: 10.1021/om010193e. [Abstract][PDF]
268. "A New Family of Chiral Chelating Diamines with Transition Metal Stereocenters: Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted Diamine (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂N(CH₃)CH₂CH₂(H₃C)NCH₂)(Ph₃P)(ON)Re(η⁵-C₅H₅)", Alvey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; Lis, T.; Gladysz, J. A. Organometallics 2001, 20, 3087-3096. DOI: 10.1021/om010153a. [Abstract][PDF]
269. "Structures and Energies of 10-Azatriquinacene and Its Hydrogenation Products: A Computational Study", Jiao, H.; Halet, J.-F.; Gladysz, J. A. J. Org. Chem. 2001, 66, 3902-3905. DOI: 10.1021/jo001800v. [Abstract][PDF]
270. "Bent and Stretched but not yet to the Breaking Point: C₈-C₁₆ sp Carbon Chains the Span two Platinum Atoms, and the First Structurally Characterized 1,3,5,7,9,11,13,15-Octayne", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2001, 40, 3263-3264. DOI: 10.1021/ic010309z. [Abstract][PDF]
271. "Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Construction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands", Ruwwe, J.; Martín-Alvarez, J. M.; Horn, C. R.; Bauer, E. B.; Szafert, S.; Lis, T.; Hampel, F.; Cagle, P. C.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 3931-3950. DOI: 10.1002/1521-3765(20010917)7:18. [Abstract][PDF]
272. "Fluorous Catalysis Without Fluorous Solvents: A Friendlier Catalyst Recovery/Recycling Protocol Based upon Thermorphic Properties and Liquid/Solid Phase Separation", Wende, M.; Meier, R.; Gladysz, J. A. J. Am. Chem. Soc. 2001, 123, 11490-11491. DOI: 10.1021/ja011444d. [Abstract][PDF]
273. "Recoverable Catalysts: Ultimate Goals, Criteria of Evaluation, and the Green Chemistry Interface", Gladysz, J. A. Pure Appl. Chem. 2001, 73, 1319-1324. (invited article, CHEMRAWN XIV thematic issue) DOI:10.1351/ pac200173081319. [Abstract][PDF]
274. "Syntheses and Structures of Monoplatinum Model Complexes for Diplatinum Polyynediyl Adducts L_nPt(C≡C)_zPtL_n", Peters, T. B.; Zheng, Q.; Stahl, J.; Bohling, J. C.; Arif, A. M.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2002, 641, 53-61. (invited article, interactions of π systems with metals thematic issue) DOI: 10.1016/ S0022-328X(01)01311-0. [Abstract][PDF]
275. "Vibrational Progressions in the Valence Ionizations of Transition Metal Hydrides: Evaluation of Metal-Hydride Bonding and Vibrations in (η⁵-C₅R₅)Re(NO)(CO)(H) [R = H, CH₃]", Lichtenberger, D. L.; Gruhn, N.; Rai-Chaudhuri, A.; Renshaw, K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, A. J. Am. Chem. Soc. 2002, 124, 1417-1423. DOI: 10.1021/ja0120227. [Abstract][PDF]
276. "An Unexpected Insertion of Acetone into the Silicon-Carbon Terminus of an sp Carbon Chain: Syntheses and Structures of Model Monoplatinum Hexatriynyl and Octatetraynyl Complexes", Mohr, W.; Peters, T. B.; Bohling, J. C.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Comptes Rendus Chemie 2002, 5, 111-118. (invited article, Gecom-Concoord thematic issue) DOI: 10.1016/S1631-0748(02)01351-6. [Abstract][PDF]
277. "How to Insulate a Reactive Site from a Perfluoroalkyl Group: Photoelectron Spectroscopy, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH₂)_m(CF₂)₇CF₃)₃", Jiao, H.; Le Stang, S.; Soós, T.; Meier, R.; Kowski, K.; Rademacher, P.; Jafarpour, L.; Hamard, J.-B.; Nolan, S. P.; Gladysz, J. A. J. Am. Chem. Soc. 2002, 124, 1516-1523. DOI: 10.1021/ja011877g. [Abstract][PDF]
278. "New Perfluorocarbon System for Multilayer Growth of Anchorage Dependent Mammalian Cells", Rappaport, C.; Rensch, Y.; Abbasi, M.; Kempe, M.; Rocaboy, C. Gladysz, J. A.; Trujillo, E. M. BioTechniques 2002, 32, 142-151. ISSN: 0736-6205. [PDF]
279. "Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphosphines that Contain a Rhenium Stereocenter in the Backbone", Kromm, K.; Hampel, F.; Gladysz, J. A. Helv. Chim. Acta 2002, 85, 1778-1789. DOI: 10.1002/1522-2675(200206)85:6. [Abstract][PDF]
280. "Fluorous Chemistry: From Biphasic Catalysis to a Parallel Chemical Universe and Beyond", Gladysz, J. A.; Curran, D. P. Tetrahedron 2002, 58, 3823-3825. DOI: 10.1016SO040-4020(02)00222-3. [Abstract][PDF]
281. "Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Precursors to Highly Active Catalysts for the Suzuki Coupling", Rocaboy, C.; Gladysz, J. A. Tetrahedron 2002, 58, 4007-4014. (invited article, fluorous chemistry thematic issue) DOI: 10.1016SO04020(02)00275-2. [Abstract][PDF]
282. (a) "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. DOI: 10.1021/ja0716103. [Abstract][PDF] (b) "Von sp³-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte molekulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957. DOI: 10.1002/1521-3757(20020603)114:11<1951::AID-ANGE1951>3.0.CO;2-Z. [Abstract][PDF]
283. "New Approaches to High-Activity Transition Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Couplings", Eichenseher, S.; Kromm, K.; Delacroix, O.; Gladysz, J. A., Chem. Commun. 2002, 1046-1047. DOI: 10.1021/om0492956. [Abstract][PDF]
284. "Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Reaction; Evidence for a Palladium Nanoparticle Pathway", Rocaboy, C.; Gladysz, J. A. Org. Lett. 2002, 4, 1993-1996. DOI: 10.1021/ol025790r. [Abstract][PDF]
285. "A New Family of Chelating Diphosphines with Transition Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System", Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2002, 21, 4264-4274. DOI: 10.1021/om020431l. [Abstract][PDF]
286. "Chelating Diphosphines that Contain a Rhenium Stereocenter in the Backbone: Applications in Rhodium-Catalyzed Enantioselective Ketone Hydrosilylations and Alkene Hydrogenations", Kromm, K.; Osburn, P. L.; Gladysz, J. A. Organometallics 2002, 21, 4275-4280. DOI: 10.1021/om020432d. [Abstract][PDF]
287. "Syntheses and Reactivities of Disubstituted and Trisubstituted Fluorous Pyridines with High Fluorous Phase Affinities: Solid State, Liquid Crystal, and Ionic Liquid Phase Properties", Rocaboy, C.; Hampel, F.; Gladysz, J. A. J. Org. Chem. 2002, 67, 6863-6870. DOI: 10.1021/jo011173p. [Abstract][PDF]
288. "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η⁵-C₅Me₅)Re(NO)(PR₃)(C≡CC≡CC≡CC≡C)(R₃P)(ON)Re(η⁵-C₅Me₅)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. DOI: 10.1021/om020676y. [Abstract][PDF]
289. "Facile and Selective Carbonylation of Methane in Superacids", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Adv. Synth. Catal. 2002, 344, 1059-1062. DOI: 10.1002/1615-4169(200212)344:10<1059::AID-ADSC1059>3.0.CO;2-O. [Abstract][PDF]
290. "Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Sukuki Cross-Couplings", Giner Planas, J.; Gladysz, J. A. Inorg. Chem. 2002, 41, 6947-6949. DOI: 10.1021/ic020589y. [Abstract][PDF]
291. "How do the Electronic Structures of Low-Symmetry Metal-Hydride and -Alkyl Complexes Compare? Photoelectron Spectroscopy and Computational Studies of (η⁵-C₅R₅)Re(NO)(L)R' [L = CO, P(C₆H₅)₃; R, R' = H, CH₃)]", Lichtenberger, D. L.; Gruhn, N. E.; Rai-Chaudhuri, A.; Renshaw, S. K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, I. Organometallics 2002, 21, 5494-5504. DOI: 10.1021/om020793t. [Abstract][PDF]
292. "Convenient Syntheses of Fluorous Aryl Iodides and Hypervalent Iodine Compounds: ArI(L)_n Reagents that are Recoverable by Simple Liquid/Liquid Biphase Workups, and Applications in Oxidations of Hydroquinones", Rocaboy, C.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 88-95. DOI: 10.1002/chem.200390034. [Abstract][PDF]
293. "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age", Delacroix, O.; Gladysz, J. A. Chem. Commun. 2003, 665-675 (feature article). DOI: 10.1002/chin.200325223. [Abstract][PDF]
294. "Thermomorphic Fluorous Imine and Thioether Palladacycles as Precursors for Highly Active Heck and Suzuki Catalysts; Evidence for Palladium Nanoparticle Pathways", Rocaboy, C.; Gladysz, J. A. New J. Chem. 2003, 27, 39-49. DOI: 10.1039/b208545n. [Abstract][PDF]
295. "Synthesis, Structure, and Reactivity of sp Carbon Chains with bis(phosphine) Pentafluorophenylplatinum Endgroups: Butadiynediyl (C₄) through Hexadecaoctaynediyl (C₁₆) Bridges, and Beyond", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324-3340. DOI: 10.1002/chem.200204741. [Abstract][PDF]
296. "Convenient Syntheses of Fluorous Phenols of the Formula HOC₆H_5-n((CH₂)₃(CF₂)₇CF₃)_n (n = 1,2) and the Corresponding Triarylphosphites", Le Stang, S.; Meier, R.; Rocaboy, C.; Gladysz, J. A. J. Fluorine Chem. 2003, 119, 141-149. DOI:10.1016/S0022-1139(02)00242-7. [Abstract][PDF]
297. "Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear bis(1,3-Butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η⁵-C₅Me₅)Re(NO)(PR₃)(C≡CC≡CC≡CC≡C)(R₃P)(ON)Re(η⁵-C₅Me₅)]", Horn, C. R.; Gladysz, J. A. Eur. J. Inorg. Chem. 2003, 9, 2211-2218. (feature article). DOI: 10.1002/ejic.200300043. [Abstract][PDF]
298. "Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A "Greener" Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation", Wende, M.; Gladysz, J. A. J. Am. Chem. Soc. 2003, 125, 5861-5872. DOI: 10.1021/ja029241s. [Abstract][PDF]
299. "Convenient and Convergent Syntheses of Long-Chain α,ω-Dibromides and Diphosphines of the Formula X(CH₂)_nX (n = 18-32)", Mohr, W.; Horn, C. R.; Stahl, J.; Gladysz, J. A. Synthesis 2003, 1279-1285. DOI: 10.1055/s-2003-39414. [Abstract][PDF]
300. "Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC₄M']ⁿ⁺: Computational Analyses of the Effect of the Metal", Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; Lapinte, C. J. Am. Chem. Soc. 2003, 125, 9511-9522. DOI: 10.1021/ja034619n. [Abstract][PDF]
301. "Tungsten-Catalyzed Alkyne Metatheses in Transition Metal Coordination Spheres: Versatile New Synthesis of Metallamacrocycles", Bauer, E. B.; Szafert, S.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 2184-2186. DOI: 10.1021/om030195u. [Abstract][PDF]
302. "Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2003, 103, 4175-4205. DOI: 10.1021/cr030041o. [Abstract][PDF]
303. "Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres", Bauer, E. B.; Gladysz, J. A. in Handbook of Metathesis, Grubbs, R. H. Ed.; Wiley/VCH, New York, 2003, Vol 2, pp 403-431. DOI: 10.1002/9783527619481.ch26. [Abstract][PDF]
304. "Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties ("Split Pony Tails")", Wende, M.; Seidel, F.; Gladysz, J. A. J. Fluorine Chem. 2003, 124, 45-54. DOI: 10.1016/S0022-1139(03)00171-4. [Abstract][PDF]
305. "Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Substitution on the Efficiencies of Macrocyclizations that join trans Positions of Square-Planar Platinum Complexes", Bauer, E. B.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 5567-5580. DOI: 10.1021/om034121u. [Abstract][PDF]
306. "Fluorous Chemistry: Scope and Definition", Horváth, I. T.; Curran, D. P.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 1-4. DOI: 10.1002/3527603905.ch1. [Abstract] 307. "Fluorous Solvents and Related Media", Gladysz, J. A.; Emnet, C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 11-23. DOI: 10.1002/3527603905.ch3. [Abstract] 308. "Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation", Gladysz, J. A.; Corrêa da Costa, R. C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 24-40. DOI: 10.1002/3527603905.ch4. [Abstract] 309. "Ponytails: Structural and Electronic Considerations", Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 41-55. DOI: 10.1002/3527603905.ch5. [Abstract] 310. "Partition Coefficients involving Fluorous Solvents", Gladysz, J. A.; Emnet, C.; Rábai, J. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 56-100. DOI: 10.1002/3527603905.ch6. [Abstract] 311. "9H, 9H, 10H, 11H, 11H-Perfluoro-11-nonadecyl Iodide. Free Radical Chain Reactions of Fluorous Primary Alkyl Iodides", Wende, M.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 464-465. DOI: 10.1021/op050147g. [Abstract]
312. "Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Diphosphine Ligands", Shima, T.; Bauer, E. B.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2004, 1012-1028. DOI: 10.1039/b400156g. [Abstract][PDF]
313. "Convenient Syntheses of 'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails", Dinh, L. V.; Gladysz, J. A. Chem. Commun. 2004, 998-999. DOI: 10.1039/b401540a. [Abstract][PDF]
314. "Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten- and Molybdenum-Catalyzed Syntheses of Novel Metallamacrocycles", Bauer, E. B.; Hampel, F.; Glaydsz, J. A. Adv. Synth. Catal. 2004, 346, 812-822. DOI: 10.1002/ adsc.200404026. [Abstract][PDF]
315. "Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, In which the sp Carbon Chains are shielded by sp³ Carbon Chains", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889-5892. DOI: 10.1021/om0493558. [Abstract][PDF]
316. "Syntheses and Structures of Tetraplatinum bis(Polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains", Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893-5895. DOI: 10.1021/om049354f. [Abstract][PDF]
317. "Longitudinally Extended Molecular Wires based upon PtC≡CC≡CC≡CC≡C Repeat Units; Iterative Syntheses of Functionalized Linear PtC₈Pt, PtC₈PtC₈Pt, and PtC₈PtC₈PtC₈Pt Assemblies", Zheng, Q.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5896-5899. DOI: 10.1021/om049353n. [Abstract][PDF]
318. "Transition-Metal-Based Fluorous Catalysts", Corrêa da Costa, R. ; Gladysz, J. A. in Transition Metals for Organic Synthesis, 2nd ed, Beller, M.; Bolm, C. Eds.; Wiley/VCH, Weinheim, 2004, 527-543. DOI: 10.1002/9783527619405.ch6b. [Abstract]
319. (a) "Molecular Gyroscopes: {Fe(CO)₃} and {Fe(CO)₂(NO)}⁺ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. DOI: 10.1002/anie.200460534. [Abstract][PDF] (b) "Molekulare Gyroskope: {Fe(CO)₃}- und {Fe(CO)₂(NO)}⁺-Rotatoren in einem Stator aus drei Speichen; Einfache Synthese durch Alken-Metathese", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2004, 116, 5653-5656. DOI: 10.1002/ange.200460534. [Abstract][PDF]
320. "Electronic Structure and Chain Length Effects in Diplatinum Polyynediyl Complexes trans, trans-[(X)(R₃P)₂Pt(C≡C)_nPt(PR₃)₂(X)]: A Computational Investigation", Zhuravlev, F.; Gladysz, J. A. Chem. Eur. J. 2004, 10, 6510-6522. DOI: 10.1002/chem.200400643. [Abstract][PDF]
321. "Syntheses and Structures of Missing Links among Polybromocyclopentadienyl Rhenium and Manganese Tricarbonyl Complexes" , Dinh, L. V.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2005, 690, 493-503. DOI: 10.1016/J.JORGANCHEM.2004.09.072. [Abstract][PDF]
322. "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems", Eichenseher, S.; Delacroix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 245-255. DOI: 10.1021/om0492956. [Abstract][PDF]
323. "Monophasic and Biphasic Hydrosilylations of Enones and Ketones using a Fluorous Rhodium Catalyst that is Easily Recycled under Fluorous/Organic Liquid/Liquid Biphase Conditions", Dinh, L. V.; Gladysz, J. A. New. J. Chem. 2005, 29, 173-181. DOI: 10.1039/B415344H [Abstract][PDF]
324. "Generation and Reactions of Ruthenium Phosphido Complexes [(η⁵-C₅H₅)Ru(PR'₃)₂(PR₂)]: Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions", Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416. DOI: 10.1002/chem.200400925. [Abstract][PDF]
325. "Efficient Syntheses of Fluorous Primary Phosphines that do not Require PH₃", Emnet, C.; Gladysz, J. A. Synthesis 2005, 1012-1018. DOI: 10.1055/s-2005-861815. [Abstract][PDF]
326. "Theoretical Study on the Spin State Energy Splittings and Local Spin in Cationic [Re]-C_n-[Re] Complexes", Herrmann, C.; Neugebauer, J.; Gladysz, J. A.; Reiher, M. Inorg. Chem. 2005, 44, 6174-6182. DOI: 10.1021/ic050240l. [Abstract][PDF]
327. (a) "'Catalyst-on-a-Tape' – Teflon: A New Delivery and Recovery Method for Homogeneous Fluorous Catalysts", Dinh, L. V.; Gladysz, J. A. Angew. Chem., Int. Ed. 2005, 44, 4095-4097. DOI: 10.1002/anie.200500237. [Abstract][PDF] (b) "'Katalysatoren am laufenden Band' – Teflon: Eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren", Dinh, L. V.; Gladysz, J. A. Angew. Chem., 2005, 26 4164-4167. DOI: 10.1002/ange.200500237. [Abstract][PDF]
328. "Synthesis and Reactivity of 1,2- and 1,3-Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis" Kromm, K.; Eichenseher, S.; Prommesberger, M.; Hampel, F.; Gladysz, J. A. Eur. J. Inorg. Chem. 2005, 2983-2998. DOI: 10.1002/ejic.200500254. [Abstract][PDF]
329. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Ligands and Metal Complexes", Tuba, R.; Tesevic, V.; Dinh, L. V.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2005, 13, 2275-2283. DOI: 10.1039/B502309B [Abstract][PDF]
330. "A Synthetic Breakthrough into an Unanticipated Stability Regime: Readily Isolable Complexes in which C₁₆-C₂₈ Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Gladysz, J. A. J. Am. Chem. Soc. 2005, 127, 10508-10509. DOI: 10.1021/ja0534598. [Abstract][PDF]
331. "Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives", Emnet, C.; Tuba, R.; Gladysz, J. A. Adv. Synth. Catal., 2005, 347, 1819-1826. DOI: 10.1002/adsc.200505145. [Abstract][PDF]
332. "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions", Friedlein, F. K.; Hampel, F.; Gladysz, J. A. Organometallics, 2005, 24, 4103-4105. DOI: 10.1021/om0504708. [Abstract][PDF]
333. "Fluorous Solvents: Physical Properties", Gladysz, J. A.; Emnet, C. in Green Reaction Media in Organic Synthesis, Mikami, K. Ed.; Blackwell, Oxford, UK, 2005, pp 62-80 (Ch 3.2). ISBN: 978-1-4051-3402-6. DOI: 10.1002/9780470988770.ch3 [Abstract][PDF]
334. "An Easily Accessed Class of Recyclable Hypervalent Iodide Reagents for Functional Group Oxidations: bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF₃(CF₂)_n-1I(OCOCF₃)₂", Tesevic, V.; Gladysz, J. A. Green Chem. 2005, 7, 833-836. DOI: 10.1039/b511951k. [Abstract][PDF]
335. "'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails: Syntheses from Polybromocyclopentadienyl Complexes, Phase Properties, and Electronic Effects", Dinh, L. V.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 7211-7222. DOI: 10.1002/chem.200500595. [Abstract][PDF]
336. "Wire-Like PtC≡CC≡CC≡CC≡CPt Moieties Surrounded by Double-Helical 'Insulation': New Motifs Featuring P(CH₂)₂₀P and P(CH₂)₄O(CH₂)₂O(CH₂)₄P Linkages", de Quadras, L.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2006, 2929-2933. DOI: 10.1039/b604465b. [Abstract][PDF]
337. "π Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts", Dinh, L. V.; Consorti, C. S.; Emnet, C.; Gladysz, J. A. Organometallics 2006, 25, 1245-1251. DOI: 10.1021/om050950z. [Abstract][PDF]
338. "Gyroscope-Like Molecules Consisting of PdX₂/PtX₂ Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetallation", Nawara, A. J.; Shima, T.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2006, 128, 4962-4963. DOI: 10.1021/ja061044w. [Abstract][PDF]
339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", Corrêa da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. DOI: 10.1039/B602428A. [Abstract][PDF]
340. "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link in a Series of Square-Planar Platinum Complexes", Lewanzik, N.; Oeser, T.; Blümel, J.; Gladysz, J. A. J. Mol. Catal. A. 2006, 254, 20-28. (invited article, 16th International Symposium on Olefin Metathsis thematic issue) DOI: 10.1016/j.molcata.2005.10.047. [Abstract][PDF]
341. "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies", Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 5267-5281. DOI: 10.1002/chem.200501540. [Abstract][PDF]
342. (a) "Giant" Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25-27 Membered Macrocycles", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 2006, 45, 4372-4375. DOI: 10.1002/anie.200601191. [Abstract][PDF] (b) "Gyroskop-Giganten": Dipolare Cl-Rh-CO-Roatoren, umgeben von Startoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2006, 118, 4479-4482. DOI: 10.1002/ange.200601191. [Abstract][PDF]
343. "Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Ponytails; New Candidates for Phase Transfer Catalysts and Ionic Liquids", Emnet, C.; Weber, K. M.; Vidal, J. A.; Consorti, C. S.; Stuart, A. M. Gladysz, J. A. Adv. Synth. Catal. 2006, 348, 1625-1634. (invited article, "multiphase catalysis, green solvents, and immobilization" issue) DOI: 10.1002/adsc.200606138. [Abstract][PDF]
344. "A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C₆, C₈, C₁₀, C₁₂, C₁₆, C₂₀, C₂₄, and C₂₈ Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Bohling, J. C.; Peters, T. B.; Frisch, A. C.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 6486-6505. DOI: 10.1002/chem.200600615. [Abstract][PDF]
345. "Oxidation of Secondary Alcohols to Ketones Using Easily Recyclable bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF₃(CF₂)_n-1I(OCOCF₃)₂", Tesevic, V.; Gladysz, J. A.; J. Org. Chem. 2006, 71, 7433-7440. DOI: 10.1021/jo0612067. [Abstract][PDF]
346. "A Promising New Catalyst Family for Enantioselective [3+2] Cycloadditions of Allenes and Imines: Chiral Phosphines with a Transition Metal–CH₂–P: Linkage" Scherer, A.; Gladysz, J. A. Tetrahedron Lett. 2006, 47, 6335-6337. DOI: 10.1016/j.tetlet.2006.07.005. [Abstract][PDF]
347. "Fluorous to the Core", Gladysz, J. A. Science 2006, 313, 1249-1250. DOI: 10.1126/ science.1131944. [Abstract][PDF]
348. "Gyroscope-Like Molecules Consisting of Three-Spoke Stators that Enclose "Switchable" Neutral Dipolar Rhodium Rotators; Reversible Cycling between Faster and Slower Spinning Rh(CO)I and Rh(CO)₂I Species" Wang, L.; Shima, T.; Hampel, F.; Gladysz, J. A. Chem. Commun. 2006, 4075-4077. DOI: 10.1039/b606728j. [Abstract][PDF]
349. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Complexes Derived From P(CH₂)₅P Backbones", Consorti, C. S.; Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2006, 359, 4874-4884. DOI: 10.1016/j.ica.2006.07.092. [Abstract][PDF]
350. "Update 1 of: Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2006, 106, PR1–PR33. (inaugural "Perennial Review") DOI: 10.1021/cr030041o. [Abstract][PDF]
351. "Crystal Structure of an Unusual bis(fluorous phosphine) Ruthenium(III) Complex Derived from a Fluorous Grubbs' Catalyst", Corrêa da Costa, R.; Hampel, F.; Gladysz, J. A. Polyhedron 2007, 26, 581-588. DOI: 10.1016/j.poly.206.08.015. [Abstract][PDF]
352. "Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂PAr₂)", Seidel, F.; Gladysz, J. A. Synlett 2007, 6, 986-988. DOI: 10.1055/s-2007-973859. [Abstract][PDF]
353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", Corrêa da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. (invited article, olefin metathesis thematic issue) DOI: 10.1002 /adsc.200600461. [Abstract][PDF]
354. "Monophosphine and Diphosphine Ligands for Diplatinum Polyyendiyl Complexes: Efficient Syntheses of New Functionality-Containing Systems and Model Compounds", de Quadras, L.; Stahl,J.; Zhuravlev, F.; Gladysz, J. A. J. Organomet. Chem. 2007, 692, 1859-1870. DOI: 10.1016/J.JORGANCHEM.2006.12.023. [Abstract][PDF]
355. "Gyroscopes and the Chemical Literature: 1852-2002" Skopek, K.; Hershberger, M. C.; Gladysz, J. A. Coord. Chem. 2007, Coord. Chem. Rev. 2007, 251, 1723-1733. (invited article, 37th ICCC thematic issue) DOI:10.1016/j.ccr.2006.12.015 [Abstract][PDF]
356. "Temperature Controlled Catalyst Recycling: New Protocols based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid-Liquid Phase Separations", Tesevic, V.; Gladysz, J. A. Topics in Organometallic Chemistry 2008, 23, 67-89. (published on the web in 2006) DOI: 10.1007/3418_043. [Abstract][PDF]
357. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Coordination-Driven Self Assembly of Wirelike Pt(C≡C)_nPt Moieties That Are Spanned by Two P(CH₂)_mP Linkages", Stahl, J.; Mohr, W.; de Quadras, L.; Peters, T. B.; Bohling, J. C.; Martín-Alvarez, J. M.; Owen, G. R.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8282-8295. DOI: 10.1021/ja0716103. [Abstract][PDF]
358. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Directed Syntheses of Wirelike Pt(C≡C)_nPt Moieties That Are Spanned by Two P(CH₂)_mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. DOI: 10.1021/ja071612n. [Abstract][PDF]
359. "Ionic Chemistry in Extremely Nonpolar Fluorous Media: Phase Transfer Catalysis of Halide Substitution Reactions", Consorti, C. S.; Jurisch, M.; Gladysz, J. A. Org. Lett. 2007, 9, 2309-2312. DOI: 10.1021/ol0706354. [Abstract][PDF]
360. "Octahedral Gyroscope-Like Molecules with M(CO)₃(X) Rotators Encased in Three-Spoked Diphosphine Stators: Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities", Hess, G. D.; Hampel, F.; Gladysz, J. A. Organometallics 2007, 26, 5129-5131. DOI: 10.1021/om700625u. [Abstract][PDF]
361. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Wire-Like Pt(C≡C)_nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]
362. "Chiral Phosphorus Donor Ligands Containing Monocyclopentadienyl Metal Fragments", Castillo, D. A.; Gladysz, J. A. in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Börner, A. Ed; Wiley/VCH, Weinheim, 2008, 408-437. DOI: 10.1002/chin.200942263.
363. "Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity", Boswell, P. G.; Szíjjáró, C.; Jurisch, M.; Gladysz, J. A.; Rábai, J.; Bühlmann, P. Anal. Chem. 2008, 80, 2084-2090. DOI: 10.1021/ac702161c. [Abstract][PDF]
364. "Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains", Farley, R.; Zheng, Q.; Gladysz, J. A.; Schanze, K. S. Inorg. Chem. 2008, 47, 2955-2963. DOI: 10.1021/ic701220t. [Abstract][PDF]
365. "Syntheses of Gyroscope-Like Molecules via Three-Fold Ring Closing Metatheses of bis(Phosphine) Complexes trans-L_yM(P((CH₂)_nCH=CH₂)₃)₂, and Extensions to bis(Phosphite) Complexes trans-Fe(CO)₃(P(O(CH₂)_nCH=CH₂)₃)₂", Skopek, K.; Gladysz, J. A. J. Organomet. Chem. 2008, 693, 857-866. (invited article, "Frontiers in Organometallic Chemistry" thematic issue) DOI: 10.1016/J.JORGANCHEM.2007.11.001. [Abstract][PDF]
366. "Thermomorphic Fluorous Palladacycles", Gladysz, J. A. in Palladacycles, Dupont, J.; Pfeffer, M. Eds; Wiley/VCH, Weinheim, 2008, 341-359. DOI:10.1002/ 9783527623211.ch14. [Abstract][PDF]
367. "Coordination-Driven Self Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp³ Carbon Chains: Towards Endgroup-Endgroup Interactions", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 73-87. DOI: 10.1002/ chem.200701268. [Abstract][PDF]
368. "Synthesis of Fluorous Sulfur/Carbon/Sulfur Pincer Ligands and Palladium Complexes; New Catalyst Precursors for the Heck Reaction", Corrêa da Costa, R.; Jurisch, M.; Gladysz, J. A. Inorg. Chim. Acta 2008, 361, 3205-3214. (invited article, issue in honor of Robert Angelici) DOI: 10.1016/j.ica.2007.11.016. [Abstract][PDF]
369. "En Route to Diplatinum Polyynediyl Complexes trans,trans-(Ar)(R₃P)₂Pt(C≡C)_nPt(PR₃)₂(Ar): Untold Tales, Including End-Group Strategies", Stahl, J.; Bohling, J. C.; Peters, T. B.; de Quadras, L.; Gladysz, J. A. Pure Appl. Chem. 2008, 80, 459-474. (invited article, ISNA-12 thematic issue) DOI: 10.1351/pac200880030459. [Abstract][PDF]
370. "Three-Fold Intramolecular Ring-Closing Metatheses Involving Square Planar Platinum Complexes with cis Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute Like Complexes", Skopek, K.; Barbasiewicz, M.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2008, 47, 3474-3476. DOI: 10.1021/ic702391m. [Abstract][PDF]
371. "Synthesis and Reactivity of New Heterodinuclear Iron/Rhenium C_x Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡C)_n(η²-dppe)Fe(η⁵-C₅Me₅) (n = 3, 4); Redox Properties and a Dicobalt Hexacarbonyl Adduct", Szafert, S.; Paul, F.; Meyer, W. E.; Gladysz, J. A.; Lapinte, C. C. R. Chimie 2008, 11, 693-701. (invited article, Gecom-Concoord thematic issue) DOI:10.1016/j.crci.2007.10.009. [Abstract][PDF]
372. "Phase Transfer of Enantiopure Werner Cations into Organic Solvents; An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis", Ganzmann, C.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 5397-5400. DOI: 10.1002/chem.200800226. [Abstract][PDF]
373. "Syntheses, Structures, and Electronic Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C₆F₅)(R₃P)₂Pt, (p-tol)(R₃P)₂Pt, and (Ph₃P)Au End-Groups", de Quadras, L.; Shelton, A. H.; Kuhn, H.; Hampel, F.; Schanze, K. S.; Gladysz, J. A. Organometallics 2008, 27, 4979-4991. DOI: 10.1021/om800493x. [Abstract][PDF]
374. "Ionic Transformations in Extremely Nonpolar Fluorous Media: Easily Recoverable Phase Transfer Catalysts for Halide Substitution Reactions", Mandal, D.; Jurisch, M.; Consorti, C. S.; Gladysz, J. A. Chem. Asian J. 2008, 3, 1772-1782. DOI: 10.1002/asia.200800138. [Abstract][PDF]
375. "Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains", Samoc, M.; Dalton, G. T.; Gladysz, J. A.; Zheng, Q.; Yelkov, Y.; Ågren, H.; Norman, P.; Humphrey, M. G. Inorg. Chem. 2008, 47, 9946-9957. DOI: 10.1021/ic801145c. [Abstract][PDF]
376. "Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Proctocols Involving Precipitation, Teflon® Tape and Gore-Rastex® Fiber", Seidel, F. O.; Gladysz, J. A. Adv. Synth. Catal. 2008, 350, 2443-2449. DOI: 10.1002/adsc.200800403. [Abstract][PDF]
377. "Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes", Kuhn, H.; Hampel, F.; Gladysz, J. A. Organometallics 2009, 28, 4979-4987. DOI: 10.1021/om9005017. [Abstract][PDF]
378. "Synthesis and Reactivity of Fluorous and non-Fluorous Aryl and Alkyl Iodine(III) Dichlorides: New Chlorinating Reagents that are Easily Recycled using Biphasic Protocols", Podgoršek, A.; Jurisch, M.; Stavber, S.; Zupan, M.; Iskra, J.; Gladysz, J. A. J. Org. Chem. 2009, 74, 3133-3140. DOI: 10.1021/jo900233h. [Abstract][PDF]
379. "'Click' Chemistry in Metal Coordination Spheres: Copper(I) Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C₆F₅)(p-tol₃P)₂Pt(C≡C)_nH (n = 2-6)", Gauthier, S.; Weisbach, N.; Gladysz, J. A Organometallics 2009, 28, 5597-5599. DOI: 10.1021/om900680q. [Abstract][PDF]
380. "Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies", Gladysz, J. A. in Handbook of Green Chemistry, Anastas, P.; Crabtree, R. H. Eds; Volume 1: Homogeneous Catalysis; Crabtree, R. H. Volume Ed; Wiley/VCH, Weinheim, 2009, 17-38. ISBN: 9783527324965 3527324968.
381. "The Experimental Assay of Catalyst Recovery: General Concepts", Gladysz, J. A. in Recoverable and Recyclable Catalysts, Benanglia, M. Ed; Wiley-Blackwell, Oxford, England, 2009, pp. 1-22. ISBN: 978-0470681954.
382. "Syntheses and Structural Analyses of Chiral Rhenium Containing Amines of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)((CH₂)_nNRR') (n = 0, 1)", Seidel, S. N.; Prommesberger, M.; Eichenseher, S.; Meyer, O. Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2010, 363, 533-548. (invited article, issue in honor of Paul Pregosin) DOI:10.1016/j.ica.2009.03.047. [Abstract][PDF]
383. "Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents", Mandal, D.; Gladysz, J. A. Tetrahedron 2010, 66, 1070-1077. DOI: 10.1016/j.tet.2009.11.012. [Abstract][PDF]
384. "Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Nawara-Hultzsch, A. J.; Skopek, K.; Shima, T.; Barbasiewicz, M.; Hess, G. D.; Skaper, D.; Gladysz, J. A. Z. Naturforsch. B.. 2010, 65, 414-424. (invited article, issue in honor of Rolf Saalfrank) DOI: 10.1515/ZNB-2010-0327 [Abstract] [PDF]
385. "Molecular Wires in Single Molecule Junctions: Charge Transport and Vibrational Excitations", Ballmann, S.; Hieringer, W.; Secker, D.; Zheng, Q.; Gladysz, J. A.; Görling, A.; Weber, H. B. ChemPhysChem 2010, 11, 2256-2260. DOI: 10.1002/cphc.200900974. [Abstract][PDF]
386. "Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes", Chen, L. D.; Mandal, D.; Gladysz, J. A.; Bühlmann, P. New. J. Chem. 2010, 34, 1867-1874. DOI: 10.1039/B9NJ00696F. [Abstract][PDF]
387. "Towards Multistranded Molecular Wires: Syntheses, Structures, and Reactivities of Tetraplatinum bis(Polyynediyl) Complexes with Pt-C_x-Pt-(P(CH₂)₃P)₂-Pt-C_x-Pt-(P(CH₂)₃P)₂ Cores (x = 4, 6, 8)", Owen, G. R.; Gauthier, S.; Weisbach, N.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Dalton Trans. 2010, 5260-5271. DOI: 10.1039/c002041a. [Abstract][PDF]
388. "Square Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH=CH₂ Substituents; Two- and Three-Fold Intramolecular Ring Closing Metatheses", Han, J.; Deng, C.; Fang, R.; Zhao, D.; Wang, L.; Gladysz, J. A. Organometallics 2010, 29, 3231-3234. DOI: 10.1021/om100536g. [Abstract][PDF]
389. "Thermomorphic Fluorous Phosphines as Organocatalysts for Michael Addition Reactions", Gimbert, C.; Vallribera, A.; Gladysz, J. A.; Jurisch, M. Tetrahedron Lett. 2010, 51, 4662-4665. DOI: 10.1016/j.tetlet.2010.06.136. [Abstract][PDF]
390. "New C₁-Symmetric Ph₂C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Polypropylene Polymerization: Synthetic Approach via Activated Fulvenes" Kirillov, E.; Marquet, N.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2010, 29, 5073-5082. (invited article, issue in honor of Dietmar Seyferth) DOI: 10.1021/om100289y. [Abstract][PDF]
391. "Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes", Lai, C.-Z.; Fierke, M. A.; Corrêa da Costa, R.; Gladysz, J. A.; Stein, A.; Bühlmann, P. Anal. Chem. 2010, 82, 7634-7640. DOI: 10.1021/ac1013767. [Abstract][PDF]
392. "The Future of Organometallic Chemistry", Gladysz, J. A. Organometallics 2011, 30, 1-4. DOI: 10.1021/om1011215. [Abstract][PDF]
393. "Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R¹R²C)-(3,6-tBu₂Flu)(3-R₃-5-Me-C₅H₂)}MCl₂: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization", Kirillov, E.; Marquet, N.; Bader, M.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics, 2011, 30, 263-272. DOI: 10.1021/om100897j. [Abstract][PDF]
394. (a) "Dibridgehead Diphosphines that Turn Themselves Inside-Out", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2011, 50, 6647-6651. DOI: 10.1002/ange.201100893. [Abstract][PDF] (b) "Dreifach-verbrückte Diphosphine mit von innen nach außen invertierender Konfiguration", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem. 2011, 123, 6777-6781. DOI: 10.1002/ange.201100893. [Abstract][PDF]
395. "Analogs of Grubbs' Second Generation Catalyst with Hydrophilic Phosphine Ligands: Phase Transfer Activation of Ring Closing Alkene Metathesis", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Org. Lett. 2011, 13, 6188-6191. DOI: 10.1021/ol202548q. [Abstract][PDF]
396. "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines that can turn themselves Inside-Out", Stollenz, M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2011, 30, 6510-6513. DOI: 10.1021/om200924g. [Abstract][PDF]
397. "Potentiometric Sensors Based on Fluorous Membranes Doped with Highly Selective Ionophores for Carbonate", Chen, L. D.; Mandal, D.; Pozzi, G.; Gladysz, J. A.; Bühlmann, P. J. Am. Chem. Soc. 2011, 133, 20869-20877. DOI: 10.1021/ja207680e. [Abstract][PDF]
398. "Organometallics Roundtable 2011", Gladysz, J. A.; Ball, Z. T.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Manners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam, V. W.-W. Organometallics 2012, 31, 1-18. DOI: 10.1021/om201234x. [Abstract][PDF]
399. "Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts", Hilliard, C. R.; Gladysz, J. A.; Blümel, J. Dalton. Trans. 2012, 41, 1742-1754. DOI: 10.1039/c1dt11863c. [Abstract][PDF]
400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Abstract][PDF]
401. "Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands", Zeits, P. D.; Rachiero, G. P.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2012, 31, 2854-2877. [Abstract][PDF]
402. "Structural, Physical, and Chemical Properties of Fluorous Compounds", Gladysz, J. A.; Jurisch, M. Top. Curr. Chem. 2012, 308, 1-24. [PDF]
403. "A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated polyyne", Weisbach, N.; Baranová, Z.; Gauthier, S.; Reibenspies, J. H.; Gladysz, J. A. Chem. Commun. 2012, 48, 7562-7564. DOI: 10.1039/C2CC33321J. [Abstract][PDF]
404. "Ring opening metathesis polymerization of an η⁴-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments", Zeits, P. D.; Fiedler, T.; Gladysz, J. A. Chem. Commun. 2012, 48, 7925-7927. DOI: 10.1039/C2CC32150E. [Abstract][PDF]
405. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluorous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g. [Abstract][PDF]
406. "Toward Permetalated Alkyne/Azide 3+2 or 'Click' Cycloadducts", Clough, M. C.; Zeits, P. D. Bhuvanesh, N.; Gladysz, J. A. Organometallics 2012, 31, 5231-5234. DOI: 10.1021/om300542a. [Abstract][PDF]
407. "Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Level Detection and In-Situ Monitoring of Absorption", Chen, L. D.; Lai, C.-Z.; Granda, L. P.; Fierke, M. A.; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P. Anal. Chem. 2013, 85, 7471-7477. DOI: 10.1021/ac401424j. [Abstract][PDF]
408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Guerrero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u. [Abstract][PDF]
409. "A Metal-capped Conjugated Polyyne Threaded Through a Phenanthroline-based Macrocycle. Probing Beyond the Mechanical Bond to Interactions in Interlocked Molecular Architectures", Sahnoune, H.; Baranová, Z.; Bhuvanesh, N.; Gladysz, J. A.; Halet, J.-F. Organometallics, 2013, 32, 6360-6367. DOI: 10.1021om400709q. [Abstract][PDF]
410. "Multifold Ring Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities", Fiedler, T.; Gladysz, J. A. in Olefin Metathesis – Theory and Practice, Grela, K., Ed.; John Wiley & Sons, Hoboken, New Jersey, 2014, 311-328. ISBN: 978-1-118-20794-9.
411. "Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladium Catalyzed Suzuki Cross-Coupling Reactions", Sierra Castro, D.; Bhuvanesh, N.; Reibenspeis, J. H.; Gladysz, J. A.; Klahn, A. H. J. Organomet. Chem. 2014, 749, 416-420. DOI: 10.1016/j.jorganchem.2013.10.029. [Abstract][PDF]
412. "Gyroscope Like Molecules Consisting of PdX₂/PtX₂ Rotators Within Three-Spoke Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Nawara-Hultzsch, A. J.; Stollenz, M.; Barbasiewicz, M.; Szafert, S.; Lis, T.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Chem. Eur. J. 2014, 20, 4617-4637. DOI: 10.1002/chem.201304419 [Abstract][PDF]
413. "Highly Active Families of Catalysts for the Ring Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole", Thomas, C.; Gladysz, J. A. ACS Catalysis 2014, 4, 1134-1138. DOI: 10.1021/cs500134z. ("ACS Editor's Choice" article for 14 March 2014: [Link]) [Abstract][PDF]
414. "Photophysics of Platinum Tetrayne Oligomers: Delocalization of Triplet Exciton", Li, Y.; Winkel, R. W.; Weisbach, N.; Gladysz, J. A.; Schanze, K. S. J. Phys. Chem. A. 2014, 115, 10333-10339. DOI: 10.1021/jp5021388. [Abstract][PDF]
415. "Organometallics Roundtable 2013-2014", Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaï, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. Organometallics 2014, 33, 1505-1527. DOI: 10.1021/om500253z. [Abstract][PDF]
416. "Synthesis, Photovoltaic Perfomances, and TD-DFT Modeling of Push-Pull Diacetylide Platinum Complexes in TiO₂ Based Dye-Sensitized Solar Cells", Gauthier, S.; Caro, B.; Robin-Le Guen, F.; Bhuvanesh, N.; Gladysz, J. A.; Wojcik, L.; Le Poul, N.; Planchat, A.; Pellegrin, Y.; Blart, E.; Jacquemin, D.; Odobel, F. Dalton Trans. 2014, 43, 11233-11242. DOI:10.1039/C4DT00301B [Abstract][PDF]
417. "Metal Templated Hydrogen Bond Donors as 'Organocatalysts' for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes", Scherer, A.; Mukherjee, T.; Hampel, F.; Gladysz, J. A. Organometallics 2014, 33, 6709-6722. DOI:10.1021/om500704u. [Abstract][PDF]
418. "Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions", Mukherjee, T.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6723-6737. DOI:10.1021/om500705s. [Abstract][PDF]
419. "Liquid/Solid Phase Transfer Activation of Grubbs-Type Alkene Metathesis Catalysts; Application of Silver Salts of Sulfonated Polystyrene", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Catal. Sci. Technol. 2014, 4, 4178-4182. DOI:10.1039/c4cy01021c. [Abstract][PDF]
420. "Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces", Hilliard, C. R.; Kharel, S.; Cluff, K. J.; Bhuvanesh, N.; Gladysz, J. A.; Blümel, J. Chem. Eur. J. 2014, 20, 17292-17295. DOI: 10.1002/chem.201404880. [Abstract][PDF]
421. "Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles", Baranová, Z.; Amini, H.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6746-6749. DOI:10.1021/om501026u. [Abstract][PDF]
422. "An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2-Substituted Benzimidazoles", Gladysz, J. A.; Safaei, H. R.; Nouri, S. Helv. Chim. Acta 2014, 97, 1539-1545. DOI: 10.1002/hlca.201400033. [Abstract] [PDF]
423. "Fluorous Chemistry Meets Green Chemistry: A Concise Primer", Mukherjee, T.; Gladysz, J. A. Aldrichimica Acta, 2015, 48, 25-28. [PDF]
424. "Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis", Lewis, K. G.; Ghosh, S. K.; Bhuvanesh, N.; Gladysz, J. A. ACS Cent. Sci., 2015, 1, 50-56. DOI:10.1021/acscentsci.5b00035. [Abstract] [PDF]
425. "Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Lang, G. M.; Skaper, D.; Shima, T.; Otto, M.; Wang, L.; Gladysz, J. A. Aust. J. Chem. 2015, 68, 1342-1351. DOI: 10.1071/CH15178. (invited contribution, issue commemorating the 2014 RACI National Congress) [Abstract] [PDF]
426. "Phase and Redox Shifted Four Iron/Four Sulfur Clusters; Fluorous Analogs of Metalloensyme Cofactors", Zhang, C.-P.; Xi, Z.; Mueller, K. M.; Holliday, B. J.; Bazzi, H. S.; Gladysz, J. A. Dalton Trans. 2015, 44, 19615-19624. DOI:10.1039/C5DT01959A [Abstract] [PDF]
427. "Steric Control of the in/out Sense of Bridgehead Substituents in Macrobicyclic Compounds: Isolation of New "Crossed Chain" Variants of in/out Isomers", Stollenz, M.; Taher, D.; Bhuvanesh, N.; Reibenspies, J. H.; Baranová, Z.; Gladysz, J. A. Chem. Commun. 2015, 51, 16053-16056. DOI: 10.1039/c5cc05620a. [Abstract] [PDF]
428. "Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands", Xi, Z.; Bazzi, H.S.; Gladysz, J. A. J. Am. Chem. Soc. 2015, 137, 10930-10933. DOI:10.1021/jacs.5b06562 [Abstract] [PDF]
429. "Substitution and Catalytic Chemistry of Gyroscope Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands", Estrada, A. L.; Jia, T.; Bhuvanesh, N.; Blümel, J.; Gladysz, J. A. Eur. J. Inorg. Chem.. 2015 2015 5318-5321. DOI:10.1002/ejic.201500953 [Abstract] [PDF]
430. "Phase Transfer Activation of Transition Metal Catalysts", Tuba, R.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Chem. Eur. J. 2015, 21, 15894-15906. DOI:10.1002/chem.201502403. [Abstract] [PDF]
431. "Synthesis of a Series of ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands for use in Enantioselective Catalysis", Ghosh, S. K.; Ganzmann, C.; Gladysz, J. A. Tetrahedron: Asymmetry 2015, 26, 1273-1280. DOI:10.1016/j.tetasy.2015.09.012 [Abstract] [PDF]
432. "An Analogue of Grubbs' Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis", Balogh, J.; Hlil, A. R.; Su, H.-L.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. ChemCatChem. 2016, 8, 125-128. DOI: 10.1002/cctc.201500913 [Abstract] [PDF]
433. "A Phase Based Approach to Insulated Molecular Wires: Diplatinum Octatetraynediyl Complexes Bearing Fluorous Trialkylphosphine Ligands", Clough, M. C.; Fiedler, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2016, 812, 34-42. DOI:10.1016/j.jorganchem.2015.09.020. (invited contribution, special issue dedicated to Jack Lewis) [Abstract] [PDF]
434. (a) "Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen Bond Donor Catalysts for Highly Enantioselective Michael Additions", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2016, 55, 4356-4360. DOI: 10.1002/anie.201511314. [Abstract][PDF] (b) "Werner-Komplexe mit ω-dimethylaminoalkylsubstitutierten Ethylenediamin-liganden: Bifunktionale Wasserstoffbrückenbindungsdonor-Katalysatoren für hochgradig enantioselektive Michael Additionen", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., 2016, 128, 4429-4433. DOI: 10.1002/ange.201511314. [Abstract][PDF]
435. "Gyroscope Like Molecules Consisting of Trigonal or Square Planar Osmium Rotators Within Three-Spoked Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Fiedler, T.; Bhuvanesh, N.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Dalton Trans. 2016, 45, 7131-7147. DOI:10.1039/c6dt00692b [Abstract] [PDF]
436. " Tris(1,2-diphenylethylenediamine) Cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds", Kumar, A.; Ghosh, S. K.; Gladysz, J. A. Org. Lett. 2016, 18, 760-763. DOI:10.1021/acs.orglett.6b00023 [Abstract] [PDF]
437. " Gyroscope Like Complexes based upon Dibridgehead Diphosphine Cages that are Accessed by Three Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)₃, Fe(CO)₂(NO)⁺ and Fe(CO)₃(H)⁺ Rotators", Lang, G. M.; Shima, T.; Wang, L.; Cluff, K. J.; Skopek, K.; Hampel, F.; Blümel, J.; Gladysz, J. A. J. Am. Chem. Soc. 2016, 138, 7649-7663. DOI:10.1021/jacs.6b03178 [Abstract] [PDF]
438. "Octahedral Werner Complexes with Substituted Ethylenediamine Ligands: A Stereochemical Primer for a Historic Series of Compounds now Emerging as a Modern Family of Catalysts", Ehnbom, A.; Ghosh, S. K.; Lewis, K. G.; Gladysz, J. A. Chem. Soc. Rev. 2016, 45, 6799-6811. DOI:10.1039/c6cs00604c [Abstract] [PDF]
439. "Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR", Fiedler, T.; Chen, L.; Wagner, N. D.; Russell, D. R.; Gladysz, J. A. Organometallics 2016, 35, 2071-2075. DOI:10.1021/acs.organomet.6b00249 [Abstract] [PDF]
440. " Convenient Protocols for Mizoroki-Heck Reactions of Aromatic Bromides and Polybromides with Fluorous Alkenes of the Formula H₂C=CH(CF₂)_n–1CF₃ (n = 8, 10)", Su, H.-L.; Balogh, J.; Al-Hashimi, M.; Seapy, D. G.; Bazzi, H. S.; Gladysz, J. A. Org. Biomol. Chem. 2016, 10058-10069. DOI:10.1039/c6ob01980c. [Abstract] [PDF]
441. "Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Carbonyl Complexes based upon Dibridgehead Diarsine Cages", Lang, G. M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2016, 35, 2873-2889. DOI: 10.1021/acs.organomet.6b00447. [Abstract] [PDF]
442. "Synthesis, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Complexes with Dibridgehead Diphosphine Cages: Pre- vs. Post-Metathesis Substitutions as Routes to Adducts with Neutral Dipolar Fe(CO)(NO)(X) Rotors", Lang, G. M.; Skaper, D.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2016, 45, 16190-16204. DOI: 10.1039/c6dt03258c. [Abstract] [PDF]
443. "Mono- and Disubstitution Reactions of Gyroscope Like Complexes Derived from Cl-Pt-Cl Rotators within Cage Like Dibridgehead Diphosphine Ligands", Taher, D.; Nawara-Hultzsch, A. J.; Bhuvanesh, N.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2016, 821, 136-141. DOI: 10.1016/j.jorganchem.2016.03.022. (invited contribution, special issue dedicated to Heinrich Lang) [Abstract] [PDF]
444. "A Quest for Atropisomerism in Cojoined Square Planar Metal Complexes: Syntheses and Structures of Sterically Congested Diplatinum Ethynediyl Adducts", Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. Eur. J. Inorg. Chem. 2017, 2017, 1017-1025. DOI: 10.1002/ejic.201601307. [Abstract] [PDF]
445. "Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 1,7-Dihydroxynaphthalene", Baranová, Z.; Amini, H.; Neupane, H.; Garrett, S. C.; Ehnbom, A.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Aust. J. Chem. 2017, 70, 373-386. DOI: 10.1071/CH16587 (invited contribution, special issue, Heron Island Conference on Reactive Intermediates) [Abstract] [PDF]
446. "Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl₂ Species (M = Pt, Pd, Ni)", 2016, Kharel, S.; Joshi, H.; Bierschenk, S.; Stollenz, M.; Taher, D.; Bhuvanesh, N.; Gladysz, J. A. J. Am. Chem. Soc. 2017, 139, 2172-2175. DOI: 10.1021/jacs.6b12788. [Abstract] [PDF]
447. "Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts derived from Trications of the Formula [Co(NH₂CHArCHArNH₂)₃]³⁺", Ghosh, S. K.; Lewis, K. G.; Kumar, A.; Gladysz, J. A. Inorg. Chem. 2017, 56, 2304-2320. DOI: 10.1021/acs.inorg chem.6b03042. [Abstract] [PDF]
448. (a) "Gigging Benzene", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem., Int. Ed. 2017, 58, 5664-5666. DOI: 10.1002/anie.201702942. [Abstract] [PDF] (b) "Vom Aufspießen des Benzols", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem. 2017, 129, 5756–5758. DOI: 10.1002/ange.201702942. [Abstract] [PDF]

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