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All Publications -- Publications by Area

Publications by Area


Fluorous   |   Gyroscopes   |   Molecular Wires   |   Werner Complexes



High Activity and Enantioselectivty Using Werner-type Complexes

372. "Phase Transfer of Enantiopure Werner Cations into Organic Solvents; An Overlooked Family of Chiral Hydrogen Bond Donors for Enantioselective Catalysis", Ganzmann, C.; Gladysz, J. A. Chem. Eur. J. 2008, 14, 5397-5400. DOI: 10.1002/chem.200800226. [Abstract]

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408. "New Media for Classical Coordination Chemistry: Phase Transfer of Werner and Related Polycations into Highly Nonpolar Fluorous Solvents", Ghosh, S. K.; Ojeda, A. S.; Guerrero-Leal, J.; Bhuvanesh, N.; Gladysz, J. A. Inorg. Chem. 2013, 52, 9369-9378. DOI: 10.1021/ic400945u. [Abstract]

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413. "Highly Active Families of Catalysts for the Ring Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimida­zole", Thomas, C.; Gladysz, J. A. ACS Catalysis 2014, 4, 1134-1138. DOI: 10.1021/cs500134z. ("ACS Editor's Choice" article for 14 March 2014: [Link]) [Abstract]

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417. "Metal Templated Hydrogen Bond Donors as 'Organocatalysts' for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes", Scherer, A.; Mukherjee, T.; Hampel, F.; Gladysz, J. A. Organometallics 2014, 33, 6709-6722. DOI:10.1021/om500704u. [Abstract]

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418. "Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions", Mukherjee, T.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2014, 33, 6723-6737. DOI:10.1021/om­500705s. [Abstract]

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424. "Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis", Lewis, K. G.; Ghosh, S. K.; Bhuvanesh, N.; Gladysz, J. A. ACS Cent. Sci., 2015, 1, 50-56. DOI:10.1021/acscentsci.5b00035. [Abstract]

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431. "Synthesis of a Series of ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands for use in Enantioselective Catalysis", Ghosh, S. K.; Ganzmann, C.; Gladysz, J. A. Tetrahedron: Asymmetry 2015, 26, 1273-1280. DOI:10.1016/j.tetasy.2015.09.012 [Abstract]

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434. (a) "Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen Bond Donor Catalysts for Highly Enantioselective Michael Additions", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., Int. Ed. 2016, 55, 4356-4360. DOI: 10.1002/anie.201511314. [Abstract]

(b) "Werner-Komplexe mit ω-dimethylaminoalkylsubstitutierten Ethylenediamin-liganden: Bifunktionale Wasserstoffbrückenbindungsdonor-Katalysatoren für hochgradig enantioselektive Michael Additionen", Ghosh, S. K.; Ganzmann, C.; Bhuvanesh, N.; Gladysz, J. A. Angew. Chem., 2016, 128, 4429-4433. DOI: 10.1002/ange.201511314. [Abstract]

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436. " Tris(1,2-diphenylethylenediamine) Cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds", Kumar, A.; Ghosh, S. K.; Gladysz, J. A. Org. Lett. 2016, 18, 760-763. DOI:10.1021/acs.orglett.6b00023 [Abstract]

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438. "Octahedral Werner Complexes with Substituted Ethylenediamine Ligands: A Stereochemical Primer for a Historic Series of Compounds now Emerging as a Modern Family of Catalysts", Ehnbom, A.; Ghosh, S. K.; Lewis, K. G.; Gladysz, J. A. Chem. Soc. Rev. 2016, 45, 6799-6811. DOI:10.1039/c6cs00604c [Abstract]

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447. "Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3+", Ghosh, S. K.; Lewis, K. G.; Kumar, A.; Gladysz, J. A. Inorg. Chem. 2017, 56, 2304-2320. DOI: 10.1021/acs.inorg chem.6b03042. [Abstract]

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449. "Enantioselective Additions of Stabilized Carbanions to Imines Generated from α-Amido Sulfones by Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt (III) Trications as Hydrogen Bond Donor Catalysts", Joshi, H.; Ghosh, S. K.; Gladysz, J. A. Synthesis 2017, 3905-3915. DOI: 10.1055/s-0036-1590502. (invited contribution, special issue on cobalt in organic synthesis) [Abstract]

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451. "Hydrogen Bonding Motifs in Structurally Characterized Salts of the Tris(ethylenediamine) Cobalt Trication, [Co(en)3]3+; an Interpretive Review, including Implications for Catalysis", Ghosh, S. K.; Ehnbom, A.; Lewis, K. G.; Gladysz, J. A. Coord. Chem. Rev. 2017, 350, 30-48. DOI: 10.1016/j.ccr.2017.04.002. [Abstract]

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458. "The Robust, Readily Available Cobalt(III) Trication [Co(NH2CHPhCHPhNH2)3]3+ is a Progenitor of Broadly Applicable Chirality and Prochirality Sensing Agents", Luu, Q. H.; Lewis, K, G.; Banerjee, A.; Bhuvanesh, N.; Gladysz, J. A. Chem. Sci. 2018, 9, 5087-5099. DOI: 10.1039/C8SC01510D. [Abstract]

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469. "Lipophilic Chiral Cobalt(III) Complexes of Hexaamine Ligands; Efficacies as Enantio-selective Hydrogen Bond Donor Catalysts", Maximuck, W. J.; Gladysz, J. A. Molecular Catalysis 2019, 473, 110360.
DOI: 10.1016/j.mcat.2019.03.018. [Abstract]

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474. "Tricationic tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Configurations at the Carbon and Metal Stereocenters; The Effect of Chiral Counter Anions upon Enantioselectivities", Kabes, C. Q.; Maximuck, W. J.; Ghosh, S. K.; Kumar, A.; Lewis, K. G.; Bhuvanesh, N.; Gladysz, J. A. ACS Catalysis 2020, 10, 3249-3263. DOI: 10.1021/acscatal.9b05496. [Abstract]

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475. "Rendering Classical Hydrophilic Enantiopure Werner Salts [M(en)3]n+nX Lipophilic (M/n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); New Chiral Hydrogen Bond Donor Catalysts and Enantioselectivities as a Function of Metal and Charge", Maximuck, W. J.; Ganzmann, C.; Scheherzad, A.; Hooda, K. R.; Gladysz, J. A. Dalton Trans. 2020, Accepted. DOI: 10.1039/D0DT00523A. [Abstract]

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479. "An Air and Water Stable Hydrogen Bond Donor Catalyst for the Enantioselective Generation of Quaternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters", Luu, Q. H.; Gladysz, J. A. Chem. Eur. J. 2020, 26, 10230-10239. DOI: 10.1002/chem.202001639. [Abstract]

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480. "Syntheses of Enantiopure 1,2-Ethylenediamines with Tethered Secondary Amines of the Formula H2NCH2CH((CH2)nNHMe)NH2 (n = 1-4) from α-Amino Acids", Kabes, C. Q.; Gunn, J. H.; Selbst, M. A.; Lucas, R. F.; Gladysz, J. A. Synthesis 2020, 52, 3277-3285. DOI: 10.1055/s-0040-1707146.
(invited contribution, special issue on "Recent advances in amide bond formation) [Abstract]

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481. "Λ-[Co((S,S)-dpen)3]3+ 2IB(C6F5)4: A Second Generation Air- and Water-Stable Chiral Solvating Agent for Chirality Sensing (dpen = NH2CHPhCHPhNH2)", Alimohammadi, M.; Hasaninejad, A.; Luu, Q. H.; Gladysz, J. A. J. Org. Chem. 2020, 85, 11250-11257. DOI: 10.1021/acs.joc.0c01332. [Abstract]

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482. "Launching Werner Complexes into the Modern Era of Catalytic Enantioselective Organic Synthesis", Wegener, A. R.; Kabes, C. Q.; Gladysz, J. A. Acc. Chem. Res. 2020, 53, 2299-2313. DOI: 10.1021/acs.accounts.0c00410. [Abstract]

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488. "Chiral Cobalt(III) tris(1,2-Diamine) Catalysts that Incorporate Nitrogeneous Base Con-taining Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in En-antioselective Addition Reactions", Kabes, C. Q.; Lucas, R.; Gunn, J. H.; Gladysz, J. A. ACS Catalysis 2021, 11, 7762-7771. DOI: 10.1021/acscatal.1c01883. [Abstract]

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492. "Solvent Free Enantioselective Catalysis with Chiral Cobalt(III) Werner Complexes via Ball Milling", Kabes, C. Q.; Jameson, B. L.; Gladysz, J. A. New J. Chem. 2021, 45, 17101-17107. DOI: 10.1039/D1NJ03698J. [Abstract]

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General High Activity and Enantioselectivity

263.     "A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of 'Chiral-at-Rhenium' Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations", Kromm, K.; Zwick, B. D.; Meyer, O.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2001, 7, 2015-2027. DOI: 10.1002/1521-3765(20010504)7:9. [Abstract]

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268.     "A New Family of Chiral Chelating Diamines with Transition Metal Stereocenters: Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted Diamine (η5-C5H5)Re(NO)(PPh3)(CH2N(CH3)CH2CH2(H3C)NCH2)(Ph3P)(ON)Re(η5-C5H5)", Alvey, L. J.; Delacroix, O.; Wallner, C.; Meyer, O.; Hampel, F.; Szafert, S.; Lis, T.; Gladysz, J. A. Organometallics 2001, 20, 3087-3096. DOI: 10.1021/om010153a. [Abstract]

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279.     "Syntheses, Structures, and Catalytic Reactions of Palladium Adducts of Chiral Diphos­phines that Contain a Rhenium Stereocenter in the Backbone", Kromm, K.; Hampel, F.; Gladysz, J. A. Helv. Chim. Acta 2002, 85, 1778-1789. DOI: 10.1002/1522-2675(200206)85:6. [Abstract]

283.     "New Approaches to High-Activity Transition Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catal­yzed Suzuki Cross-Couplings", Eichenseher, S.; Kromm, K.; Delacroix, O.; Gladysz, J. A., Chem. Commun. 2002, 1046-1047. DOI: 10.1021/om0492956. [Abstract]

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285.     "A New Family of Chelating Diphosphines with Transition Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System", Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2002, 21, 4264-4274. DOI: 10.1021/om020431l. [Abstract]

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286.     "Chelating Diphosphines that Contain a Rhenium Stereocenter in the Backbone: Applica­tions in Rhodium-Catalyzed Enantioselective Ketone Hydrosilylations and Alkene Hydro­genations", Kromm, K.; Osburn, P. L.; Gladysz, J. A. Organometallics 2002, 21, 4275-4280. DOI: 10.1021/om020432d. [Abstract]

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290.     "Highly Bulky and Electron-Rich Terminal Ruthenium Phosphido Complexes: New Donor Ligands for Palladium-Catalyzed Sukuki Cross-Couplings", Giner Planas, J.; Gladysz, J. A. Inorg. Chem. 2002, 41, 6947-6949. DOI: 10.1021/ic020589y. [Abstract]

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293.     "Transition-Metal-Containing Chiral Bidentate Ligands for Enantioselective Catalysis: Non-Metallocene Architectural Units Come of Age", Delacroix, O.; Gladysz, J. A. Chem. Comm­un. 2003, 665-675 (feature article). DOI: 10.1002/chin.200325223. [Abstract]

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322.     "Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions; A New Strategy for High-Activity Systems", Eichenseher, S.; Dela­croix, O.; Kromm, K.; Hampel, F.; Gladysz, J. A. Organometallics 2005, 24, 245-255. DOI: 10.1021/om0492956. [Abstract]

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324.     "Generation and Reactions of Ruthenium Phosphido Complexes [(η5-C5H5)Ru(PR'3)2(PR2)]: Remarkably High Phosphorus Basicities and Applications as Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions", Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416. DOI: 10.1002/chem.200400925. [Abstract]

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328.     "Synthesis and Reactivity of 1,2- and 1,3-Diphosphanes that Contain Four Chiral Rhenium Fragments: Architecturally Novel Tetrametallo-DMPE and -DMPP Species that are Unprivileged Ligands for Enantioselective Catalysis" Kromm, K.; Eichenseher, S.; Prommesberg­er, M.; Hampel, F.; Gladysz, J. A. Eur. J. Inorg. Chem. 2005, 2983-2998. DOI: 10.1002/ejic.200500254. [Abstract]

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332. "A New Cyclometalation Motif: Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone and are Catalyst Precursors for Heck Reactions", Friedlein, F. K.; Hampel, F.; Gladysz, J. A. Organometallics, 2005, 24, 4103-4105. DOI: 10.1021/om0504708. [Abstract]

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341. "Synthesis, Structure, and Reactivity of Palladacycles that Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies", Friedlein, F. K.; Kromm, K.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2006, 12, 5267-5281. DOI: 10.1002/chem.200501540. [Abstract]

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346. "A Promising New Catalyst Family for Enantioselective [3+2] Cycloadditions of Allenes and Imines: Chiral Phosphines with a Transition Metal–CH2–P: Linkage" Scherer, A.; Gladysz, J. A. Tetrahedron Lett. 2006, 47, 6335-6337. DOI: 10.1016/j.tetlet.2006.07.005. [Abstract]

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352. "Enantioselective Catalysis of Intramolecular Morita-Baylis-Hillman and Related Reactions by Chiral Rhenium-Containing Phosphines of the Formula (η5-C5H5)Re(NO)(PPh3)(CH2PAr2)", Seidel, F.; Gladysz, J. A. Synlett 2007, 6, 986-988. DOI: 10.1055/s-2007-973859. [Abstract]

362. "Chiral Phosphorus Donor Ligands Containing Monocyclopentadienyl Metal Fragments", Castillo, D. A.; Gladysz, J. A. in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Börner, A. Ed; Wiley/VCH, Weinheim, 2008, 408-437. DOI: 10.1002/chin.200942263.

 
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382. "Syntheses and Structural Analyses of Chiral Rhenium Containing Amines of the Formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR') (n = 0, 1)", Seidel, S. N.; Prommesberger, M.; Eichenseher, S.; Meyer, O. Hampel, F.; Gladysz, J. A. Inorg. Chim. Acta 2010, 363, 533-548. (invited article, issue in honor of Paul Pregosin) DOI:10.1016/j.ica.2009.03.047. [Abstract]

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411. "Syntheses, Structures, and Reactions of Cyrhetrenylphosphines; Applications in Palladium Catalyzed Suzuki Cross-Coupling Reactions", Sierra Castro, D.; Bhuvanesh, N.; Reibenspeis, J. H.; Gladysz, J. A.; Klahn, A. H. J. Organomet. Chem. 2014, 749, 416-420. DOI: 10.1016/j.jorganchem.2013.10.029. [Abstract]

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476. "A Computational Study of Hydrogen Bonding Motifs in Halide, Tetrafluoroborate, Hexafluorophosphate, and Tetraarylborate Salts of Chiral Cationic Ruthenium and Cobalt Guanidinobenzimidazole Hydrogen Bond Donor Catalysts: Acceptor Properties of the 'BArf' Anion", Wititsuwannakul, T.; Mukherjee, T.; Hall, M. B.; Gladysz, J. A. Polyhedron 2020, 187, 114618 (article number). DOI: 10.1016/j.poly.2020.114618.
(invited contribution, special issue honoring John E. Bercaw) [Abstract]

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477. "Computational Investigations of Enantioselection in Carbon-Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts", Wititsuwannakul, T.; Mukherjee, T.; Hall, M. B.; Gladysz, J. A. Organometallics 2020, 39, 1149-1162. DOI: 10.1021/acs.organomet.0c00072. [Abstract]

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478. "Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts", Mukherjee, T.; Ghosh, S. K.; Wititsuwannakul, T.; Bhuvanesh, N.; Gladysz, J. A. Organometallics 2020, 39, 1163-1175. DOI: 10.1021/acs.organomet.0c00073. [Abstract]

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486. "Computational Investigation of Dichloromethane Ligand Substitution in the Enantiopure Cation [(η5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+, a Functional Equivalent of a Chiral Lewis Acid", Wititsuwannakul, T.; Hall, M. B.; Gladysz, J. A. Organometallics 2021, 40, 742-759. DOI: 10.1021/acs.organomet.1c00006. [Abstract]

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490. "Synthesis, Structures, Reactivities, and Basicities of Quinolinyl and Isoquinolinyl Complexes of an Electron Rich Chiral Rhenium Fragment and Their Electrophilic Addition Products", Castillo Molina, D. A.; Wititsuwannakui, T.; Hampel, F.; Hall, M. B.; Glad¬ysz, J. A. Chem. Eur. J. 2021, 27, 13399-13417. DOI: 10.1002/chem.202101949. [Abstract]

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