Gladysz Research Group

Contact

321 Reed McDonald Building
Ph: 979-845-7048

Mailing Address:
Department of Chemistry Texas A&M University
P.O. Box 30012
College Station, TX 77843-3012

Shipping Address:
Department of Chemistry
Texas A&M University
580 Ross Street
MS3255 TAMU
College Station, TX 77843-3255

People

Prof. John A. Gladysz -- Research Personnel -- Office Personnel

Prof. John A. Gladysz
Distinguished Professor
Dow Chair in Chemical Invention

Office: 318 Reed McDonald
gladysz@mail.chem.tamu.edu
Ph: (979) 845-1399
Fax: (979) 845-5629

Assistant: Bryan Stewart
rbryanstewart@tamu.edu
(979) 845-7048

PROFESSIONAL

Professional Positions Assistant Professor, University of California, Los Angeles, 1974-1982 Associate Professor, University of Utah, 1982-1985 Professor, University of Utah, 1985-1998 Professor Ordinarius (Chair, Organic Chemistry), Friedrich-Alexander-Universitt Erlangen-Nrnberg (Germany), 1998-2008 Distinguished Professor and Dow Chair in Chemical Invention, Texas A&M University, 2008

Consulting Gas Research Institute, Panel Member; New Directions, Chicago, Illinois, Basic Research on Coal Gasification,1979-1980 G.D. Searle & Company, Consultant on Pharmaceutical Synthesis, Chicago, Illinois, High Pressure/Organometallic Methods,1980-1981 Procter & Gamble Company, Consultant for Corporate Technology Cincinnati, Ohio,Division, Miami Valley Laboratory, 1983-1985 Monsanto Corporation, Consultant for Polymer Products, Springfield Massachusetts Division, 1984-1986 Union Camp Corporation, Consultant for Terpene Products, Princeton, New Jersey Division, 1988-1989 Exxon Research & Engineering, Consultant for Corporate Research Annandale, New Jersey, Laboratories, 1993-1998 Kimberly Clark Corporation, Consultant for New Technologies Roswell, Georgia Division, 1997-1998 3M Corporation, Consultant for Fluorocarbon Products, Minneapolis Minnesota Division, 1998-1999 Rhodia (Rhône-Poulenc) Corporation, Consultant for Catalysis Division Lyon (Saint-Fons), France, 1999-2001 Total/Fina/Elf,Consultant for Polyolefin Division, Paris, France Seneffe,Belgium, 2002-2005 Edwards Nanoscience, Consultant for Oxidation Technologies Houston, Texas, 2009-2011 Terrabon, Inc., Consultant for Biofuels Processing Bryan, Texas, 2011-2012

Professional Service Editor-in-Chief, Organometallics, 2010-2014 Associate Editor, Chemical Reviews, 1984-present Co-PI, NSF Organometallic Workshop, 1991-1993 Member, NIH Medicinal Chemistry (A) Study Section, 1995-1999 Chair, Organometallic Chemistry Gordon Conference, 1996 (1995) International Advisory Board Member, Encyclopedia of Catalysis (Wiley; I. Horvath, Ed.), 1999-2003

Advisory Boards Organometallics (1990-1992) Bulletin de la Socit Chimique de France (1992-1997) Sheffield Academy Press, Postgraduate Chemistry Series (1998- ) New Journal of Chemistry (2001- )
Professional Awards and Honors Alfred P. Sloan Foundation Fellow, 1980-1984 Camille and Henry Dreyfus Teacher-Scholar, 1980-1985 Arthur C. Cope Scholar Award, 1988 University of Utah Distinguished Research Award, 1992 American Chemical Society Award in Organometallic Chemistry, 1994 von Humboldt Foundation Research Award for Senior Scientists, 1995-1996 Who's Who in the World, 2002- Lady Davis Professorship, Technion - Israel Institut of Technology, 2003-2004 Fellow, American Association for the Advancement of Science, 2004 International Fluorous Technologies Award, 2007
Professional Societies and Organizations American Chemical Society, 1970- The Chemical Society, 1974- American Association for the Advancement of Science, 1975- Gesellschaft Deutscher Chemiker, 1997- Phi Beta Delta (Honor Society for International Scholars, 2009-)

PERSONAL

Family Details [link]
Wife - Dr. Janet Bluemel [link]
Mother - Margean A. Gladysz [link]
Father - Edward M. Gladysz [link under construction]
Crow's Nest Ranch
- Directions [pdf]
- House [link under construction]
- Animals [link under construction]
- Agriculture [link under construction]
- Oil well [link under construction]
- Depth schematic, July 2010 [pdf]
- Drilling team, July 2010 [pdf]

Biographical Sketch

John A. Gladysz is a native of the Kalamazoo, Michigan area, and obtained his B. S. degree from the University of Michigan (1971) and his Ph. D degree from Stanford University (1974) with E. E. van Tamelen. He subsequently held appointments at UCLA (Assistant Professor, 1974-1982), the University of Utah (Associate Professor and Professor, 1982-1998), the Chair of Organic Chemistry at the University of Erlangen-Nuremberg in Germany, where he succeeded Paul von Ragu Schleyer, and is currently Distinguished Professor and DOW Chair at Texas A&M University. He is a fellow of the Alfred P. Sloan Foundation (1980-1984) and a Camille and Henry Dreyfus Teacher-Scholar Grant recipient (1980-1985). He received an Arthur C. Cope Scholar Award in 1988, the University of Utah Distinguished Research Award in 1992, the ACS Award in Organometallic Chemistry in 1994, and a von Humboldt Foundation Research Award for Senior Scientists in 1995. From June 1984 through July 2010, he served as the Associate Editor of Chemical Reviews. He then succeeded Dietmar Seyferth as the Editor in Chief of Organometallics.

Prof. Gladysz has authored over 400 papers and patents, and his research spans a wide range of problems in the general areas of synthetic and mechanistic organometallic chemistry, and catalysis.

On the personal side, he enjoys runing (5+ miles 4-5 times per week), all types of literature, and a good red wine. He is married to Janet Blümel, a Professor of Chemistry at Texas A&M University who specializes in inorganic chemistry, supported catalysts, and solid state NMR spectroscopy.

Personal/Family Biography [Link]

Publications

1970 | 1980 | 1990 | 2000 | 2010 |bottom of list

1. "Nonenzymatic Nitrogen Fixation by an Iron-Molybdenum Model for Nitrogenase", van Tamelen, E. E.; Gladysz, J. A.; Miller, J. S. J. Am. Chem. Soc. 1973, 95, 1347-1348. DOI: 10.1021/ja00785a063. [Abstract] [PDF]
2. "Biological and Abiological Nitrogen Fixation by Molybdenum-Bound N₂/4Fe-4S Cluster Systems", van Tamelen, E. E.; Gladysz, J. A.; Brûlet, C. R. J. Am. Chem. Soc. 1974, 96, 3020-3021. DOI: 10.1021/ja00816a074. [Abstract] [PDF]
3. "Direct Conversion of Aldehydes, Esters, and 1,2-Oxides to Alkanes with Carbon Skeleton Preservation", van Tamelen, E. E.; Gladysz, J. A. J. Am. Chem. Soc. 1974, 96, 5290-5291. DOI: 10.1021/ja00823a065. [Abstract][PDF]
4. "I. Titanocene Induced Reductive Deligandations of Organic Compounds; II. Iron-Molybdenum Models for Nitrogenase", Gladysz, J. A. Diss. Abstr. Int. B. 1974, 35, 2654.
5. "Thione Complexes of Group VIB Pentacarbonyls", Gladysz, J. A.; Avakian, R. W. Syn. React. Inorg. Metal-Org. Chem. 1975, 5, 247-255. DOI: 10.1080/00945717508057315. [Abstract]
6. "Deoxygenation of Epoxides by Metal Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. J. Org. Chem. 1976, 41, 3647-3648. DOI: 10.1021/jo01303a023. [Abstract][PDF]
7. "5,6-Dehydro[3.3]Paracyclophane: Bridged Benzobarrelene Formation by Intramolecular Trapping of a Novel Aryne", Longone, D. T.; Gladysz, J. A. Tetrahedron Lett. 1976, 17, 4559-4562. DOI: 10.1016/SO040-4039(00)93931-5. [Abstract][PDF]
8. "Deoxygenation of Nitro and Nitroso Arenes via Chromium Atom Cocondensation", Gladysz, J. A.; Fulcher, J. G.; Togashi, S. Tetrahedron Lett. 1977, 18, 521-524. DOI: 10.1016/SO040-4039(01)92683-8. [Abstract][PDF]
9. "A Convenient Preparation of Transition Metal Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; Observation and Reactions of a Bimetallic Manganese-Formyl Intermediate", Gladysz, J. A.; Williams, G. M.; Tam, W; Johnson, D. L. J. Organomet. Chem. 1977, 140, C1-C6. DOI: 10.1016/SO022-328X(00)84402-2. [Abstract][PDF]
10. "A Convenient Synthesis of [3.3]Paracyclophane", Longone, D. T.; Kusefoglu, S. H.; Gladysz, J. A. J. Org. Chem. 1977, 42, 2787-2788. DOI: 10.1021/jo00436a033. [Abstract][PDF]
11. "Cyclotrimerization of Cyclic Diynes via Metal Atom Cocondensation; Revised Structure for the Reported 'Percyclophane-4'", Gladysz, J. A.; Fulcher, J. G.; Lee, S. J.; Bocarsly, A. B. Tetrahedron Lett. 1977, 18, 3421-3424. DOI: 10.1016/SO040-4039(01)83256-1. [Abstract][PDF]
12. "High Pressure Cycloadditions of Pyrones; Synthesis of Highly Functionalized Six-Membered Rings by Inhibitions of Carbon Dioxide Loss", Gladysz, J. A.; Lee, S. J.; Tomasello, J. A. V.; Yu, Y. S. J. Org. Chem. 1977, 42, 4170-4172. DOI: 10.1021/jo00445a050. [Abstract][PDF]
13. "Transition Metal Formyl Complexes: Synthesis by Trialkylborohydride Attack on Metal Carbonyl Acyls", Gladysz, J. A.; Selover, J. C. Tetrahedron Lett. 1978, 19, 319-322. DOI: 10.1016/SO040-4039(01)85114-5. [Abstract][PDF]
14. "A Convenient One-Flask Synthesis of Dialkyl Selenides and Diselenides via Lithium Triethylborohydride Reduction of Se_x", Gladysz, J. A.; Hornby, J. L.; Garbe, J. E. J. Org. Chem. 1978, 43, 1204-1208. DOI: 10.1021/jo00400a040. [Abstract][PDF]
15. "Binuclear and Mixed Metal Formyl Complexes; Isolation, Characterization, and Chemistry", Gladysz, J. A.; Tam, W. J. Am. Chem. Soc. 1978, 100, 2545-2547. DOI: 10.1021/ ja00476a046. [Abstract][PDF]
16. "Ligand Wrapping Around Chromium: Reactions of Diphenylmethane, 1,4-Diphenylbutane, Benzyl Ether, and Benzyl Sulfide with Chromium Atoms", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Tetrahedron Lett. 1978, 19, 1725-1728. DOI: 10.1016/SO040-4039(78)80027-6. [Abstract][PDF]
17. "A One-Flask Preparation of Analytically Pure K₂Fe(CO)₄", Gladysz, J. A.; Tam, W. J. Org. Chem. 1978, 43, 2279-2280. DOI: 10.1021/jo00405a041. [Abstract][PDF]
18. "Ene Reactions of β-Pinene at Room Temperature and 40 kbar Pressure", Gladysz, J. A.; Yu, Y. S. J. Chem. Soc., Chem. Commun. 1978, 599-600. DOI: 10.1039/C39780000599. [Abstract][PDF]
19. "Hydride Transfer Reactions of Anionic Formyl Complexes: A Mechanistic Test", Gladysz, J. A.; Merrifield, J. H. Inorg. Chim. Acta 1978, 30, L317-L318. DOI:10.1016/S0020-1693(00)88992-6. [Abstract][PDF]
20. "Introduction of Sulfur into Organic Molecules via Lithium Triethylborohydride Reduction of S₈", Gladysz, J. A.; Wong, V. K.; Jick, B. S. J. Chem. Soc., Chem. Commun. 1978, 838-839. DOI: 10.1039/C39780000838. [Abstract][PDF]
21. "Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds", Gladysz, J. A. in Fundamental Research in Homogeneous Catalysis, Vol. 2, Plenum, New York, 1978, pp. 101-115. (invited article, proceedings of international workshop on homogeneous catalysis)
22. "α-Silyloxy and α-Hydroxy Manganese Alkyls; Generation Via a New Five-membered Metallocycle", Gladysz, J. A.; Selover, J. C.; Strouse, C. E. J. Am. Chem. Soc. 1978, 100, 6766-6768. DOI: 10.1021/ja00489a044. [Abstract][PDF]
23. "²⁹Si NMR Spectra of Transition Metal Silanes by the Selective Population Transfer Method", Li, S.; Johnson, D. L.; Gladysz, J. A.; Servis, K. L. J. Organomet. Chem. 1979, 166, 317-321. DOI:10.1016/S0022-328X(00)82549-8. [Abstract][PDF]
24. "The Synthesis of Metal Carbonyl Monoanions by Trialkylborohydride Cleavage of Metal Carbonyl Dimers; A Convenient One-flask Preparation of Metal Alkyls, Metal Acyls, and Mixed Metal Compounds", Gladysz, J. A.; Williams, G. M.; Tam, W.; Johnson, D. L.; Parker, D. L.; Selover, J. C. Inorg. Chem. 1979, 18, 553-558. DOI: 10.1021/ic50193a006. [Abstract][PDF]
25. "Neutral Metal Formyl Complexes; Generation, Reactivity, and Models for Fischer-Tropsch Catalyst Intermediates", Tam, W.; Wong, W. K.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 1589-1591. DOI: 10.1021/ja00500a037. [Abstract][PDF]
26. "Trialkylborohydrides: Applications in Organometallic Syntheses", Gladysz, J. A. Aldrichimica Acta 1979, 12, 13-18. [Link]
27. "Reactions of Organocyclopropanes and Spirocycles with Metal Atoms", Gladysz, J. A.; Fulcher, J. G.; Ugolick, R. C.; Hanlan, A. J. L.; Bocarsly, A. B. J. Am. Chem. Soc. 1979, 101, 3388-3390. DOI: 10.1021/ja00506a048. [Abstract][PDF]
28. "Simplified in situ Syntheses of Anhydrous HMn(CO)₅", Gladysz, J. A.; Tam, W.; Williams, G. M.; Johnson, D. L.; Parker, D. W. Inorg. Chem. 1979, 18, 1163-1165. DOI: 10.1021/ic50194a05. [Abstract][PDF]
29. "X-Ray Crystal Structure and Chemical Transformations of the Neutral Metal Formyl (η-C₅H₅)Re(PPh₃)(NO)(CHO)", Wong, W.-K; Tam, W.; Strouse, C. E.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1979, 530-531. DOI: 10.1039/C39790000530. [Abstract][PDF]
30. "Squeezing the Transition State", Gladysz, J. A. CHEMTECH 1979, 9, 372-377.
31. "Electrophile Induced Disproportionation of the Neutral For (η-C₅H₅)Re(NO)(PPh₃)(CHO); Generation of Cationic Rhenium Carbenes of the Formula [(η-C₅H₅)Re(NO)(PPh₃)(CHX)]⁺ (X = H, OCH₃, OH)", Wong, W.-K; Tam, W.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 5440-5442. DOI: 10.1021/ja00512a069. [Abstract][PDF]
32. "New Methodology for the Introduction of Sulfur into Organic Molecules; Synthesis of Anhydrous Li₂S, Li₂S₂ and LiSR Species by Lithium Triethylborohydride Reduction of Elemental Sulfur and Disulfides", Gladysz, J. A.; Wong, V. K.; Jick, B. S. Tetrahedron 1979, 35, 2329-2335. DOI: 10.1016SO040-4020(01)93746-9. [Abstract][PDF]
33. "Reactions of Benzaldehyde with Trialkylsilyl Metal Carbonyl Complexes", Johnson, D. L.; Gladysz, J. A. J. Am. Chem. Soc. 1979, 101, 6433-6435. DOI: 10.1021/ja00515a048. [Abstract][PDF]
34. "Substitution Mechanisms at Metal Carbonyl Centers; Conversion of Ph₃P(CO)₄ReBr to Ph₃P(CO)₄ReCH₃ via an Anionic Acyl Intermediate", Parker, D. W.; Marsi, M. M.; Gladysz, J. A. J. Organomet. Chem. 1980, 194, C1-C4. DOI:10.1016/S0022-328X(00)90345-0. [Abstract][PDF]
35. "Deoxygenation and Desulfurization of Organic Compounds via Transition Metal Atom Cocondensation", Togashi, S.; Fulcher, J. C.; Cho, B.-R.; Hasegawa, M.; Gladysz, J. A. J. Org. Chem. 1980, 45, 3044-3053. DOI: 10.1021/jo01303a023. [Abstract][PDF]
36. "Unprecedented Regiospecificity and Stereospecificity in Reactions of Ph₃C⁺PF₆^- with Rhenium Alkyls of the Formula (η-C₅H₅)Re(NO)(PPh₃)(CH₂R)", Kiel, W. A.; Lin, G.-Y.; Gladysz, J. A. J. Am. Chem. Soc. 1980, 102, 3299-3301. DOI: 10.1021/ja00529a092. [Abstract][PDF]
37. "Chemistry via Metal Atom Cocondensation: Isomerization and Complexation Reactions of Organocyclopropanes and Spirocycles", Hanlan, A. J. L.; Ugolick, R. C.; Fulcher, J. G.; Togashi, S.; Bocarsly, A. B.; Gladysz, J. A. Inorg. Chem. 1980, 19, 1543-1551. DOI: 10.1021/ic50208a023. [Abstract][PDF]
38. "Stereospecific and Chemospecific Interconversions of the Rhenium Alkylidene [(η-C₅H₅)Re(NO)(PPh₃)(CHC₆H₅)]⁺ PF₆^- and the Alkylrhenium (η-C₅H₅)Re(NO)(PPh₃)(CH(OCH₃)C₆H₅)", Constable, A. G.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, C21-C24. DOI:10.1016/S0022-328X(00)81394-7. [Abstract][PDF]
39. "New Methods for Metal-Carbon Bond Formation: Reactions of (CO)₅MnSi(CH₃)₃ with Cyclic Ethers", Brinkman, K. C.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1980, 1260-1261. DOI: 10.1039/C39800001260. [Abstract][PDF]
40. "Preparation and Properties of (η-C₅H₅)₂ZrCl[Si(CH₃)₃] and (η-C₅H₅)₂Zr[Si(CH₃)₃]₂: Trimethylsilyl Group Transfer from Mercury to Zirconium", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1980, 202, 263-268. DOI:10.1016/S0022-328X(00)92674-3. [Abstract][PDF]
41. "Preparation and Alkylation Reactions of K⁺[(CO)₄FeSi(CH₃)]^-; Reductive Elimination of Tetramethylsilane and Benzyl Trimethylsilane from Isolable (CO)₄FeRSi(CH₃)₃ Complexes", Blakeney, A. J.; Gladysz, J. A. Inorg. Chim. Acta 1981, 53, L25-L27. DOI:10.1016/S0020-1693(00)84730-1. [Abstract][PDF]
42. "Mononuclear Anionic Formyl Complexes; Synthesis and Properties", Selover, J. C.; Marsi, M.; Parker, D. W.; Gladysz, J. A. J. Organomet. Chem. 1981, 206, 317-329. DOI:10.1016/S0022-328X(00)83029-6. [Abstract][PDF]
43. "Nickel and Palladium Complexes in the Synthesis of Macrocyclic Compounds", Halweg, K. M.; Gladysz, J. A. The Strem Chemiker 1981, 9, 7-14.
44. "Electrophile Induced Disproportionation of the Neutral Formyl (η-C₅H₅)Re(NO)(PPh₃)(CHO); Isolation and Properties of the Rhenium Methylidene [(η-C₅H₅)Re(NO)(PPh₃)(CH₂)]⁺ PF₆^-, Gladysz, J. A.; Kiel, W. A.; Lin, G.-Y.; Wong, W.-K.; Tam, W. ACS Symposium Series 1981, 152, 147-164. DOI: 10.1021/bk-1981-0152.ch010. [Abstract]
45. "New Deoxygenative Transformations: Reactions of (CO)₄Fe[Si(CH₃)₃]₂ with Acyclic Ethers", Blakeney, A. J.; Gladysz, J. A. J. Organomet. Chem. 1981, 210, 303-312. DOI:10.1016/S0022-328X(00)80889-X. [Abstract][PDF]
46. "Reactions of (CO)₅MnSi(CH₃)₃ with Organic Carbonyl Compounds", Johnson, D. L.; Gladysz, J. A. Inorg. Chem. 1981, 20, 2508-2515. DOI: 10.1021/ic50222a028. [Abstract][PDF]
47. "Exploratory Organometal-Sulfur Chemistry: Syntheses and Unusual Properties of Rhenium -CH₂SR, -CH₂S⁺RR' and =CHSR]⁺ Complexes", McCormick, F. B.; Gladysz, J. A. J. Organomet. Chem. 1981, 218, C57-C61. DOI:10.1016/S0022-328X(00)81018-9. [Abstract][PDF]
48. "Three Rational Syntheses of New Stable Metal α-Hydroxyalkyl Complexes", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1981, 103, 5608-5609. DOI: 10.1021/ja00408a073. [Abstract][PDF]
49. "Synthesis of Iron Carbonyl Trimethylsilanes; Preparations and Interconversions of cis-(CO)₄Fe[Si(CH₃)₃]₂, M⁺ [(CO)₄FeSi(CH₃)₃]^-, and trans-[Fe(CO)₄Si(CH₃)₃]₂", Blakeney, A. J.; Johnson, D. L.; Donovan, P. W.; Gladysz, J. A. Inorg. Chem. 1981, 20, 4415-4419. DOI: 10.1021/ic50226a076. [Abstract][PDF]
50. "Synthesis and Electrophile Induced Disproportionation of the Neutral Formyl (η-C₅H₅)Re(NO)(PPh₃)CHO)", Tam, W.; Lin, G.-Y.; Wong, W.-K.; Kiel, W. A.; Wong, V. K.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 141-152. DOI: 10.1021/ja00365a027. [Abstract][PDF]
51. "A New Organometallic Photoreaction: Interconversion of Metal-Alkylidene Geometric Isomers", McCormick, F. B.; Kiel, W. A.; Gladysz, J. A. Organometallics 1982, 1, 405-408. DOI: 10.1021/om00062a033. [Abstract][PDF]
52. "Organic Transformations via Metal Silane Reagents: Syntheses of Vinyl Ethers from Dimethyl Ketals and (CO)₅MnSi(CH₃)₃", Marsi, M.; Gladysz, J. A. Tetrahedron Lett. 1982, 23, 631-634. DOI: 10.1016/SO040-4039(00)86908-7. [Abstract][PDF]
53. "Syntheses of Kinetically Unstable Neutral Formyl Complexes via Li(C₂H₅)₃BH and 'Transformylation' Reactions of Metal Carbonyl Cations", Tam, W.; Lin, G.-Y.; Gladysz, J. A. Organometallics 1982, 1, 525-529. DOI: 10.1021/om00063a022. [Abstract][PDF]
54. "Transition Metal Formyl Complexes", Gladysz, J. A. Adv. Organomet. Chem. 1982, 20, 1-38. DOI:10.1016/S0065-3055(08)60519-5. [Abstract]
55. "Substituent Effects upon Alkyl Migration to Coordinated CO: Syntheses and Carbonylation Studies of (CO)₅MnCH₂I and (CO)₅MnCH₂OSi(CH₃)₃", Brinkman, K. C.; Vaughn, G. D.; Gladysz, J. A. Organometallics 1982, 1, 1056-1060. DOI: 10.1021/om00068a010. [Abstract][PDF]
56. "Synthesis and Properties of [(η-C₅H₅)Re(NO)(PPh₃)(=CHC₆H₅)]⁺ PF₆^-: A Benzylidene Complex that is Formed by a Stereospecific α-Hydride Abstraction, Exists as Two Geometric Isomers, and Undergoes Stereospecific Nucleophilic Attack", Kiel, W. A.; Lin, G.-Y.; Constable, A. G.; McCormick, F. B.; Strouse, C. E.; Eisenstein, O.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4865-4878. DOI: 10.1021/ja00382a021. [Abstract][PDF]
57. "Synthesis, Optical Resolution, and Absolute Configuration of Pseudotetrahedral Organorhenium Complexes (η-C₅H₅)Re(NO)(PPh₃)(X)", Merrifield, J. H.; Strouse, C. E.; Gladysz, J. A. Organometallics 1982, 1, 1204-1211. DOI: 10.1021/om00069a018. [Abstract][PDF]
58. "Syntheses and Reactions of Rhenium Vinylidene and Acetylide Complexes; Unprecedented Chirality Transfer through a C≡C Triple Bond", Wong, A.; Gladysz, J. A. J. Am. Chem. Soc. 1982, 104, 4948-4950. DOI: 10.1021/ja00382a036. [Abstract][PDF]
59. "Reactions of Ketals and Acetals with (CO)₅MnSi(CH₃)₃; A New Vinyl Ether Synthesis", Marsi, M.; Gladysz, J. A. Organometallics 1982, 1, 1467-1473. DOI: 10.1021/om00071a012. [Abstract][PDF]
60. "Synthesis, Chemical Properties, and X-ray Crystal Structures of Rhenium Formaldehyde and Thioformaldehyde Complexes", Buhro, W. E.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A.; McCormick, F. B.; Etter, M. C. J. Am. Chem. Soc. 1983, 105, 1056-1058. DOI: 10.1021/ja00342a070. [Abstract][PDF]
61. "Bimetallic Anionic Formyl Complexes; Synthesis and Properties", Tam, W.; Marsi, M.; Gladysz, J. A. Inorg. Chem. 1983, 22, 1413-1421. DOI: 10.1021/ic00152a001. [Abstract][PDF]
62. "Synthesis and Decarboxylation Mechanism of the Chiral Rhenium Formate (η-C₅H₅)Re(NO)(PPh₃)(OCHO)", Merrifield, J. H.; Gladysz, J. A. Organometallics 1983, 2, 782-784. DOI: 10.1021/om00078a022. [Abstract][PDF]
63. "Regiospecific and Stereospecific Reactions of Ph₃C⁺ PF₆^- with Rhenium Alkyls (η-C₅H₅)Re(NO)(PPh₃)(R); α vs β Hydride Abstraction", Kiel, W. A.; Lin, G.-Y.; Bodner, G. S.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 4958-4972. DOI: 10.1021/ja00353a020. [Abstract][PDF]
64. "Syntheses, Properties and X-ray Crystal Structures of Stable Methylidene Complexes of the Formula [(η-C₅Me₅)Re(NO)(L)(=CH₂)]⁺ PF₆^-", Patton, A. T.; Strouse, C. E.; Knobler, C. B.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5804-5811. DOI: 10.1021/ja00356a018. [Abstract][PDF]
65. " Mechanism of Coupling of =CH₂ to H₂C=CH₂ at a Homogeneous (η-C₅H₅)Re(NO)(PPh₃)⁺ Center; Remarkable Enantiomer Self-Recognition", Merrifield, J. H.; Lin, G.-Y.; Kiel, W. A.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 5811-5819. DOI: 10.1021/ja00356a019. [Abstract][PDF]
66. "Synthesis and Chemistry of Chiral Vinyl Rhenium Complexes (η-C₅H₅)Re(NO)(PPh₃)(CH=CHR). Stereoselective Reactions with Electrophiles and a Spontaneous Alkylidene to Olefin Rearrangement", Hatton, W. G.; Gladysz, J. A. J. Am. Chem. Soc. 1983, 105, 6157-6158. DOI: 10.1021/ja00356a018. [Abstract][PDF]
67. "Atomos de Metales de Transicion en la Sintesis y la Catalisis Organica", Gladysz, J. A.; Fulcher, J. G.; Bocarsly, A. B. Rev. Soc. Quim. Mex. 1983, 27, 146-148.
68. "A New Route to Metal Alkylidene Complexes; Synthesis of Ylide Adducts (CO)₄Fe^-CH(R)P⁺Ar₃ from Aldehydes, Triarylphosphines, and (CO)₄FeSi(CH₃)₂CH₂CH₂Si(CH₃)₂", Nakazawa, H.; Johnson, D. L.; Gladysz, J. A. Organometallics 1983, 2, 1846-1851. DOI: 10.1021/om50006a025. [Abstract][PDF]
69. "Synthesis and Chemistry of Chiral Rhenium Acyls (η-C₅H₅)Re(NO)(PPh₃)(COR)", Buhro, W. E.; Wong, A.; Merrifield, J. H.; Lin, G.-Y.; Constable, A. G.; Gladysz, J. A. Organometallics 1983, 2, 1852-1859. DOI: 10.1021/om50006a026. [Abstract][PDF]
70. "Reactions of (CO)₅MnSi(CH₃)₃ and CO with Aldehydes and Cyclic Ethers; Syntheses of Functionalized Pentacarbonyl Manganese Acyls and Homologated Organic Compounds", Brinkman, K. C.; Gladysz, J. A. Organometallics 1984, 3, 147-155. DOI: 10.1021/om00079a026. [Abstract][PDF]
71. (a) "Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese. Synthesis of Ylide Complexes (CO)₄MnCR(OSiMe₃)PPh₂ and a New Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1984, 23, 245-246. DOI: 10.1002/ange.1984096031. [Abstract][PDF] (b) "Reaktionen von Diphenyl(trimethylsilyl)phosphan mit Alkyl(pentacarbonyl)mangan; Synthese der Ylidkomplexe (CO)₄MnCR(OSiMe₃)PPh₂ unter Beteiligung einer CO-Einschiebung", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Angew. Chem. 1984, 96, 230-231. DOI: 10.1002/ange.19840960316. [Abstract][PDF]
72. "Reaction of Benzylrhenium Complexes (η-C₅H₅)Re(NO)(L)(CH₂Ar) with Ph₃C⁺PF₆^-; Analysis of the Re-C_α Rotamers Involved in α-Hydride Abstraction", Kiel, W. A.; Buhro, W. E.; Gladysz, J. A. Organometallics 1984, 3, 879-886. DOI: 10.1021/om00084a010. [Abstract][PDF]
73. "Alkylation and Acylation of the Iron Carbonyl Anion [(CO)₄FeSi(CH₃)₃]^-. Evidence for 1,3-Silatropic Shifts from Iron to Acyl Oxygen", Brinkman, K. C.; Blakeney, A. J.; Krone-Schmidt, W.; Gladysz, J. A. Organometallics 1984, 3, 1325-1332. DOI: 10.1021/ om00087a001. [Abstract][PDF]
74. "New Synthetic Chemistry of Transition Metal Trialkylsilane Complexes", Gladysz, J. A. Acc. Chem. Res. 1984, 17, 326-332. DOI: 10.1021/ar00105a005. [Abstract][PDF]
75. "Reactions of Phosphorus Electrophiles with [(η⁵-C₅Me₅)Fe(CO)₂]^-: Spectroscopic Evidence for a Phosphinidene Complex", Nakazawa, H.; Buhro, W. E.; Bertrand, G.; Gladysz, J. A. Inorg. Chem. 1984, 23, 3431-3433. DOI: 10.1021/ic00190a001. [Abstract][PDF]
76. "Hydrogen Bonding in Organometallic Ligands and Possible Implications for CO/H₂ Chemistry: First Carbonylation of an Isolable Metal α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. Organometallics 1984, 3, 1596-1598. DOI: 10.1021/om00088a028. [Abstract][PDF]
77. "Deprotonation and Anionic Rearrangements of Organometallic Compounds, 1. Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Gladysz, J. A. J. Am. Chem. Soc. 1984, 106, 7636-7637. DOI: 10.1021/ja00336a062. [Abstract][PDF]
78. "Cleavage of Rhenium-Methyl Bond of (η-C₅H₅)Re(NO)(PPh₃)(CH₃) by Protic and Halogen Electrophiles; Stereochemistry at Rhenium", Merrifield, J. H.; Fernández, J. M.; Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1984, 23, 4022-4029. DOI: 10.1021/ic00192a036. [Abstract][PDF]
79. "Deprotonation and Anionic Rearrangements of Organometallic Compounds. Reactions of the Hydride Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(H) with n-Butyl-lithium-Tetramethylethylenediamine", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1985, 283-284. DOI: 10.1039/C39850000283. [Abstract][PDF]
80. "Electrochemical Oxidation of Rhenium Alkyl Complexes [Re(η⁵-C₅H₅)(NO)(PPh₃)R]; Implications for the Mechanism of Hydride Abstraction by Ph₃C⁺PF₆^-", Asaro, M. F.; Bodner, G. S.; Gladysz, J. A.; Cooper, S. R.; Cooper N. J. Organometallics 1985, 4, 1020-1024. DOI: 10.1021/om00125a010. [Abstract][PDF]
81. "Synthesis, Conformation, and Reactivity of the Rhenium Phosphide Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(PPh₂). The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 3346-3348. DOI: 10.1021/ja00297a050. [Abstract][PDF]
82. "Deprotonation and Anionic Rearrangements of Organometallic Compounds, III. The First Carbon-Carbon Bond-Forming Reaction of an η¹-Formyl Ligand", Heah, P. C.; Gladysz, J. A. J. Mol. Cat. 1985, 31, 207-209. DOI:10.1016/0304-5102(85)85062-8. [Abstract][PDF]
83. "Reactions of Cyanomethyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂CN) with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of a Transition Metal Substituted Carbanion", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1985, 107, 4103-4104. DOI: 10.1021/ja00299a071. [Abstract][PDF]
84. "Reactions of Chiral α-Methoxyvinyl Rhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(C(OCH₃)=CHR) with Alkyl Halides; Efficient 1,3-Asymmetric Induction", Smith, D. E.; Gladysz, J. A. Organometallics 1985, 4, 1480-1481. DOI: 10.1021/om00127a039. [Abstract][PDF]
85. "Reactions of (CO)₅MnSi(CH₃)₃ with α-Bromocarbonyl and Related Organic Compounds; Facile Reductive Silylation", Marsi, M.; Brinkman, K. C.; Lisensky, C. A.; Vaughn, G. D.; Gladysz, J. A. J. Org. Chem. 1985, 50, 3396-3401. DOI: 10.1021/jo00218a030. [Abstract][PDF]
86. "Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PRR')", Buhro, W. E.; Gladysz, J. A. Inorg. Chem. 1985, 24, 3505-3507. DOI: 10.1021/ic00216a005. [Abstract][PDF]
87. "Reactions of Organorhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂R) with Ph₃C⁺PF₆^-; Analysis of the Energetics of α-Hydride Abstraction", Georgiou, S.; Gladysz, J. A. Tetrahedron 1986, 42, 1109-1116. DOI: 10.1016/SO040-4020(01)87514-1. [Abstract][PDF]
88. "Deprotonation and Anionic Rearrangements of Organometallic Compounds. V. Kinetic vs Thermodynamic Deprotonation in Reactions of Cyclopentadienyl Rhenium Acyl and Alkyl Complexes with Strong Bases", Heah, P. C.; Patton, A. T.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1185-1195. DOI: 10.1021/ja00266a012. [Abstract][PDF]
89. "Synthesis and Reactivity of Metal α-Hydroxyalkyl Complexes; Generation of (CO)₅MCH(C₆H₅)OH (M = Mn, Re)", Selover, J. C.; Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1455-1462. DOI: 10.1021/ja00267a015. [Abstract][PDF]
90. "Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium α-Hydroxyalkyl Complexes of the Formula (CO)₄MP(C₆H₅)₂)(o-C₆H₄CHOH)", Vaughn, G. D.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1462-1473. DOI: 10.1021/ja00267a016. [Abstract][PDF]
91. "Synthesis and Reactivity of Metallacyclic Manganese α-Hydroxyalkyl Complexes Containing Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms; First Carbonylation of an Isolable α-Hydroxyalkyl Complex", Vaughn, G. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 1473-1480. DOI: 10.1021/ja00267a017. [Abstract][PDF]
92. " Synthesis and Reactivity of Metallacyclic Manganese α-(Silyloxy)alkyl Complexes (CO)₄MnC(R)(OSi(CH₃)₃)P(C₆H₅)₂; A New Thermodynamic Driving Force for CO Insertion", Vaughn, G. D.; Krein, K. A.; Gladysz, J. A. Organometallics 1986, 5, 936-942. DOI: 10.1021/om00136a016. [Abstract][PDF]
93. "Synthesis, Structure, and Reactivity of the Formaldehyde Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-H₂C=O)]⁺PF₆^-", Buhro, W. E.; Georgiou, S.; Fernández, J. M.; Patton, A. T.; Strouse, C. E.; Gladysz, J. A. Organometallics 1986, 5, 956-965. DOI: 10.1021/om00136a020. [Abstract][PDF]
94. "Generation and Reactions of Chiral, Pyramidal, Transition Metal Lewis Acids of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺X^-", Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1986, 25, 2672-2674. DOI: 10.1021/ic00236a00. [Abstract][PDF]
95. "Reaction of Ylide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂PAr₃)]⁺PF₆^- with n-Butyl-lithium-Tetramethylethylenediamine: Generation and Stereospecific Alkylation of a Transition-Metal-Substituted-Wittig Reagent", Crocco, G. L.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1986, 1154-1156. DOI: 10.1039/C39860001154. [Abstract][PDF]
96. "Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂)]_nS⁺(CH₃)_3-n (n = 1,2,3)", McCormick, F. B.; Gleason, W. B.; Zhao, X.; Heah, P. C.; Gladysz, J. A. Organometallics 1986, 5, 1778-1785. DOI: 10.1021/om00140a004. [Abstract][PDF]
97. "A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-RCH=O)]⁺PF₆^-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1986, 108, 8268-8270. DOI: 10.1021/ja00286a030. [Abstract][PDF]
98. "Novel Electron Impact-Induced Hydrogen Rearrangements in the Mass Spectra of Organorhenium Hydrides and Alkyls", Crocco, G. L.; Sharp, T. L.; Gladysz J. A. Int. J. Mass. Spectrum. Ion. Phys. 1986, 73, 181-185. DOI:10.1016/0168-1176(86)80019-2. [Abstract][PDF]
99. "New Mechanistic Probes of Hydride Abstraction from Rhenium Alkyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R) by Ph₃C⁺PF₆^-; Evidence for Initial Electron Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 1757-1764. DOI: 10.1021/ja00240a027. [Abstract][PDF]
100. "Synthesis, Structure, and Reactivity of the Thioformaldehyde Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-H₂C=S)]⁺PF₆^-", Buhro, W. E.; Etter, M. C.; Georgiou, S.; Gladysz, J. A.; McCormick, F. B. Organometallics 1987, 6, 1150-1156. DOI: 10.1021/om00149a003. [Abstract][PDF]
101. "A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups; Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R)", O'Connor, E. J.; Kobayashi, M.; Floss, H. G.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 4837-4844. DOI: 10.1021/ja00250a014. [Abstract][PDF]
102. "Electrochemical Oxidation of Rhenium Alkyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(R): Evidence for One-Electron Charge Transfer", Bodner, G. S.; Gladysz, J. A.; Nielsen, M. F.; Parker, V. D. Organometallics 1987, 6, 1628-1633. DOI: 10.1021/om00151a006. [Abstract][PDF]
103. "Synthesis, Structure, and Reactivity of Transition Metal/Main Group Metal Bridging Carboxylate Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CO₂ML_n) (M = Li, K, Ge, Sn, Pb)", Senn, D. R.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Inorg. Chem. 1987, 26, 2737-2739. DOI: 10.1021/ic00264a001. [Abstract][PDF]
104. (a) "A Novel Heterobimetallic Asymmetric Hydrogenation Catalyst Based Upon A Chiral Rhenium Template Containing Two Phosphido Substituents", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1987, 26, 910-912. DOI: 10.1002/anie.198709101. [Abstract][PDF] (b) "Ein neuartiger heterodinuclearer Katalysator für die asymmetrische Hydrierung ein Bisphosphido-Ligand mit einem stereogenen Rheniumzentrum", Zwick, B. D.; Arif, A. M.; Patton, A. T.; Gladysz, J. A. Angew. Chem. 1987, 99, 921-922. DOI: 10.1002/ange.19870990914. [Abstract][PDF]
105. "Crystallographic and Theoretical Analyses of the Structures of Rhenium Formyl and Acyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(COR)", Bodner, G. S.; Patton, A. T.; Smith, D. E.; Georgiou, S.; Tam, W.; Wong, W.-K.; Strouse, C. E.; Gladysz, J. A. Organometallics 1987, 6, 1954-1961. DOI: 10.1021/om00152a021. [Abstract][PDF]
106. "A New Method for the Activation of Metal-Bound Methyl Groups. Oxidative Disproportionation to Coordinated Ethylene and Methane", Tilset, M.; Bodner, G. S.; Senn, D. R.; Gladysz, J. A.; Parker, V. D. J. Am. Chem. Soc. 1987, 109, 7551-7553. DOI: 10.1021/ ja00258a062. [Abstract][PDF]
107. "A General Class of Stable Alkyl Halide Complexes; Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(IR)]⁺BF₄^-", Winter, C. H.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7560-7561. DOI: 10.1021/ja00258a067. [Abstract][PDF]
108. "Synthesis, Structure, and Alkylation of Chiral Vinyl Rhenium Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(CX=CHR) (X = H, OCH₃). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium To Carbon", Bodner, G. S.; Smith, D. E.; Hatton, W. G.; Heah, P. C.; Georgiou, S.; Rheingold, A. L.; Geib, S. J.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1987, 109, 7688-7705. DOI: 10.1021/ja00259a018. [Abstract][PDF]
109. "The Selective Activation of One Ketone Enantioface via σ-Binding to a Chiral Metal Template: Synthesis and Reactivity of Rhenium Ketone Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-RR'C=O)]⁺PF₆^-", Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1988, 37-39. DOI: 10.1039/C39880000037. [Abstract][PDF]
110. "Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands", Crocco, G. L.; Gladysz, J. A. Chem. Ber. 1988, 121, 375-377. DOI: 10.1002/cber.19881210227. [Abstract][PDF]
111. "Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PR₂): The "Gauche Effect" in Transition Metal Chemistry", Buhro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439. DOI: 10.1021/ja00216a015. [Abstract][PDF]
112. "Aldehyde and Ketone Ligands in Organometallic Complexes and Catalysis", Huang, Y.-H.; Gladysz, J. A. J. Chem. Ed. 1988, 65, 298-303. DOI: 10.1021/ed065p298. [Abstract][PDF]
113. "Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]", Bodner, G. S.; Fernández, J. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 4082-4084. DOI: 10.1021/ ja00220a082. [Abstract][PDF]
114. "Synthesis and Reactivity of Functionalized Rhenium Germyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(GePh₂X); Dynamic Equilibria with Germylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GePh₂)]⁺ X^-", Lee, K. E.; Gladysz, J. A. Polyhedron 1988, 7, 2209-2211. DOI: 10.1016/S0277-5387(00)81805-7. [Abstract][PDF]
115. "Synthesis, Structure, and Reactions of Chiral Rhenium Vinylidene and Acetylide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(X)]ⁿ⁺; Vinylidene Complexes that are Formed by Stereospecific C_β Electrophilic Attack, Exist as Two Re=C=C Geometric Isomers, and Undergo Stereospecific Nucleophilic C_α Attack", Senn, D. R.; Wong, A.; Patton, A. T.; Marsi, M.; Strouse, C. E.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6096-6109. DOI: 10.1021/ja00226a026. [Abstract][PDF]
116. "Divergent Kinetic and Thermodynamic Acidity in Organotransition-Metal Hydride Complexes; Synthesis, Structure, and Reactivity of the Rhenium Anion Li⁺ [(η⁵-C₅H₅)Re(NO)(PPh₃)]^-", Crocco, G. L.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 6110-6118. DOI: 10.1021/ja00226a027. [Abstract][PDF]
117. "Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(SiR₂X). Anionic Rearrangements Leading to the New Disilametallacycle ((η⁵-C₅H₅)Re(NO)(PPh₃)Si(CH₃)₂)", Crocco, G. L.; Young, C. S.; Lee, K. E.; Gladysz, J. A. Organometallics 1988, 7, 2158-2162. DOI: 10.1021/om00100a012. [Abstract][PDF]
118. "Generation of the Dichloromethane Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClCH₂Cl)]⁺ BF₄^-, and its Conversion to the Oxidative Addition Product (η⁵-C₅H₅)Re(NO)(PPh₃)Cl)(CH₂Cl)]⁺ BF₄^-", Winter, C. H.; Gladysz, J. A. J. Organomet. Chem. 1988, 354, C33-C36. DOI:10.1016/0022-328X(88)80664-8. [Abstract][PDF]
119. "Synthetic Approaches to the Chiral, Pyramidal, Transition Metal Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ X^-; Generation, Characterization, and Reactions of a Dichloromethane Adduct", Fernández, J. M.; Gladysz, J. A. Organometallics 1989, 8, 207-219. DOI: 10.1021/om00103a027. [Abstract][PDF]
120. "Synthesis, Structure, and Reactivity of Bridging Halide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]₂X⁺ BF₄^-; Preferential Binding of One Enantiomer of Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) by the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Winter, C. H.; Arif, A. M.; Gladysz, J. A. Organometallics 1989, 8, 219-225. DOI: 10.1021/om00103a028. [Abstract][PDF]
121. "Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ by K(s-C₄H₉)₃BH; Synthesis of Optically Active Secondary Alcohols and Derivatives", Dalton, D. M.; Gladysz, J. A. J. Organomet. Chem. 1989, 370, C17-C21. DOI:10.1016/0022-328X(89)87307-3. [Abstract][PDF]
122. "Synthesis, Structure and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(IR)]⁺ BF₄^-", Winter, C. H.; Veal, W. R.; Garner, C. M.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1989, 111, 4766-4776. DOI: 10.1021/ja00195a033. [Abstract][PDF]
123. "The Role of Virtual Halogen d Orbitals in the Stability and Reactivity of Rhenium Alkyl-Halide Complexes of the Form [(η⁵-C₅H₅)Re(NO)(PPh₃)(XR)]⁺", Czech, P. T.; Gladysz, J. A.; Fenske, R. F. Organometallics 1989, 8, 1806-1810. DOI: 10.1021/om00109a038. [Abstract][PDF]
124. "Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae [(η⁵-C₅H₅)Re(NO)(PPh₃)(η2-O=CHR)]⁺ BF₄^-; A New Synthesis of Optically Active Cyanohydrin Derivatives", Garner, C. M.; Fernández, J. M.; Gladysz, J. A. Tetrahedron Lett. 1989, 30, 3931-3934. DOI: 10.1016/SO040-4039(00)99278-6. [Abstract][PDF]
125. "Synthesis and Reactivity of Functionalized Rhenium Phosphido Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(PXX'). An Unusual CCl₄ 1,3-Addition Leading to an Exo-Substituted η⁴-Cyclopentadiene Complex", Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1989, 28, 3837-3845. DOI: 10.1021/ic00319a018. [Abstract][PDF]
126. "Synthesis and Structure of Chiral Rhenium Allyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂C(R')=CHR)", Bodner, G. S.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. Organometallics 1989, 8, 2399-2404. DOI: 10.1021/om00112a022. [Abstract][PDF]
127. "Tetracarbonyl{[2-(diphenylphosphino)phenyl]hydroxymethyl-C,P}manganese", Vaughn, G. D.; Gladysz, J. A. Inorg. Synth. 1989, 26, 169-171. DOI: 10.1002/9780470132579.ch30. [Abstract][PDF]
128. "Optical Resolution and Absolute Configuration of the Chiral Pentamethylcyclopentadienyl Rhenium Carbonyl Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CO)]⁺ BF₄^-", Huang, Y.-H.; Niedercorn, F.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 383, 213-225. DOI: 10.1016/0022-328X(90)85133-J. [Abstract][PDF]
129. "Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(OR₂)]⁺ X^-", Agbossou, S. K.; Fernández, J. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 476-480. DOI: 10.1021/ic00328a027. [Abstract][PDF]
130. "Synthesis and Structure of σ-Pyridine, Quinoline, and Isoquinoline Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(NC_xH_y)]⁺ CF₃SO₃^-", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1990, 384, C29-C32. DOI: 10.1016/0022328X(90)87079-S. [Abstract][PDF]
131. "Synthesis, Structure, and Reactivity of the Chiral Rhenium Phenyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(C₆H₅)", Agbossou, S. K.; Bodner, G. S.; Patton, A. T.; Gladysz, J. A. Organometallics 1990, 9, 1184-1191. DOI: 10.1021/om00118a046. [Abstract][PDF]
132. "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ X^-", Bodner, G. S.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organometallics 1990, 9, 1191-1205. DOI: 10.1021/om00118a047. [Abstract][PDF]
133. "Isomerization of Diastereomeric Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺; the Alkene Enantioface Bound to the Metal can "Flip" Without Alkene Dissociation", Peng, T.-S.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1990, 902-903. DOI: 10.1039/C39900000902. [Abstract][PDF]
134. "Synthesis and Reactivity of Chiral Rhenium Amine and Amide Complexes of the Formulas [(η⁵-C₅H₅)Re(NO)(PPh₃)(NHRR')]⁺ TfO^- and (η⁵-C₅H₅)Re(NO)(PPh₃)(NRR')", Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1349-1351. DOI: 10.1021/om00118a083. [Abstract][PDF]
135. "Mechanism of Equilibration of Diastereomeric Rhenium Amide Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(NHCHRR'); Rhenium vs Carbon Epimerization", Dewey, M. A.; Gladysz, J. A. Organometallics 1990, 9, 1351-1353. DOI: 10.1021/om00118a084. [Abstract][PDF]
136. "Selective Binding of One Aldehyde Enantioface by a Chiral Transition Metal Lewis Acid: Synthesis, Structure and Reactivity of Rhenium Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHR)]⁺ X^-", Garner, C. M.; Quirós Méndez, N.; Kowalczyk, J. J.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 5146-5160. DOI: 10.1021/ja00169a024. [Abstract][PDF]
137. "Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ROH)]⁺ BF₄^-", Agbossou, S. K.; Smith, W. W.; Gladysz, J. A. Chem. Ber. 1990, 123, 1293-1299. DOI: 10.1002/cber.19901230612. [Abstract][PDF]
138. "Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions to Chiral Monosubstituted Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Gladysz, J. A. Tetrahedron Lett. 1990, 31, 4417-4420. DOI: 10.1016/SO040-4039(00)97636-6. [Abstract][PDF]
139. "Synthesis, Structure, and Reactivity of the Nitrosyl Ligand/Lewis Acid Adduct (η⁵-C₅H₅)Re(NO·BCl₃)(PPh₃)(SiMe₂Cl)", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1990, 29, 2885-2887. DOI: 10.1021/ic00341a005. [Abstract][PDF]
140. "Reactions of Cyanomethyl Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂CN) and Ylide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂P(p-tol)₃)]⁺ PF₆^- with n-BuLi/TMEDA; Generation, Stereospecific Alkylation, and Basicity of Transition-Metal-Substituted Carbanions and Ylides", Crocco, G. L.; Lee, K. E.; Gladysz, J. A. Organometallics 1990, 9, 2819-2831. DOI: 10.1021/om00160a034. [Abstract][PDF]
141. "Generation and Reactivity of the Chiral Rhenium Chlorobenzene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClC₆H₅)]⁺ BF₄^-: An Improved Functional Equivalent of the Chiral Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ BF₄^-", Kowalczyk, J. J.; Agbossou, S. K.; Gladysz, J. A. J. Organomet. Chem. 1990, 397, 333-346. DOI: 10.1016/0022-328X(90)85333-T. [Abstract][PDF]
142. "A New Carbon-Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^- by the Base t-BuO^- K⁺", Peng, T.-S.; Gladysz, J. A. Organometallics 1990, 9, 2884-2886. DOI: 10.1021/om00161a016. [Abstract][PDF]
143. "Selective Activation of One Methyl Ketone Enantioface via σ-Binding to a Chiral Transition Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-O=C(CH₃)R]⁺ X^-", Dalton, D. M.; Fernández, J. M.; Emerson, K.; Larsen, R. D.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1990, 112, 9198-9212. DOI: 10.1021/ja00181a024. [Abstract][PDF]
144. (a) "π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Aromatic Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]⁺ X^-", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1473-1474. DOI: 10.1002/anie.199014731. [Abstract][PDF] (b) "π/σ-Gleichgewichte in Metall-Komplexen organischer Carbonylverbindungen; Synthese und Struktur chiraler Rhenium-Komplexe [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]X", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1990, 102, 1507-1509. DOI: 10.1002/ange.19901021245. [Abstract][PDF]
145. (a) "Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHAr)]BF₄", Quirós Méndez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1990, 29, 1475-1476. DOI: 10.1002/anie.199014751. [Abstract][PDF] (b) "Thermodynamisch kontrollierte enantiofaciale Selektivität bei der Bindung von Aldehyden an chirale Metall-Komplexfragmente, der Mechanismus der Interkonversion diastereomerer π-Aldehyd-Komplexe [(η⁵-C₅H₅)Re(NO)(PPh₃)(η²-O=CHAr)]BF₄", Quirós Méndez, N.; Mayne, C. L.; Gladysz, J. A. Angew. Chem. 1990, 102, 1509-1511. DOI: 10.1002/ange.19901021246. [Abstract][PDF]
146. "Synthesis, Structure, and Reactivity of Functionalized Germyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(GePh₂X); Equilibria Involving the Germylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GePh₂)]⁺ TfO^-", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 751-760. DOI: 10.1021/om00049a040. [Abstract][PDF]
147. "Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(SiMe₂X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base-Free Silylene Complexes", Lee, K. E.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 309-320 (1991). ISSN 0009-2940. [Abstract][PDF]
148. "Synthesis, Structure, and Reactivity of Chiral Rhenium Alkyne Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(RC≡CR')]⁺ BF₄^-", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079-1088. DOI: 10.1021/om00050a045. [Abstract][PDF]
149. "Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(CH=CH(CH₂)_n-2)]⁺ BF₄^-; Facile Vinylic Deprotonation of a Coordinated Alkene", Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1991, 124, 729-742. DOI: 10.1002/cber.19911240410. [Abstract][PDF]
150. "Delocalized Electronic Interactions in Chiral Cyclopentadienyl Rhenium Halide Complexes. The Valence Photoelectron Spectra of the Formula CpRe(NO)(L)X", Lichtenberger, D. L.; Rai-Chaudhuri, A. R.; Seidel, M. J.; Gladysz, J. A.; Agbossou, S. K.; Igau, A.; Winter, C. H. Organometallics 1991, 10, 1355-1364. DOI: 10.1021/om00051a028. [Abstract][PDF]
151. "Synthesis and Structure of the Rhenium Phenylamido Complex (η⁵-C₅H₅)Re(NO)(PPh₃)(NHPh); An Unprecedented Pyramidal Amido Ligand", Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 712-714. DOI: 10.1039/C399¬10000712. [Abstract][PDF]
152. "Facile Separations of Enantiomers of Chiral Organometallic Compounds with A Bakerbond Chiralcel HPLC Column", Ramsden, J. A.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 1631-1633. DOI: 10.1021/om00051a066. [Abstract][PDF]
153. "π/σ Equilibria in rhenium ketone complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CRR')]⁺X^-; a marked electronic effect upon the binding mode", Klein, D. P.; Dalton, D. M.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1991, 412, C7-C10. DOI:10.1016/0022-328X(91)86066-Y. [Abstract][PDF]
154. "Synthesis, Structure, and Dynamic Behavior of Rhenium Sulfide and Sulfoxide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(L)(XRR')]⁺ X'^- (X = S, SO)", Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 2199-2209. DOI: 10.1021/om00053a024. [Abstract][PDF]
155. "Reactions of the Neohexyl Iodide Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(ICH₂CH₂C(CH₃)₃)]⁺BF₄^- and Nucleophiles: Stereochemistry of Carbon-Iodine Bond Cleavage in Highly Accelerated S_N2 Reactions", Igau, A.; Gladysz, J. A. Organometallics 1991, 10, 2327-2334. DOI: 10.1021/om00053a040. [Abstract][PDF]
156. "Reactions of the Terminal Rhenium Acetylide Complex Re(η⁵-C₅H₅)(NO)(PPh₃)(C≡CH) and Butyllithium; Generation, Alkylation, and Stannylation of Lithiocarbide Complexes of the Formula Re(η⁵-C₅H₅)(NO)(PPh₃)(C≡CLi) (X = H, Li)", Ramsden, J. A.; Agbossou, F.; Senn, D. R.; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1991, 1360-1362. ISSN 0022-4936. [Abstract][PDF]
157. "A New Catalyst for the Epimerization of Secondary Alcohols: Carbon-Hydrogen Bond Activation in the Rhenium Alkoxide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(OCHRR')", Saura-Llamas, I.; Garner, C. M.; Gladysz, J. A. Organometallics 1991, 10, 2533-2535. DOI: 10.1021/om00054a003. [Abstract][PDF]
158. "Synthesis and Characterization of Chiral Rhenium σ-Ketone Complexes. Binding Properties of Symmetrical Ketones and Alkylcyclohexanones", Dalton, D. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1991, 2741-2747. ISSN 0300-9246. [Abstract][PDF]
159. "Mechanism of Isomerization of Alkylidene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(=CHCHR'R'')]⁺X^- to Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CR'R'')]⁺X^-: An Organometallic Wagner-Meerwein-Type Rearrangement", Roger, C.; Bodner, G. S.; Hatton, W. G.; Gladysz, J. A. Organometallics 1991, 10, 3266-3274. DOI: 10.1021/om00055a051. [Abstract][PDF]
160. "A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives: Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CRR')]⁺BF₄^-", Dalton, D. M.; Garner, C. M.; Fernández, J. M.; Gladysz, J. A. J. Org. Chem. 1991, 56, 6823-6829. DOI: 10.1021/jo00024a023. [Abstract][PDF]
161. "Synthesis and Chemistry of Secondary Alkyl Iodide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ICHRR')]⁺BF₄^-", Igau, A.; Gladysz, J. A. Polyhedron 1991, 10, 1903-1909. DOI: 10.1016/S0277-2387(00)86054-4. [Abstract][PDF]
162. "Synthesis, Structure, and Reactivity of Chiral Rhenium Amine Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(NRR'R")]⁺TfO^-", Dewey, M. A.; Knight, D. A.; Klein, D. P.; Arif, A. M.; Gladysz, J. A. Inorg. Chem. 1991, 30, 4995-5002. DOI: 10.1021/ic00026a026. [Abstract][PDF]
163. "Synthesis, Structure, and Reactivity of Chiral Rhenium Carboxylic and Carbonic Acid Ester Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-O=C(X)X')]⁺X''^-", Saura-Llamas, I.; Dalton, D. M.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 683-693. DOI: 10.1021/om00038a028. [Abstract][PDF]
164. "Synthesis, Structure, and Reactivity of (Pentamethylcyclopentadienyl)Rhenium Aldehyde Complexes [(η⁵-C₅Me₅)Re(NO)(PPh₃)(η²-O=CHR)]⁺BF₄^-: Highly Diastereoselective Deuteride Additions", Agbossou, F.; Ramsden, J. A.; Huang, Y.-H.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 693-701. DOI: 10.1021/om00038a029. [Abstract][PDF]
165. "Epimerization of Secondary Alcohols by New Homogeneous, Low Oxidation State Metal Catalysts: Carbon-Hydrogen Bond Activation in Rhenium Alkoxide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(OCHRR')", Saura-Llamas, I.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 2136-2144. DOI: 10.1021/ja00032a030. [Abstract][PDF]
166. "Synthesis and Reactivity of Chiral Metal Fluoride and Water Complexes Derived from the Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Agbossou, S. K.; Roger, C.; Igau, A.; Gladysz, J. A. Inorg. Chem. 1992, 31, 419-424. DOI: 10.1016/S0277-5387(00)860544. [Abstract][PDF]
167. "Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition Metal Lewis Acid; Equilibration of Diastereomeric (Cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Helv. Chim. Acta 1992, 75, 442-456. DOI: 10.1002/hlca.19920750204. [Abstract][PDF]
168. "Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(NRR')", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Chem. Ber. 1992, 125, 815-824. DOI: 10.1002/cber.19921250410. [Abstract][PDF]
169. "Mechanism of Equilibration of Diastereomeric Chiral Rhenium Alkene Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺BF₄^–. the Metal Traverses between Alkene Enantiofaces without Dissociation", Peng, T.-S.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 4174-4181. DOI: 10.1021/ja00037a020. [Abstract][PDF]
170. "Cyclopentadienyl Rhenium Complexes", Agbossou, F.; O'Connor, E. J.; Garner, C. M.; Quirós Méndez, N.; Fernández, J. M.; Patton, A. T.; Ramsden, J. A.; Gladysz, J. A. Inorg. Synth. 1992, 29, 211-225. DOI: 10.1016/j.organchem.2007.11.024. [Abstract][PDF]
171. "Synthesis, Structure, Dynamic Behavior, and Reactivity of Chiral Rhenium Primary Phosphine and Phosphido Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(PRH₂)]⁺ X^- and ((η⁵-C₅H₅)Re(NO)(PPh₃)(PRH)", Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673-2685. DOI: 10.1021/om00043a061. [Abstract][PDF]
172. "A Versatile New Route to Carbon Complexes of the Formula L_nMC≡CM'L'_n': Deprotonation and Metalation of the Terminal Acetylide Complex (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CH)", Ramsden, J. A.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 5890-5891. DOI: 10.1021/ja00040a079. [Abstract][PDF]
173. "Synthesis and Structure of σ-Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ and Aromatic Nitrogen Heterocycles", Dewey, M. A.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1992, 47, 1175-1184. ISSN: 0932-0776. [PDF]
174. "Synthesis, Structure, and Reactivity of Allene Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Pu, J.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 3232-3241. DOI: 10.1021/om00046a020. [Abstract][PDF]
175. "Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Roger, C.; Peng, T.-S.; Gladysz, J. A. J. Organomet. Chem. 1992, 439, 163-175. DOI: 10.1016/0022-328X(92)80227-O. [Abstract][PDF]
176. "Activation of Organic Carbonyl Compounds by Lewis Acids: Relative Reactivities of σ and π Adducts towards Nucleophiles, and Implications for Enantioselective Addition Reactions", Klein, D. P.; Gladysz, J. A. J. Am. Chem. Soc. 1992, 114, 8710-8711. DOI: 10.1021/ja00048a060. [Abstract][PDF]
177. "Deprotonation of Rhenium Terminal Acetylide Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(C≡CH): Generation and Reactivity of Rhenium/Lithium C₂ Complexes", Ramsden, J. A.; Weng, W.; Gladysz, J. A. Organometallics 1992, 11, 3635-3645. DOI: 10.1021/om00059a029. [Abstract][PDF]
178. "Reactions of Rhenium Halide Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(X) and Organocopper Nucleophiles; New Routes to Racemic and Optically Active Hydrocarbyl Complexes (η⁵-C₅H₅)Re(NO)(PPh₃)(R)", Ramsden, J. A.; Peng, T.-S.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1992, 129, 625-631. ISSN:0037-8968.
179. "Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1993, 450, 157-164. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]
180. "Synthesis, Structure, and Spectroscopic Properties of Chiral Rhenium Aromatic Aldehyde Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(O=CHAr)]⁺X^-: Equilibria between π and σ Aldehyde Bonding Modes", Quirós Méndez, N.; Seyler, J. W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 2323-2334. DOI: 10.1016/0022-328X(93)80152-2. [Abstract][PDF]
181. "Synthesis and Reactivity of Bimetallic Bridging Haloalkyl Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)X(CH₂)_xM(CO)₅]⁺BF₄^- (X = I, Br, Cl; M = Re, Mn; x = 1,4)", Zhou, Y.; Gladysz, J. A. Organometallics 1993, 12, 1073-1078. DOI: 10.1021/om00028a023. [Abstract][PDF]
182. "A New Form of Coordinated Carbon: An Unsupported C₃ Chain Spanning Two Different Transition Metals", Weng, W.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 3824-3825. DOI: 10.1021/ja00062a078. [Abstract][PDF]
183. (a) "A New Form of Coordinated Carbon: A C₃ Chain That is Anchored by a Transition Metal on Each End and Spanned by a Third", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 891-892. DOI: 10.1002/anie.199308911. [Abstract][PDF] (b) "Ein neuer Kohlenstoffligand; eine durch ein Re-Atom überdachte Re-C₃Re-Kette", Weng, W.; Arif, A. M.; Gladysz, J. A. Angew. Chem. 1993, 105, 937-938. DOI: 10.1002/ange.19931050632. [Abstract][PDF]
184. "Optical Rotation Measurements of Organometallic Compounds: Caveats and Recommended Procedures", Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 2390-2392. DOI: 10.1021/om00030a061. [Abstract][PDF]
185. "Synthesis, structure, and dynamic behavior of symmetrical cis- and trans- alkene complexes of the chiral rhenium Lewis acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: binding selectivities and isomerization processes", Pu, J.; Peng, T.-S.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2686-2698. DOI: 10.1021/om00031a044. [Abstract][PDF]
186. "Synthesis and Structure of Complexes of α,β-Unsaturated Carbonyl Compounds and the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Divergent Kinetic and Thermodynamic C=O/C=C and C=O/C-C Binding Selectivities", Wang, Y.; Agbossou, F.; Dalton, D. M.; Liu, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 2699-2713. DOI: 10.1021/om00031a045. [Abstract][PDF]
187. "New Families of Coordinated Carbon: Oxidative Coupling of an Ethynyl Complex to Isolable and Crystallographically Characterized MC≡CC≡CM and M=C=C=C=C=M Assemblies", Zhou, Y.; Seyler, J. W.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 8509-8510. DOI: 10.1021/ja00071a095. [Abstract][PDF]
188. "An Isolable Organometallic Cation Radical in which a C₄ Chain Conducts Charge Between Two Chiral and Configurationally Stable Rhenium Termini", Seyler, J. W.; Weng, W.; Zhou, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 3802-3804. DOI: 10.1021/om00034a008. [Abstract][PDF]
189. "Synthesis and Reactivity of Chiral Rhenium Indenyl Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(X)]ⁿ⁺", Zhou, Y.; Dewey, M. A.; Gladysz, J. A. Organometallics 1993, 12, 3918-3923. DOI: 10.1021/om00034a026. [Abstract][PDF]
190. "Reactions of Rhenium Cyclopentadienyl and Indenyl Dichloromethane Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(ClCH₂Cl)]⁺ BF₄^- with Ketones; Substitution Rates and Mechanism", Dewey, M. A.; Zhou, Y.; Liu, Y.; Gladysz, J. A. Organometallics 1993, 12, 3924-3932. DOI: 10.1021/om00034a027. [Abstract][PDF]
191. "Synthesis, Structure and Reactivity of Chiral Rhenium Imine and Methyleneamido Complexes of the Formulas [(η⁵-C₅H₅)Re(NO)(PPh₃)(η¹-N(R")=C(R)R')]⁺ TfO^- and (η⁵-C₅H₅)Re(NO)(PPh₃)N=C(R)R')", Knight, D. A.; Dewey, M. A.; Stark, G. A.; Bennett, B. K.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4523-4534. DOI: 10.1021/om00035a043. [Abstract][PDF]
192. "Synthesis, Structure, and Reactivity of η²-1,3-Diene and Enyne Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Ozonolysis Within a Metal Coordination Sphere", Peng, T.-S.; Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4535-4544. DOI: 10.1021/om00035a044. [Abstract][PDF]
193. "Pyrrolyl-N and Pyrrolyl-C Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Synthesis, Protonation, and Rearrangement Chemistry", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1993, 12, 4728-4730. DOI: 10.1021/om00036a006. [Abstract][PDF]
194. "New Strategies for Enantioselective Syntheses of 1-Alkyl and 1,4-Dialkyl 1,2,3,4-Tetrahydroisoquinolines: Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Richter-Addo, G. B.; Knight, A. D.; Dewey, M. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 11863-11873. DOI: 10.1021/ja00078a026. [Abstract][PDF]
195. "Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(GeMe₂X); Equilibria Involving the Dimethylgermylene Complex [(η⁵-C₅H₅)Re(NO)(PPh₃)(=GeMe₂)]⁺ TfO^-", Lee, K. E.; Gladysz, J. A. Phosphorus, Sulfur, Silicon, and the Related Elements 1994, 87, 113-123. DOI: 10.1080/10426509408037445. [Abstract]
196. "Syntheses and Structures of Unsymmetrically 1,1-and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Enantioface Binding Selectivities and Conformational Equilibria", Peng, T.-S.; Pu, J.; Gladysz, J. A. Organometallics 1994, 13, 929-940. DOI: 10.1021/om00015a029. [Abstract][PDF]
197. "Enantioselective Syntheses of Organosulfur Compounds via [2,3]-Sigmatropic Rearrangements of Ylides of Di(allyl) and Di(propargyl) Sulfonium Salts. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1994, 116, 3655-3656. DOI: 10.1021/ja00087a084. [Abstract][PDF]
198. "Generation and Reactivity of Substitution-Labile Dichloromethane and Chlorobenzene Adducts of the Chiral Pentamethylcyclopentadienyl Rhenium Lewis Acid [(η⁵-C₅Me₅)Re(NO)(PPh₃)]⁺", Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534-2542. DOI: 10.1021/ic00090a011. [Abstract][PDF]
199. "Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Wang, Y.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 2164-2169. DOI: 10.1021/om00018a008. [Abstract][PDF]
200. (a) "Towards One-Dimensional Carbon Wires Connecting Single Metal Centers: A Cumulenic C₅ Chain that Mediates Charge Transfer Between Rhenium and Manganese Termini", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1994, 33, 2199-2202. DOI: 10.1002/anie.199421991. [Abstract][PDF] (b) "Auf dem Weg zur Verknüpfung einzelner Metalle durch "eindimensionale Kohlenstoffdrähte": Ladungstransfer zwischen terminalen Rhenium- und Manganzentren über ein C₅-Cumulen", Weng, W.; Bartik, T.; Gladysz, J. A. Angew. Chem. 1994, 106, 2269-2272. DOI: 10.1002/ange.19941062112. [Abstract][PDF]
201. "Syntheses of Cyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺ by Hydride Ion Abstraction from Amido Complexes", Cantrell, W. R. Jr.; Richter-Addo, G. B.; Gladysz, J. A. J. Organomet. Chem. 1994, 472, 195-204. DOI: 10.1016/0022-328X(94)80206-8. [Abstract][PDF]
202. "Synthesis, Structure and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Diastereoselective Electrophilic Additions", Johnson, T. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 3182-3193. DOI: 10.1021/om00020a035. [Abstract][PDF]
203. "New Families of Coordinated Carbon: Oxidative Coupling and Cross-coupling of a Transition Metal Butadiynyl Complex to Bimetallic M-C≡CC≡CC≡CC≡C-M and M-C≡CC≡CC≡C-M Adducts", M. Brady; W. Weng; Gladysz, J. A. J. Chem. Soc., Chem. Commun. 1994, 2655-2656. DOI: 10.1021/ja9631817. [Abstract][PDF]
204. "Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1994, 13, 4523-4530. DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]
205. "Are Teflon Ponytails the Coming Fashion for Catalysts?", Gladysz, J. A. Science 1994, 266, 55-56. DOI: 10.1126/science.266.5182.55. [Abstract][PDF]
206. "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Quirós Méndez, N.; Seyler, J. W.; Arif, A. M; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]
207. "Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C₂Li Complexes of the Formula ((η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CX); Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C₄H₃ and C₄H₄ Species", Weng, W.; Bartik, T.; Johnson, M. T.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 889-897. DOI: 10.1021/om00002a041. [Abstract][PDF]
208. "A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of Chiral Cationic Rhenium Alkene Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(H₂C=CHR)]⁺ BF₄^-", Peng, T.-S.; Gladysz, J. A. Organometallics 1995, 14, 898-911. DOI: 10.1021/om00002a041. [Abstract][PDF]
209. "Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(=CHR)]⁺ PF₆^-; A Versatile and Highly Stereoselective Route to Alkene Complexes", Wang, Y.; Gladysz, J. A. Chem. Ber. 1995, 128, 213-220. DOI: 10.1002/cber.19951280303. [Abstract][PDF]
210. "Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Enantioselective Syntheses of 3-Substituted Cycloalkanones", Wang, Y.; Gladysz, J. A. J. Org. Chem. 1995, 60, 903-909. DOI: 10.1021/jo00109a022. [Abstract][PDF]
211. "A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprotonation of a Chiral Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon", Meyer, O.; Arif, A. M.; Gladysz, J. A. Organometallics 1995, 14, 1844-1849. DOI: 10.1021/om00004a043. [Abstract][PDF]
212. "Diastereoselective Additions of Nucleophiles and Electrophiles to Isoquinoline and Quinoline Mediated by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary; Enantioselective Syntheses of Alkyl, Dialkyl, and Trialkyl Hydroisoquinoline Derivatives", Stark, G. A.; Dewey, M. A.; Richter-Addo, G. B.; Knight, D. A.; Arif, A. M.; Gladysz, J. A. in Stereoselective Reactions of Metal-Activated Molecules; Werner, H.; Sundermeyer, J. Eds.; Vieweg-Verlag: Braunschweig, Germany, 1995; pp. 51-71. ISBN: 3-528-06664-4, 9783528066642.
213. "Nucleophilic Additions to the Chiral Rhenium Alkene Complexes [Re(η⁵-C₅H₅)(NO)(PPh₃)(H₂C=CHR)]BF₄ (R = H, Me, CH₂CH₂Me, Ph or CH₂Ph): Regio-, Diastereo-, and Enantioselectivities", Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 1995, 1857-1865. DOI: 10.1039/DT9950001857. [Abstract][PDF]
214. "Synthesis, Structure, and Reactivity of Chiral Rhenium N-Pyrrolyl Complexes [(η⁵-C₅H₅)Re(NO)(PPh₃)(NCR=CR'CH=CH)]; Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon-Ligated Species", Johnson, T. J.; Alvey, L. J.; Brady, M.; Mayne, C. L.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1995, 1, 294-302. DOI: 10.1002/chem.19950010506. [Abstract][PDF]
215. "Crystal Structures of Diastereomeric Styrene Complexes of the Chiral Rhenium Fragment [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺; Effect of Ligating Enantioface upon Bonding and Conformation", Sanau, M.; Peng, T.-S.; Arif, A. M.; Gladysz, J. A. J. Organomet. Chem. 1995, 503, 235-241. DOI: 10.1016/0022-328X(95)05565-7. [Abstract][PDF]
216. "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Rearrangements of Ylides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary", Cagle, P. C.; Meyer, O.; Weickhardt, K.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11730-11744. DOI: 10.1021/ja00152a014. [Abstract][PDF]
217. "Synthesis, Structure and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC₂M', MC₄M' and MC₄M'C₄M Linkages. Transmetalations of Lithiocarbon Complexes (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CLi) and (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC≡CLi)", Weng, W.; Bartik, T. ; Brady, M.; Bartik, B.; Ramsden, J. A.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1995, 117, 11922-11931. DOI: 10.1021/ja953523t. [Abstract][PDF]
218. "Reactions of t-BuOK and Di(Benzyl), Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Highly Diastereoselective or Chemoselective [2,3] Sigmatropic Rearrangements", Cagle, P. C.; Meyer, O.; Vichard, D.; Weickhardt, K; Arif, A. M.; Gladysz, J. A. Organometallics 1996, 15, 194-204. DOI: 10.1021/om950701i. [Abstract][PDF]
219. (a) "A Step-Growth Approach to Metal-Capped One-Dimensional Carbon Allotropes; Syntheses of C₁₂, C₁₆, and C₂₀ μ-Polyynendiyl Complexes", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 414-417. DOI: 10.1002/anie.19961080415. [Abstract][PDF] (b) "Schrittweises Kettenwachstum eindimensionaler Kohlenstoffallotrope mit terminalen Metallgruppen; Synthese von C₁₂-, C₁₆-, und C₂₀-μ-Polyindiylkomplexen", Bartik, T.; Bartik, B.; Brady, M.; Dembinski, R.; Gladysz, J. A. Angew. Chem. 1996, 108, 467-469. DOI: 10.1002/ange.19961080415. [Abstract][PDF]
220. "A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid: Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State", Boone, B. J.; Klein, D. P.; Seyler, J. W.; Quirós Méndez, N.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1996, 118, 2411-2421. DOI: 10.1021/ja953523t. [Abstract][PDF]
221. "Enantioselective Syntheses of Organosulfur Compounds via [2,3] Sigmatropic Rearrangements of Ylides Derived from Di(allyl), Di(propargyl), and Di(benzyl) Sulfide Complexes; Control of Carbon Configuration by an Easily Resolved and Recycled Rhenium Auxiliary", Meyer, O.; Cagle, P. C.; Weickhardt, K.; Vichard, D.; Gladysz, J. A. Pure Appl. Chemistry 1996, 68, 79-88. (invited article, 8th OMCOS symposium thematic issue) DOI: 10.1351/pac199668010079. [Abstract][PDF]
222. "A Search for π/σ Equilibria in Chiral Rhenium Imine Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(N(H)=C(CF₃)X)]⁺ TfO^-; Investigation of Electronic Effects Upon the Binding Mode", Stark, G. A.; Gladysz, J. A. Inorg. Chem. < 1996, 35, 5509-5513. DOI: 10.1021/ic960302v. [Abstract][PDF]
223. "Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids: Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements to Give Thiolate Complexes with New Carbon Stereocenters", Bell, P. T.; Cagle, P. C.; Vichard, D.; Gladysz, J. A. Organometallics 1996, 15, 4695-4701. DOI: 10.1021/om960541q. [Abstract][PDF]
224. "Configurational Equilibria in Amido and Lithioamido Complexes of Formulas (η⁵-C₅H₅)Re(NO)(PAr₃)(NHCHRR') and (η⁵-C₅H₅)Re(NO)(PAr₃)(NLiR"): Epimerization Occurs at Rhenium via Phosphine Dissociation", Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798-4807. DOI: 10.1021/om960662q. [Abstract][PDF]
225. "Consanguineous Families of Coordinated Carbon: A ReC₄Re Assembly that is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC≡CC≡CRe and ⁺Re=C=C=C=C=Re⁺ Adducts and a Radical Cation in which Charge is Delocalized Between Rhenium Termini", Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, A. J.; Arif, A. M.; Böhme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788. DOI: 10.1021/ja9631817. [Abstract][PDF]
226. "Methods for Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Carbon Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(CC)_nOs₃(CO)₁₀(H)", Falloon, S. B.; Arif, A. M.; Gladysz, J. A. Chem. Commun. 1997, 629-630. DOI: 10.1039/a607884b. [Abstract][PDF]
227. (a) "Chiral Recognition in π Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities", Gladysz, J. A.; Boone, B. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 551-583. DOI: 10.1002/anie.199705501. [Abstract][PDF] (b) "Chirale Erkennung in π-Komplexen von Alkenen, Aldehyden und Ketonen mit Übergangsmetall-Lewis-Säuren; Entwicklung eines allgemeinen Modells für enantiofacialle Komplexierungsselektivitäten", Gladysz, J. A.; Boone, B. J. Angew. Chem. 1997, 109, 566-602. DOI: 10.1002/ange.19971090604. [Abstract][PDF]
228. "Spectroscopic Observation of the Formyl Cation in a Condensed Phase", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Science 1997, 276. 776-779. DOI: 10.1126/science.276.5313.776. [Abstract][PDF]
229. "Synthesis, Structure, and Reactivity of Polymetallic C₃OMe Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC(OMe)=)M_m(CO)_n (M/m/n = Re/2/9, Os/3/11): A New Form of Coordinated Carbon in which a C₃ Chain Links two Metals and Spans a Third", Falloon, S. B.; Weng, W.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2008-2015. DOI: 10.1021/om970055i. [Abstract][PDF]
230. (a) "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroboration", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1610-1612. DOI: 10.1002/anie.19971091509. [Abstract][PDF] (b) "Übergangsmetallkatalyse in fluorhaltigen Medien: Anwendung eines neuen Immobilisierungsprinzips auf die Rh-katalysierte Hydroborieirung", Juliette, J. J. J.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1682-1684. DOI: 10.1002/ange.19971091509. [Abstract][PDF]
231. (a) "Synthesis, Structure, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH₂CH₂(CF₂)₅CF₃)₃]₂; Altered Reactivity in Fluorocarbons, and Implications for Catalysis", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 1997, 36, 1612-1615. DOI: 10.1002/anie.199716121. [Abstract][PDF] (b) "Synthese, Struktur, und oxidative Additionen eines fluorhaltigen Analogons des Vaska-Komplexes, trans-[IrCl(CO){P[CH₂CH₂(CF₂)₅CF₃]₃}₂] – Reaktivitätsänderung in Fluorkohlenwasserstoffen und Auswirkungen auf die Katalyse", Guillevic, M.-A.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Angew. Chem. 1997, 109, 1685-1687. DOI: 10.1002/ange.19971091510. [Abstract][PDF]
232. "Synthesis and Crystal Structure of the Conjugated Tetrayne (η⁵-C₅H₅)Re(NO)(PPh₃)(C≡CC≡CC≡CC≡CSiMe3): Application of the Cadiot-Chodkiewicz Coupling Reaction to the Chain Extension of Metal-Capped sp Carbon Wires", Bartik, B.; Dembinski, R.; Bartik, T.; Arif, A. M.; Gladysz, J. A. New J. Chem. 1997, 21, 739-750. (invited article, 13th summer school in coordination chemistry thematic issue)
233. "Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η⁵-C₅R₅)Re(NO)(PPh₃)CN(Ph₃P)(ON)Re(η⁵-C₅R₅)]⁺TfO^- (R, R' = H, Me)", Stark, G. A.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 2909-2918. DOI: 10.1021/om970167+. [Abstract][PDF]
234. "Synthesis and Crystallographic Characterization of the 'Sometimes-Chiral' Dirhenium Polyoxotungstate Salt {(η⁵-C₅H₅)Re(NO)(PPh₃)(CO)]⁺}₂[W₆O₁₉]^2-, Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Bull. Soc. Chim. Fr. 1997, 134, 793-799. ISSN: 0037-8968.
235. "Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6", Amoroso, A. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1997, 16, 6032-6034. DOI: 10.1021/om970792e. [Abstract][PDF]
236. "Additions of Carbon Nucleophiles to Acyclic Imine Complexes of the Chiral Rhenium Lewis Acid [(η⁵-C₅H₅)Re(NO)(PPh₃)]⁺: Controlling Factors in 1,3-Asymmetric Induction and Syntheses of Non-Racemic Organic Amines", Stark, G. A.; Gladysz, J. A. Inorg. Chim. Acta 1998, 269, 167-180. (invited article, issue in honor of Wolfgang Beck) DOI: 10.1016/S0020-1693(97)05787-3. [Abstract][PDF]
237. "Organometallic Reactivity Patterns in Fluorocarbons, and Implications for Catalysis; Synthesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analog of Vaska's Complex, trans-Ir(CO)(Cl)[P(CH₂CH₂(CF₂)₅CF₃)₃]₂", Guillevic, M.-A.; Rocaboy, C.; Arif, A. M.; Horváth, I. T.; Gladysz, J. A. Organometallics 1998, 17, 707-717. DOI: 10.1021/om9710834. [Abstract][PDF]
238. "Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η⁵-C₅Me₅)Re(NO)(PPh₃)(CC)_nOs₃(CO)_y(X)_z]^m+, Including Carbon Geometries more Distorted than Planar Tetracoordinate", Falloon, S. B.; Szafert, S.; Arif, A. M.; Gladysz, J. A. Chem. Eur. J. 1998, 4, 1033-1042. DOI:10.1002/(SICI)1521-3765(19980615)4:6<1033::AID-CHEM1033>3.0.CO;2-P. [Abstract][PDF]
239. "Transition Metal Catalysis in Fluorous Media: Application of a New Immobilization Principle to Rhodium Catalyzed Hydrogenation of Alkenes", Rutherford, D.; Juliette, J. J. J.; Rocaboy, C.; Horváth, I. T.; Gladysz, J. A. Catalysis Today 1998, 42, 381-388. (invited article, phase separable homogeneous catalysis thematic issue) DOI: 10.1016/S0920-5861(98)00120-5. [Abstract][PDF]
240. "New Forms of Coordinated Carbon: Wire-Like Cumulenic C₃ and C₅ sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer", Bartik, T.; Weng, W.; Ramsden, J. A.; Szafert, S.; Falloon S. B.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1998, 120, 11071-11081. DOI: 10.1021/ja981927q. [Abstract][PDF]
241. "Additions of PH₃ to Monosubstituted Alkenes of the Formula H₂C=CH(CH₂)_x(CF₂)_yCF₃; Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkyl Phosphines with Modulated Electronic Properties and Fluorous Phase Affinities", Alvey, L. J.; Rutherford, D.; Juliette, J. J. J.; Gladysz, J. A., J. Org. Chem. 1998, 63, 6302-6308. DOI: 10.1021/jo980692y. [Abstract][PDF]
242. "Olefin Metatheses in Metal Coordination Spehres: A New Strategy for Cyclic and Macrocyclic Organometallic Compounds", Martin-Alvarez, J. M.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 955-957. DOI: 10.1021/om9808920. [Abstract][PDF]
243. "Transition Metal Catalysis in Fluorous Media: Practical Application of a New Immobilization Principle to Rhodium-Catalyzed Hydroborations of Alkenes and Alkynes", Juliette, J. J. J.; Rutherford, D.; Horváth, I. T.; Gladysz, J. A. J. Am. Chem. Soc. 1999, 121, 2696-2704. DOI: 10.1021/ja982955b. [Abstract][PDF]
244. "Appreciably Bent sp Carbon Chains: Synthesis, Structure, and Protonation of Organometallic 1,3,5-Triynes and 1,3,5,7-Tetraynes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)((C≡C)_n-p-C₆H₄Me)", Dembinski, R.; Lis, T.; Szafert, S.; Mayne, C. L.; Bartik, T.; Gladysz, J. A. J. Organomet. Chem. 1999, 578, 229-246. DOI:10.1016/S0022-328X(98)01128-0. [Abstract][PDF]
245. "Chemistry in Fluorous Media: A User's Guide to Practical Considerations in the Application of Fluorous Catalysts and Reagents", Barthel-Rosa, L. P.; Gladysz, J. A. Coord. Chem. Rev. 1999, 190-192, 587-605. (invited article, 33rd ICCC thematic issue) DOI: 10.1016/S0010-8545(99)00102-2. [Abstract][PDF]
246. "C₈ and C₁₂ sp Carbon Chains that Span Two Platinum Atoms; The First Structurally Characterized 1,3,5,7,9,11-hexayne", Peters, T. B.; Bohling, J. C.; Arif, A. M.; Gladysz, J. A. Organometallics 1999, 18, 3261-3263. DOI: 10.1021/om990448c. [Abstract][PDF]
247. "Synthesis, Properties, and Reactions of Enantiomerically Pure, Chiral Fluorous Phosphines of the Formula (menthyl)P(CH₂CH₂(CF₂)_n-1CF₃)₂ (n = 6, 8)", Klose, A.; Gladysz, J. A. Tetrahedron–Asymmetry 1999, 10, 2665-2674. DOI: 10.1016/SO957-4166(99)00272-4. [Abstract][PDF]
248. "Wire-Like sp Carbon Chains that Span Two Platinum Atoms: Synthesis and Crystal Structures of Building Blocks of the Formula trans-(p-tolyl)(Ph₃P)₂Pt(C≡C)_nSiMe₃", Bohling, J. C.; Peters, T. B.; Arif, A. M.; Hampel, F.; Gladysz, J. A., in Coordination Chemistry at the Turn of the Century; Ondrejoviç, G.; Sirota, A. Eds.; Slovak Technical University Press: Bratislava, Slovokia, 1999; pp. 47-52.
249. "Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones", Dinh, L. V.; Gladysz, J. A. Tetrahedron Lett. 1999, 40, 8995-8998. DOI: 10.1016SO040-4039(99)01924-3. [Abstract][PDF]
250. "A New Route to Heterobimetallic C₃ Complexes via C≡C Metatheses of 1,3-Diynyl Ligands: Synthesis and Structure of (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡CC≡)W(O-t-Bu)₃", Dembinski, R.; Szafert, S.; Haquette, P.; Lis, T.; Gladysz, J. A. Organometallics 1999, 18, 5438-5440. DOI: 10.1021/om990766b. [Abstract][PDF]
251. "Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C₆-C₂₀ Polyynediyl Chains that Span Two Redox-Active (η⁵-C₅Me₅)Re(NO)(PPh₃) Endgroups", Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810-822. DOI: 10.1021/ja992747z. [Abstract][PDF]
252. " Synthesis and Properties of Chiral Rhenium Pentatetraenylidene Complexes of the Formula [(η⁵-C₅Me₅)Re(NO)(PPh₃)(=C=C=C=C=CAr₂)]⁺BF₄^- (CAr₂ = 9-fluorenylidene)", Szafert, S.; Haquette, P.; Falloon, S. B.; Gladysz, J. A. J. Organomet. Chem. 2000, 604, 52-58. DOI:10.1016/S0022-328X(00)00201-1. [Abstract][PDF]
253. "Strategy and Design in Fluorous Phase Immobilization: A Systematic Study of the Effect of "Pony Tails" (CH₂)₃(CF₂)_n-1CF₃ Upon the Partition Coefficients of Benzenoid Compounds", Rocaboy, C.; Rutherford, D.; Bennett, B. L.; Gladysz, J. A. J. Phys. Org. Chem. 2000, 13, 596-603. (invited article, organic reactivity (ESOR 7) thematic issue). DOI: 10.1002/1099-1395(200010)13. [Abstract][PDF]
254. "A 'Conjugal' Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C₄ Species", Paul, F.; Meyer, W. E.; Toupet, L.; Jiao, H.; Gladysz, J. A.; Lapinte, C. J. Am. Chem. Soc. 2000, 122, 9405-9414. DOI: 10.1021/ja0011055. [Abstract][PDF]
255. "Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Second, and Tertiary Aliphatic Amines NH_3-x((CH₂)_m(CF₂)₇CF₃)_x (m = 3-5; x = 1-3); Fine Tuning of Basicities and Fluorous Phase Affinities", Rocaboy, C.; Bauer, W.; Gladysz, J. A. Eur. J. Org. Chem. 2000, 2621-2628. DOI: 10.1002/1099-0690(200007)2000:14. [Abstract][PDF]
256. "Synthesis and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Trialkylphosphines: Precision Tuning of Electronic Properties, Including Insulation of the Perfluoroalkyl Group", Alvey, L. J.; Meier, R.; Soós, T.; Bernatis, P.; Gladysz, J. A. Eur. J. Inorg. Chem. 2000, 1975-1983. DOI: 10.1002/1099-0682(200009)2000:9<1975::AID-EJIC1975>3.0.CO;2-M. [Abstract][PDF]
257. "Synthesis and Oxidation of Chiral Rhenium Phosphine Methyl Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(CH₃): In Search of Radical Cations with Enhanced Kinetic Stabilities", Meyer, W. E.; Amoroso, A. J.; Jaeger, M.; Le Bras, J.; Wong W.-T.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 44-53. DOI: 10.1016/S0022-328X(00)00528-3. [Abstract][PDF]
258. "Synthesis, Crystal Structure, and Reactions of the Seventeen-Valence-Electron Rhenium Methyl Complex [(η⁵-C₅Me₅)Re(NO)(P(4-C₆H₄CH₃)₃)(CH₃)]^·+ (B(3,5-C₆H₃(CF₃)₂)₄^-: Experimental and Computational Bonding Comparisons with Eighteen-Electron Methyl and Methylidene Complexes", Le Bras, J.; Jiao, H.; Meyer, W. E.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2000, 616, 54-66. DOI: 10.1016/S0022-328X(00)00531-3- [Abstract][PDF]
259. "Tails and Steeds versus Heads and Beads: The Case for Fluorous Phase Methodology in Combinatorial and Parallel Synthesis", Rocaboy, C.; Gladysz, J. A. Actualité Chimique 2000, 47-50 (September).
260. "Olefin Metatheses in Metal Coordination Spheres: Novel trans-Spanning Bidentate and Facially-Spanning Tridentate Macrocyclic Phosphine Complexes", Bauer, E. B.; Ruwwe, J.; Martín-Alvarez, J. M.; Peters, T. B.; Bohling, J. C.; Hampel, F. A.; Szafert, S.; Lis, T.; Gladysz, J. A. Chem. Commun. 2000, 2261-2262. DOI: 10.1039/b007405p. [Abstract][PDF]
261. "Surface Reactivity Studies of Bimetallic Complexes (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡C)_n(Ph₃P)(ON)Re(η₅-C₅Me₅) (n = 2, 4, 6): Candidates for Molecular Wires", Schennach, R.; Naugle, D. G.; Cocke, D.; Dembinski, R.; Gladysz, J. A. Vacuum 2000, 56, 115-121. DOI:10.1016/S0042-207X(99)00178-5. [Abstract][PDF]
262. "New Chiral Cyclopentadienyl Rhenium Lewis Acids Featuring Fluorinated Triaryl Phosphines and Enhanced Acceptor Abilities - An Unusual Carbon-Fluorine Bond Activation in a Metal Coordination Sphere", Mohr, W.; Stark, G. A.; Jiao, H.; Gladysz, J. A. Eur. J. Inorg. Chem. 2001, 925-933. DOI:10.1002/1099-0682(200104)2001:4<925::AID-EJIC925>3.0.CO;2-N. [Abstract][PDF]
263. "A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of 'Chiral-at-Rhenium' Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations", Kromm, K.; Zwick, B. D.; Meyer, O.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 2015-2027. DOI: 10.1002/1521-3765(20010504)7:9. [Abstract][PDF]
264. "Synthesis and Oxidation of Dirhenium C₄, C₆, and C₈ Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PR₃)(C≡C)_n(R₃P)(ON)Re(η⁵-C₅Me₅) (R = 4-C₆H₄R', c-C₆H₁₁): In Search of Dications and Radical Cations with Enhanced Stabilities", Meyer, W. E.; Amoroso, A. J.; Horn, C. R.; Jaeger, M.; Gladysz, J. A. Organometallics 2001, 20, 1115-1127. DOI: 10.1021/om000961m. [Abstract][PDF]
265. "Metal-Metal Interactions Across Bridging Elemental Carbon Chains: A Computational Study of Odd-Carbon Complexes", Jiao, H.; Gladysz, J. A. New J. Chem. 2001, 25, 551-562. DOI: 10.1039/b008786f. [Abstract][PDF]
266. "Synthesis, Structure, and Interconversion of Chiral Rhenium Oxygen- and Sulfur-Bound Sulfoxide Complexes of the Formula [(η⁵-C₅H₅)Re(NO)(PPh₃)(OS(Me)R)]⁺ X^-; Diastereoselective Oxidations of Coordinated Methyl Alkyl Sulfides", Otto, M.; Boone, B. J.; Arif, A. M.; Gladysz, J. A. J. Chem. Soc., Dalton Trans. 2001, 1218-1229. DOI: 10.1039/b009533h. [Abstract][PDF]
267. "Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P(p-C₆H₄(CH₂)₃(CF₂)_n-1CF₃)₃ (n = 6, 8, 10)", Soós, T.; Bennett, B. L.; Rutherford, D.; Barthel-Rosa, L. P.; Gladysz, J. A. Organometallics 2001, 20, 3079-3086. DOI: 10.1021/om010193e. [Abstract][PDF]
268. "A New Family of Chiral Chelating Diamines with Transition Metal Stereocenters: Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted Diamine (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂N(CH₃)CH₂CH₂(H₃C)NCH₂)(Ph₃P)(ON)Re(η⁵-C₅H₅)", Alvey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; Lis, T.; Gladysz, J. A. Organometallics 2001, 20, 3087-3096. DOI: 10.1021/om010153a. [Abstract][PDF]
269. "Structures and Energies of 10-Azatriquinacene and Its Hydrogenation Products: A Computational Study", Jiao, H.; Halet, J.-F.; Gladysz, J. A. J. Org. Chem. 2001, 66, 3902-3905. DOI: 10.1021/jo001800v. [Abstract][PDF]
270. "Bent and Stretched but not yet to the Breaking Point: C₈-C₁₆ sp Carbon Chains the Span two Platinum Atoms, and the First Structurally Characterized 1,3,5,7,9,11,13,15-Octayne", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2001, 40, 3263-3264. DOI: 10.1021/ic010309z. [Abstract][PDF]
271. "Olefin Metatheses in Metal Coordination Spheres: Versatile New Strategies for the Construction of Novel Monohapto or Polyhapto Cyclic, Macrocyclic, Polymacrocyclic, and Bridging Ligands", Ruwwe, J.; Martín-Alvarez, J. M.; Horn, C. R.; Bauer, E. B.; Szafert, S.; Lis, T.; Hampel, F.; Cagle, P. C.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 3931-3950. DOI: 10.1002/1521-3765(20010917)7:18. [Abstract][PDF]
272. "Fluorous Catalysis Without Fluorous Solvents: A Friendlier Catalyst Recovery/Recycling Protocol Based upon Thermorphic Properties and Liquid/Solid Phase Separation", Wende, M.; Meier, R.; Gladysz, J. A. J. Am. Chem. Soc. 2001, 123, 11490-11491. DOI: 10.1021/ja011444d. [Abstract][PDF]
273. "Recoverable Catalysts: Ultimate Goals, Criteria of Evaluation, and the Green Chemistry Interface", Gladysz, J. A. Pure Appl. Chem. 2001, 73, 1319-1324. (invited article, CHEMRAWN XIV thematic issue) DOI:10.1351/ pac200173081319. [Abstract][PDF]
274. "Syntheses and Structures of Monoplatinum Model Complexes for Diplatinum Polyynediyl Adducts L_nPt(C≡C)_zPtL_n", Peters, T. B.; Zheng, Q.; Stahl, J.; Bohling, J. C.; Arif, A. M.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2002, 641, 53-61. (invited article, interactions of π systems with metals thematic issue) DOI: 10.1016/ S0022-328X(01)01311-0. [Abstract][PDF]
275. "Vibrational Progressions in the Valence Ionizations of Transition Metal Hydrides: Evaluation of Metal-Hydride Bonding and Vibrations in (η⁵-C₅R₅)Re(NO)(CO)(H) [R = H, CH₃]", Lichtenberger, D. L.; Gruhn, N.; Rai-Chaudhuri, A.; Renshaw, K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, A. J. Am. Chem. Soc. 2002, 124, 1417-1423. DOI: 10.1021/ja0120227. [Abstract][PDF]
276. "An Unexpected Insertion of Acetone into the Silicon-Carbon Terminus of an sp Carbon Chain: Syntheses and Structures of Model Monoplatinum Hexatriynyl and Octatetraynyl Complexes", Mohr, W.; Peters, T. B.; Bohling, J. C.; Hampel, F.; Arif, A. M.; Gladysz, J. A. Comptes Rendus Chemie 2002, 5, 111-118. (invited article, Gecom-Concoord thematic issue) DOI: 10.1016/S1631-0748(02)01351-6. [Abstract][PDF]
277. "How to Insulate a Reactive Site from a Perfluoroalkyl Group: Photoelectron Spectroscopy, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH₂)_m(CF₂)₇CF₃)₃", Jiao, H.; Le Stang, S.; Soós, T.; Meier, R.; Kowski, K.; Rademacher, P.; Jafarpour, L.; Hamard, J.-B.; Nolan, S. P.; Gladysz, J. A. J. Am. Chem. Soc. 2002, 124, 1516-1523. DOI: 10.1021/ja011877g. [Abstract][PDF]
278. "New Perfluorocarbon System for Multilayer Growth of Anchorage Dependent Mammalian Cells", Rappaport, C.; Rensch, Y.; Abbasi, M.; Kempe, M.; Rocaboy, C. Gladysz, J. A.; Trujillo, E. M. BioTechniques 2002, 32, 142-151. ISSN: 0736-6205. [PDF]
279. "Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphosphines that Contain a Rhenium Stereocenter in the Backbone", Kromm, K.; Hampel, F.; Gladysz, J. A. Helv. Chim. Acta 2002, 85, 1778-1789. DOI: 10.1002/1522-2675(200206)85:6. [Abstract][PDF]
280. "Fluorous Chemistry: From Biphasic Catalysis to a Parallel Chemical Universe and Beyond", Gladysz, J. A.; Curran, D. P. Tetrahedron 2002, 58, 3823-3825. DOI: 10.1016SO040-4020(02)00222-3. [Abstract][PDF]
281. "Syntheses, Oxidations, and Palladium Complexes of Fluorous Dialkyl Sulfides: New Precursors to Highly Active Catalysts for the Suzuki Coupling", Rocaboy, C.; Gladysz, J. A. Tetrahedron 2002, 58, 4007-4014. (invited article, fluorous chemistry thematic issue) DOI: 10.1016SO04020(02)00275-2. [Abstract][PDF]
282. (a) "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: An Unprecedented New Class of Molecules that are Accessible by Self-Assembly and Models for "Insulated" Molecular-Scale Devices", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2002, 41, 1871-1876. DOI: 10.1021/ja0716103. [Abstract][PDF] (b) "Von sp³-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für isolierte molekulare Bauelemente sind", Stahl, J.; Bohling, J. C.; Bauer, E. B.; Peters, T. B.; Mohr, W.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2002, 114, 1951-1957. DOI: 10.1002/1521-3757(20020603)114:11<1951::AID-ANGE1951>3.0.CO;2-Z. [Abstract][PDF]
283. "New Approaches to High-Activity Transition Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Couplings", Eichenseher, S.; Kromm, K.; Delacroix, O.; Gladysz, J. A., Chem. Commun. 2002, 1046-1047. DOI: 10.1021/om0492956. [Abstract][PDF]
284. "Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Reaction; Evidence for a Palladium Nanoparticle Pathway", Rocaboy, C.; Gladysz, J. A. Org. Lett. 2002, 4, 1993-1996. DOI: 10.1021/ol025790r. [Abstract][PDF]
285. "A New Family of Chelating Diphosphines with Transition Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System", Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2002, 21, 4264-4274. DOI: 10.1021/om020431l. [Abstract][PDF]
286. "Chelating Diphosphines that Contain a Rhenium Stereocenter in the Backbone: Applications in Rhodium-Catalyzed Enantioselective Ketone Hydrosilylations and Alkene Hydrogenations", Kromm, K.; Osburn, P. L.; Gladysz, J. A. Organometallics 2002, 21, 4275-4280. DOI: 10.1021/om020432d. [Abstract][PDF]
287. "Syntheses and Reactivities of Disubstituted and Trisubstituted Fluorous Pyridines with High Fluorous Phase Affinities: Solid State, Liquid Crystal, and Ionic Liquid Phase Properties", Rocaboy, C.; Hampel, F.; Gladysz, J. A. J. Org. Chem. 2002, 67, 6863-6870. DOI: 10.1021/jo011173p. [Abstract][PDF]
288. "Olefin Metatheses in Metal Coordination Spheres: A New Approach to Steric Shielding in Dirhenium sp Carbon Chain Complexes of the formula (η⁵-C₅Me₅)Re(NO)(PR₃)(C≡CC≡CC≡CC≡C)(R₃P)(ON)Re(η⁵-C₅Me₅)", Horn, C. R.; Martín-Alvarez, J. M.; Gladysz, J. A. Organometallics 2002, 21, 5386-5393. DOI: 10.1021/om020676y. [Abstract][PDF]
289. "Facile and Selective Carbonylation of Methane in Superacids", de Rege, P. J. F.; Gladysz, J. A.; Horváth, I. T. Adv. Synth. Catal. 2002, 344, 1059-1062. DOI: 10.1002/1615-4169(200212)344:10<1059::AID-ADSC1059>3.0.CO;2-O. [Abstract][PDF]
290. "Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Sukuki Cross-Couplings", Giner Planas, J.; Gladysz, J. A. Inorg. Chem. 2002, 41, 6947-6949. DOI: 10.1021/ic020589y. [Abstract][PDF]
291. "How do the Electronic Structures of Low-Symmetry Metal-Hydride and -Alkyl Complexes Compare? Photoelectron Spectroscopy and Computational Studies of (η⁵-C₅R₅)Re(NO)(L)R' [L = CO, P(C₆H₅)₃; R, R' = H, CH₃)]", Lichtenberger, D. L.; Gruhn, N. E.; Rai-Chaudhuri, A.; Renshaw, S. K.; Gladysz, J. A.; Jiao, H.; Seyler, J.; Igau, I. Organometallics 2002, 21, 5494-5504. DOI: 10.1021/om020793t. [Abstract][PDF]
292. "Convenient Syntheses of Fluorous Aryl Iodides and Hypervalent Iodine Compounds: ArI(L)_n Reagents that are Recoverable by Simple Liquid/Liquid Biphase Workups, and Applications in Oxidations of Hydroquinones", Rocaboy, C.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 88-95. DOI: 10.1002/chem.200390034. [Abstract][PDF]
293. "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age", Delacroix, O.; Gladysz, J. A. Chem. Commun. 2003, 665-675 (feature article). DOI: 10.1002/chin.200325223. [Abstract][PDF]
294. "Thermomorphic Fluorous Imine and Thioether Palladacycles as Precursors for Highly Active Heck and Suzuki Catalysts; Evidence for Palladium Nanoparticle Pathways", Rocaboy, C.; Gladysz, J. A. New J. Chem. 2003, 27, 39-49. DOI: 10.1039/b208545n. [Abstract][PDF]
295. "Synthesis, Structure, and Reactivity of sp Carbon Chains with bis(phosphine) Pentafluorophenylplatinum Endgroups: Butadiynediyl (C₄) through Hexadecaoctaynediyl (C₁₆) Bridges, and Beyond", Mohr, W.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2003, 9, 3324-3340. DOI: 10.1002/chem.200204741. [Abstract][PDF]
296. "Convenient Syntheses of Fluorous Phenols of the Formula HOC₆H_5-n((CH₂)₃(CF₂)₇CF₃)_n (n = 1,2) and the Corresponding Triarylphosphites", Le Stang, S.; Meier, R.; Rocaboy, C.; Gladysz, J. A. J. Fluorine Chem. 2003, 119, 141-149. DOI:10.1016/S0022-1139(02)00242-7. [Abstract][PDF]
297. "Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear bis(1,3-Butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η⁵-C₅Me₅)Re(NO)(PR₃)(C≡CC≡CC≡CC≡C)(R₃P)(ON)Re(η⁵-C₅Me₅)]", Horn, C. R.; Gladysz, J. A. Eur. J. Inorg. Chem. 2003, 9, 2211-2218. (feature article). DOI: 10.1002/ejic.200300043. [Abstract][PDF]
298. "Fluorous Catalysis under Homogeneous Conditions without Fluorous Solvents: A "Greener" Catalyst Recycling Protocol Based upon Temperature-Dependent Solubilities and Liquid/Solid Phase Separation", Wende, M.; Gladysz, J. A. J. Am. Chem. Soc. 2003, 125, 5861-5872. DOI: 10.1021/ja029241s. [Abstract][PDF]
299. "Convenient and Convergent Syntheses of Long-Chain α,ω-Dibromides and Diphosphines of the Formula X(CH₂)_nX (n = 18-32)", Mohr, W.; Horn, C. R.; Stahl, J.; Gladysz, J. A. Synthesis 2003, 1279-1285. DOI: 10.1055/s-2003-39414. [Abstract][PDF]
300. "Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC₄M']ⁿ⁺: Computational Analyses of the Effect of the Metal", Jiao, H.; Costuas, K.; Gladysz, J. A.; Halet, J.-F.; Guillemot, M.; Toupet, L.; Paul, F.; Lapinte, C. J. Am. Chem. Soc. 2003, 125, 9511-9522. DOI: 10.1021/ja034619n. [Abstract][PDF]
301. "Tungsten-Catalyzed Alkyne Metatheses in Transition Metal Coordination Spheres: Versatile New Synthesis of Metallamacrocycles", Bauer, E. B.; Szafert, S.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 2184-2186. DOI: 10.1021/om030195u. [Abstract][PDF]
302. "Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2003, 103, 4175-4205. DOI: 10.1021/cr030041o. [Abstract][PDF]
303. "Metal-Catalyzed Olefin Metathesis in Metal Coordination Spheres", Bauer, E. B.; Gladysz, J. A. in Handbook of Metathesis, Grubbs, R. H. Ed.; Wiley/VCH, New York, 2003, Vol 2, pp 403-431. DOI: 10.1002/9783527619481.ch26. [Abstract][PDF]
304. "Synthesis and Properties of Fluorous Arenes and Triaryl Phosphorus Compounds with Branched Fluoroalkyl Moieties ("Split Pony Tails")", Wende, M.; Seidel, F.; Gladysz, J. A. J. Fluorine Chem. 2003, 124, 45-54. DOI: 10.1016/S0022-1139(03)00171-4. [Abstract][PDF]
305. "Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Substitution on the Efficiencies of Macrocyclizations that join trans Positions of Square-Planar Platinum Complexes", Bauer, E. B.; Hampel, F.; Gladysz, J. A. Organometallics 2003, 22, 5567-5580. DOI: 10.1021/om034121u. [Abstract][PDF]
306. "Fluorous Chemistry: Scope and Definition", Horváth, I. T.; Curran, D. P.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 1-4. DOI: 10.1002/3527603905.ch1. [Abstract] 307. "Fluorous Solvents and Related Media", Gladysz, J. A.; Emnet, C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 11-23. DOI: 10.1002/3527603905.ch3. [Abstract] 308. "Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation", Gladysz, J. A.; Corrêa da Costa, R. C. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 24-40. DOI: 10.1002/3527603905.ch4. [Abstract] 309. "Ponytails: Structural and Electronic Considerations", Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 41-55. DOI: 10.1002/3527603905.ch5. [Abstract] 310. "Partition Coefficients involving Fluorous Solvents", Gladysz, J. A.; Emnet, C.; Rábai, J. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 56-100. DOI: 10.1002/3527603905.ch6. [Abstract] 311. "9H, 9H, 10H, 11H, 11H-Perfluoro-11-nonadecyl Iodide. Free Radical Chain Reactions of Fluorous Primary Alkyl Iodides", Wende, M.; Gladysz, J. A. in Handbook of Fluorous Chemistry, Gladysz, J. A.; Curran, D. P.; Horváth, I. T. Eds.; Wiley/VCH, Weinheim, 2004, pp. 464-465. DOI: 10.1021/op050147g. [Abstract]
312. "Alkene Metatheses in Transition Metal Coordination Spheres: Dimacrocyclizations that join trans Positions of Square-Planar Platinum Complexes to give Topologically Novel Diphosphine Ligands", Shima, T.; Bauer, E. B.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2004, 1012-1028. DOI: 10.1039/b400156g. [Abstract][PDF]
313. "Convenient Syntheses of 'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails", Dinh, L. V.; Gladysz, J. A. Chem. Commun. 2004, 998-999. DOI: 10.1039/b401540a. [Abstract][PDF]
314. "Alkyne Metatheses in Transition Metal Coordination Spheres: Convenient Tungsten- and Molybdenum-Catalyzed Syntheses of Novel Metallamacrocycles", Bauer, E. B.; Hampel, F.; Glaydsz, J. A. Adv. Synth. Catal. 2004, 346, 812-822. DOI: 10.1002/ adsc.200404026. [Abstract][PDF]
315. "Syntheses and Structures of Diplatinum Hexatriynediyl Complexes, In which the sp Carbon Chains are shielded by sp³ Carbon Chains", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5889-5892. DOI: 10.1021/om0493558. [Abstract][PDF]
316. "Syntheses and Structures of Tetraplatinum bis(Polyynediyl) Complexes with Laterally Arrayed sp Carbon Chains", Owen, G. R.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5893-5895. DOI: 10.1021/om049354f. [Abstract][PDF]
317. "Longitudinally Extended Molecular Wires based upon PtC≡CC≡CC≡CC≡C Repeat Units; Iterative Syntheses of Functionalized Linear PtC₈Pt, PtC₈PtC₈Pt, and PtC₈PtC₈PtC₈Pt Assemblies", Zheng, Q.; Hampel, F.; Gladysz, J. A. Organometallics 2004, 23, 5896-5899. DOI: 10.1021/om049353n. [Abstract][PDF]
318. "Transition-Metal-Based Fluorous Catalysts", Corrêa da Costa, R. ; Gladysz, J. A. in Transition Metals for Organic Synthesis, 2nd ed, Beller, M.; Bolm, C. Eds.; Wiley/VCH, Weinheim, 2004, 527-543. DOI: 10.1002/9783527619405.ch6b. [Abstract]
319. (a) "Molecular Gyroscopes: {Fe(CO)₃} and {Fe(CO)₂(NO)}⁺ Rotators Encased in Three-Spoke Stators; Facile Assembly via Alkene Metatheses", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. 2004, 43, 5537-5540. DOI: 10.1002/anie.200460534. [Abstract][PDF] (b) "Molekulare Gyroskope: {Fe(CO)₃}- und {Fe(CO)₂(NO)}⁺-Rotatoren in einem Stator aus drei Speichen; Einfache Synthese durch Alken-Metathese", Shima, T.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2004, 116, 5653-5656. DOI: 10.1002/ange.200460534. [Abstract][PDF]
320. "Electronic Structure and Chain Length Effects in Diplatinum Polyynediyl Complexes trans, trans-[(X)(R₃P)₂Pt(C≡C)_nPt(PR₃)₂(X)]: A Computational Investigation", Zhuravlev, F.; Gladysz, J. A. Chem. Eur. J. 2004, 10, 6510-6522. DOI: 10.1002/chem.200400643. [Abstract][PDF]
321. "Syntheses and Structures of Missing Links among Polybromocyclopentadienyl Rhenium and Manganese Tricarbonyl Complexes" , Dinh, L. V.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2005, 690, 493-503. DOI: 10.1016/J.JORGANCHEM.2004.09.072. [Abstract][PDF]
322. "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems", Eichenseher, S.; Delacroix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 245-255. DOI: 10.1021/om0492956. [Abstract][PDF]
323. "Monophasic and Biphasic Hydrosilylations of Enones and Ketones using a Fluorous Rhodium Catalyst that is Easily Recycled under Fluorous/Organic Liquid/Liquid Biphase Conditions", Dinh, L. V.; Gladysz, J. A. New. J. Chem. 2005, 29, 173-181. DOI: 10.1039/B415344H [Abstract][PDF]
324. "Generation and Reactions of Ruthenium Phosphido Complexes [(η⁵-C₅H₅)Ru(PR'₃)₂(PR₂)]: Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions", Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416. DOI: 10.1002/chem.200400925. [Abstract][PDF]
325. "Efficient Syntheses of Fluorous Primary Phosphines that do not Require PH₃", Emnet, C.; Gladysz, J. A. Synthesis 2005, 1012-1018. DOI: 10.1055/s-2005-861815. [Abstract][PDF]
326. "Theoretical Study on the Spin State Energy Splittings and Local Spin in Cationic [Re]-C_n-[Re] Complexes", Herrmann, C.; Neugebauer, J.; Gladysz, J. A.; Reiher, M. Inorg. Chem. 2005, 44, 6174-6182. DOI: 10.1021/ic050240l. [Abstract][PDF]
327. (a) "'Catalyst-on-a-Tape' – Teflon: A New Delivery and Recovery Method for Homogeneous Fluorous Catalysts", Dinh, L. V.; Gladysz, J. A. Angew. Chem., Int. Ed. 2005, 44, 4095-4097. DOI: 10.1002/anie.200500237. [Abstract][PDF] (b) "'Katalysatoren am laufenden Band' – Teflon: Eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren", Dinh, L. V.; Gladysz, J. A. Angew. Chem., 2005, 26 4164-4167. DOI: 10.1002/ange.200500237. [Abstract][PDF]
328. "Synthesis and Reactivity of 1,2- and 1,3-Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis" Kromm, K.; Eichenseher, S.; Prommesberger, M.; Hampel, F.; Gladysz, J. A. Eur. J. Inorg. Chem. 2005, 2983-2998. DOI: 10.1002/ejic.200500254. [Abstract][PDF]
329. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Ligands and Metal Complexes", Tuba, R.; Tesevic, V.; Dinh, L. V.; Hampel, F.; Gladysz, J. A. Dalton Transactions 2005, 13, 2275-2283. DOI: 10.1039/B502309B [Abstract][PDF]
330. "A Synthetic Breakthrough into an Unanticipated Stability Regime: Readily Isolable Complexes in which C₁₆-C₂₈ Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Gladysz, J. A. J. Am. Chem. Soc. 2005, 127, 10508-10509. DOI: 10.1021/ja0534598. [Abstract][PDF]
331. "Convenient Modular Syntheses of Fluorous Secondary Phosphines and Selected Derivatives", Emnet, C.; Tuba, R.; Gladysz, J. A. Adv. Synth. Catal., 2005, 347, 1819-1826. DOI: 10.1002/adsc.200505145. [Abstract][PDF]
332. "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions", Friedlein, F. K.; Hampel, F.; Gladysz, J. A. Organometallics, 2005, 24, 4103-4105. DOI: 10.1021/om0504708. [Abstract][PDF]
333. "Fluorous Solvents: Physical Properties", Gladysz, J. A.; Emnet, C. in Green Reaction Media in Organic Synthesis, Mikami, K. Ed.; Blackwell, Oxford, UK, 2005, pp 62-80 (Ch 3.2). ISBN: 978-1-4051-3402-6. DOI: 10.1002/9780470988770.ch3 [Abstract][PDF]
334. "An Easily Accessed Class of Recyclable Hypervalent Iodide Reagents for Functional Group Oxidations: bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF₃(CF₂)_n-1I(OCOCF₃)₂", Tesevic, V.; Gladysz, J. A. Green Chem. 2005, 7, 833-836. DOI: 10.1039/b511951k. [Abstract][PDF]
335. "'Heavy Fluorous' Cyclopentadienes and Cyclopentadienyl Complexes with Three to Five Ponytails: Syntheses from Polybromocyclopentadienyl Complexes, Phase Properties, and Electronic Effects", Dinh, L. V.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 7211-7222. DOI: 10.1002/chem.200500595. [Abstract][PDF]
336. "Wire-Like PtC≡CC≡CC≡CC≡CPt Moieties Surrounded by Double-Helical 'Insulation': New Motifs Featuring P(CH₂)₂₀P and P(CH₂)₄O(CH₂)₂O(CH₂)₄P Linkages", de Quadras, L.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2006, 2929-2933. DOI: 10.1039/b604465b. [Abstract][PDF]
337. "π Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts", Dinh, L. V.; Consorti, C. S.; Emnet, C.; Gladysz, J. A. Organometallics 2006, 25, 1245-1251. DOI: 10.1021/om050950z. [Abstract][PDF]
338. "Gyroscope-Like Molecules Consisting of PdX₂/PtX₂ Rotators Encased in Three-Spoke Stators: Synthesis via Alkene Metathesis, and Facile Substitution and Demetallation", Nawara, A. J.; Shima, T.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2006, 128, 4962-4963. DOI: 10.1021/ja061044w. [Abstract][PDF]
339. "Fluorous Phase-Transfer Activation of Catalysts: Application of a New Rate-Enhancement Strategy to Alkene Metathesis", Corrêa da Costa, R. C.; Gladysz, J. A. Chem. Commun. 2006, 2619-2621. DOI: 10.1039/B602428A. [Abstract][PDF]
340. "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link in a Series of Square-Planar Platinum Complexes", Lewanzik, N.; Oeser, T.; Blümel, J.; Gladysz, J. A. J. Mol. Catal. A. 2006, 254, 20-28. (invited article, 16th International Symposium on Olefin Metathsis thematic issue) DOI: 10.1016/j.molcata.2005.10.047. [Abstract][PDF]
341. "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies", Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 5267-5281. DOI: 10.1002/chem.200501540. [Abstract][PDF]
342. (a) "Giant" Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25-27 Membered Macrocycles", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem., Int. Ed. Engl. 2006, 45, 4372-4375. DOI: 10.1002/anie.200601191. [Abstract][PDF] (b) "Gyroskop-Giganten": Dipolare Cl-Rh-CO-Roatoren, umgeben von Startoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen", Wang, L.; Hampel, F.; Gladysz, J. A. Angew. Chem. 2006, 118, 4479-4482. DOI: 10.1002/ange.200601191. [Abstract][PDF]
343. "Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Ponytails; New Candidates for Phase Transfer Catalysts and Ionic Liquids", Emnet, C.; Weber, K. M.; Vidal, J. A.; Consorti, C. S.; Stuart, A. M. Gladysz, J. A. Adv. Synth. Catal. 2006, 348, 1625-1634. (invited article, "multiphase catalysis, green solvents, and immobilization" issue) DOI: 10.1002/adsc.200606138. [Abstract][PDF]
344. "A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C₆, C₈, C₁₀, C₁₂, C₁₆, C₂₀, C₂₄, and C₂₈ Polyynediyl Chains Span Two Platinum Atoms", Zheng, Q.; Bohling, J. C.; Peters, T. B.; Frisch, A. C.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 6486-6505. DOI: 10.1002/chem.200600615. [Abstract][PDF]
345. "Oxidation of Secondary Alcohols to Ketones Using Easily Recyclable bis(trifluoroacetate) Adducts of Fluorous Alkyl Iodides, CF₃(CF₂)_n-1I(OCOCF₃)₂", Tesevic, V.; Gladysz, J. A.; J. Org. Chem. 2006, 71, 7433-7440. DOI: 10.1021/jo0612067. [Abstract][PDF]
346. "A Promising New Catalyst Family for Enantioselective [3+2] Cycloadditions of Allenes and Imines: Chiral Phosphines with a Transition Metal–CH₂–P: Linkage" Scherer, A.; Gladysz, J. A. Tetrahedron Lett. 2006, 47, 6335-6337. DOI: 10.1016/j.tetlet.2006.07.005. [Abstract][PDF]
347. "Fluorous to the Core", Gladysz, J. A. Science 2006, 313, 1249-1250. DOI: 10.1126/ science.1131944. [Abstract][PDF]
348. "Gyroscope-Like Molecules Consisting of Three-Spoke Stators that Enclose "Switchable" Neutral Dipolar Rhodium Rotators; Reversible Cycling between Faster and Slower Spinning Rh(CO)I and Rh(CO)₂I Species" Wang, L.; Shima, T.; Hampel, F.; Gladysz, J. A. Chem. Commun. 2006, 4075-4077. DOI: 10.1039/b606728j. [Abstract][PDF]
349. "Synthesis, Structure, and Reactivity of Fluorous Phosphorus/Carbon/Phosphorus Pincer Complexes Derived From P(CH₂)₅P Backbones", Consorti, C. S.; Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2006, 359, 4874-4884. DOI: 10.1016/j.ica.2006.07.092. [Abstract][PDF]
350. "Update 1 of: Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes", Szafert, S.; Gladysz, J. A. Chem. Rev. 2006, 106, PR1–PR33. (inaugural "Perennial Review") DOI: 10.1021/cr030041o. [Abstract][PDF]
351. "Crystal Structure of an Unusual bis(fluorous phosphine) Ruthenium(III) Complex Derived from a Fluorous Grubbs' Catalyst", Corrêa da Costa, R.; Hampel, F.; Gladysz, J. A. Polyhedron 2007, 26, 581-588. DOI: 10.1016/j.poly.206.08.015. [Abstract][PDF]
352. "Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)(CH₂PAr₂)", Seidel, F.; Gladysz, J. A. Synlett 2007, 6, 986-988. DOI: 10.1055/s-2007-973859. [Abstract][PDF]
353. "Synthesis and Reactivity of Analogues of Grubbs' Second Generation Methathesis Catalyst with Fluorous Phosphines: A New Phase-Transfer Strategy for Catalyst Activation", Corrêa da Costa, R.; Gladysz, J. A. Adv. Synth. Catal. 2007, 349, 243-254. (invited article, olefin metathesis thematic issue) DOI: 10.1002 /adsc.200600461. [Abstract][PDF]
354. "Monophosphine and Diphosphine Ligands for Diplatinum Polyyendiyl Complexes: Efficient Syntheses of New Functionality-Containing Systems and Model Compounds", de Quadras, L.; Stahl,J.; Zhuravlev, F.; Gladysz, J. A. J. Organomet. Chem. 2007, 692, 1859-1870. DOI: 10.1016/J.JORGANCHEM.2006.12.023. [Abstract][PDF]
355. "Gyroscopes and the Chemical Literature: 1852-2002" Skopek, K.; Hershberger, M. C.; Gladysz, J. A. Coord. Chem. 2007, Coord. Chem. Rev. 2007, 251, 1723-1733. (invited article, 37th ICCC thematic issue) DOI:10.1016/j.ccr.2006.12.015 [Abstract][PDF]
356. "Temperature Controlled Catalyst Recycling: New Protocols based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid-Liquid Phase Separations", Tesevic, V.; Gladysz, J. A. Topics in Organometallic Chemistry 2008, 23, 67-89. (published on the web in 2006) DOI: 10.1007/3418_043. [Abstract][PDF]
357. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Coordination-Driven Self Assembly of Wirelike Pt(C≡C)_nPt Moieties That Are Spanned by Two P(CH₂)_mP Linkages", Stahl, J.; Mohr, W.; de Quadras, L.; Peters, T. B.; Bohling, J. C.; Martín-Alvarez, J. M.; Owen, G. R.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8282-8295. DOI: 10.1021/ja0716103. [Abstract][PDF]
358. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Directed Syntheses of Wirelike Pt(C≡C)_nPt Moieties That Are Spanned by Two P(CH₂)_mP Linkages via Alkene Metathesis", de Quadras, L.; Bauer, E. B.; Mohr, W.; Bohling, J. C.; Peters, T. B.; Martín-Alvarez, J. M.; Hampel, F.; Gladysz, J. A. J. Am. Chem. Soc. 2007, 129, 8296-8309. DOI: 10.1021/ja071612n. [Abstract][PDF]
359. "Ionic Chemistry in Extremely Nonpolar Fluorous Media: Phase Transfer Catalysis of Halide Substitution Reactions", Consorti, C. S.; Jurisch, M.; Gladysz, J. A. Org. Lett. 2007, 9, 2309-2312. DOI: 10.1021/ol0706354. [Abstract][PDF]
360. "Octahedral Gyroscope-Like Molecules with M(CO)₃(X) Rotators Encased in Three-Spoked Diphosphine Stators: Syntheses by Alkene Metathesis/Hydrogenation Sequences, Structures, Dynamic Properties, and Reactivities", Hess, G. D.; Hampel, F.; Gladysz, J. A. Organometallics 2007, 26, 5129-5131. DOI: 10.1021/om700625u. [Abstract][PDF]
361. "sp Carbon Chains Surrounded by sp³ Carbon Double Helices: Wire-Like Pt(C≡C)_nPt Moieties that are Spanned by two α,ω-Diphosphines that Bear Heteroatoms or Alkyl Substituents", de Quadras, L.; Bauer, E. B.; Stahl, J.; Zhuravlev, F.; Hampel, F.; Gladysz, J. A. New. J. Chem. 2007, 31, 1594-1604. DOI: 10.1039/b708690n. [Abstract][PDF]
362. "Chiral Phosphorus Donor Ligands Containing Monocyclopentadienyl Metal Fragments", Castillo, D. A.; Gladysz, J. A. in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Börner, A. Ed; Wiley/VCH, Weinheim, 2008, 408-437. DOI: 10.1002/chin.200942263.
363. "Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity", Boswell, P. G.; Szíjjáró, C.; Jurisch, M.; Gladysz, J. A.; Rábai, J.; Bühlmann, P. Anal. Chem. 2008, 80, 2084-2090. DOI: 10.1021/ac702161c. [Abstract][PDF]
364. "Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains", Farley, R.; Zheng, Q.; Gladysz, J. A.; Schanze, K. S. Inorg. Chem. 2008, 47, 2955-2963. DOI: 10.1021/ic701220t. [Abstract][PDF]
365. "Syntheses of Gyroscope-Like Molecules via Three-Fold Ring Closing Metatheses of bis(Phosphine) Complexes trans-L_yM(P((CH₂)_nCH=CH₂)₃)₂, and Extensions to bis(Phosphite) Complexes trans-Fe(CO)₃(P(O(CH₂)_nCH=CH₂)₃)₂", Skopek, K.; Gladysz, J. A. J. Organomet. Chem. 2008, 693, 857-866. (invited article, "Frontiers in Organometallic Chemistry" thematic issue) DOI: 10.1016/J.JORGANCHEM.2007.11.001. [Abstract][PDF]
366. "Thermomorphic Fluorous Palladacycles", Gladysz, J. A. in Palladacycles, Dupont, J.; Pfeffer, M. Eds; Wiley/VCH, Weinheim, 2008, 341-359. DOI:10.1002/ 9783527623211.ch14. [Abstract][PDF]
367. "Coordination-Driven Self Assembly, Structures, and Dynamic Properties of Diplatinum Hexatriynediyl and Butadiynediyl Complexes in which the sp Carbon Chains are Shielded by sp³ Carbon Chains: Towards Endgroup-Endgroup Interactions", Owen, G. R.; Stahl, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 73-87. DOI: 10.1002/ chem.200701268. [Abstract][PDF]
368. "Synthesis of Fluorous Sulfur/Carbon/Sulfur Pincer Ligands and Palladium Complexes; New Catalyst Precursors for the Heck Reaction", Corrêa da Costa, R.; Jurisch, M.; Gladysz, J. A. Inorg. Chim. Acta 2008, 361, 3205-3214. (invited article, issue in honor of Robert Angelici) DOI: 10.1016/j.ica.2007.11.016. [Abstract][PDF]
369. "En Route to Diplatinum Polyynediyl Complexes trans,trans-(Ar)(R₃P)₂Pt(C≡C)_nPt(PR₃)₂(Ar): Untold Tales, Including End-Group Strategies", Stahl, J.; Bohling, J. C.; Peters, T. B.; de Quadras, L.; Gladysz, J. A. Pure Appl. Chem. 2008, 80, 459-474. (invited article, ISNA-12 thematic issue) DOI: 10.1351/pac200880030459. [Abstract][PDF]
370. "Three-Fold Intramolecular Ring-Closing Metatheses Involving Square Planar Platinum Complexes with cis Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute Like Complexes", Skopek, K.; Barbasiewicz, M.; Hampel, F.; Gladysz, J. A. Inorg. Chem. 2008, 47, 3474-3476. DOI: 10.1021/ic702391m. [Abstract][PDF]
371. "Synthesis and Reactivity of New Heterodinuclear Iron/Rhenium C_x Complexes of the Formula (η⁵-C₅Me₅)Re(NO)(PPh₃)(C≡C)_n(η²-dppe)Fe(η⁵-C₅Me₅) (n = 3, 4); Redox Properties and a Dicobalt Hexacarbonyl Adduct", Szafert, S.; Paul, F.; Meyer, W. E.; Gladysz, J. A.; Lapinte, C. C. R. Chimie 2008, 11, 693-701. (invited article, Gecom-Concoord thematic issue) DOI:10.1016/j.crci.2007.10.009. [Abstract][PDF]
372. "Phase Transfer of Enantiopure Werner Cations into Organic Solvents; An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis", Ganzmann, C.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 5397-5400. DOI: 10.1002/chem.200800226. [Abstract][PDF]
373. "Syntheses, Structures, and Electronic Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C₆F₅)(R₃P)₂Pt, (p-tol)(R₃P)₂Pt, and (Ph₃P)Au End-Groups", de Quadras, L.; Shelton, A. H.; Kuhn, H.; Hampel, F.; Schanze, K. S.; Gladysz, J. A. Organometallics 2008, 27, 4979-4991. DOI: 10.1021/om800493x. [Abstract][PDF]
374. "Ionic Transformations in Extremely Nonpolar Fluorous Media: Easily Recoverable Phase Transfer Catalysts for Halide Substitution Reactions", Mandal, D.; Jurisch, M.; Consorti, C. S.; Gladysz, J. A. Chem. Asian J. 2008, 3, 1772-1782. DOI: 10.1002/asia.200800138. [Abstract][PDF]
375. "Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains", Samoc, M.; Dalton, G. T.; Gladysz, J. A.; Zheng, Q.; Yelkov, Y.; Ågren, H.; Norman, P.; Humphrey, M. G. Inorg. Chem. 2008, 47, 9946-9957. DOI: 10.1021/ic801145c. [Abstract][PDF]
376. "Catalysis of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Proctocols Involving Precipitation, Teflon® Tape and Gore-Rastex® Fiber", Seidel, F. O.; Gladysz, J. A. Adv. Synth. Catal. 2008, 350, 2443-2449. DOI: 10.1002/adsc.200800403. [Abstract][PDF]
377. "Syntheses, Structures, and Dynamic Properties of Dicobalt π Complexes of Diplatinum Polyynediyl Complexes", Kuhn, H.; Hampel, F.; Gladysz, J. A. Organometallics 2009, 28, 4979-4987. DOI: 10.1021/om9005017. [Abstract][PDF]
378. "Synthesis and Reactivity of Fluorous and non-Fluorous Aryl and Alkyl Iodine(III) Dichlorides: New Chlorinating Reagents that are Easily Recycled using Biphasic Protocols", Podgoršek, A.; Jurisch, M.; Stavber, S.; Zupan, M.; Iskra, J.; Gladysz, J. A. J. Org. Chem. 2009, 74, 3133-3140. DOI: 10.1021/jo900233h. [Abstract][PDF]
379. "'Click' Chemistry in Metal Coordination Spheres: Copper(I) Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C₆F₅)(p-tol₃P)₂Pt(C≡C)_nH (n = 2-6)", Gauthier, S.; Weisbach, N.; Gladysz, J. A Organometallics 2009, 28, 5597-5599. DOI: 10.1021/om900680q. [Abstract][PDF]
380. "Catalysis Involving Fluorous Phases: Fundamentals and Directions for Greener Methodologies", Gladysz, J. A. in Handbook of Green Chemistry, Anastas, P.; Crabtree, R. H. Eds; Volume 1: Homogeneous Catalysis; Crabtree, R. H. Volume Ed; Wiley/VCH, Weinheim, 2009, 17-38. ISBN: 9783527324965 3527324968.
381. "The Experimental Assay of Catalyst Recovery: General Concepts", Gladysz, J. A. in Recoverable and Recyclable Catalysts, Benanglia, M. Ed; Wiley-Blackwell, Oxford, England, 2009, pp. 1-22. ISBN: 978-0470681954.
382. "Syntheses and Structural Analyses of Chiral Rhenium Containing Amines of the Formula (η⁵-C₅H₅)Re(NO)(PPh₃)((CH₂)_nNRR') (n = 0, 1)", Seidel, S. N.; Prommesberger, M.; Eichenseher, S.; Meyer, O. Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2010, 363, 533-548. (invited article, issue in honor of Paul Pregosin) DOI:10.1016/j.ica.2009.03.047. [Abstract][PDF]
383. "Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents", Mandal, D.; Gladysz, J. A. Tetrahedron 2010, 66, 1070-1077. DOI: 10.1016/j.tet.2009.11.012. [Abstract][PDF]
384. "Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Nawara-Hultzsch, A. J.; Skopek, K.; Shima, T.; Barbasiewicz, M.; Hess, G. D.; Skaper, D.; Gladysz, J. A. Z. Naturforsch. B.. 2010, 65, 414-424. (invited article, issue in honor of Rolf Saalfrank) DOI: 10.1515/ZNB-2010-0327 [Abstract] [PDF]
385. "Molecular Wires in Single Molecule Junctions: Charge Transport and Vibrational Excitations", Ballmann, S.; Hieringer, W.; Secker, D.; Zheng, Q.; Gladysz, J. A.; Görling, A.; Weber, H. B. ChemPhysChem 2010, 11, 2256-2260. DOI: 10.1002/cphc.200900974. [Abstract][PDF]
386. "Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes", Chen, L. D.; Mandal, D.; Gladysz, J. A.; Bühlmann, P. New. J. Chem. 2010, 34, 1867-1874. DOI: 10.1039/B9NJ00696F. [Abstract][PDF]
387. "Towards Multistranded Molecular Wires: Syntheses, Structures, and Reactivities of Tetraplatinum bis(Polyynediyl) Complexes with Pt-C_x-Pt-(P(CH₂)₃P)₂-Pt-C_x-Pt-(P(CH₂)₃P)₂ Cores (x = 4, 6, 8)", Owen, G. R.; Gauthier, S.; Weisbach, N.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Dalton Trans. 2010, 5260-5271. DOI: 10.1039/c002041a. [Abstract][PDF]
388. "Square Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH=CH₂ Substituents; Two- and Three-Fold Intramolecular Ring Closing Metatheses", Han, J.; Deng, C.; Fang, R.; Zhao, D.; Wang, L.; Gladysz, J. A. Organometallics 2010, 29, 3231-3234. DOI: 10.1021/om100536g. [Abstract][PDF]
389. "Thermomorphic Fluorous Phosphines as Organocatalysts for Michael Addition Reactions", Gimbert, C.; Vallribera, A.; Gladysz, J. A.; Jurisch, M. Tetrahedron Lett. 2010, 51, 4662-4665. DOI: 10.1016/j.tetlet.2010.06.136. [Abstract][PDF]
390. "New C₁-Symmetric Ph₂C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Polypropylene Polymerization: Synthetic Approach via Activated Fulvenes" Kirillov, E.; Marquet, N.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics 2010, 29, 5073-5082. (invited article, issue in honor of Dietmar Seyferth) DOI: 10.1021/om100289y. [Abstract][PDF]
391. "Highly Selective Detection of Silver in the Low ppt Range with Ion-Selective Electrodes Based on Ionophore-Doped Fluorous Membranes", Lai, C.-Z.; Fierke, M. A.; Corrêa da Costa, R.; Gladysz, J. A.; Stein, A.; Bühlmann, P. Anal. Chem. 2010, 82, 7634-7640. DOI: 10.1021/ac1013767. [Abstract][PDF]
392. "The Future of Organometallic Chemistry", Gladysz, J. A. Organometallics 2011, 30, 1-4. DOI: 10.1021/om1011215. [Abstract][PDF]
393. "Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R¹R²C)-(3,6-tBu₂Flu)(3-R₃-5-Me-C₅H₂)}MCl₂: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization", Kirillov, E.; Marquet, N.; Bader, M.; Razavi, A.; Belia, V.; Hampel, F.; Roisnel, T.; Gladysz, J. A.; Carpentier, J.-F. Organometallics, 2011, 30, 263-272. DOI: 10.1021/om100897j. [Abstract][PDF]
394. (a) "Dibridgehead Diphosphines that Turn Themselves Inside-Out", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2011, 50, 6647-6651. DOI: 10.1002/ange.201100893. [Abstract][PDF] (b) "Dreifach-verbrückte Diphosphine mit von innen nach außen invertierender Konfiguration", Stollenz, M.; Barbasiewicz, M.; Nawara-Hultzsch, A. J.; Fiedler, T.; Laddusaw, R. M.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem. 2011, 123, 6777-6781. DOI: 10.1002/ange.201100893. [Abstract][PDF]
395. "Analogs of Grubbs' Second Generation Catalyst with Hydrophilic Phosphine Ligands: Phase Transfer Activation of Ring Closing Alkene Metathesis", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Org. Lett. 2011, 13, 6188-6191. DOI: 10.1021/ol202548q. [Abstract][PDF]
396. "Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines that can turn themselves Inside-Out", Stollenz, M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2011, 30, 6510-6513. DOI: 10.1021/om200924g. [Abstract][PDF]
397. "Potentiometric Sensors Based on Fluorous Membranes Doped with Highly Selective Ionophores for Carbonate", Chen, L. D.; Mandal, D.; Pozzi, G.; Gladysz, J. A.; Bühlmann, P. J. Am. Chem. Soc. 2011, 133, 20869-20877. DOI: 10.1021/ja207680e. [Abstract][PDF]
398. "Organometallics Roundtable 2011", Gladysz, J. A.; Ball, Z. T.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Manners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam, V. W.-W. Organometallics 2012, 31, 1-18. DOI: 10.1021/om201234x. [Abstract][PDF]
399. "Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts", Hilliard, C. R.; Gladysz, J. A.; Blümel, J. Dalton. Trans. 2012, 41, 1742-1754. DOI: 10.1039/c1dt11863c. [Abstract][PDF]
400. "Phase Transfer Activation of Fluorous Analogs of Grubbs' Second Generation Catalyst: Ring Opening Metathesis Polymerization", Tuba, R.; Corrêa da Costa, R.; Bazzi, H. S.; Gladysz, J. A. ACS Catalysis 2012, 2, 155-162. DOI: 10.1021/cs200487j. [Abstract][PDF]
401. "Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands", Zeits, P. D.; Rachiero, G. P.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2012, 31, 2854-2877. [Abstract][PDF]
402. "Structural, Physical, and Chemical Properties of Fluorous Compounds", Gladysz, J. A.; Jurisch, M. Top. Curr. Chem. 2012, 308, 1-24. [PDF]
403. "A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated polyyne", Weisbach, N.; Baranová, Z.; Gauthier, S.; Reibenspies, J. H.; Gladysz, J. A. Chem. Commun. 2012, 48, 7562-7564. DOI: 10.1039/C2CC33321J. [Abstract][PDF]
404. "Ring opening metathesis polymerization of an η⁴-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments", Zeits, P. D.; Fiedler, T.; Gladysz, J. A. Chem. Commun. 2012, 48, 7925-7927. DOI: 10.1039/C2CC32150E. [Abstract][PDF]
405. "The Crystal Structure of an Analog of Grubbs' Second Generation Catalyst with a Fluorous Phosphine", Tuba, R.; Brothers, E. N.; Reibenspies, J. H.; Bazzi, H. S.; Gladysz, J. A. Inorg. Chem. 2012, 51, 9943-9949. DOI: 10.1021/ic301434g. [Abstract][PDF]
406. "Toward Permetalated Alkyne/Azide 3+2 or 'Click' Cycloadducts", Clough, M. C.; Zeits, P. D. Bhuvanesh, N.; Gladysz, J. A. Organometallics 2012, 31, 5231-5234. DOI: 10.1021/om300542a. [Abstract][PDF]
407. "Fluorous Membrane Ion-Selective Electrodes for Perfluorinated Surfactants: Trace Level Detection and In-Situ Monitoring of Absorption", Chen, L. D.; Lai, C.-Z.; Granda, L. P.; Fierke, M. A.; Mandal, D.; Stein, A.; Gladysz, J. A.; Bühlmann, P. Anal. Chem. 2013, 85, 7471-7477. DOI: 10.1021/ac401424j. [Abstract][PDF]
408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Guerrero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u. [Abstract][PDF]
409. "A Metal-capped Conjugated Polyyne Threaded Through a Phenanthroline-based Macrocycle. Probing Beyond the Mechanical Bond to Interactions in Interlocked Molecular Architectures", Sahnoune, H.; Baranová, Z.; Bhuvanesh, N.; Gladysz, J. A.; Halet, J.-F. Organometallics, 2013, 32, 6360-6367. DOI: 10.1021om400709q. [Abstract][PDF]
410. "Multifold Ring Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities", Fiedler, T.; Gladysz, J. A. in Olefin Metathesis – Theory and Practice, Grela, K., Ed.; John Wiley & Sons, Hoboken, New Jersey, 2014, 311-328. ISBN: 978-1-118-20794-9.
411. "Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladium Catalyzed Suzuki Cross-Coupling Reactions", Sierra Castro, D.; Bhuvanesh, N.; Reibenspeis, J. H.; Gladysz, J. A.; Klahn, A. H. J. Organomet. Chem. 2014, 749, 416-420. DOI: 10.1016/j.jorganchem.2013.10.029. [Abstract][PDF]
412. "Gyroscope Like Molecules Consisting of PdX₂/PtX₂ Rotators Within Three-Spoke Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Nawara-Hultzsch, A. J.; Stollenz, M.; Barbasiewicz, M.; Szafert, S.; Lis, T.; Hampel, F.; Bhuvanesh, N.; Gladysz, J. A. Chem. Eur. J. 2014, 20, 4617-4637. DOI: 10.1002/chem.201304419 [Abstract][PDF]
413. "Highly Active Families of Catalysts for the Ring Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole", Thomas, C.; Gladysz, J. A. ACS Catalysis 2014, 4, 1134-1138. DOI: 10.1021/cs500134z. ("ACS Editor's Choice" article for 14 March 2014: [Link]) [Abstract][PDF]
414. "Photophysics of Platinum Tetrayne Oligomers: Delocalization of Triplet Exciton", Li, Y.; Winkel, R. W.; Weisbach, N.; Gladysz, J. A.; Schanze, K. S. J. Phys. Chem. A. 2014, 115, 10333-10339. DOI: 10.1021/jp5021388. [Abstract][PDF]
415. "Organometallics Roundtable 2013-2014", Gladysz, J. A.; Bedford, R. B.; Fujita, M.; Gabbaï, F. P.; Goldberg, K. I.; Holland, P. L.; Kiplinger, J. L.; Krische, M. J.; Louie, J.; Lu, C. C.; Norton, J. R.; Petrukhina, M. A.; Ren, T.; Stahl, S. S.; Tilley, T. D.; Webster, C. E.; White, M. C.; Whiteker, G. T. Organometallics 2014, 33, 1505-1527. DOI: 10.1021/om500253z. [Abstract][PDF]
416. "Synthesis, Photovoltaic Perfomances, and TD-DFT Modeling of Push-Pull Diacetylide Platinum Complexes in TiO₂ Based Dye-Sensitized Solar Cells", Gauthier, S.; Caro, B.; Robin-Le Guen, F.; Bhuvanesh, N.; Gladysz, J. A.; Wojcik, L.; Le Poul, N.; Planchat, A.; Pellegrin, Y.; Blart, E.; Jacquemin, D.; Odobel, F. Dalton Trans. 2014, 43, 11233-11242. DOI:10.1039/C4DT00301B [Abstract][PDF]
417. "Metal Templated Hydrogen Bond Donors as 'Organocatalysts' for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes", Scherer, A.; Mukherjee, T.; Hampel, F.; Gladysz, J. A. Organometallics 2014, 33, 6709-6722. DOI:10.1021/om500704u. [Abstract][PDF]
418. "Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions", Mukherjee, T.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6723-6737. DOI:10.1021/om500705s. [Abstract][PDF]
419. "Liquid/Solid Phase Transfer Activation of Grubbs-Type Alkene Metathesis Catalysts; Application of Silver Salts of Sulfonated Polystyrene", Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Catal. Sci. Technol. 2014, 4, 4178-4182. DOI:10.1039/c4cy01021c. [Abstract][PDF]
420. "Structures and Unexpected Dynamic Properties of Phosphine Oxides Adsorbed on Silica Surfaces", Hilliard, C. R.; Kharel, S.; Cluff, K. J.; Bhuvanesh, N.; Gladysz, J. A.; Blümel, J. Chem. Eur. J. 2014, 20, 17292-17295. DOI: 10.1002/chem.201404880. [Abstract][PDF]
421. "Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles", Baranová, Z.; Amini, H.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6746-6749. DOI:10.1021/om501026u. [Abstract][PDF]
422. "An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2-Substituted Benzimidazoles", Gladysz, J. A.; Safaei, H. R.; Nouri, S. Helv. Chim. Acta 2014, 97, 1539-1545. DOI: 10.1002/hlca.201400033. [Abstract] [PDF]
423. "Fluorous Chemistry Meets Green Chemistry: A Concise Primer", Mukherjee, T.; Gladysz, J. A. Aldrichimica Acta, 2015, 48, 25-28. [PDF]
424. "Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis", Lewis, K. G.; Ghosh, S. K.; Bhuvanesh, N.; Gladysz, J. A. ACS Cent. Sci., 2015, 1, 50-56. DOI:10.1021/acscentsci.5b00035. [Abstract] [PDF]
425. "Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH₂)_mCH=CH₂)₃", Lang, G. M.; Skaper, D.; Shima, T.; Otto, M.; Wang, L.; Gladysz, J. A. Aust. J. Chem. 2015, 68, 1342-1351. DOI: 10.1071/CH15178. (invited contribution, issue commemorating the 2014 RACI National Congress) [Abstract] [PDF]
426. "Phase and Redox Shifted Four Iron/Four Sulfur Clusters; Fluorous Analogs of Metalloensyme Cofactors", Zhang, C.-P.; Xi, Z.; Mueller, K. M.; Holliday, B. J.; Bazzi, H. S.; Gladysz, J. A. Dalton Trans. 2015, 44, 19615-19624. DOI:10.1039/C5DT01959A [Abstract] [PDF]
427. "Steric Control of the in/out Sense of Bridgehead Substituents in Macrobicyclic Compounds: Isolation of New "Crossed Chain" Variants of in/out Isomers", Stollenz, M.; Taher, D.; Bhuvanesh, N.; Reibenspies, J. H.; Baranová, Z.; Gladysz, J. A. Chem. Commun. 2015, 51, 16053-16056. DOI: 10.1039/c5cc05620a. [Abstract] [PDF]
428. "Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands", Xi, Z.; Bazzi, H.S.; Gladysz, J. A. J. Am. Chem. Soc. 2015, 137, 10930-10933. DOI:10.1021/jacs.5b06562 [Abstract] [PDF]
429. "Substitution and Catalytic Chemistry of Gyroscope Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands", Estrada, A. L.; Jia, T.; Bhuvanesh, N.; Blümel, J.; Gladysz, J. A. Eur. J. Inorg. Chem.. 2015 2015 5318-5321. DOI:10.1002/ejic.201500953 [Abstract] [PDF]
430. "Phase Transfer Activation of Transition Metal Catalysts", Tuba, R.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. Chem. Eur. J. 2015, 21, 15894-15906. DOI:10.1002/chem.201502403. [Abstract] [PDF]
431. "Synthesis of a Series of ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands for use in Enantioselective Catalysis", Ghosh, S. K.; Ganzmann, C.; Gladysz, J. A. Tetrahedron: Asymmetry 2015, 26, 1273-1280. DOI:10.1016/j.tetasy.2015.09.012 [Abstract] [PDF]
432. "An Analogue of Grubbs' Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis", Balogh, J.; Hlil, A. R.; Su, H.-L.; Xi, Z.; Bazzi, H. S.; Gladysz, J. A. ChemCatChem. 2016, 8, 125-128. DOI: 10.1002/cctc.201500913 [Abstract] [PDF]
433. "A Phase Based Approach to Insulated Molecular Wires: Diplatinum Octatetraynediyl Complexes Bearing Fluorous Trialkylphosphine Ligands", Clough, M. C.; Fiedler, T.; Bhuvanesh, N.; Gladysz, J. A. J. Organomet. Chem. 2016, 812, 34-42. DOI:10.1016/j.jorganchem.2015.09.020. (invited contribution, special issue dedicated to Jack Lewis) [Abstract] [PDF]
434. (a) "Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen Bond Donor Catalysts for Highly Enantioselective Michael Additions", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2016, 55, 4356-4360. DOI: 10.1002/anie.201511314. [Abstract][PDF] (b) "Werner-Komplexe mit ω-dimethylaminoalkylsubstitutierten Ethylenediamin-liganden: Bifunktionale Wasserstoffbrückenbindungsdonor-Katalysatoren für hochgradig enantioselektive Michael Additionen", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., 2016, 128, 4429-4433. DOI: 10.1002/ange.201511314. [Abstract][PDF]
435. "Gyroscope Like Molecules Consisting of Trigonal or Square Planar Osmium Rotators Within Three-Spoked Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties", Fiedler, T.; Bhuvanesh, N.; Hampel, F.; Reibenspies, J. H.; Gladysz, J. A. Dalton Trans. 2016, 45, 7131-7147. DOI:10.1039/c6dt00692b [Abstract] [PDF]
436. " Tris(1,2-diphenylethylenediamine) Cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds", Kumar, A.; Ghosh, S. K.; Gladysz, J. A. Org. Lett. 2016, 18, 760-763. DOI:10.1021/acs.orglett.6b00023 [Abstract] [PDF]
437. " Gyroscope Like Complexes based upon Dibridgehead Diphosphine Cages that are Accessed by Three Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)₃, Fe(CO)₂(NO)⁺ and Fe(CO)₃(H)⁺ Rotators", Lang, G. M.; Shima, T.; Wang, L.; Cluff, K. J.; Skopek, K.; Hampel, F.; Blümel, J.; Gladysz, J. A. J. Am. Chem. Soc. 2016, 138, 7649-7663. DOI:10.1021/jacs.6b03178 [Abstract] [PDF]
438. "Octahedral Werner Complexes with Substituted Ethylenediamine Ligands: A Stereochemical Primer for a Historic Series of Compounds now Emerging as a Modern Family of Catalysts", Ehnbom, A.; Ghosh, S. K.; Lewis, K. G.; Gladysz, J. A. Chem. Soc. Rev. 2016, 45, 6799-6811. DOI:10.1039/c6cs00604c [Abstract] [PDF]
439. "Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR", Fiedler, T.; Chen, L.; Wagner, N. D.; Russell, D. R.; Gladysz, J. A. Organometallics 2016, 35, 2071-2075. DOI:10.1021/acs.organomet.6b00249 [Abstract] [PDF]
440. " Convenient Protocols for Mizoroki-Heck Reactions of Aromatic Bromides and Polybromides with Fluorous Alkenes of the Formula H₂C=CH(CF₂)_n–1CF₃ (n = 8, 10)", Su, H.-L.; Balogh, J.; Al-Hashimi, M.; Seapy, D. G.; Bazzi, H. S.; Gladysz, J. A. Org. Biomol. Chem. 2016, 10058-10069. DOI:10.1039/c6ob01980c. [Abstract] [PDF]
441. "Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Carbonyl Complexes based upon Dibridgehead Diarsine Cages", Lang, G. M.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Organometallics 2016, 35, 2873-2889. DOI: 10.1021/acs.organomet.6b00447. [Abstract] [PDF]
442. "Synthesis, Reactivity, Structures, and Dynamic Properties of Gyroscope Like Iron Complexes with Dibridgehead Diphosphine Cages: Pre- vs. Post-Metathesis Substitutions as Routes to Adducts with Neutral Dipolar Fe(CO)(NO)(X) Rotors", Lang, G. M.; Skaper, D.; Hampel, F.; Gladysz, J. A. Dalton Trans. 2016, 45, 16190-16204. DOI: 10.1039/c6dt03258c. [Abstract] [PDF]
443. "Mono- and Disubstitution Reactions of Gyroscope Like Complexes Derived from Cl-Pt-Cl Rotators within Cage Like Dibridgehead Diphosphine Ligands", Taher, D.; Nawara-Hultzsch, A. J.; Bhuvanesh, N.; Hampel, F.; Gladysz, J. A. J. Organomet. Chem. 2016, 821, 136-141. DOI: 10.1016/j.jorganchem.2016.03.022. (invited contribution, special issue dedicated to Heinrich Lang) [Abstract] [PDF]
444. "A Quest for Atropisomerism in Cojoined Square Planar Metal Complexes: Syntheses and Structures of Sterically Congested Diplatinum Ethynediyl Adducts", Zhang, T.; Bhuvanesh, N.; Gladysz, J. A. Eur. J. Inorg. Chem. 2017, 2017, 1017-1025. DOI: 10.1002/ejic.201601307. [Abstract] [PDF]
445. "Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 1,7-Dihydroxynaphthalene", Baranová, Z.; Amini, H.; Neupane, H.; Garrett, S. C.; Ehnbom, A.; Bhuvanesh, N.; Reibenspies, J. H.; Gladysz, J. A. Aust. J. Chem. 2017, 70, 373-386. DOI: 10.1071/CH16587 (invited contribution, special issue, Heron Island Conference on Reactive Intermediates) [Abstract] [PDF]
446. "Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl₂ Species (M = Pt, Pd, Ni)", 2016, Kharel, S.; Joshi, H.; Bierschenk, S.; Stollenz, M.; Taher, D.; Bhuvanesh, N.; Gladysz, J. A. J. Am. Chem. Soc. 2017, 139, 2172-2175. DOI: 10.1021/jacs.6b12788. [Abstract] [PDF]
447. "Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts derived from Trications of the Formula [Co(NH₂CHArCHArNH₂)₃]³⁺", Ghosh, S. K.; Lewis, K. G.; Kumar, A.; Gladysz, J. A. Inorg. Chem. 2017, 56, 2304-2320. DOI: 10.1021/acs.inorg chem.6b03042. [Abstract] [PDF]
448. (a) "Gigging Benzene", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem., Int. Ed. 2017, 58, 5664-5666. DOI: 10.1002/anie.201702942. [Abstract] [PDF] (b) "Vom Aufspießen des Benzols", Luu, Q.; Fiedler, T.; Gladysz. J. A. Angew. Chem. 2017, 129, 5756–5758. DOI: 10.1002/ange.201702942. [Abstract] [PDF]

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