D. J. Darensbourg - Research Laboratories

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Publications

• 452. Axial Carbonate-Bridged Dy₂ Complexes Having Rigid N₃O₂Equatorial Planes: Stepwise Boosting and Tuning of the Zero-Field SMM Behavior. N. Ahmed and D. J. Darensbourg, Cryst. Growth Des.,2025, 25, 1992-2001
DOI: 10.1021/acs.cgd.4c01468
• 451. Nitric oxide transfer between nominal Fe and Co biomimetics of the nitrile hydratase active site. S. Sanfui, M. Jana, N.Small, D.J. Darensbourg, M.Y. Darensbourg, J. Biological Inorg. Chem. ,2025, 30, 161-168.
DOI: 10.1007/s00775-024-02092-8.
• 450. Bridging Polymer Architecture, Printability, and Properties by Digital Light Processing of Block Copolycarbonates. K.G. Schoonover, C.-M. Hsieh, M. Sengoden, N. Ahmed, M.S. Kalairaj, T.H. Ware, D.J. Darensbourg, E.B. Pentzer, P. Wei, Chem.Sci.,2024, 15, 14228-14240.
DOI: 10.1039/d4sc04593a
• 449. Insection reactions of CO₂ and COS into metal-alkoxide bonds: Reactivity differences on copolymer formation with epoxides. D.J. Darensbourg, J. Organomet. Chem.,2024, 1017, 123264.
DOI: 10.1016/j.jorganchem.2024.123264
• 448. Post-polymerization fuctionalization of aliphatic polycarbonates using click chemistry. Mohsin Hassan, Gulzar A. Bhat and Donald J. Darensbourg. Polym. Chem., 2024, 15, 1803-1820.
DOI: 10.1039/d4py00174e
• 447. Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO₂ and eugenol to achieve polycarbonates. Mani Sengoden, Gulzar A. Bhat, Tristan Roland, Chia-Min Hsieh and Donald J. Darensbourg. RSC Sustainability, 2024, 2, 1431-1443.
DOI: 10.1039/d4su00145a
• 446. Bond Trading: Intramolecular Metal and Ligand Exchange within a NO/Ni/Co Complex. Jana, M.; Zheng, X.; Le, T.; Quiroz, M.; Guererro-Almaraz, P.; Darensbourg, D.J.; Darensbourg, M.Y.; Adv. Sci.. 2024, 11, 2307113.
DOI: 10.1002/advs.202307113
• 445. Micellar catalysis: Polymer bound palladium catalyst for carbon-carbon coupling reactions in water. Sengoden, M.; Gulzar, A. B.; Rutledge, R.J; Darensbourg, D.J.; PNAS. 2023, 120(46), e2312907120.
DOI: 10.1073/pnas.2312907120
• 444. Structural Metamorphoses of d-Xylose Oxetane- and Carbonyl Sulfide-Based Polymers In Situ during Ring-Opening Copolymerizations. Tran, D.K.; Braaksma, A. N.; Andas, A.M.; Boopathi, S.K.; Darensbourg, D.J.; Wooley, K.L.; J. Am. Chem. Soc. 2023, 145, 18560-18567.
DOI: 10.1021/jacs.3c05529
• 443. Enabling New Approaches: Recent Advances in Processing Aliphatic Polycarbonate-Based Materials. Wei, P.; Bhat, G.A.; Darensbourg, D.J.; Angew. Chem. Int. Ed. 2023, 62, e202307507.
DOI: 10.1002/anie.202307507
• 442. Coordination Complexes as Catalysts for the Coupling Reactions of Oxiranes and Carbon Dioxide. Bhat, G.A.; Darensbourg, D.J.; Coord.Chem.Rev. 2023, 492, 215277.
DOI:10.1016/j.ccr.2023.215277
• 441.  Sustainable Synthesis of CO₂-Derived Polycarbonates from the Natural Product, Eugenol: Terpolymerization with Propylene Oxide. Sengoden, M.; Bhat, G.A.; Darensbourg, D.J.; Macromolecules. 2023, 56, 2362-2369.
DOI:10.1021/acs.macromol.3c00079
• 440.  Bifunctional Organoboron-Phosphonium Catalysts for Coupling Reactions of CO₂ and Epoxides. Sengoden, M.; Bhat, G.A.; Darensbourg, D.J.; RSC Advances. 2022, 12, 32440-32447.
DOI:10.1039/D2RA06358A
• 439.  Chirality-Guided Isomerization of Mn₂S₂ Diamond Core Complexes: A Mechanistic Study. Le, H.T.; Nguyen, H.; Arnold, A.H.; Darensbourg, D.J.; Darensbourg, M.Y.; Inorg.chem. 2022, 61, 16405-16413.
DOI:10.1021/acs.inorgchem.2c02460
• 438.  3D Printed CO₂-Based Triblock Copolymers and Post-Printing Modification. Wei, P.; Bhat, G.A.; Cipriani, E.C.; Mohammad, H.; Schoonover, K.; Pentzer, E.B.; Darensbourg, D.J; Angew.Chem.Int.Ed. 2022, 61, e202208355.
DOI:10.1002/anie.202208355
• 437.  Polymerization of Epoxides. Darensbourg, D.J.; Bhat, G.A.; Comprehensive Organometallic Chemistry IV. 2022 13, 431-455.
DOI:10.1016/B978-0-12-820206-7.00123-2
• 436.  Studies of the Interactions of the Tungsten Pentacarbonyl Fluoride Anion with Carbon Dioxide. Samouei, H.; Reibenspies, J.H.; Darensbourg, D.J., Polyhedron. 2022, 221, 115852.
DOI: 10.1016/j.poly.2022.115852
• 435.  Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO₂ Reduction in Aqueous Media. Ren, F.-Y.; Chen, K.; Qiu, L-Q.; Chen, J.-M.; Darensbourg, D.J.; He, L.-N., Angew.Chem.Int.Ed. 2022, 61, e202200751.
DOI: 10.1002/ange.202200751
• 434.  Progress in the Catalytic Reactions of CO₂ and Epoxides to Selectively Provide Cyclic or Polymeric Carbonates. Bhat, G.; Darensbourg, D.J., Green Chem. 2022, 24, 5007-5034.
DOI: 10.1039/D2GC01422J
• 433.  Explorations into the Sustainable Synthesis of Cyclic and Polymeric Carbonates and Thiocarbonates from Eugenol-Derived Monomers Reactions with CO₂, COS, or CS₂. Sengoden, M.; Bhat, G.A.; Darensbourg, D.J. Green Chem. 2022, 24, 2535-2541.
DOI:10.1039/D2GC00327A
• 432.  Kinetic and Computational Analysis of CO Substitution in a Dinuclear Osmium Carbonyl Complex: Intersection between Dissociative and Dissociative-Interchange Mechanisms. Martinez, Z.M.; Folsom, T.M.; Tong, Y.; Archambeau, A.K.; Darensbourg, D.J; Hall, M.B; Powell, C.B; Powell, G.L.; Inorg.Chem. 2022, 61,1, 246-253.
DOI: 10.1021/acs.inorgchem.1c02797
• 431.  Sustainable Synthesis of CO₂-derived polycarbonates from D-xylose. Tran, D.K.; Rashad, A.Z.; Darensbourg, D.J.; Wooley, K.L.; Polym.Chem.. 2021, 12, 5271-5278.
DOI: 10.1039/D1PY00784J
• 430.  TEMPO Containing Radical Polymonothiocarbonate Polymers with Regio- and Stereo-Regularities: Synthesis, Characterization, and Electrical Conductivity Studies. Bhat, G.A.; Rashad, A.Z.; Ji, X.; Quiroz, M.; Fang, L.; Darensbourg, D.J.; Angew.Chem.Int.Ed. 2021, 60, 20734-20738.
DOI: 10.1002/anie.202108041
• 429.  Carbon disulfide-derived polymers. Bhat, G.A. ; Darensbourg, D.J. Contribution in Sulfur-containing Polymers: From Synthesis to Functional Materials. Eds. Xinghong Zhang and Patrick Theato. Wiley-VCH, 2021, 39 - 79.
DOI: 10.1002/9783527823819.ch2
• 428.  Randomly Distributed Sulfur Atoms in the Main Chains of CO₂-based Polycarbonates: Enhanced Optical Properties. Yue, T.-J.; Bai-Hao Ren, B.-H.; Zhang, W.-J.; Lu, X.-B.; Ren, W.-M.; Darensbourg, D. J. Angew. Chem. Int. Ed. 2021, 60, 4315 - 4321. DOI: 10.1002/anie.202012565
• 427. Copolymerization of Propylene Oxide and ¹³CO₂ to Afford Completely Alternating Regioregular ¹³C-Labelled Poly(propylene carbonate). Bhat, G. A.; Darensbourg, M. Y.; Darensbourg, D. J. Polymer Journal 2021, 53, 215-218.
DOI: 10.1038/s41428-020-0391-0
• 426. Catalysis of Carbon Dioxide and Oxetanes to Produce Aliphatic Polycarbonates. Bhat, G. A.; Luo, M.; Darensbourg, D. J.Green Chem. 2020, 22, 7707 - 7724.
DOI: 10.1039/D0GC03219K
• 425. Synthesis of Terpyridine-Containing Polycarbonates with Post Polymerization Providing Water-Soluble and Micellar Polymers and Their Metal Complexes. Bhat, G. A.; Rashad, A. Z.; Darensbourg, D. J. Polym. Chem. 2020, 11, 4699 - 4705.
DOI: 10.1039/d0py00850h
• 424.  CO₂-Based Block Copolymers: Present and Future Designs. Zhang, Y.-Y.; Wu, G.-P.; Darensbourg, D. J. Trends in Chemistry 2020, 2, 750-763.
DOI: 10.1016/j.trechm.2020.05.002/
• 423.  Facile Synthesis of Well‐Defined Branched Sulfur‐Containing Copolymers via a “One‐Pot” Copolymerization of Carbonyl Sulfide and Epoxide. Yue, T.-J.; Bhat, G. A.; Zhang, W.-J.; Ren, W.-M.; Lu, X.-B.; Darensbourg, D. J. Angew. Chem. Int. Ed. 2020, 59, 13633-13637.
DOI: 10.1002/anie.202005806
• 422.  Zwitterionic Alternating Polymerization to Generate Semicrystalline and Recyclable Cyclic Polythiourethanes. Tan, D.; Hu, X.; Cao, Z.; Luo, M.; Darensbourg, D. J. ACS Macro Lett. 2020, 9, 866-871.
DOI: 10.1021/acsmacrolett.0c00302
• 421.  Synthetic Metallodithiolato Ligands as Pendant Bases in [Fe^IFe^I], [Fe^I[Fe(NO)]^II], and [(μ-H)Fe^IIFe^II] Complexes. Kariyawasam Pathirana, K. D.; Ghosh, P.; Hsieh, C.-H.; Elrod, L. C.; Bhuvanesh, N.; Darensbourg, D. J.; Darensbourg, M. Y. Inorg. Chem. 2020, 59, 3753-3763.
DOI: 10.1021/acs.inorgchem.9b03409
• 420.  Non-Isocyanate and Catalyst-Free Synthesis of a Recyclable Polythiourethane with Cyclic Structure; Wu, S.; Luo, M.; Darensbourg, D.J.; Zeng, D.; Yao, Y.; Zuo, X.-B.; Hu, X.; Tan, D.; ACS Sustainable Chem. Eng. 2020, 8, 5693-5703.
DOI: 10.1021/acssuschemeng.0c00435
• 419.  Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Diamanganese Complex; Le, T.; Nguyen, H.; Perez, L.M.; Darensbourg D.J.; Darensbourg, M.Y.; Angew. Chem., Int. Ed., 2020, 59, 3645-3649.
DOI: 10.1002/anie.201913259
• 418.  Placing Single Metal Complexes into the Backbone of CO₂-Based Polycarbonate Chains, Construction of Nanostructures for Prospective Micellar Catalysis; Bhat, G.A.; Rashad, A.Z.; Folsom, T.M.; Darensbourg, D.J., Organometallics, 2020, 39, 1612-1618.
DOI: 10.1021/acs.organomet.9b00704
• 417. Catalyst-Free Construction of Versatile and Functional CS₂-Based Polythioureas: Characteristics from Self-Healing to Heavy Metal Absorption; Wu, S.; Luo, M.; Darensbourg, D.J.; Zuo, X.-B., Macromolecules, 2019, 52, 8596-8603.
DOI: 10.1021/acs.macromol.9b01811
• 416. Approach for Introducing a Single Metal Complex into a Polymer Chain. Metallo-Chain Transfer Agents in CO₂ or COS/Epoxide Copolymerization Processes; Folsom, T.M.; Bhat, G.A.; Rashad, A.Z.; Darensbourg, D.J., Macromolecules, 2019, 52, 5217-5222.
DOI: 10.1021/acs.macromol.9b00906
• 415. Thermal Dehydrogenation of Dimethylamine Borane Catalyzed by a Bifunctional Rhenium Complex; Yempally, V.; Moncho, S.; Wang, Y.; Kyran, S.J.; Fan, W.Y.; Brothers, E.N.; Darensbourg, D.J.; Bengali, A.A., Organometallics, 2019, 38, 2602-2609.
DOI: 10.1021/acs.organomet.9b00115
• 414. Chain transfer agents utilized in epoxide and CO₂ copolymerization processes; Darensbourg, D.J., Green Chemistry, 2019, 21, 2214-2223.
DOI: 10.1039/C9GC00620F
• 413.  Kinetic studies of thermal dissociation of carbon monoxide ligands from manganese tri- and tetra-carbonyl derivatives containing the bulky dipiperidylmethane ligand, CH₂Pip₂;. Folsom, T. M..; Darensbourg, D.J., Inorganica Chimica Acta, 2019, 484, 443-449.
DOI: 10.1016/j.ica.2018.09.004
• 412.  One-Pot Synthesis of Ion-Containing CO₂-Based Polycarbonates Using Protic Ionic Liquids as Chain Transfer Agents;. Huang, Z.; Wang, Y.; Zhang, N.; Zhang, L.; Darensbourg, D.J., Macromolecules, 2018, 51, 9122-9130.. DOI: 10.1021/acs.macromol.8b01834
• 411.  Oxygen Atom Exchange in Rhenium Bipyridine and Phenanthroline Tetracarbonyl Cations with H₂¹⁸O . Folsom, T. M..; Darensbourg, D.J., Polyhedron, 2018, 156, 58-63.
DOI: 10.1016/j.poly.2018.08.074
• 410.  Design of Betaine Functional Catalyst for Efficient Copolymerization of Oxirane and CO₂. Chen, K.; Shi, G.; Li, H.; Wang, C.; Darensbourg, D.J., Macromolecules, 2018, 51, 6057-6062.
DOI: 10.1021/acs.macromol.8b01103
• 409.  Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process. Sil, D.; Martinez, Z.; Ding, S.; Bhuvanesh, N.; Darensbourg, D.J.; Hall, M.B.; Darensbourg, M.Y.; J. Am. Chem. Soc. 2018, 140 (31), 9904–9911.
DOI: 10.1021/jacs.8b04189
• 408.  Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO₂ and epoxides. Wang, Y.; Darensbourg, D.J., Coord. Chem. Rev., 2018, 372, 85-100.
DOI: 10.1016/j.ccr.2018.06.004
• 407.  Construction of Autonomic Self-Healing CO₂-Based Polycarbonates via One-Pot Tandem Synthetic Strategy. Yang, G.-W.; Zhang, Y.-Y.; Wang, Y.; Wu, G.-P.; Xu, Z.-K.; Darensbourg, D.J., Macromolecules., 2018, 51, 1308-1313.
DOI: 10.1021/acs.macromol.7b02715
• 406.  Synthesis of CO₂-based Block Copolymers via Chain Transfer Polymerization Using Macro-initiators: Activity, Blocking Efficiency and Nano Structure. Zhang, Y.-Y.; Yang, G.-W.; Wang, Y.; Lu, X.-Y.; Wu, G.-P.; Zhang, Z.-S.; Wang, K.; Zhang, R.-Y.; Nealey, P. F.; Darensbourg, D.J.; Xu, Z.-K., Macromolecules, 2018, 51, 791-800.
DOI: 10.1021/acs.macromol.7b02231
• 405.  Comments on the depolymerization of polycarbonates derived from epoxides and carbon dioxide: A Mini Review. Darensbourg, D.J., Polymer Degradation and Stability., 2018, 149, 45-51.
DOI: 10.1016/j.polymdegradstab.2018.01.019
• 404.  Mechanistic Study of Regio-Defects in the Copolymerization of Propylene Oxide/Carbonyl Sulfide Catalyzed by (Salen)CrX Complexes. Li, Y., Duan, H.-Y., Luo, M., Zhang, Y.-Y., Zhang, X.-H., Darensbourg, D.J., Macromolecules., 2017, 50, 8426-8437.
DOI: 10.1021/acs.macromol.7b01867
• 403.  A quest for polycarbonates provided via sustainable epoxide/CO₂ copolymerization processes. Poland, S.J., Darensbourg, D.J., Green Chem., 2017, 19, 4990-5011.
DOI: 10.1039/C7GC02560B
• 402.  Copolymerization of Epoxides and CO₂: Polymer Chemistry for Incorporation in Undergraduate Inorganic Chemistry. Darensbourg, D.J., J. Chem. Ed., 2017, 94, 1691-1695.
DOI: 10.1021/acs.jchemed.6b00505
• 401.  Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides via Metal-free Lewis Pairs. Yang, J.-L.; Wu, H.-L.; Li, Y.; Zhang, X.-H.; Darensbourg, D.J., Angew. Chem. Int. Ed., 2017, 56, 5774-5779.
DOI: 10.1002/anie.201701780
• 400.  Switchable Catalytic Processes Involving the Copolymerization of Epoxides and Carbon Dioxide for the Preparation of Block Polymers, Darensbourg, D.J., Inorg. Chem. Front., 2017, 4, 412-419.
DOI:10.1039/C7QI00013H
• 399.  Directed Self-Assembly of Polystyrene-b-poly(propylene carbonate) on Chemical Patterns via Thermal Annealing for Next-Generation Lithography, Yang, G.-W.; Wu, G.-P.; Chen, X.; Xiong, S.; Arges, C. G.; Ji, S; Nealy, P. F.; Lu, X.-B.; Darensbourg, D.J.; Xu, Z.-K., Nano Lett. 2017, 17, 1233-1239.
DOI:10.1021/acs.nanolett.6b05059
• 398.  Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer, Wu, H.-L; Yang, J.-L.; Luo, M; Wang, R.-Y.; Xu, J.-T.; Du, B.-Y.; Zhang, X.-H.; Darensbourg, D.J., Macromolecules, 2016, 49, 8863-8868.
DOI:10.1021/acs.macromol.6b02285
• 397.  Poly(monothiocarbonate)s from the Alternating and Regioselective Copolymerization of Carbonyl Sulfide with Epoxides. Luo, M.; Zhang, X.-H.; Darensbourg, D.J., Acc. Chem. Res., 2016, 49, 2209-2219.
DOI:10.1021/acs.accounts.6b00345
• 396.  Environmentally Benign CO₂-Based Copolymers: Degradable Polycarbonates Derived from Dihydroxybutyric Acid and Their Platinum-Polymer Conjugates. Tsai,F.; Wang, Y.; Darensbourg, D.J., J. Am. Chem. Soc., 2016, 4626-4633.
DOI:10.1021/jacs.6b01327
• 395.  Copolymerization of Carbon Dioxide and Cyclohexene Oxide Catalyzed by Chromium Complexes Bearing Semirigid [ONSO]-Type Ligands. Han, B.; Zhang, L.; Kyran, S.J.; Liu, B.; Duan, Z.; Darensbourg, D. J., J. Polym. Sci. Part A: Polym. Chem., 2016, 54, 1938-1944.
DOI:10.1002/pola.28052
• 394.  Mechanistic Insights into Water-Mediated Tandem Catalysis of Metal Coordination CO₂/Epoxide Copolymerization and Organocatalytic Ring-Opening Polymerization: One-Pot, Two Steps, and Three Catalysis Cycles for Triblock Copolymers Synthesis. Wu, G.-P.; Darensbourg, D. J., Macromolecules, 2016, 49(3),807-814.
DOI:10.1021/acs.macromol.5b02752
• 393.  Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides. Luo, M.; Zhang, X.-H.; Darensbourg, D. J., Catal. Sci. Technol., 2016, 6, 188-192.
DOI: 10.1039/C5CY00977D
• 392.  An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide. Luo, M.; Zhang, X.-H.; Darensbourg, D. J., Macromolecules, 2015, 48, 6057-6062.
DOI: 10.1021/acs.macromol.5b01427
• 391.  Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether. Luo, M.; Zhang, X.-H.; Darensbourg, D. J., Polym. Chem., 2015, 6, 6955-6958.
DOI: 10.1039/C5PY01197C
• 390.  An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane. Luo, M.; Zhang, X.-H.; Darensbourg, D. J., Macromolecules, 2015, 48, 5526-5532.
DOI: 10.1021/acs.macromol.5b01251
• 389. Carbon Dioxide Copolymerization Study with a Sterically Encumbering Naphthalene-Derived Oxide. Darensbourg, D. J.; Kyran, S. J., ACS Catal., 2015, 5, 5421-5430.
DOI: 10.1021/acscatal.5b01375
• 388.  Syntheses and Structures of [CH₂(NC_nH_2n)₂]Mo(CO)₄ (n = 4,5) Complexes with Bis(cycloamine) Ligands Easily Prepared from CH₂Cl₂. Kyran, S. J.; Sanchez, S. G.; Arp, C. J.; Darensbourg, D. J. Organometallics, 2015, 34, 3598-3602.
DOI: 10.1021/acs.organomet.5b00396
• 387.  Construction of Versatile and Functional Nanostructures Derived from CO₂-based Polycarbonates. Wang, Y.; Fan, J.; Darensbourg, D. J. Angew. Chem. Int. Ed., 2015, 54, 10206-10210.
DOI: 10.1002/anie.201505076
• 386.  Dramatic Behavioral Differences of the Copolymerization Reactions of 1,4-Cyclohexadiene and 1,3-Cyclohexadiene Oxides with Carbon Dioxide. Darensbourg, D. J.; Chung, W.-C.; Yeung, A. D.; Luna, M. Macromolecules, 2015, 48, 1679-1687.
DOI: 10.1021/acs.macromol.5b00172
• 385.  Terpolymerization of Propylene Oxide and Vinyl Oxides with CO₂: Copolymer Cross-linking and Surface Modification via Thiol-ene Click Chemistry. Darensbourg, D. J.; Wang, Y. Polym. Chem., 2015, 6, 1768 - 1776.
DOI: 10.1039/C4PY01612B
• 384.  Kinetics of the (salen)Cr(III)- and (salen)Co(III)-Catalyzed Copolymerization of Epoxides with CO₂, and of the Accompanying Degradation Reactions. Darensbourg, D. J.; Yeung, A. Y. Polym. Chem. 2015, 6, 1103 - 1117.
DOI: 10.1039/C4PY01322K
• 383.  Copolymerization and Cycloaddition Products Derived from Coupling Reactions of 1,2-Epoxy-4-cyclohexene and Carbon Dioxide. Postpolymerization Functionalization via Thiol-ene Click Reactions. Darensbourg, D. J.; Chung, W.-C.; Arp, C. J.; Tsai, F.-T.; Kyran, S. J., Macromolecules 2014, 47, 7347-7353.
DOI: 10.1021/ma501781k
• 382.  Availability of Other Aliphatic Polycarbonates Derived from Geometric Isomers of Butene Oxide and Carbon Dioxide Coupling Reactions. Darensbourg, D. J.; Chung, W.-C., Macromolecules, 2014, 47, 4943—4948.
DOI: 10.1021/ma501004w
• 381.  Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes. Pulukkody, R.; Kyran, S. J.; Drummond, M. J.; Hsieh, C.-H.; Darensbourg, D. J.; Darensbourg, M. Y., Chem. Sci., 2014, 5, 3795—3802.
DOI: 10.1039/c4sc01523a
• 380.  Post-Polymerization Functionalization of Copolymers Produced from Carbon Dioxide and 2-Vinyloxirane: Amphiphilic/Water-Soluble CO2-Based Polycarbonates. Darensbourg, D. J.; Tsai, F.-T., Macromolecules, 2014, 47, 3806—3813.
DOI: 10.1021/ma500834r
• 379.  Iron Complexes Containing Electrochemically Active Diazocycle-bis(di-tert-butyl-phenol) Ligands.  Mendes, L. L.; Fernandes, C.; Franco, R. W. A.; Lube, L. M.; Wei, S.-H.; Reibenspies, J. H.; Darensbourg, D. J.; Horn, Jr., A.  J. Braz. Chem. Soc. 2014, 25, 1050—1061. 
DOI: 10.5935/0103-5053.20140078
• 378.  A concise review of computational studies of the carbon dioxide-epoxide copolymerization reactions. Darensbourg, D. J.; Yeung, A. D. Polymer Chemistry 2014, 5, 3949—3962.
DOI: 10.1039/c4py00299g
• 377.  Sequestering CO₂ for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes. Darensbourg, D. J.; Chung, W.-C.; Wang, K.; Zhou, H.-C. ACS Catalysis, 2014, 4, 1511–1515.
DOI: 10.1021/cs500259b
• 376.  Thermal and Photochemical Reactivity of Manganese Tricarbonyl and Tetraarbonyl Complexes with a Bulky Diazabutadiene Ligand. Yempally, V.; Kyran, S. J.; Raju, R. K.; Fan, W. Y.; Brothers, E. N.; Darensbourg, D. J.; Bengali, A. A. Inorg. Chem. 2014, 53, 4081–4088.
DOI: 10.1021/ic500025k
• 375.  Personal Adventures in the Synthesis of Copolymers from Carbon Dioxide and Cyclic Ethers. Darensbourg, D. J., contribution in Advances in Inorganic Chemistry Volume 66: CO2 Chemistry, Eds. Rudi van Eldik and Michele Aresta, Elsevier Inc., Burlington: Academic Press, 2014, 1-23.
DOI: 10.1016/B978-0-12-420221-4.00001-9
• 374.  Kinetics and Thermodynamics of the Decarboxylation of 1,2-Glycerol Carbonate to Produce Glycidol: Computational Insights.  Darensbourg, D. J.; Yeung, A. D. Green Chem. 2014, 16, 247–252.
DOI: 10.1039/C3GC41643G
• 373.  Catalytic Coupling of Cyclopentene Oxide and CO2 Utilizing Bifunctional (salen)Co(III) and (salen)Cr(III) Catalysts.  Comparative Processes Involving Binary (salen)Cr(III) Analogs.  Darensbourg, D. J.; Chung, W.-C.; Wilson, S. J. ACS Catalysis 2013, 3, 3050–3057.
DOI: 10.1021/cs4008667
• 372.  Construction of an Ultrastable Porphyrin Zr Metal-Organic Framework through Linker Elimination.  Feng, D.; Chung, W.-C.; Wei, Z.-W.; Gu, Z. Y.; Jiang, H. L.; Darensbourg, D. J.; Zhou, H.-C. J. Am. Chem. Soc. 2013, 135, 17105–17110.
DOI: 10.1021/ja408084j
• 371.  Light-Enhanced Displacement of Methyl Acrylate from Iron Carbonyl: Investigation of the Reactive Intermediate via Rapid-Scan Fourier Transform Infrared and Computational Studies. S. Muhammad, S. Moncho, B. Li, S. J. Kyran, E. N. Brothers, D. J. Darensbourg, A. A. Bengali, Inorg. Chem. 2013, 52, 12655–12660.
DOI: 10.1021/ic401836n
• 370.  Oxygen/Sulfur Scrambling During the Copolymerization of Cyclopentene Oxide and Carbon Disulfide: Selectivity for Copolymer vs Cyclic [Thio]carbonates. D. J. Darensbourg, S. J. Wilson, A. D. Yeung, Macromolecules 2013, 46, 8102–8110.
DOI: 10.1021/ma4015438
• 369.   A One-Pot Synthesis of a Triblock Copolymer from Propylene Oxide/Carbon Dioxide and Lactide: Intermediacy of Polyol Initiators. D. J. Darensbourg, G.-P. Wu, Angew. Chem., Int. Ed. 2013, 52, 10602–10606.
DOI: 10.1002/anie.201304778
• 368.  Synthesis of CO₂-Derived Poly(indene carbonate) from Indene Oxide Utilizing Bifunctional Cobalt(III) Catalysts. D. J. Darensbourg, S. J. Wilson, Macromolecules 2013, 46 5929–5934.
DOI: 10.1021/ma4013779
• 367.   An Efficient Method of Depolymerization of Poly(cyclopentene carbonate) to Its Comonomers: Cyclopentene Oxide and Carbon Dioxide. D. J. Darensbourg, S.-H. Wei, A. D. Yeung, W. C. Ellis, Macromolecules 2013, 46 5850–5855.
DOI: 10.1021/ma401286x
• 366.  Kinetic and Thermodynamic Investigations of CO2 Insertion Reactions into Ru-CH3 and Ru-H Bonds. An Experimental and Computational Study. D. J. Darensbourg, S. J. Kyran, A. D. Yeung, A. A. Bengali, Eur. J. Inorg. Chem. 2013, 4024–4031.
DOI: 10.1002/ejic.201300179
• 365.  Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/Thiolate Dinitrosyl Iron Complex (DNIC), Randara Pulukkody , Samuel J. Kyran , Ryan D. Bethel , Chung-Hung Hsieh , Michael B. Hall , Donald J. Darensbourg, Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2013, 135, 8423–8430.
DOI: 10.1021/ja403916v
• 364.  Depolymerization of Poly(indene carbonate). A Unique Degradation Pathway, Donald J. Darensbourg, Sheng-Hsuan Wei, Stephanie J. Wilson, Macromolecules 2013, 46, 3228–3233.
DOI: 10.1021/ma400441m
• 363.  Acrylic Acid Derivatives of Group 8 Metal Carbonyls: A Structural and Kinetic Study, Bo Li, Samuel J. Kyran, Andrew D. Yeung, Ashfaq A. Bengali, and Donald J. Darensbourg, Inorg. Chem. 2013, 52, 5438–5447.
DOI: 10.1021/ic4003737
• 362.  Base initiated depolymerization of polycarbonates to epoxide and carbon dioxide co-monomers: a computational study, Donald J. Darensbourg, Andrew D. Yeung and Sheng-Hsuan Wei, Green Chem. 2013, 15, 1578-1583.
DOI: 10.1039/c3gc40475g
• 361.  Estimating the strength of the M—H—B interaction: a kinetic approach, Muhammad Sohail, Salvador Moncho, Edward N. Brothers, Donald J. Darensbourg and Ashfaq A. Bengali, Dalton Trans. 2013, 42, 6720–6723.
DOI: 10.1039/C3DT50813G
• 360.  Crystalline CO₂ Copolymer from Epichlorohydrin via Co(III)-Complex-Mediated Stereospecific Polymerization, Guang-Peng Wu, Peng-Xiang Xu, Xiao-Bing Lu, Yu-Ping Zu, Sheng-Hsuan Wei, Wei-Min Ren, Donald J. Darensbourg, Macromolecules 2013, 46, 2128–2133.
DOI: 10.1021/ma400252h
• 359.  Relative Basicities of Cyclic Ethers and Esters. Chemistry of Importance to Ring-Opening Co- and Ter-polymerization Reactions, Donald J. Darensbourg, Wan-Chun Chung, Polyhedron, 2013, 58, 139–143.
DOI: 10.1016/j.poly.2012.08.076
• 358.  Thermodynamics of the Carbon Dioxide-Epoxide Copolymerization, and Kinetics of the Metal-free Degradation — A Computational Study, Donald J. Darensbourg, Andrew D. Yeung, Macromolecules 2013, 46, 83–95.
DOI: 10.1021/ma3021823
• 357.  Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation, Sohail Muhammad, Veeranna Yempally, Muhammad Anas, Salvador Moncho, Samuel J. Kyran, Edward N. Brothers, Donald J. Darensbourg, Ashfaq A. Bengali, Inorg. Chem., 2012, 51, 13041–13049.
DOI: 10.1021/ic302182b
• 356.  Tandem Metal-Coordination Copolymerization and Organocatalytic Ring-Opening Polymerization via Water To Synthesize Diblock Copolymers of Styrene Oxide/CO2 and Lactide, Guang-Peng Wu, Donald J. Darensbourg Xiao-Bing Lu, J. Am. Chem. Soc., 2012, 134, 17739–17745.
DOI: 10.1021/ja307976c
• 355.  What's New with CO2? Recent Advances in its Copolymerization with Oxiranes, Donald J. Darensbourg, Stephanie J. Wilson, Green Chem. 2012, 14, 2665–2671.
DOI: 10.1039/C2GC35928F
• 354.  Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-Component Aluminum-Salen Complexes, Dawei Tian, Binyuan Liu, Quanying Gan, Huanrong Li, Donald. J. Darensbourg, ACS Catalysis 2012, 2, 2029–2035.
DOI: 10.1021/cs300462r
• 353.  Depolymerization of Polycarbonates Derived from Carbon Dioxide and Epoxides to Provide Cyclic Carbonates — A Kinetic Study, Donald J. Darensbourg, Sheng-Hsuan Wei, Macromolecules, 2012, 45, 5916–5922.
DOI: 10.1021/ma301110c
• 352.  Time Resolved Infrared Spectroscopy. Kinetic Studies of Weakly Binding Ligands in an Iron-Iron Hydrogenase Model Compound, Sohail Muhammad, Salvador Moncho, Edward N. Brothers, Marcetta Y. Darensbourg, Donald J. Darensbourg, Ashfaq A. Bengali, Inorg. Chem. 2012, 51, 7362–7369.
DOI: 10.1021/ic300785z
• 351.  Time-Resolved Infrared Spectroscopy Studies of Olefin Binding in Photogenerated CpRu(CO)X (X = Cl, I) Transients, Sohail Muhammad, Samuel J. Kyran, Rajesh K. Raju, Edward N. Brothers, Donald J. Darensbourg, Ashfaq A. Bengali, Organometallics 2012, 31, 3972–3979.
DOI: 10.1021/om300197b
• 350.  Photochemically Generated Transients from κ²- and κ³-Triphos Derivatives of Group 6 Metal Carbonyls and Their Reactivity with Olefins, Samuel J. Kyran, Sohail Muhammad, Matthew Knestrick, Ashfaq A. Bengali, Donald J. Darensbourg, Organometallics 2012, 31, 3163–3170.
DOI: 10.1021/om300044k
• 349.  Kinetic Studies of the Alternating Copolymerization of Cyclic Acid Anhydrides and Epoxides, and the Terpolymerization of Cyclic Acid Anhydrides, Epoxides, and CO₂ Catalyzed by (salen)Cr^IIICl, Donald J. Darensbourg, Ross R. Poland, and Christina Escobedo, Macromolecules, 2012, 45, 2242–2248.
DOI: 10.1021/ma2026385
• 348.  Cobalt Catalysts for the Coupling of CO₂ and Epoxides To Provide Polycarbonates and Cyclic Carbonates, Xiao-Bing Lu, Donald J. Darensbourg, Chem. Soc. Rev., 2012, 41, 1462–1484.
DOI: 10.1039/C1CS15142H
• 347.  (Salan)CrCl, An Effective Catalyst for the Co- and Ter-polymerizatin of Epoxides and Carbon Dioxide, D. J. Darensbourg, RR Poland, AL Strickland, J. Polym. Sci. Part A: Polym. Chem., 2012, 50, 127–133.
DOI: 10.1002/pola.24996
• 346.  Salen Metal Complexes as Catalysts for the Synthesis of Polycarbonates from Cyclic Ethers and Carbon Dioxide, D. J. Darensbourg contribution in Advances in Polymer Science, Eds. Geoffrey W. Coates and Bernhard Rieger, Springer-Publishers, 2012, 245, 1–28.
DOI: 10.1007/12_2011_135
• 345.  Alternating Copolymerization of CO₂ and Styrene Oxide with Co(III)-Based Catalyst Systems: Differences Between Styrene Oxide and Propylene Oxide in Reactivity, Polymer Selectivity, and Regioselective Ring-Opening. G-P Wu, S-H Wei, W-M Ren, X-B Lu, B Li, Y-P Zu, D. J. Darensbourg, Energy & Environmental Sci. 2011, 4, 5084–5092.
DOI: 10.1039/C1EE02566J
• 344.  The Synthesis of Poly(indene carbonate) from Indene Oxide and Carbon Dioxide — A Polycarbonate with a Rigid Backbone, Donald J. Darensbourg, Stephanie J. Wilson, J. Am. Chem. Soc. 2011, 133, 18610–18613.
DOI: 10.1021/ja208711c
• 343.  Perfectly Alternating Copolymerization of CO2 and Epichlorohydrin Using Cobalt(III)-based Catalyst Systems, Guang-Peng Wu, Sheng-Hsuan Wei, Wei-Min Ren, Xiao-Bing Lu, Tie-Qi Xu, Donald J. Darensbourg, J. Am. Chem. Soc., 2011, 133, 15191–15199.
DOI: 10.1021/ja206425j
• 342.  Ring-Opening Polymerization of Cyclic Esters and Trimethylene Carbonate Catalyzed by Aluminum Half-Salen Complexes, Donald J. Darensbourg, Osit Karroonnirun, and Stephanie J. Wilson, Inorg. Chem. 2011, 50, 6775–6787.
DOI: 10.1021/ic2008057
• 341.  Ligand Displacement from TpMn(CO)2L Complexes: A Large Rate Enhancement Compared to the Cp Analog, Bert H. G. Swennenhuis, Ross Poland, Nathan J. DeYonker, Charles Edwin Webster, Donald J. Darensbourg, Ashfaq A. Bengali, Organometallics 2011, 30, 3054–3063.
DOI: 10.1021/om200161g
• 340.  Book Review of Poly(Lactic Acid): Synthesis, Structures, Properties, Processing, and Applications, D. J. Darensbourg, J. Am. Chem. Soc. 2011, 133, 7237.
DOI: 10.1021/ja203078c
• 339.  Aliphatic Polycarbonates Produced from the Coupling of Carbon Dioxide and Oxetanes and Their Depolymerization via Cyclic Carbonate Formation, D. J. Darensbourg, Adriana I. Moncada, Sheng-Hsuan Wei, Macromolecules, 2011, 44, 2568–2576.
DOI: 10.1021/ma2002323
• 338.  Ring-Opening Polymerization of Renewable Six-Membered Cyclic Carbonates. Monomer Synthesis and Catalysis, D. J. Darensbourg, Adriana I. Moncada, Stephanie J. Wilson, contribution in Green Polymerization Methods, Eds. Robert T. Mathers and Michael A. R. Meier, Wiley-VCH Verlag GmbH & Co. Weinheim, 2011, 165–200.
• 337.  Chemistry of Carbon Dioxide Relevant to Its Utilization — A personal Perspective, D. J. Darensbourg, Inorg. Chem. 2010, 49, 10765–10780.
DOI: 10.1021/ic101800d
• 336.  Highly Selective Synthesis of CO₂ Copolymer from Styrene Oxide, G.-P. Wu, S.-H. Wei, X.-B. Lu, W.-M. Ren, D. J. Darensbourg, Macromolecules 2010, 43, 9202–9204.
DOI: 10.1021/ma1021456
• 335.  Ring-Opening Polymerization of L-Lactide and ε-Caprolactone Utilizing Biocompatible Zinc Catalysts. Random Copolymerization of L-Lactide and ε-Caprolactone, D. J. Darensbourg; O. Karroonnirun, Macromolecules 2010, 43, 8880–8886.
DOI: 10.1021/ma101784y
• 334.  Ligand Substitution from the (η5-DMP)Mn(CO)2(Solv) [DMP= 2,5,dimethylpyrrole, Solv = solvent] Complexes: To Ring Slip or Not to Ring Slip?, B. H. G. Swennenhuis; R. Poland; W. Y. Fan; D. J. Darensbourg; A. A. Bengali, Inorg. Chem. 2010, 49, 7597–7604.
DOI: 10.1021/ic101123y
• 333.  Stereoselective Ring-Opening Polymerization of Rac-Lactides Catalyzed by Chiral and Achiral Aluminum half-Salen Complexes, D. J. Darensbourg; O. Karroonnirun, Organometallics 2010, 29, 5627-5634.
DOI: 10.1021/om100518e
• 332.  Facile Catalytic Synthesis of Trimethylene Carbonate from Trimethylene Oxide and Carbon Dioxide, D. J. Darensbourg; Adolfo Horn, Jr; Adriana I. Moncada, Green Chem. 2010, 12, 1376-1379.
DOI: 10.1039/c0gc00136h
• 331.  Tuning the Selectivity of the Oxetane and CO₂ Coupling Process Catalyzed by (Salen)CrCl/n-Bu₄NX: Cyclic Carbonate Formation vs Aliphatic Polycarbonate Production, Darensbourg, Donald J.; Moncada, Adriana, Macromolecules 2010, 43, 5996-6003.
DOI: 10.1021/ma100896x
• 330.  Ring-Opening Polymerization of Lactides Catalyzed by Natural Amino-Acid Based Zinc Catalysts, Darensbourg, Donald J.; Karroonnirun, Osit, Inorg. Chem. 2010, 49, 2360-2371.
DOI: 10.1021/ic902271x
• 329.  Polymers from Carbon Dioxide: Polycarbonates, Polythiocarbonates, and Polyurethanes, D. J. Darensbourg, Jeremy R. Andreatta, Adriana I. Moncada contribution in Aresta – Carbon Dioxide as Chemical Feedstock, First Edition, Ed. Michele Aresta, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010,  213-248.
• 328.  Highly Selective and Reactive (Salan)CrCl Catalysts for the Copolymerization and Block Copolymerization of Epoxides with Carbon Dioxide, Donald J. Darensbourg, Mahmut Ulusoy, Osit Karronnirun, Ross R. Poland, Joseph H. Reibenspies, and Bekir Çetinkaya Macromolecules  2009, 42, 6992-6998.
DOI: 10.1021/ma901364x
• 327.  Displacement Kinetics of η2 Bound Furan and 2,3-dihydrofuran from Mn and Cr Centers: Evidence for the Partial Dearomatization of the Furan Ligans, Jeremy R. Andreatta, Benjamin Cieslinski, Madeeha Batool, Xue-Zhong Sun, Michael W. George, Edward N. Brothers, Donald J. Darensbourg, Ashfaq A. Bengali Inorg. Chem.  2009,  48, 7787-7793.
DOI: 10.1021/ic900724f
• 326.  Investigations into the Coupling of Cyclohexene Oxide and Carbon Disulfide Catalyzed by (Salen)CrCl.  Selectivity for the Production of Copolymers vs Cyclic Thiocarbonates, Donald J. Darensbourg, Jeremy R. Andreatta, Matthew J. Jungman, and Joseph H. Reibenspies, Dalton Trans. 2009, 41, 8891-8899.
DOI: 10.1039/b911061e
• 325.  Copolymerization of Epoxides and Carbon Dioxide. Evidence Supporting the Lack of Dual Catalysis at a Single Metal Site, Donald J. Darensbourg, Shawn B. Fitch, Inorg. Chem. 2009, 48, 8668-8677.
DOI: 10.1021/ic900780a
• 324.  (Salen)Co(II)/n-Bu₄NX Catalysts for the Coupling of CO₂ and Oxetane: Selectivity for Cyclic Carbonate Formation in the Production of Poly-(trimethylene carbonate), Donald J. Darensbourg, Adriana I. Moncada, Macromolecules 2009, 42, 4063–4070.
DOI: 10.1021/ma9002006
• 323.  An Exploration of the Coupling Reactions of Epoxides and Carbon Dioxide Catalyzed by Tetramethyltetraazaannulene Chromium(III) Derivatives: Formation of Copolymers vs Cyclic Carbonates, Donald J. Darensbourg, Shawn B. Fitch, Inorg. Chem. 2008, 47, 11868-11878.
DOI: 10.1021/ic801728e
• 322.  Mechanistic Insight into the Initiation Step of the Coupling Reaction of Oxetane or Epoxides and CO₂ Catalyzed by (salen)CrX Complexes, Donald J. Darensbourg, A. I. Moncada, Inorg. Chem. 2008, 47, 10000-10008.
DOI: 10.1021/ic801231p
• 321.  X-ray Crystal Structures of Five-Coordinate (Salen)MnN₃ Derivatives and Their Binding Abilities Towards Epoxides. Chemistry Relevant to the Epoxide/CO₂ Copolymerization Process, Donald J. Darensbourg, Eric B. Frantz, Dalton Trans. 2008, 5031-5036.
DOI: 10.1039/b806364h
• 320.  Studies of the Carbon Dioxide and Epoxide Coupling Reaction in the Presence of Fluorinated Manganese(III) Acacen Complexes: Kinetics of Epoxide Ring-Opening, Donald J. Darensbourg, Eric B. Frantz, Inorg. Chem. 2008, 47, 4977-4987.
DOI: 10.1021/ic800286p
• 319.  Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate) and Their Copolymers, Donald J. Darensbourg, Wonsook Choi, Osit Karroonnirun, and Nattamai Bhuvanesh, Macromolecules 2008, 41, 3493-3502.
DOI: 10.1021/ma800078t
• 318.  Mechanistic Studies of the Copolymerization Reaction of Oxetane and Carbon Dioxide to Provide Aliphatic Polycarbonates Catalyzed by (Salen)CrX Complexes, Donald J. Darensbourg, Adriana I. Moncada, Wonsook Choi, and Joseph H. Reibenspies J. Am. Chem. Soc. 2008, 130, 6523-6533.
DOI: 10.1021/ja800302c
• 317.  A Phase Separable Polycarbonate Polymerization Catalyst, Chayanant Hongfa, Jianhua Tian, Jeremy Andreatta, Donald J. Darensbourg, David E. Bergbreiter Chem. Commun. 2008, 975-977.
DOI: 10.1039/b711861a
• 316.  Switchable-Polarity Solvents Prepared with a Single Liquid Component, Lam Phan, Jeremy R. Andreatta, Loel K. Horvey, Colin F. Edie, Aimée-Lee Luco, Anish Michandani, Donald J. Darensbourg, Philip G. Jessop J. Org. Chem. 2008, 73, 127-132.
DOI: 10.1021/jo7017697
• 315.  What is the Real Steric Impact of Triphenylphosphite? Solid-State and Solution Structural Studies of Cis- and Trans-Isomers of M(CO)₄[P(OPh)₃]₂ (M = Mo and W), Donald J. Darensbourg, Jeremy R. Andreatta, Sarah M. Stranahan, and Joseph H. Reibenspies, Organometallics 2007, 26, 6832-6838.
DOI: 10.1021/om700761q
• 314.  Biomimetic Studies of a Polymeric Composite Material for Joint Repair Application, Rahul Ribeiro, Poulomi Ganguly, Donald J. Darensbourg, Meitin Usta, A. Hikmet Ucisik, Hong Liang, Journal of Materials Research 2007, 22, 1632-1639.
  DOI: 10.1557/JMR.2007.0204
• 313.  Inquiry into the Formation of Cyclic Carbonates During the (Salen)CrX Catalyzed CO₂/Cyclohexene Oxide Copolymerization Process in the Presence of Ionic Initiators, Donald J. Darensbourg, Paolo Bottarelli, and Jeremy R. Andreatta Macromolecules 2007, 40, 7727-7729.
  DOI: 10.1021/ma071206o
• 312.  Manganese(III) Schiff Base Complexes. Chemistry Relevant to the Copolymerization of Epoxides and Carbon Dioxide, Donald J. Darensbourg and Eric B. Frantz, Inorg. Chem. 2007, 46, 5967-5978.
  DOI: 10.1021/ic7003968
• 311.  (Tetramethyltetraazaannulene)ChromiumCl: A Highly Active Catalyst for the Alternating Copolymerization of Epoxides and Carbon Dioxide, Donald J. Darensbourg, Shawn B. Fitch, Inorg. Chem. 2007, 46, 5474-5476.
  DOI: 10.1021/ic7007842
• 310.  Making Plastics from Carbon Dioxide. Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO₂, Donald J. Darensbourg, Chemical Reviews, 2007, 107, 2388-2410.
  DOI: 10.1021/cr068363q
• 309.  Ring-Opening Polymerization of Cyclic Monomers by Biocompatible Metal Complexes. Production of Poly(lactide), Polycarbonates and Their Copolymers, Donald J. Darensbourg, Wonsook Choi, and Casseday P. Richers, Macromolecules 2007, 40, 3521-3523.
  DOI: 10.1021/ma062780n
• 308.  Further Studies Related to the Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by Chromium Schiff Base Complexes. Crystal Structures of Two μ-Hydroxo-Bridged Schiff Base Dimers of Chromium(III), Donald J. Darensbourg, Eric B. Frantz, Jeremy R. Andreatta, Inorganica Chimica Acta 2007, 360, 523-528.
  DOI: 10.1016/j.ica.2006.07.093
• 307.  Biometal Derivatives as Catalysts for the Ring-Opening Polymerization of Trimethylene Carbonate. Optimization of the Ca(II) Salen Catalyst System, Donald. J. Darensbourg, Wonsook Choi , Poulomi Ganguly, and Casseday P. Richers, Macromolecules, 2006, 39, 4374-4379.
  DOI: 10.1021/ma0603433
• 306.  Metal Salen Derivatives as Catalysts for the Alternating Copolymerization of Oxetanes and Carbon Dioxide to Afford Polycarbonates, Donald J. Darensbourg, Poulomi Ganguly, Wonsook Choi Inorg. Chem. 2006, 45, 3831-3833.
  DOI: 10.1021/ic052109j
• 305.  A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands, Andrea L. Phelps, Marilyn V. Rampersad, Shawn B. Fitch, Marcetta Y. Darensbourg, Donald J. Darensbourg,Inorg. Chem. 2006,45, 119-126.
  DOI: 10.1021/ic051367d
• 304.  Characterization of Steric and Electronic Properties of NiN₂S₂ Complexes as S-donor Metallodithiolate Ligands, Marilyn V. Rampersad, Stephen P. Jeffery, Melissa L. Golden, Jonghyuk Lee, Joseph H. Reibenspies, Donald J. Darensbourg, and Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2005, 127, 17323-17334.
  DOI: 10.1021/ja055051g
• 303.  The Role of the Cocatalyst in the Copolymerization of CO₂ and Cyclohexene oxide Utilizing Chromium Salen Complexes, Donald. J. Darensbourg, Ryan M. Mackiewicz, Jody L. Rodgers J. Am. Chem. Soc. 2005, 127, 14026-14038.
  DOI: 10.1021/ja053544f
• 302.  The Synthesis and Characterization of Iron Cyanide Building Blocks. [K]₂[CpFe(CN)₃] and its Pentamethylcyclopentadienyl (Cp*) Analog, Donald J. Darensbourg, Way-Zen Lee, Andrea L. Phelps, Inorganica Chimica Acta 2005, 358, 4095-4098.
  DOI: 10.1016/j.ica.2005.06.027
• 301.  Ring Opening Polymerization of Trimethylene Carbonate Using Aluminum (III) and Tin (IV) Salen Chloride Catalysts, Donald. J. Darensbourg, Poulomi Ganguly, Damon Billodeaux Macromolecules 2005, 38, 5406-5410.
  DOI: 10.1021/ma050666j
• 300.  Effective, Selective Coupling of Propylene Oxide and Carbon Dioxide to Poly(propylene carbonate) Using (salen)CrN₃ Catalysts, Donald J. Darensbourg, Andrea L. Phelps, Inorg. Chem. 2005, 44, 4622-4629.
  DOI: 10.1021/ic050443+
• 299.  N₂S₂Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity, Marilyn V. Rampersad, Stephen P. Jeffery, Joseph H. Reibenspies, Cesar G. Ortiz, Donald J. Darensbourg and Marcetta Y. Darensbourg, Angew. Chem., Int. Ed., 2005, 117, 1243-1246.
  DOI: 10.1002/anie.200461747
• 298.  Aluminum Salen Complexes and Tetrabutyl Ammonium Salts: A Binary Catalytic System for Production of Polycarbonates from CO₂ and Cyclohexene Oxide, Donald J. Darensbourg and Damon R. Billodeaux, Inorg. Chem. 2005, 44, 1433-1442.
  DOI: 10.1021/ic048508g
• 297.  Pressure Dependence of the Carbon Dioxide/Cyclohexene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes.  Optimization of the Comonomer-Alternating Enchainment Pathway, Donald. J. Darensbourg, Ryan M. Mackiewicz, and Damon R. Billodeaux, Organometallics 2005, 24, 144-148.
  DOI: 10.1021/om049454l
• 296.  The Structural Characterization of Several (CO)₃(dppp)MnX Derivatives, dppp = diphenylphosphinopropane and X = H, OTs, OC₂H₅, Cl, Br or N₃.  An Assessment of Their Efficacy for Catalyzing the Coupling of Carbon Dioxide and Epoxides, Donald. J. Darensbourg, Poulomi Ganguly, and Damon R. Billodeaux, Organometallics2004, 23, 6025-6030.
  DOI: 10.1021/om049352v
• 295.  The Copolymerization of CO₂/Epoxides Catalyzed by Metal Salen Complexes, D. J. Darensbourg, Ryan M. Mackiewicz, Andrea L. Phelps, Damon R. Billodeaux Acc. Chem. Res. 2004, 37, 836-844.
  DOI: 10.1021/ar030240u
• 294.  Probing the Mechanistic Aspects of the Chromium Salen Catalyzed Carbon Dioxide/Epoxide Copolymerization Process Using in situ ART/FTIR, Donald J. Darensbourg, Jody L. Rodgers, Ryan M. Mackiewicz, Andrea L. Phelps, Catalysis Today, 2004, 98, 485-492.
  DOI: 10.1016/j.cattod.2004.09.017
• 293.  Mechanistic Studies of the Copolymerization Reaction of Aziridines and Carbon Monoxide to Produce Poly-β-peptoids, Donald J. Darensbourg, Andrea L. Phelps, Nathalie Le Gall, and Li Jia, J. Am. Chem. Soc. 2004, 126, 13808-13815.>
  DOI: 10.1021/ja046225h
• 292.  ¹¹³Cd NMR Determination of the Binding Parameters of Alicyclic Epoxides to [Hydrotris(3-phenyl-pyrazol-1-yl)borate]Cd(II) Acetate, D. J. Darensbourg, Damon R. Billodeaux, Lisa M. Perez, Organometallics, 2004, 23, 5286-5290.
  DOI: 10.1021/om049761r
• 291.  Cyclohexene/CO₂ Copolymerization Catalyzed by Chromium(III) Salen and N-Methylimidazole:  Effects of Varying Salen Ligand Substituents and Relative Cocatalyst Loading, Donald. J. Darensbourg, Jody L. Rodgers, Ryan M. Mackiewicz, Cindy C. Fang, Damon R. Billodeaux, Joseph H. Reibenspies, Inorg. Chem. 2004, 43, 6024-6034.
  DOI: 10.1021/ic049182e
• 290.  Five-coordinate Schiff base complexes of gallium.  Potential catalysts for the copolymerization of carbon dioxide and epoxides, D. J. Darensbourg, Damon R. Billodeaux, Comptes Rendus Chimie 2004, 7, 755-761.
  DOI: 10.1016/j.crci.2003.11.013
• 289.  Catalysts for an Aqueous Catalysis, D. J. Darensbourg, C. G. Ortiz contribution in Aqueous-Phase Organometallic Catalysis, Second Edition, Ed. Boy Cornils and Wolfgang A. Herrmann, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2004,  71-85.
• 288.  Cis-hexahydro-1,4-benzodioxin-2,3-dione, D. J. Darensbourg, Damon R. Billodeaux, Poulomi Ganguly, Acta. Cryst. 2004, E60, 868-869.
  DOI: 10.1107/S1600536804009055
• 287.  Phosphine Derivatives of Diamond-Shaped Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups, D. J. Darensbourg, W.-Z. Lee, M. J. Adams, Inorganic Syntheses, 2004, vol. 34, 172-177.
  
• 286.  Synthesis and Structural Characterization of Iron(III) Salen Complexes Possessing Appended Anionic Oxygen Donor Ligands, D. J. Darensbourg, C. G. Ortiz, Inorganica Chimica Acta 2004, 357, 2143-2149.
  DOI: 10.1016/j.ica.2003.12.019
• 285.  A New Water-Soluble Phosphine Derived from 1,3,5-Triaza-7-Phosphaadamantane (PTA), 3,7-Diacetyl-1,3,7-Triaza-5-Phosphabicyclo[3.3.1]-nonane.  Structural, Bonding, and Solubility Properties, D. J. Darensbourg, C. G. Ortiz, J. W. Kamplain  Organometallics 2004, 23, 1747-1754.
  DOI: 10.1021/om0343059
• 284.  (Salen)Cr^IIIX Catalysts for the Copolymerization of Carbon Dioxide and Epoxides.  Role of the Initiator and Cocatalyst, D. J. Darensbourg, R. M. Mackiewicz, J. L. Rodgers, A. L. Phelps, Inorg. Chem. 2004, 43, 1831-1833.
  DOI: 10.1021/ic0352856
• 283.  Mixed Metal Cyanide Complexes Derived from the CpCo(CN)₃^– Anion, D. J. Darensbourg, A. L. Phelps, Inorganica Chimica Acta 2004, 357, 1603-1607.
  DOI: 10.1016/j.ica.2003.11.016
• 282.  Catalytic Coupling of Carbon Dioxide and 2,3-Epoxy-1,2,3,4-tetrahydronapthalene in the Presence of a (Salen)Cr^IIICl Derivative, D. J. Darensbourg, C. C. Fang, J. L. Rodgers, Organometallics 2004, 23, 924-927.
  DOI: 10.1021/om034278m
• 281.  A Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide into fac-(CO)₃(dppe)MnOR Derivatives, D. J. Darensbourg, W-Z. Lee, A. L. Phelps, E. Guidry Organometallics 2003, 22, 5585-5588.
  DOI: 10.1021/om034087j
• 280.  The Synthesis and Structural Characterization of Double Metal Cyanides of Iron and Zinc. Catalyst Precursors for the Copolymerization of Carbon Dioxide and Epoxides, D. J. Darensbourg, M. J. Adams, J. C. Yarbrough, A. L. Phelps, Inorg. Chem. 2003, 42, 7809-7818.
  DOI: 10.1021/ic0347900
• 279.  Synthesis and Structural Characterization of Potassium Salts of Phosphine Substituted Cyclopentadienyl Iron Dicyanides, and Their Use as Bridging Ligands for Copper (I) Phosphine Derivatives, D. J. Darensbourg, M. J. Adams, J. C. Yarbrough, A. L. Phelps Eur. J. Inorg. Chem. 2003, 3639-3648.
  DOI: 10.1002/ejic.200300304
• 278.  Synthesis and Structures of Nickel and Palladium Salicylaldiminato 1,3,5-Triaza-7-Phosphaadamantane (PTA) Complexes, D. J. Darensbourg, C. G. Ortiz, J. C. Yarbrough Inorg. Chem. 2003, 42, 6915-6922.
  DOI: 10.1021/ic0341284
• 277.  The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl.  Formation of a CO₂ Soluble Polycarbonate D. J. Darensbourg, J. L. Rodgers, C. C. Fang, Inorg. Chem. 2003,42, 4498-4500.
  DOI: 10.1021/ic034363m
• 276.  Comparative Kinetic Studies of the Copolymerization of Cyclohexene Oxide and Propylene Oxide with Carbon Dioxide in the Presence of Chromium Salen Derivatives.  In situ FTIR Measurements of Copolymer vs Cyclic Carbonate Production, D. J. Darensbourg, J. C. Yarbrough, C. G. Ortiz, C. Fang J. Am. Chem. Soc. 2003, 125, 7586-7591.
  DOI: 10.1021/ja034863e
• 275.  2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-dioxide (PASO₂). A Comparative Structural and Reactivity Investigation with the Water-Soluble Phosphine Ligand, 1,3,5-triaza-7 phosphaadamantane (PTA), D. J. Darensbourg, J. C. Yarbrough Organometallics 2003, 22, 2050-2056.
  DOI: 10.1021/om0300225
• 274.  Intermolecular Hydrogen-Bonding in the Solid-State Structure of CpFe(CN)₂(PTAH).  Structural and Spectral Comparisons with its [K][CpFe(CN)₂PTA] Salt, D. J. Darensbourg, A. L. Phelps, M. J. Adams, J. C. Yarbrough Journal of Organometallic Chemistry 2003, 666, 49-53.
  DOI: 10.1016/S0022-328X(02)02032-6
• 273.  Carbon Dioxide/Epoxide Coupling Reactions Utilizing Lewis Base Adducts of Zinc Halides as Catalysts.  Cyclic Carbonate versus Polycarbonate Production, D. J. Darensbourg, S. J. Lewis, J. L. Rodgers, J. C. Yarbrough, Inorg. Chem. 2003, 42, 581-589.
  DOI: 10.1021/ic0259641
• 272.  Solution and Solid-State Structural Studies of Epoxide Adducts of Cadmium Phenoxides. Chemistry Relevant to Epoxide Activation for Ring-Opening Reactions, D. J. Darensbourg, J. R. Wildeson, S. J. Lewis, J. C. Yarbrough, J. Am. Chem. Soc. 2002, 124, 7075-7083.
  DOI: 10.1021/ja020184c
• 271.  Mechanistic Aspects of the Copolymerization Reaction of Carbon Dioxide and Epoxides using a Chiral Salen Chromium Chloride Catalyst, D. J. Darensbourg, J. C. Yarbrough, J. Am. Chem. Soc. 2002, 124, 6335-6342.
  DOI: 10.1021/ja012714v
• 270.  Solid-State Structure of Zinc(II) Benzoate Complexes. Catalysts Precursor for the Coupling of Carbon Dioxide and Epoxides, D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, Inorg. Chem. 2002, 41, 973-980.
  DOI: 10.1021/ic0107983
• 269.  Synthesis, Characterization and Crystal Structure of a Zinc bis-dithiocarboxylate Derivative, D. J. Darensbourg, M. J. Adams, J. C. Yarbrough, Inorg. Chem. Commun. 2002, 5, 38-41.
  DOI: 10.1016/S1387-7003(01)00342-2
• 268.  Towards the Design of Double Metal Cyanides for the Copolymerization of CO₂ and Epoxides, D. J. Darensbourg, M. J. Adams, J. C. Yarbrough, Inorg. Chem. 2001, 40, 6543-6544.
  DOI: 10.1021/ic0155941
• 267.  Synthesis and Characterization of Monocyanide-Bridged Bimetallic Iron(II) and Copper(I) Complexes, D. J. Darensbourg, W.-Z. Lee, J. C. Yarbrough, Inorg. Chem. 2001, 40, 6533-6536.
  DOI: 10.1021/ic010683z
• 266.  Synthesis and Structures of (Dialkylamino)ethylcyclopentadienyl Derivatives of Zinc, D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, Organometallics, 2001, 20, 4413-4417.
  DOI: 10.1021/om010519j
• 265.  Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups Containing Monodentate or Bidentate Phosphines Bound to Copper(I).  Including an Alternative Structure Based on the Nature of the Bidentate Phosphine Ligand, D. J. Darensbourg, W.-Z. Lee, M. J. Adams, J. C. Yarbrough, Eur. Jour. Inorg. Chem. 2001, 2811-2822.
  DOI: 10.1002/1099-0682(200111)2001:11
• 264.  Tricyclohexylphosphine Derivatives of Bis(2,6-difluorophenoxide)Cadmium.  A Solution and Solid-State NMR Study, D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, R. E. Taylor, Inorg. Chem. 2001, 40, 3639-3642.
  DOI: 10.1021/ic010104q
• 263.   An Experimental and Theoretical Investigation of the Carbon Dioxide Insertion Process Into the Tungsten-Nitrogen Bond of an Anionic W(0) Complex, D. J. Darensbourg, B. J. Frost, D. L. Larkins, Inorg. Chem. 2001, 40, 1993-1999.
  DOI: 10.1021/ic001006s
• 262.  Bis-Salicylaldiminato Complexes of Zinc. Catalyst Precursors for Epoxide/CO₂ Copolymerization, D.J. Darensbourg, P. Rainey, J. Yarbrough, Inorg. Chem. 2001, 40, 986-993.
  DOI: 10.1021/ic0006403
• 261.  Synthesis and Physical Characterization of Poly(Cyclohexane Carbonate), Synthesized from CO₂ and Cyclohexene Oxide, C. Koning, J. Wildeson, R. Parton, B. Plum, P. Steeman, D. J. Darensbourg, Polymer 2001, 42, 3995-4004.
  DOI: 10.1016/S0032-3861(00)00709-6
• 260.  Bis 2,6-difluorophenoxide Dimeric Complexes of Zinc and Cadmium and Their Phosphine Adducts.  Lessons Learned Relative to Carbon Dioxide/Cyclohexene Oxide Alternating Copolymerization Processes Catalyzed by Zinc Phenoxides, D. J. Darensbourg, J. R. Wildeson, J. C. Yarbrough, J. H. Reibenspies, J. Am. Chem. Soc. 2000, 122, 12487-12496.
  DOI: 10.1021/ja002855h
• 259.  Synthesis and Crystal Structure of [H₂B(3-Phpz)₂]₂Zn, D. J. Darensbourg, J. C. Yarbrough, J. of Organometal. Chem., 2000, 614-615, 305-308.
  DOI: 10.1016/S0022-328X(00)00594-5
• 258.  Organometallic Complexes of Uracil and Orotic Acid Derivatives: Coordination Mode, Structure, and Reactivity, D. J. Darensbourg, B. J. Frost, D. L. Larkins, J. H. Reibenspies, Eur. J. Inorg. Chem., 2000, 2487-2495.
  DOI: 10.1002/1099-0682(200012)2000
• 257.  Water Soluble Organometallic Compounds. 9¹. Catalytic Hydrogenation and Selective Isomerization of Olefins by Water Soluble Analogs of Vaska’s Complex, J. Kovács, T. Decuir, J.H. Reibenspies, F. Joó, D.J. Darensbourg, Organometallics, 2000, 19, 3963-3969.
  DOI: 10.1021/om000380x
• 256.  Water-Soluble Organometallic Compounds. 8¹. Synthesis, Spectral Properties, and Crystal Structures of 1,3,5-Triaza-7-phosphaadamantane (PTA) Derivatives of Metal Carbonyl Clusters: Ru₃(CO)₉(PTA)₃ and Ir(CO)₇(PTA)₅, D.J. Darensbourg, Floyd A. Beckford, J.H. Reibenspies, J. Cluster Science, 2000, 11, 95-107.
  DOI: 10.1023/A:1009060614412
• 255.  Solution and Solid State Structures of Phosphine Adducts of Monomeric Zinc (bis-phenoxide) Complexes.  The Importance of These Derivatives in CO₂/Epoxide Copolymerization Processes, D.J. Darensbourg, M.S. Zimmer, P. Rainey, D.L. Larkins, Inorg. Chem., 2000, 39, 1578-1585.
  DOI: 10.1021/ic990594a
• 254.  Solution ³¹P and ¹¹³C NMR Studies of Phosphine Adducts of Monomeric Cadmium (Bisphenoxide) Complexes and the Solid-State Structures of 2,6-Di-tert-butylphenoxide)₂Cd(PCy₃) and (2,6-Di-tert-butylphenoxide)₂Cd(Pme₃)₂, D.J. Darensbourg, P. Rainey, D.L. Larkins, J.H. Reibenspies Inorg. Chem. 2000, 39, 473-479.
  DOI: 10.1021/ic991008g
• 253.  Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl: A Theoretical and Experimental Investigation Into the Chelation/Dechelation of Thiouracil via CO Loss and Addition, D.J. Darensbourg, B.J. Frost, A. Derecskei-Kovacs, J.H. Reibenspies, Inorg. Chem., 1999, 38, 4715-4723.
  DOI: 10.1021/ic990758n
• 252.  Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexs Containing p-Donor Ligands, D. J. Darensbourg, J. D. Draper, J. H. Reibenspies, Inorg. Chem., 1999, 38, 4705-4714.
  DOI: 10.1021/ic9804216
• 251.  Water-Soluble Organometallic Compounds. 7¹. Further Studies of 1,3,5-Triaza-phosphaadamantane Derivatives of Group 10 Metals, Including Metal Carbonyls and Hydride, D.J. Daresnbourg, J.B. Robertson, D.L. Larkins, J.H. Reibenspies, Inorg. Chem., 1999, 38, 2473-2481.
  DOI: 10.1021/ic981243j
• 250.  Copolymerization and Terpolymerization of CO₂ and Epoxides Using a Soluble Zinc Crotonate Catalyst Precursor, D.J. Darensbourg, M.S. Zimmer, Macromolecules, 1999, 32, 2137-2140.
  DOI: 10.1021/ma9817471
• 249.  Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper (I) Bridged by Cyanide Groups, D.J. Darensbourg, W-Z. Lee, M.J. Adams, D.L. Larkins, J.H. Reibenspies, Inorg. Chem., 1999, 38, 1378-1379.
  DOI: 10.1021/ic981419h
• 248.  Trigonal-Planar Zn(II) and Cd(II) Tris(phenoxide) Complexes, D. J. Darensbourg, S. A. Niezgoda, J. D. Draper, J. H. Reibenspies, Inorg. Chem., 1999, 38, 1356-1359.
  DOI: 10.1021/ic9805325
• 247.  The Catalytic Activity of a Series of Zn(II) Phenoxides for the Copolymerization of Epoxides and Carbon Dioxide, D. J. Darensbourg, M. W. Holtcamp, G. E. Struck, M. S. Zimmer, S. A. Niezgoda, P. Rainey, J. B. Robertson, J. D. Draper, J. H. Reibenspies, J. Amer. Chem. Soc., 1999, 121, 107-116.
  DOI: 10.1021/ja9826284
• 246.  Bis-Triphenylphosphine Copper(I) Complexes of Orotate and L-Dihyroorotate, D. J. Darensbourg, D. L. Larkins, J. H. Reibenspies, Inorg. Chem., 1998, 37, 6125-6128.
  DOI: 10.1021/ic980464m
• 245.  Responses of the Fe(CN)₂(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase, C.-H. Lai, W.-Z. Lee, M. M. Miller, J. H. Reibenspies, D. J. Darensbourg, M. Y. Darensbourg, J. Am. Chem. Soc., 1998, 120, 10103-10114.
  DOI: 10.1021/ja982053a
• 244.  Binucleating Coordination Mode of N, N'-Ethylenebis (salicylideneimine)(H₂SALEN) to Low-Valent Group-Six Carbonyl Complexes, D. J. Darensbourg, J. D. Draper, Inorg. Chem., 1998, 37, 5383-5386.
  DOI: 10.1021/ic980173d
• 243.  (Meta-Sulfonatophenyl) Diphenylphosphine, Sodium Salts and its Complexes with Rhodium(I), Ruthenium(II), Iridium(I), F. Joo;, J. Kovacs, A. Katho;, A. C. Benyei, T. Decuir, D. J. Darensbourg, Inorg. Synthesis, 1998, 32, 1.
• 242.  Phosphine Adducts of Monomeric Zinc(bis-phenoxides): Solution and Solid-State Structures of (2,6-Di-tert-butylphenoxide)ZnL Complexes (L = PMePh₂ and PCy₃), D. J. Darensbourg, M. S. Zimmer, P. Rainey, D. L. Larkins, Inorg. Chem., 1998, 37, 2852-2853.
  DOI: 10.1021/ic980185z
• 241.  Organometallic Derivatives of Orotic Acid. CO-Labilizing Ability of the Amino Group in Chromium and Tungsten Carbonyl Complexes, D. J. Darensbourg, J. D. Draper, D. L. Larkins, B. J. Frost, J. H. Reibenspies, Inorg. Chem., 1998, 37, 2538-2546.
  DOI: 10.1021/ic980233f
• 240.  Mechanistic Aspects of the Copolymerization of CO₂ and epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogs, D. J. Darensbourg, S.A. Niezgoda, J. D. Draper, J. H. Reibenspies, J. Amer. Chem. Soc., 1998, 120, 4690-4698.
  DOI: 10.1021/ja9801487
• 239.  Crystal Structures of Aryloxide Complexes of Zinc Embracing Sodium Aryl Group Interactions Na[Zn(2,6-diphenylphenoxide)₃(H₂O)] and Na[Zn₂(2,6-diisopropylphenoxide)4Cl]•3THF, D. J. Darensbourg, J. C. Yoder, G. E. Struck, M. W. Holtcamp, J. D. Draper, and J. H. Reibenspies, Inorg. Chim. Acta, 1998, 274, 115-121.
  DOI: 10.1016/S0020-1693(97)05962-8
• 238.  The Propensity of Alkoxide and Aryloxide Derivatives of Tungsten Carbonyls to Aggregate in Solution. Synthesis and X-ray Structures of Dinuclear and Tetranuclear Complexes Derived from the MeOW(CO)₅^- Anion, D. J. Darensbourg, K. K. Klausmeyer, J. D. Draper, J. A. Chojnacki, and J. H. Reibenspies, Inorg. Chim. Acta,1998, 270, 405-413.
  DOI: 10.1016/S0020-1693(97)05996-3
• 237.  Structural Diversity in Monomeric Cadmium Phenoxides, D. J. Darensbourg, S. A. Niezgoda, J. H. Reibenspies, and J. D. Draper, Inorg. Chem., 1997, 36, 5686-5688.
  DOI: 10.1021/ic971002w
• 236.  Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase, D. J. Darensbourg, J. H. Reibenspies, C-H Lai, W-Z Lee, and M. Y. Darensbourg, J. Am. Chem. Soc., 1997, 119, 7903-7904
  DOI: 10.1021/ja971559a
• 235.  Water Soluble Organometallic Compounds. 6. Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triazaphosphaadamantane of Group 10 Metals, D. J. Darensbourg, T. J. Decuir, N. W. Stafford, J. B. Robertson, J. D. Draper, J. H. Reibenspies, A. Katho, F. Joó, Inorg. Chem., 1997, 36, 4218-4226.
  DOI: 10.1021/ic970238x
• 234.  Amino Acid Complexes of Metal Carbonyls: Mechanistic Aspects of the CO-labilizing Ability of the Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives, D. J. Darensbourg, J. D. Draper, and J. H. Reibenspies, Inorg. Chem., 1997, 36, 3648-3656.
  DOI: 10.1021/ic961344m
• 233.  Synthesis, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Process, D. J. Darensbourg, S. A. Niezgoda, M. W. Holtcamp, J. D. Draper, and J. H. Reibenspies, Inorg.Chem., 1997, 36, 2426-2432.
  DOI: 10.1021/ic9701120
• 232.  Crystal Structure of aqua-bis(2,9-dimethyl-1, 10-phenanthroline)-p-toluene-sulfonatoruthenium (II) p-toulenesulfonate-methanol-hydrate(1/2/2), [Ru(C₁4H₁₂N₂)₂(CH₃C₆H₄SO₃)(OH₂)]CH₃C₆H₄SO₃•2CH₃OH•2H₂O, J. H. Reibenspies, D. J. Darensbourg, and A. C. Benyei, Zeitschrift für Kristallographie, 1996, 211, 977.
• 231.  Cyanide Bridged Heterobimetallic Complexes of the Group 6 Metal Carbonyls and Copper(I). X-ray Structures of (CO)₅MCNCu(PPh₃)₃ (M = Cr or W) Derivatives. D. J. Darensbourg, J. C. Yoder, M. W. Holtcamp, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1996, 35, 4764-4769.
  DOI: 10.1021/ic9510627
• 230.  The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)₅OH^- Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)₅O₂COH]. D. J. Darensbourg, M. L. Meckfessel Jones, and J. H. Reibenspies, Inorg. Chem., 1996, 35, 4406-4413.
  DOI: 10.1021/ic9516525
• 229.  A Catalyst for Propylene Carbonate Production from CO₂/Propylene Oxide: Synthesis and X-ray Structure of the Novel Aluminum Complex,[{η³-HB(3-Phpz)₂(5-Phpz)}₂Al][AlCl₄], D. J. Darensbourg, E. L. Maynard, M. W. Holtcamp, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1996, 35, 2682-2684.
  DOI: 10.1021/ic951018r
• 228.  Catalysts for the Reactions of Epoxides and Carbon Dioxide, D. J. Darensbourg and M. W. Holtcamp, Coordination Chemistry Reviews, 1996, 153, 155-174.
  DOI: 10.1016/0010-8545(95)01232-X
• 227.  Structural Characterizations of Coordination Complexes of Bis-Triphenyl phosphine Copper(I) Dicarboxylates, D. J. Darensbourg, M. W. Holtcamp, and J. H. Reibenspies, Polyhedron, 1996, 15, 2341-2349.
  DOI: 10.1016/0277-5387(95)00518-8
• 226.  Aqueous Organometallic Chemistry: The Mechanism of Catalytic Hydrogenations with Chlorotris(1,3,5-triaza-7-phosphaadamantane)rhodium(I), F. Joo, L. Nadasdi, A. Cs. Benyei, and D. J. Darensbourg, J. Organomet. Chem., 1996, 512, 45-50.
  DOI: 10.1016/0022-328X(95)05946-M
• 225.  Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by p-Donating Amido Ligands, D.J. Darensbourg, K.K. Klausmeyer, and J.H. Reibenspies, Inorg. Chem., 1996, 35, 1535-1539.
  DOI: 10.1021/ic950985z
• 224.  Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the p-donating Ligand 3,5-di-tert-butylcatecholate, D. J. Darensbourg, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1996, 35, 1529-1534.
  DOI: 10.1021/ic950968+
• 223.  Crystal Structure of Tetraehylammonium bix(3,5-di-(tert-butyl)-catecholate)dioxorhenate, C₃₆H₆₀NO₆Re, J. H. Reibenspies, J. D. Draper and D. J. Darensbourg, Zeitschrift fur Kristallographie, 1995, 211, 501.
• 222.  Crystal Structure of Tricyclohexylphosphine Sulfide, (C₆H₁₁)₃PS, J. H. Reibenspies, J. D. Draper, G. Struck and D. J. Darensbourg, Zeitschrift fur Kristallographie, 1995, 211, 400.
• 221.  Supercritical Carbon Dioxide as Solvent for the Copolymerization of Carbon Dioxide and Propylene Oxide Using a Heterogeneous Zinc Carboxylate Catalyst, D. J. Darensbourg, N. W. Stafford, and T. Katsurao, J. Mol. Catal. 1995, 104, L1-L4.
  DOI: 10.1016/1381-1169(95)00142-5
• 220.  Crystal Structure of bis(tetraethylammonium)hexafluoeotungstate(IV) dihydrate, ((C₂H₅)₄N)₂(WF₆)(H₂O)₂, J. H. Reibenspies, K. K. Klausmeyer, and D. J. Darensbourg, Zeitschrift fur Kristallographie, 1995, 210, 882.
• 219.  The Catalytic Activity of Zn(II) Phenoxides Which Possess Readily Accessible Coordination Sites. The Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide, D. J. Darensbourg, and M. W. Holtcamp, Macromolecules, 1995, 28, 7577-7579.
  DOI: 10.1021/ma00126a043
• 218.  113Cd Shielding Tensors of Momomeric Cadmium Compounds Containing Nitrogen Donor Atoms. 2. Synthesis, Crystal Structures, and ¹¹³Cd NMR Spectroscopy of the Six-Coordinate Complexes [HB(pz)₃]₂Cd, [HB(3-(Phpz)₃]₂Cd, and [B(pz)₄]Cd[HB(3-Phpz)₃] (pz = pyrazolyl), D. L. Reger, S. M. Meyers, S. S. Mason, D. J. Darensbourg, M. W. Holtcamp, K. K. Klausmeyer, J. H. Reibenspies, A. S. Lipton, and P.D. Ellis, J. Am. Chem. Soc., 1995, 117, 10998-11005.
  DOI: 10.1021/ja00149a024
• 217.  The Use of 1,3,5-Triaza-7-Phosphaadamantane (PTA), A Water-Soluble, Air Stable Ligand, in Organometallic Chemistry and Catalysis, D. J. Darensbourg, T. J. Decuir, and J. H. Reibenspies, Contributions to Volume on “Aqueous Organometallic Chemistry and Catalysis”, I. T. Horvath and F. Joo, Eds. NATO ASI Series, Kluwer Academic Publishers, 1995, 61.
• 216.  Crystal Structure of Di-m-chloro-tris(triphenylphosphine)dicopper(I)-dichloromethane, C₅₅H₄₇Cl₄Cu₂P₃; D.J. Darensbourg, M.W. Holtcamp, K.K. Klausmeyer, and J.H. Reibenspies; Zeitschrift fu¨r Kristallographie, 1995, 210, 615.
• 215.  Crystal Structure of Bis(hydro(tris-3-phenylpyrazolyl)borate)-cadmium(II), C₂₇H₂₁BCd_0.50N₆, J. H. Reibenspies, K. K. Klausmeyer, S. A. Niezgoda, M. W. Holtcamp, and D. J. Darensbourg; Zeitschrift fu¨r Kristallographie, 1995, 210, 617.
• 214.  Coordination Complexes of Bis-Triphenylphosphine Copper(I) Carbonate and Bicarbonate, D. J. Darensbourg, M. W. Holtcamp, B. Khandelwal, and J. H. Reibenspies, Inorg. Chem., 1995, 34, 5390-5394.
  DOI: 10.1021/ic00125a047
• 213.  CO-Labilizing Ability of the Fluoride Ligand in Tungsten(0) Carbonyl Fluorides. The X-Ray Structure of [Et₄N]₃[W₂(CO)₆F₃], D. J. Darensbourg, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1995, 34, 4933-4934.
  DOI: 10.1021/ic00124a002
• 212.  Chromium Tricarbonyl Catecholate Derivatives. Structural and Reactivity Studies of "Sixteen Electron" Complexes.¹, D. J. Darensbourg, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1995, 34, 4676-4681.
  DOI: 10.1021/ic00122a026
• 211.  A More Intimate Examination of the Role of Copper(I) in the Decarboxylation of Derivatives of Malonic Acid. Comparisons with Zinc(II) Analogs, D. J. Darensbourg, M. W. Holtcamp, B. Khandelwal, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1995, 34, 2389-2398.
  DOI: 10.1021/ic00113a021
• 210.  Crystal Structure of Acetato-1,5,9-Triazacyclododecane-Zinc Tetraphenylborate, [(C₉H₂₁N₃)(CH₃CO₂)Zn][(C₆H₅)₄B], J. H. Reibenspies, M. W. Holtcamp, B. Khandelwal, and D. J. Darensbourg, Zeitschrift für Kristallographie, 1995, 210, 148.
• 209.  Crystal Structure of Cyanoacetato-Tetrahydrofuran-Tris(3-Phenyl-Pyrazol-1-yl)Hydroborato-Cadmium, C₃₄H₃₂BCdN₇O₃, J. H. Reibenspies, M. W. Holtcamp, B. Khandelwal, and D. J. Darensbourg, Zeitschrift für Kristallographie, 1995, 210, 146.
• 208.  Syntheses and Structures of Epoxide Adducts of Soluble Cd(II) Carboxylates. Models for the Initiation Process in Epoxide/CO₂ Coupling Reactions, D. J. Darensbourg, M. W. Holtcamp, B. Khandelwal, K. K. Klausmeyer, and J. H. Reibenspies, J. Am. Chem. Soc., 1995, 117, 538-539.
  DOI: 10.1021/ja00106a065
• 207.  The Role of the Metal Center in the Homogeneous Catalytic Decarboxylation of Select Carboxylic Acids. Copper(I) and Zinc(II) Derivatives of Cyanoacetate, D. J. Darensbourg, M. W. Holtcamp, E. M. Longridge, B. Khandelwal, K. K. Klausmeyer, and J. H. Reibenspies, J. Am. Chem. Soc., 1995, 117, 318-328.
  DOI: 10.1021/ja00106a034
• 206.  Water-Soluble Organometallic Compounds. 5.1 The Regio-Selective Catalytic Hydrogenation of Unsaturated Aldehydes to Saturated Aldehydes in an Aqueous Two-Phase Solvent System Using 1,3,5-Triaza-7-Phosphaadamantane Complexes of Rhodium, D. J. Darensbourg, N. White Stafford, F. Jóo, and J. H. Reibenspies, J. Organomet. Chem., 1995, 488, 99-108.
  DOI: 10.1016/0022-328X(94)00024-7
• 205.  Structural Characterization of Bidentate Carboxylate Derivatives of Copper(I) BisTriphenylphosphine, D. J. Darensbourg, M. W. Holtcamp, E. M. Longridge, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chimica Acta, 1994, 227, 223-232.
  DOI: 10.1016/0020-1693(94)04214-4
• 204.  Crystal Structure of Diphenylphosphinepentacarbonyltungsten(0), (C₆H₅)₂PH(CO)₅W, J. H. Reibenspies, D. J. Darensbourg, and E. V. Atnip, Zeitschrift für Kristallographie, 1994, 209, 759.
• 203.  Homogeneous Catalytic Synthesis of Formaldehyde Using the Tungsten Carbonyl Complex [(CO)₅WCl]– in the Presence of Sodium Methoxyde, C. Ovalles, C. Fernández, and D. J. Darensbourg, J. Mol. Catal., 1994, 93, 125-136.
  DOI: 10.1016/0304-5102(94)00099-9
• 202.  Amino Acid Derivatives of Tungsten Carbonyl. Structure and Reactivity Investigations of Zero-Valent Tungsten Glycine Derivatives, D. J. Darensbourg, E. V. Atnip, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1994, 33, 5230-5237.
  DOI: 10.1021/ic00101a014
• 201.  Crystal Structure of Bis(Bis(Triphenylphosphine)-m-N,O-Cyanoacetato) Copper(I)Tetrahydrofuran, C₈₆H₈₀Cu₂N₂O₆P₄, J.H. Reibenspies, D. J. Darensbourg, S. A. Niezgoda, M. W. Holtcamp, and K. K. Klausmeyer, Zeitschrift für Kristallographie, 1994, 209.
• 200.  Crystal Structure of m-N,N'-Malonitrile-Bis(Pentacarbonyltungsten) Methylene Chloride, C₁₃H₄C_l2N₂O₁₀W, J. H. Reibenspies, D. J. Darensbourg, and E. V. Atnip, Zeitschrift für Kristallographie, 1994, 209, 379.
• 199.  Crystal Structure of Tetraethylammonium O-Methyldithiocarbonate, C₁₀H₂₃NOS₂, J.H. Reibenspies, D. J. Darensbourg, and M. L. Meckfessel Jones, Zeitschrift für Kristallographie, 1994, 209, 377.
• 198.  Aryloxide and Alkoxide Derivatives of Metal Clusters. The Synthesis, Structure and Reactivity of m-Oxo-bridged Triruthenium Clusters, Ru₃(CO)₈(μ-η²-OC₆H₄Cl)₂ and Ru₃(CO)₈(μ-η²-OCH₂C₅H₄N)₂, D. J. Darensbourg, B. Fontal, S. S. Chojnacki, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1994, 33, 3526-3532.
  DOI: 10.1021/ic00094a015
• 197.  Synthesis and Structure of 1,2-bis(Diphenylphosphino)ethane Complexes of Copper(I) Acetate. Catalysts for the Decaroboxylation of Carboxylic Acids, D. J. Darensbourg, E. M. Longridge, B. Khandelwal, and J. H. Reibenspies, J. Coord. Chem., 1994, 32, 27-37.
• 196.  The Organometallic Chemistry of Carbon Dioxide Pertinent to Catalysis, D.J. Darensbourg, Contribution to Volume on "Carbon Dioxide Fixation and Reduction in Biological and Model Systems", C. I. Branden, G. Schneider, Eds., Oxford University Press, 1994, 111.
• 195.  Rational Synthesis of Dinuclear Mixed-Valence Cu(I)/Cu(II) Carboxylate Derivatives. Steric Influence of Phosphine Ligands on the Structures of the Complexes, D. J. Darensbourg, M. W. Holtcamp, B. Khandelwal, K. K. Klausmeyer, and J. H. Reibenspies, Inorg. Chem., 1994, 33, 2036-2040.
  DOI: 10.1021/ic00087a046
• 194.  Intramolecular and Intermolecular Hydrogen-Bonding in Triphenylphosphine Derivatives of Copper(I) Carboxylates, (Ph₃P)₂CuO₂C(CH₂)_nCOOH. The Role of Copper(I) in the Decarboxylation of Malonic Acid and Its Derivatives, D. J. Darensbourg, M. M. Holtcamp, and J. H. Reibenspies, Inorg. Chem., 1994, 33, 531-537.
  DOI: 10.1021/ic00081a022
• 193.  Water-Soluble Organometallic Compounds. 4. The Catalytic Hydrogenation of Aldehydes in an Aqueous Two-Phase Solvent System Using a 1,3,5-Triaza-7-phosphaadamantane Complex of Ruthenium, D. J. Darensbourg, F. Joo, M. Kannisto, A. Katho, J. H. Reibenspies, and D. J. Daigle, Inorg. Chem., 1994, 33, 200-208.
  DOI: 10.1021/ic00080a006
• 192.  Nucleophilic Addition of a Water Soluble Phosphine to Aldehydes. Isolation of 1-Hydroxyalkyl Phosphonium Salts and the Crystal Structure of (1-Methoxy-1-benzyl)meta-Sulfonato-phenyl-diphenylphosphonium, D. J. Darensbourg, F. Jóo, A. Katho, N. White Stafford, A. Bényei, and J. H. Reibenspies, Inorg. Chem., 1994, 33, 175-177.
  DOI: 10.1021/ic00079a031
• 191.  Structure of Ru₄(CO)₈(O₂CCH₂CH=CH₂)₄(NMe₃)₂, J. H. Reibenspies, B. Fontal, and D. J. Darensbourg, Acta Cryst., 1993, C49, 1619-1621.
• 190.  The Effect of Phosphonium Salt Formation on the Kinetics of Homogeneous Hydrogenations in Water Utilizing a Rhodium meta-Sulfonatophenyldiphenylphosphine Complex, A. Benyei, J. N. W. Stafford, A. Katho, D. J. Darensbourg, and F. Joo, J. Mol. Catal., 1993, 84, 157.
• 189.  Synthesis and Reactivity of Tungsten-Pentacarbonyl Hydroxo and Bicarbonato Complexes. The Molecular Structure of [PPN][W(CO)₅HCO₃], an Organometallic Analog for Carbonic Anhydrase, D.J. Darensbourg, M.L. Meckfessel Jones, and J.H. Reibenspies, Inorg. Chem., 1993, 32, 4675-4676.
  DOI: 10.1021/ic00074a003
• 188.  The Reversible Decarboxylation of Phosphine Derivatives of Cu(I) Cyanoacetate. Mechanistic Aspects Germane to Catalytic Decarboxylation of Carboxylic Acids, D. J. Darensbourg, E. M. Longridge, M. W. Holtcamp, K. K. Klausmeyer, and J. H. Reibenspies, J. Am. Chem. Soc., 1993, 115, 8839-8840.
  DOI: 10.1021/ja00072a047
• 187.  Structure of [Cu₂(dmpe)₃Cl₂]n•2CH₂Cl₂, J. H. Reibenspies, D. J. Darensbourg, and E. M. Longridge, Acta. Cryst., 1993, C49, 1140-1142.
• 186.  The Synthesis and X-ray Structure of a Phenoxide-Bridged Heterobimetallic Anion, W(CO)₅OPhCr(CO)₃, and It's Reactivity with Carbon Dioxide and Carbonyl Sulfide, D. J. Darensbourg, B. L. Mueller, and J. H. Reibenspies, J. Organomet. Chem., 1993, 451, 83-87.
  DOI: 10.1016/0022-328X(93)83011-J
• 185.  The Catalytic Decarboxylation of Cyanoacetic Acid: Anionic Tungsten Carboxylates As Homogeneous Catalysts, D. J. Darensbourg, J. A. Chojnacki, and E. V. Atnip, J. Am. Chem. Soc., 1993, 115, 4675-4682.
  DOI: 10.1021/ja00064a031
• 184.  Water-Soluble Organometallic Compounds. 3. Kinetic Investigations of Dissociative Phosphine Substitution Processes Involving Water Soluble Group 6 Metal Derivatives in Miscible Aqueous/Organic Media D. J. Darensbourg, C. Bischoff , Inorg. Chem., 1993, 32, 47-53.
  DOI: 10.1021/ic00053a008
• 183.  Structure of Tetrakis(dimethylphenylphosphine)rhodium(I) Chloride, D. J. Darensbourg and J. H. Reibenspies, Acta. Cryst., 1992, C49, 141-142.
• 182.  Catecholates as π-Donating Ligands: The Reactivity and Structure of [Et₄N]₂[(C₆H₄O₂)W(CO)₄] and the "Sixteen Electron" Analog Resulting from CO Dissociation, [Et₄N]₂[3,5-di-t-BuC₆H₂O₂)W(CO)₃], D. J. Darensbourg, K. K. Klausmeyer, B. Mueller, and J. H. Reibenspies, Angew. Chem. 1992, 104, 1496; Angew. Chem. Int. Ed. Engl. 1992, 31, 1503.
• 181.  Structural and Reactivity Studies of a Cyanoacetic Acid Derivative of Tungsten Pentacarbonyl. The X-ray Structure of W(CO)₅NCCH₂COOH, D. J. Darensbourg, E. V. Atnip, and J. H. Reibenspies, Inorg. Chem., 1992, 31, 4475-4480.
  DOI: 10.1021/ic00048a008
• 180.  A Linear, Monomeric Copper(I) Acetate Derivative, [Cu(phen)₂]₂[Cu(O₂CCH₃)₃]•(O₂CCH₃)₃H. An Effective Catalyst for the Decarboxylation of Carboxylic Acids, D. J. Darensbourg, E. M. Longridge, E. V. Atnip, and J. H. Reibenspies, Inorg. Chem., 1992, 31, 3951-3955.
  DOI: 10.1021/ic00045a018
• 179.  Anionic Group 6 Metal Carbonyl Oxalate Complexes. The X-ray Structures of [Et₄N]₂[W(CO)₄C₂O₄] and [PPN]₂[W₂(CO)₈C₂O₄]•1/2(CH₃CH₂)₂O, D. J. Darensbourg, J. A. Chojnacki, and J. H. Reibenspies, Inorg. Chem., 1992, 31, 3428-3433.
  DOI: 10.1021/ic00042a018
• 178.  Water-Soluble Organometallic Compounds. 2. The Catalytic Hydrogenation of Aldehydes and Olefins by New Water-Soluble 1,3,5-Triaza-7-phosphaadamantane Complexes of Ruthenium and Rhodium, D. J. Darensbourg, F. Joo, M. Kannisto, A. Katho, and J. H. Reibenspies, Organometatallics, 1992, 11, 1990-1993.
  DOI: 10.1021/om00042a006
• 177.  Carbon Dioxide Insertion and Deinsertion Processes Involving Metal-Carbon Bonds. Solid State Structure of [PPN][W(CO)₅CH₂CN], D. J. Darensbourg, J. A. Joyce and A. Rheingold, Organometatallics, 1991, 10, 3407-3410.
  DOI: 10.1021/om00055a070
• 176.  Investigations into the Steric Influences on the Mechanism of CO₂ Insertion Reactions into Metal-Oxygen Bonds. COS Activation as a Model for CO₂, D. J. Darensbourg, B. L. Mueller, C. J. Bischoff, S. Chojnacki, and J.H. Reibenspies, Inorg. Chem., 1991, 30, 2418-2424.
  DOI: 10.1021/ic00010a035
• 175.  Multinuclear Metal Carbonyl Alkoxide and Aryloxide Derivatives as Models for Metal Carbonyls Adsorbed on Metal Oxide Supports, D. J. Darensbourg, B. L. Mueller, C. J. Bischoff, C. C. Johnson, K. M. Sanchez, and J. H. Reibenspies, Israel J. Chem., 1990, 30, 369.
• 174.  Water-Soluble Organometallic Compounds 1. The Synthesis, Characterization, and X-ray Structure of [Na-kryptofix-221]₃[W(CO)₅P{C₆H₄-m-SO₃}₃], D.J. Darensbourg, C.J. Bischoff, and J.H. Reibenspies, Inorg. Chem., 1991, 30, 1144-1147.
  DOI: 10.1021/ic00005a049
• 173.  Further Studies on the Role of Neighboring Group Participation in CO Substitution Reactions of Group 6 Metal Carboxylates, D.J. Darensbourg, J.A. Joyce, C.J. Bischoff, and J. H. Reibenspies, Inorg. Chem., 1991, 30, 1137-1142.
  DOI: 10.1021/ic00005a047
• 172.  The Preparation and Solid-State Structure of a Novel Carboxylate Derivative of Cu(I).(Ph₃P)₂Cu(O₂CCH₂CN)₂H. D. J. Darensbourg, E. M. Longridge, E. V. Atnip, and J. H. Reibenspies, Inorg. Chem., 1991, 30, 357-358.
  DOI: 10.1021/ic00003a001
• 171.  A Photochemically Enhanced Carbon-Carbon Bond Forming Reaction Between CS₂ and [W(CO)₅CH₃]^-. The X-ray Structure of [PPN][W(CO)₄(< class="style14">h²-S₂CCH₃)], D. J. Darensbourg, H. P. Wiegreffe, and J. H. Reibenspies, Organomet., 1991, 10, 6-8.
  DOI: 10.1021/om00047a004
• 170.  Mechanistic Studies of Carbon Dioxide Insertion into Metal Hydrides and Extrusion from the Corresponding Metal Formates Utilizing Group 6 Metal Carbonyl Derivatives as Reaction Probes, D. J. Darensbourg, H. P. Wiegreffe and P. W. Wiegreffe, J. Am. Chem. Soc., 1990, 112, 9252-9257.
  DOI: 10.1021/ja00181a030
• 169.  Solid State and Solution Structure of (2,2'-bipyridine)(tetracarbonylcobalt)copper, D. J. Darensbourg, C.-S. Chao, C. J. Bischoff, J. H. Reibenspies, Inorg. Chem., 1990, 29, 4637-4640.
  DOI: 10.1021/ic00348a011
• 168.  The Organometallic Chemistry of Carbon Dioxide Pertinent to Catalysis, NATO Advanced Science Institutes Series, Kluwer Academic Publishers, 1990, 314, 43-64.
• 167.  Uses of Metal Clusters in Homogeneous and Heterogenous Catalysis, D. J. Darensbourg, Proceedings of the IUCCP, Plenum Press, 1990, 41-54.
• 166.  Mechanistic Aspects of Decarboxylation Reactions of (PCy₃)₂M(H)O₂CH (M = Ni, Pd, Pt) Derivatives, D. J. Darensbourg and P. W. Wiegreffe and C. G. Riordan, J. Am. Chem. Soc., 1990, 112, 5759-5762.
  DOI: 10.1021/ja00171a014
• 165.  "Ligand Substitution Reactions", Donald J. Darensbourg, Invited Contribution to Volume on "The Chemistry of Metal Cluster Complexes", D. F. Shriver, H. D. Kaesz, R. D. Adams, Eds., 1990, 171-192.
• 164.  Chemistry of Zero-Valent Tungsten Alkoxides. Synthesis, X-Ray Structure, and Reactivity Towards Carbon Dioxide, D.J. Darensbourg, B.L. Mueller, C.J. Bischoff, and J.H. Reibenspies, Inorg. Chem., 1990, 29, 1789-1791.
  DOI: 10.1021/ic00335a004
• 163.  Crystal Structure and Reactivity of [Cu(dmpe)₂][Cu(Co(CO)₄)₂](dmpe = 1,2-bis(dimethylphosphino)ethane): Staggered and Eclipsed Conformations of [(CO)₄Co-Cu-Co(CO)₄]^– Anions, D. J. Darensbourg, C-S. Chao, J. H. Reibenspies, and C. J. Bischoff, Inorg. Chem., 1990, 29, 2153-2157.
  DOI: 10.1021/ic00336a023
• 162.  Group 6 Pentacarbonyl Acetates as their Bis (triphenylphosphine) iminium Salts, D. J. Darensbourg, J. A. Morse, H. C. Pickner and C. Ovalles, Inorg. Syn., 1990, 27, 295.
• 161.  Isolation of pentamethylcyclopentadienylchromium tricarbonyl dimer by two methods. X-Ray structural study of two polymorphs, L. Y. Goh, T. W. Hambley, D. J. Darensbourg and J. H. Reibenspies, J. Organomet. Chem., 1990, 381, 349-356.
  DOI: 10.1016/0022-328X(90)80064-7
• 160.  Carbon Monoxide Ligand Substitutional Processes Involving Anionic Group 6 Metal Carboxylates and Their Relevance to Decarboxylation Mechanisms, D. J. Darensbourg and H. P. Wiegreffe, Inorg. Chem., 1990, 29, 592-597.
  DOI: 10.1021/ic00329a010
• 159.  Synthesis, Structure, and Reactivity of Zerovalent Group 6 Metal Pentacarbonyl Aryl Oxide Complexes. Reactions with Carbon Dioxide, D. J. Darensbourg, K. M. Sanchez, J. H. Reibenspies, and A. L. Rheingold, J. Am. Chem. Soc., 1989, 111, 7094-7103.
  DOI: 10.1021/ja00200a031
• 158.  Comparative Reactivities of Anionic Group 6 Alkyl, Silyl, and Stannyl Pentacarbonyl Metallates towards Carbon Dioxide and Sulfur Dioxide. Crystal Structure of [PPN][W(CO)₅Si(CH₃)₃], D. J. Darensbourg, C. G. Bauch, J. H. Reibenspies, and A. L. Rheingold, Inorg. Chem., 1988, 27, 4203-4207.
  DOI: 10.1021/ic00296a022
• 157.  Synthesis and Characterization of [Et₄N][M(CO)₅SR] and [Et₄N]₂[M₂(CO)₈(SR)₂ Complexes (M = Cr, Mo, W). Ligand Substitution Reactions and the X-ray Crystal Structure of [Et₄N]₂[W₂(CO)₈(SPh)₂], D. J. Darensbourg, K. M. Sanchez, and J. H. Reibenspies, Inorg. Chem., 1988, 27, 3636-3643.
  DOI: 10.1021/ic00293a040
• 156.  The Synthesis and X-Ray Structure of Zero-Valent Tungsten Aryloxide Dimers, D. J. Darensbourg, K. M. Sanchez, and J. H. Reibenspies, Inorg. Chem., 1988, 27, 3269-3270.
  DOI: 10.1021/ic00292a003
• 155.  Substitution and Insertion Reactions, D. J. Darensbourg and D.J. Mangold, Invited Contribution to Volume on "Mechanisms of Organometallic and Inorganic Reactions", 1988, Vol. V, 239.
• 154.  Cluster Synthesis Via Aggregation: The Synthesis, Solution and Solid-State Characterization of Sulfur-Capped Group 6 Metal Carbonyl Clusters, D. J. Darensbourg, D. J. Zalewski, K. M. Sanchez, and T. Delord, Inorg. Chem., 1988, 27, 821-829.
  DOI: 10.1021/ic00278a016
• 153.  Metal Induced Transformations of Carbon Dioxide, D. J. Darensbourg, C. G. Bauch, and C. Ovalles, ACS Symposium Series, 1988, 363, 26.
• 152.  FTIR, Photoacoustic, and Micro-Raman Spectra of the Dodecacarbonyl- triruthenium(O) Complexes, Ru₃(CO)₁₂ and Ru₃(CO)₁₂, I. S. Butler, Z. H. Xu, D. J. Darensbourg, and M. Pala, J. Raman Spectro., 1987, 18, 357-363.
• 151.  New Methods for Acquiring Infrared Spectral Data in Organometallic Chemistry and Catalysis, D. J. Darensbourg and G. Gibson, ACS Symposium Series, 1987, 357, 230.
• 150.  The Reaction of (Cy₃P)₂Ni(H)(CH₃) with Carbon Dioxide. Formation of an Hydridonickelformate Complex, HNi(O₂CH)(Cy₃P)₂, D. J. Darensbourg, M. Y. Darensbourg, L. Y. Goh, M. M. Ludvig, and P. W. Wiegreffe, J. Am. Chem. Soc., 1987, 109, 7539-7540.
  DOI: 10.1021/ja00258a053
• 149.  Insertion Reactions of Carbon Dioxide with Square Planar Rhodium Alkyl and Aryl Complexes, D. J. Darensbourg, G. Grotsch, P. W. Wiegreffe, and A. L. Rheingold, Inorg. Chem., 1987, 26, 3827-3830.
  DOI: 10.1021/ic00269a043
• 148.  The Synthesis, Reactivity, and X-Ray Structure of fac-W(CO)₃(dppm)(CH₃CN). Stereoselective Preparation of fac-W(CO)₃(¹³CO)(dppm) and Subsequent Intramolecular Rearrangement Processes, D. J. Darensbourg, D. J. Zalewski, C. Plepys and C. Campana, Inorg. Chem., 1987, 26, 3727-3732.
  DOI: 10.1021/ic00269a022
• 147.  Selective Homogeneous Production of Alkyl Formate from CO and Alcohol Using Metal Carbonyl/Alkoxide Catalyst Systems, D. J. Darensbourg, R. L. Gray, and C. Ovalles, J. Molec. Catal., 1987, 41, 329.
• 146.  Homogeneous Catalytic Synthesis of Alkyl Formates from the Reaction of Alkyl Halides, CO₂ and H₂ in the Presence of Anionic Group 6 Carbonyl Catalysts and Sodium Salts, D. J. Darensbourg and C. Ovalles, J. Am. Chem. Soc., 1987, 109, 3330-3336.
  DOI: 10.1021/ja00245a024
• 145.  Carbon Dioxide Insertion Process Involving Metal-Carbon Bonds. Solid State and Solution Structure of [Na(18-Crown-6)][W(CO)₅CH₃], D. J. Darensbourg, C. G. Bauch, and A. L. Rheingold, Inorg. Chem., 1987, 26, 977-980.
  DOI: 10.1021/ic00254a003
• 144.  Mechanistic Aspects of Catalytic Carbon Dioxide Methanation, D. J. Darensbourg, C. Ovalles, and C. G. Bauch, Reviews in Inorg. Chem., 1987, 7, 315.
• 143.  Substitution and Insertion Reactions, D. J. Darensbourg and R. L. Gray, Invited Contribution to Volume on "Mechanisms of Organometallic and Inorganic Reactions", 1987, Vol. IV, 291.
• 142.  Insertion of Carbon Dioxide Into Metal Alkoxide Bonds. Synthesis and Structure of Tungsten Tetracarbonyl Carbonate, D. J. Darensbourg, K. M. Sanchez, and A. L. Rheingold, J. Am. Chem. Soc., 1987, 109, 290-292.
  DOI: 10.1021/ja00235a054
• 141.  Book Review, "The Chemistry of the Metal-Carbon Bond. Volume 2. The Nature and Cleavage of Metal Carbon Bonds," M. Y. Darensbourg and D. J. Darensbourg, Wiley, New York, Organometallics, 1986, 5, 828.
• 140.  Chemical and Structural Characterization of W(CO)₅OPPh₂NPPH₃. A Novel Complex Containing a Phosphine Oxide Ligand Derived from the Bis (triphenylphosphine) nitrogen (1+) Cation, D. J. Darensbourg, M. Pala, D. Simmons, and A. L. Rheingold, Inorg, Chem., 1986, 25, 3537-3541.
  DOI: 10.1021/ic00239a047
• 139.  Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. 10. X-Ray Structural Characterization of Products Resulting from Reaction of Co₄(CO)₉ (tripod), tripod = HC (PPh₂)₃, with Phosphine Ligands, D. J. Darensbourg, D. J. Zalewski, A. L. Rheingold, and R. L. Durney, Inorg. Chem., 1986, 25, 3281-3290.
  DOI: 10.1021/ic00238a036
• 138.  Anionic Group 6 Hydrides and Carboxylates as Homogeneous Catalysts for Reduction of Aldehydes and Ketones, P. A. Tooley, C. Ovalles, S. C. Kao, D. J. Darensbourg, and M. Y. Darensbourg, J. Am. Chem. Soc., 1986, 108, 5465-5470.
  DOI: 10.1021/ja00278a016
• 137.  Catalytic Carbon Dioxide Methanation by Alumina-Supported Mono- and Poly- Nuclear Ruthenium Carbonyls, D. J. Darensbourg and C. Ovalles, Inorg. Chem., 1986, 25, 1603-1609.
  DOI: 10.1021/ic00230a018
• 136.  Intramolecular Ligand Rearrangements in Anionic Group 6 Metal Pentacarbonyl Hydride Derivatives, D.J. Darensbourg, M.Y. Darensbourg, R.L. Gray, D. Simmons, and L.W. Arndt, Inorg. Chem., 1986, 25, 880-882.
  DOI: 10.1021/ic00226a034
• 135.  Preparation and Structure of W(CO)₅OPPh₂NPPh₃. A Novel Complex Containing a Ligand Derived From the Bis(triphenylphosphine) nitrogen(1+) Cation, D.J. Darensbourg, M. Pala, and R. Rheingold, Inorg. Chem., 1986, 25, 125-127.
  DOI: 10.1021/ic00222a004
• 134.  Stereochemical Studies of the Carbon Dioxide Insertion Reactions into the Tungsten-Alkyl Bond, D.J. Darensbourg and G. Grotsch, J. Am. Chem. Soc., 1985, 107, 7473-7476.
  DOI: 10.1021/ja00311a041
• 133.  A Kinetic Investigation of Carbon Dioxide Insertion Processes Involving Anionic Tungsten-Alkyl and -Aryl Derivatives: Effects of CO₂ Pressure, Counterions, and Ancillary Ligands. Comparisons with Migratory Carbon Monoxide Insertion Processes, D.J. Darensbourg, R. Kudaroski, C.G. Bauch, M. Pala, D. Simmons, and J.N. White, J. Am. Chem. Soc., 1985, 107, 7463-7473.
  DOI: 10.1021/ja00311a040
• 132.  Cation-Anion Interaction in the [Na•kryptofix-221][W(CO)₅O₂CH] Derivative and its Relevance in Carbon Dioxide Reduction Processes, D.J. Darensbourg and M. Pala, J. Am. Chem. Soc., 1985, 107, 5687-5693.
  DOI: 10.1021/ja00306a014
• 131.  Homogeneous Activation of Carbon Dioxide by Transition Metal Complexes, D. J. Darensbourg and C. Ovalles, CHEMTECH, October, 1985, 636.
• 130.  Synthesis and Characterization of Polynuclear Chromium Carbonyl Tetra-anions, T. J. McNeese, T. E. Mueller, D. A. Wierda, D. J. Darensbourg, and T. J. Delord, Inorg. Chem., 1985, 24, 3465-3468.
  DOI: 10.1021/ic00215a032
• 129.  The Synthesis and X-Ray Structure of Anionic Chelating Phosphine-Acyl Derivative of Tungsten, [PPh₄][W(CO)₄C(O)CH₂CH₂CH₂PPh₂], and the Reactivity of its Decarbonylated Analog with Carbon Dioxide, D. J. Darensbourg, R. Kudaroski and T. Delord, Organometallics, 1985, 4, 1094-1097.
  DOI: 10.1021/om00125a026
• 128.  Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. 9. Reactions of Co₄(CO)₉[tripod], Tripod = HC(PPh₂)₃, and its Derivatives, D.J. Darensbourg and D.J. Zalewski, Organometallics, 1985, 4, 92-97.
  DOI: 10.1021/om00120a016
• 127.  The X-ray Structural Characterization of Tetrameric Binuclear bis-(µ-Oxo) Molybdenum(V) Compound Bridged by Methoxide Ligands, D. J. Darensbourg, R. L. Gray, and T. Delord, Inorg. Chimica Acta, 1985, 98, L39-l42.
  DOI: 10.1016/S0020-1693(00)84910-5
• 126.  Homogeneous Catalysis of Methyl Formate Production from Carbon Monoxide and Methanol in the Presence of Metal Carbonyl Catalysts, D. J. Darensbourg, R. L. Gray, C. Ovalles, and M. Pala, J. Molec. Catal., 1985, 29, 285.
• 125.  Ligand Substitution Processes in Tetranuclear Carbonyl Cluster. 8. Reactions of Co₄(¹²CO)₁₂/Co₄(¹³CO)₁₂ with Phosphorus Donor Ligands. A Probe for Cluster Disruption During Ligand Substitution Processes, D. J. Darensbourg and D. J. Zalewski, Inorg. Chem., 1984, 23, 4382-4384.
  DOI: 10.1021/ic00193a056
• 124.  Ligand Additivity in the Valence Photoelectron Spectroscopy of Phosphine- Substituted Molybdenum Carbonyls, B. E. Bursten, D.J. Darensbourg, G.E. Kellogg, and D.L. Lichtenberger, Inorg. Chem., 1984, 23, 4361-4365.
  DOI: 10.1021/ic00193a050
• 123.  A Convenient Route to ¹³C-Enriched Triruthenium Dodecacarbonyl. Chemistry Relevant to Methyl Formate Production From Carbon Monoxide and Methanol, D.J. Darensbourg, R.L. Gray, and M. Pala, Organometallics, 1984, 3, 1928-1930.
  DOI: 10.1021/om00090a031
• 122.  Synthesis and Characterization of Sulfur-Capped Trinuclear Group 6b Metal Clusters, D. J. Darensbourg and D. J. Zalewski, Organometallics, 1984, 3, 1598-1600.
  DOI: 10.1021/om00088a029
• 121.  Stereochemical Nonrigidity in Six-Coordinate Group 6b Metal Carbonyl Derivatives via a Nondissociative Pathway, D. J. Darensbourg and R. L. Gray, Inorg. Chem., 1984, 23, 2993-2996.
  DOI: 10.1021/ic00187a019
• 120.  Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. 7. Molecular Structure and Carbon Monoxide Exchange Processes of Co₄ (CO)₉[TRIPOD], TRIPOD = 1,1,1-Tris(diphenylphosphino) methane or HC(PPh₂)₃, D. J. Darensbourg, D. J. Zalewski, and T. Delord, Organometallics, 1984, 3, 1210-1217.
  DOI: 10.1021/om00086a012
• 119.  Anionic Group 6b Metal Carbonyls as Homogeneous Catalysts for Carbon Dioxide/Hydrogen Activation. The Production of Alkyl Formates, D. J. Darensbourg and C. Ovalles, J. Am. Chem. Soc., 1984, 106, 3750-3754.
  DOI: 10.1021/ja00325a007
• 118.  Metal Induced Transformations of Carbon Dioxide. Carbon-Carbon Bond Forming Processes Involving Anionic Group 6b Metal Derivatives and the X-ray Structure of [PNP][cis-CH₃W(CO)₄P(CH₃)₃], D. J. Darensbourg and R. Kudaroski, J. Am. Chem. Soc., 1984, 106, 3672-3673.
  DOI: 10.1021/ja00324a045
• 117.  "Organometallic Compounds. Synthesis, Structure, and Theory", B. L. Shapiro, Ed.: D. J. Darensbourg, R. A. Kudaroski, C. Ovalles, M. Pala; Texas A&M University Press, College Station, Texas, 1983, p. 179.
• 116.  Homogeneous Catalysts for Carbon Dioxide/Hydrogen Activation. Alkyl Formate Production Using Anionic Ruthenium Clusters as Carbonyls, D. J. Darensbourg, C. Ovalles, and M. Pala, J. Am. Chem. Soc., 1983, 105, 5937-5939.
  DOI: 10.1021/ja00356a049
• 115.  Potential Intermediates in Carbon Dioxide Reduction Processes. Syntheses and Structure of (µ-formato) decacarbonyltriruthenium and (µ-acetato) decacarbonyl Triruthenium Anions, D. J. Darensbourg, M. Pala, and J. Waller, Organometallics, 1983, 2, 1285-1291.
  DOI: 10.1021/om50004a003
• 114.  The Activation Carbon Dioxide by Metal Complexes, D. J. Darensbourg and R. Kudaroski, Advances in Organomet. Chem., 1983, 22, 129.
• 113.  Mechanistic Pathways for Ligand Substitution Processes in Metal Carbonyls, D. J. Darensbourg, Advances in Organomet. Chem., 1982, 21, 113.
• 112.  Anionic Group 6b Metal Carbonyl Hydrides and Formates. Chemistry Relevant to Catalysis of the Water-Gas Shift Reaction by Group 6b Metal Hexacarbonyls, D. J. Darensbourg and A. Rokicki, Organometallics, 1982, 1, 1685-1693.
  DOI: 10.1021/om00072a026
• 111.  Reactions of Cryptand Solubilized NaSH in Aprotic Solvents with the Group 6b Metal Hexacarbonyls. X-Ray Structural Analysis and Ligand Lability Studies of the Isolated M(CO)₅SH- Anions, D. J. Darensbourg, A. Rokicki, and R. Kudaroski, Organometallics, 1982, 1, 1161-1166.
  DOI: 10.1021/om00069a010
• 110.  Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. VI. Steric Contribution to Ligand Dissociation in Multi-substituted Ir₄(CO)₁₂ Derivatives, D. J. Darensbourg and B. J. Baldwin-Zuschke, J. Am. Chem. Soc., 1982, 104, 3906-3910.
  DOI: 10.1021/ja00378a020
• 109.  X-Ray Structural Studies of cis-Mo(CO)₄[PR₃]₂(R = Me, Et, n-Bu) Derivatives and Their Relationship to Solution Isomerization Processes in These Octahedral Species, F. A. Cotton, D. J. Darensbourg, S. Klein, and B. W. S. Kolthammer, Inorg. Chem., 1982, 21, 2661-2666.
  DOI: 10.1021/ic00137a026
• 108.  Intermediates in the Reaction of trans-Cr(CO)₄[PPh₃]₂ with ¹³CO and Fluxionality in Octahedral Group 6b Metal Carbonyls via a Nondissociative Mechanism, D. J. Darensbourg, R. Kudaroski, and W. Schenk, Inorg. Chem., 1982, 21, 2488-2491.
  DOI: 10.1021/ic00136a071
• 107.  Solid-State and Solution Structures of [PNP][W(CO)₅O₂CCH₃] and [PNP]- [W(CO)₄[PEt₃]O₂CCH₃] and the CO-Labilizing Ability of the Acetato Ligand in these Anionic Derivatives, F. A. Cotton, D. J. Darensbourg, B. W. S. Kolthammer, and R. Kudaroski, Inorg. Chem., 1982, 21, 1656-1662.
  DOI: 10.1021/ic00134a076
• 106.  Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. V. A Kinetic and Infrared Investigation of ¹³CO Incorporation into Co₄(CO)₉(µ-CO)₃ and Its Monosubstituted Derivatives, D. J. Darensbourg, B. S. Peterson, and R. E. Schmidt, Jr., Organometallics, 1982, 1, 306-311.
  DOI: 10.1021/om00062a013
• 105.  Reduction of Carbon Dioxide and Carbonyl Sulfide by Anionic Group 6B Metal Hydrides and Alkyls. Carbon-Hydrogen and Carbon-Carbon Bond Formation Processes and the Structure of [PNP][Cr(CO)₅SC(O)H], D. J. Darensbourg and A. Rokicki, J. Am. Chem. Soc., 1982, 104, 349-350.
  DOI: 10.1021/ja00365a089
• 104.  Steric Contributions to the Solid State Structures of bis Phosphine Derivatives of Molybdenum Carbonyl. X-Ray Structural Studies of cis-Mo(CO)₄[PPh₃-n Men]2(n = 0, 1, 2), F. A. Cotton, D. J. Darensbourg, S. Klein, and B. W. S. Kolthammer, Inorg. Chem., 1982, 21, 294-299.
  DOI: 10.1021/ic00131a055
• 103.  Structural Characterizations of cis-Mo(CO)₄[PPhMe₂]NHC₅H₁ and cis-Mo(CO)₄ (PPhMe₂)(PPh₃) and Their Solution Reactivities Towards Carbon Monoxide, F. A. Cotton, D. J. Darensbourg, S. Klein, and B. W. S. Kolthammer, Inorg. Chem., 1981, 21, 1651-1655.
  DOI: 10.1021/ic00134a075
• 102.  The Length of a Tungsten-Phosphine Bond Free of Excessive Steric Interactions; the Crystal Structure of W(CO)₅P(CH₃)₃, F. A. Cotton, D. J. Darensbourg, and B. W. S. Kolthammer, Inorg. Chem., 1981, 20, 4440-4442.
  DOI: 10.1021/ic50226a083
• 101.  Kinetic Studies of Ligand Substitution Reactions and General Base Catalysis in Amine-Ligand Exchange Processes for Group 6b Metal Carbonyl Amine Derivatives. Kinetic and Spectroscopic Evidence for Hydrogen-Bonded Intermediates, D. J. Darensbourg and J. A. Ewen, Inorg. Chem., 1981, 20, 4168-4177.
  DOI: 10.1021/ic50226a029
• 100.   Molecular and Electronic Structures of Three Pyridine- and Piperidine- substituted Chromium Carbonyl Compounds: Cr(CO)₅(C₆H₅N), Cr(CO)₅ (C₅H₁₀NH) and cis-Cr(CO)₄(C₅H₁₀NH)[P(OMe)₃], F. A. Cotton, D. J. Darensbourg, A. Fang, B. W. S. Kolthammer, D. Reed, and J. L. Thompson, Inorg. Chem., 1981, 20, 4090-4096.
  DOI: 10.1021/ic50226a011
• 99.    Chromium, Molybdenum, and Tungsten, ANNUAL, SURVEYS OF ORGANOMETALLIC CHEMISTRY, J. D. Atwood, M. L. Atwood, M. Y. Darensbourg, and D. J. Darensbourg, J. Organomet. Chem., 1981, 223, 49.
• 98.    Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. 4. Molecular Structure and Reactivity of Ir₄(CO)₈[P(CH₃)₃]₄, D. J. Darensbourg and B. J. Baldwin-Zuschke, Inorg. Chem., 1981, 20, 3846-3850.
  DOI: 10.1021/ic50225a049
• 97.    Electrochemical Investigations of Compounds Having Isomeric Forms with Similar Standard Redox Potentials: Oxidation of Bis (tri-nbutylphosphine)-molybdenum Tetracarbonyl and Related Complexes, A. M. Bond, D. J. Darensbourg, E. Mocellin, and B. J. Stewart, J. Am. Chem. Soc., 1981, 103, 6827-6832.
  : DOI: 10.1021/ja00413a008
• 96.    Crystal and Molecular Structure of Dicarbonyl (< class="style14">h⁵-cyclopentadienyl)-(formato) iron(II), D. J. Darensbourg, C. S. Day, and M. B. Fischer, Inorg. Chem., 1981, 20, 3577-3579.
  DOI: 10.1021/ic50224a087
• 95.    Reactions of M₂Cl₄(PR₃)₄ (M = Mo and W) with Carbon Monoxide, F. A. Cotton, D. J. Darensbourg, and B. W. S. Kolthammer, J. Organomet. Chem., 1981, 217, C14.
• 94.    Further Studies of the Unusual Nature of Tris-(β-cyanoethyl) phosphine: The Structures of the Phosphine and the Phosphine Oxide, F. A. Cotton, D. J. Darensbourg, M. F. Fredrich, W. H. Ilsley, and J. M. Troup, Inorg. Chem., 1981, 20, 1869-1872.
  DOI: 10.1021/ic50220a051
• 93.    The Facile Reduction of Carbon Dioxide by Anionic Group 6B Metal Hydrides. Chemistry Relevant to Catalysis of the Water-Gas Shift Reaction, D. J. Darensbourg, A. Rokicki, and M. Y. Darensbourg, J. Am. Chem. Soc., 1981, 103, 3223-3224.
  DOI: 10.1021/ja00401a055
• 92.    Studies Using Tributylphosphine Oxide as a Carbon Monoxide-Labilizing Ligand in the Synthesis of Metal Carbonyl Complexes Highly Enriched in ¹³CO, D. J. Darensbourg, M. Y. Darensbourg, and N. Walker, Inorg. Chem., 1981, 20, 1918-1921.
  DOI: 10.1021/ic50220a059
• 91.    Ligand Substitution Processes in Tetranuclear Carbonyl Clusters. III. Molecular Structures of Co₄(CO)₈(µ-CO)₃[P(C₆H₅)₃] and Co₄(CO)₇(µ-CO)₃-[P(OCH₃)]₂, D. J. Darensbourg and M. J. Incorvia, Inorg. Chem., 1981, 20, 1911-1918.
  DOI: 10.1021/ic50220a058
• 90.    The Importance of Reactions of Oxygen Bases with Metal Carbonyl Derivatives in Catalysis. Homogeneous Catalysis of the Water Gas Shift Reaction, D. J. Darensbourg and A. Rokicki, ACS Symposium Series, 1981, 152, 107.
• 89.    On the Use of ¹³C-¹³C Coupling in Establishing Intramolecular versus Intermolecular CO Ligand Rearrangement Processes in Metal Carbonyl Derivatives, D. J. Darensbourg, J. Organomet. Chem., 1981, 209, C37.
• 88.    The Formate Ion as a Monodentate Ligand. Synthesis, Structure, and Decar-boxylation of (η⁵-C₅H₅)Fe(CO)₂O₂CH, D. J. Darensbourg, B. Fischer, R. E. Schmidt, Jr., and B. J. Baldwin, J. Am. Chem. Soc., 1981, 103, 1297-1298.
  DOI: 10.1021/ja00395a087
• 87.    X-Ray Molecular Structures of Mn(CO)₅(O₂CCF₃) and Mn(CO)₃[C₅H₅N]₂(O₂CCF₃), F. A. Cotton, D. J. Darensbourg, and B. W. S. Kolthammer, Inorg. Chem., 1981, 20, 1287-1291.
  DOI: 10.1021/ic50218a064
• 86.    πAcidity of Tris (2-cyanoethyl) phosphine. X-ray Structural Studies of M(CO)₅P(CH₂CH₂CN)₃ (M = Cr, Mo) and Mo(CO)₅P(C₆H₅)₃, F. A. Cotton, D. J. Darensbourg, and W. J. Ilsley, Inorg. Chem., 1981, 20, 578-583.
  DOI: 10.1021/ic50216a051
• 85.    Chemical and X-ray Structural Studies on the (Acetato) - and (Trifluoroacetato) pentacarbonylmetalates of Chromium and Molybdenum, F. A. Cotton, D. J. Darensbourg, and B. W. S. Kolthammer, J. Am. Chem. Soc., 1981, 103, 398-405.
  DOI: 10.1021/ja00392a026
• 84.    Book Review, "Organometallic Photochemistry," D. J. Darensbourg, Academic Press, New York, J. Am. Chem. Soc., 1980, 102, 7163.
• 83.    Photochemistry of Piperidine Pentacarbonyl Complexes of the Group 6B Metals Isolated in an Argon Matrix at 10 K, G. Boxhoorn, G.C. Shoemaker, D. J. Stufkens, A. Oskam, A. J. Rest, and D. J. Darensbourg, Inorg. Chem., 1980, 19, 3455-3461.
  DOI: 10.1021/ic50213a048
• 82.    Phase-Transfer Catalyzed Nucleophilic Reactions of Hydroxide Ions at Metal Bound Carbon Monoxide Centers, D. J. Darensbourg, B. J. Baldwin, and J. A. Froelich, J. Am. Chem. Soc., 1980, 102, 4688-4694.
  DOI: 10.1021/ja00534a022
• 81.    Synthesis of Metal Carbonyl Complexes Highly Enriched in Carbon-13: Utilization of the CO-Labilizing Ability of (n-Bu)₃ P=O, D. J. Darensbourg, N. Walker, and M. Y. Darensbourg, J. Am. Chem. Soc., 1980, 102, 1213-1214.
  DOI: 10.1021/ja00523a075
• 80.    Ligand Substitution Processes in Tetranuclear Metal Carbonyl Clusters. II Co₄(CO)₉(µ₂-CO)₃ Derivatives, D. J. Darensbourg and M. J. Incorvia, Inorg. Chem., 1980, 19, 2585-2590.
  DOI: 10.1021/ic50211a020
• 79.    Intramolecular Hydrogen-Bonding Implications on the Lability of the Molybdenum-Piperidine Bond. Kinetic and Mechanistic Studies of the Reaction of cis-Mo(CO)₄[P(OCH)₃]NHC₅H₁₀ with Carbon Monoxide, D. J. Darensbourg, Inorg. Chem., 1979, 18, 2821-2825.
  DOI: 10.1021/ic50200a039
• 78.    Oxygen-18 Isotope Shifts on the ¹³C Nuclear Magnetic Resonance of Metal Carbonyl Derivatives, D. J. Darensbourg, J. Organomet. Chem., 1979, 174, C70.
• 77.    Intramolecular Rearrangement of Carbonyl Ligands in the Octahedral Complex, W(CO)₅P(OMe)₃, by a Nondissociative Process: An Example of the Utility of the Oxygen-18 Isotope Shift on the ¹³C NMR Resonance of the Carbonyl Ligand, D. J. Darensbourg and B. J. Baldwin, J. Am. Chem. Soc., 1979, 101, 6447-6449.
  DOI: 10.1021/ja00515a058
• 76.    Concomitant Bond Formation and Bond Fission in the Mass Spectral Fragmentation of an Organometallic Molecule, R. Davis, M. L. Webb, and D. J. Darensbourg, J. Chem. Soc., Chem. Commun., 1979, 409.
• 75.    Ligand Substitution Processes in Tetranuclear Metal Carbonyl Clusters. I. Co₄(CO)₉ (µ²-CO)₃ Derivatives, D. J. Darensbourg and M. Y. Incorvia, J. Organomet. Chem., 1979, 171, 89.
• 74.    Origin of the Structure in M-H-M Vibrational Modes of HW₂(CO)₁₀–, C. B. Cooper, III, D. F. Shriver, D. J. Darensbourg, and J. A. Froelich, Inorg. Chem., 1979, 18, 1407-1408.
  DOI: 10.1021/ic50195a055
• 73.    Reaction of Iron Pentacarbonyl with Oxygen-18 Enriched Hydroxide. Decarboxylation versus Oxygen Exchange in the [Fe(COOH)] Intermediate, D. J. Darensbourg, M. Y. Darensbourg, N. Walker, J. A. Froelich, and H. L. C. Barros, Inorg. Chem., 1979, 18, 1401-1402.
  DOI: 10.1021/ic50195a053
• 72.    Steric Contributions to the Solution Dynamics Involving Phosphorus Ligand Dissociation in Substituted Derivatives of Molybdenum Hexacarbonyl, D. J. Darensbourg and A. H. Graves, Inorg. Chem., 1979, 18, 1257-1261.
  DOI: 10.1021/ic50195a017
• 71.    Solution Photochemistry of Anionic Metal Carbonyl Hydride Derivatives. Substitution and Dimer Disruption Processes in µ-H(M(CO)₅]₂- (M = Cr and W), D. J. Darensbourg and M. J. Incorvia, Inorg. Chem., 1979, 18, 18-22.
  DOI: 10.1021/ic50191a004
• 70.    Intramolecular Isomerization of an Octahedral Complex: Bis-(Tri-n-butyl-phosphine) molybdenum Tetracarbonyl, D. J. Darensbourg, Inorg. Chem., 1979, 18, 14.
  DOI: 10.1021/ic50191a003
• 69.    Oxygen-Exchange and Ligand Substitution Reactions in Cr(CO)₆ and µ-H[Cr(CO)₅]₂, and the Water-Gas Shift Reaction, D. J. Darensbourg, M. Y. Darensbourg, R. R. Burch, Jr., J. A. Froelich, and M. J. Incorvia, Adv. Chem. Ser., 1979, 173, 106.
• 68.    A Mass Spectral Study of Intramolecular Rearrangements in cis-M(CO)₄(¹³CO) piperidine (M = Cr, W) Derivatives, R. Davis and D. J. Darensbourg, J. Organomet. Chem., 1978, 161, C11.
• 67.    The Preparation of Oxygen-18 Labelled Derivaties of [Mn(CO)₃(diphos)H](diphos = bis(1, 2-diphenylphosphino)ethane) via Reaction of [Mn(CO)₄(diphos)][PF₆] With H₂¹⁸O in the Presence of Triethylamine, D. J. Darensbourg and J. A. Froelich, Inorg. Chem., 1978, 17, 3300-3302.
  DOI: 10.1021/ic50189a070
• 66.    A Convenient Synthesis of cis-Mo(CO)₄L₂ Derivatives (L = Group 5a Ligand) and a Qualitative Study of Their Thermal Reactivity Toward Ligand Dissociation, D. J. Darensbourg and R. L. Kump, Inorg. Chem., 1978, 17, 2680-2682.
  DOI: 10.1021/ic50187a062
• 65.    The Preparation of a Stereospecifically ¹³CO Labelled μ-H[Mo(CO)₅]₂– Species and an Analysis of Its CO Stretching Vibrational Modes, D. J. Darensbourg, R. R. Burch, Jr., and M. Y. Darensbourg, Inorg. Chem., 1978, 17, 2677-2680.
  DOI: 10.1021/ic50187a061
• 64.    The Solution Behavior of Unsaturated Molybdenum Carbonyl Species as Evidenced via Stereospecific ¹³CO Labelling Studies, D. J. Darensbourg and A. Salzer, J. Am. Chem. Soc., 1978, 100, 4119-4124.
  DOI: 10.1021/ja00481a022
• 63.    The Solution Photosubstitution Chemistry of Amine Pentacarbonyl Derivatives of the Groups 6b Metals in the Presence of ¹³CO, D. J. Darensbourg and M. A. Murphy, Inorg. Chem., 1978, 17, 884-888.
  DOI: 10.1021/ic50182a018
• 62.    The Solution Photosubstitution Chemistry of Triphenylphosphine Derivatives of Molybdenum Hexacarbonyl, D. J. Darensbourg and M.A. Murphy, J. Am. Chem. Soc., 1978, 100, 463-468.
  DOI: 10.1021/ja00470a016
• 61.    The Solution Structure and Reactivity of Hydridoirontetracarbonyl Anion, [HFe(CO)₄]–M. Y. Darensbourg, D. J. Darensbourg, and H. L. C. Barros, Inorg. Chem., 1978, 17, 297-301.
  DOI: 10.1021/ic50180a022
• 60.    Phase-Transfer Catalyzed Oxygen-18 Labelling Studies of the Carbonyl Ligands in Neutral Metal Carbonyl Derivatives, D. J. Darensbourg, and J. A. Froelich, J. Am. Chem. Soc., 1978, 100, 338-340.
  DOI: 10.1021/ja00469a086
• 59.    Book Review, "Infrared and Raman Spectra of Inorganic and Coordination Compounds," 3rd edition, D. J. Darensbourg, Wiley-Interscience, New York, J. Organomet. Chem., 1978, 156, C47.
• 58.    A Thermal Route to Stereospecifically 13CO labelled Group 6b Metal Pentacarbonyl Amine Derivatives, D. J. Darensbourg and R. L. Kump, J. Organomet. Chem., 1977, 140, C29.
• 57.    The Lack of Intramolecular Carbonyl Ligand Rearrangement in the Stereo-specifically 13CO Labelled (Diamine) Molybdenum Tetracarbonyl Derivatives, D. J. Darensbourg, L .J. Todd, and J. P. Hickey, J. Organomet. Chem., 1977, 137, C1.
• 56.    The Chemical and Infrared Spectral Details of Reactions Involving Stereospecific Incorporation of Oxygen-18 into Substituted Managanese and Rhenium Carbonyl Derivatives via Exchange Reactions with H₂¹⁸O, D. J. Darensbourg and J. A. Froelich, J. Am. Chem. Soc., 1977, 99, 5940-5946.
  DOI: 10.1021/ja00460a017
• 55.    Oxygen Exchange Reactions of H₂¹⁸O with the Hexacarbonyl Cations of Manganese and Rhenium, D. J. Darensbourg and J. A. Froelich, J. Am. Chem. Soc., 1977, 99, 4726-4729.
  DOI: 10.1021/ja00456a033
• 54.    Intramolecular Hydrogen Bonding Implications on the Lability of the Molybdenum-Piperidine Bond. The Molecular Structure of cis-Mo (CO)₄– [P(OCH₃)₃] NHC₅H₁₀, J. L. Atwood and D. J. Darensbourg, Inorg. Chem., 1977, 16, 2314-2317.
  DOI: 10.1021/ic50175a032
• 53.    The Reaction of Cationic Group VIIb Metal Carbonyl Derivatives with Sodium Hydrogen Sulfide. Production of Metal Hydrides, J. A. Froelich and D. J. Darensbourg, Inorg. Chem., 1977, 16, 960-962.
  DOI: 10.1021/ic50170a053
• 52.    Photochemical Substitution Reactions of Group VIb Metal Tetracarbonyl Norbornadiene Complexes with ¹³CO and the Kinetics of Subsequent Thermal Rearrangements in the Stereospecifically Labelled Species. The Relationship of these Results to the Photoinduced Hydrogenation Process, D. J. Darensbourg, H. H. Nelson, III, and M. A. Murphy, J. Am. Chem. Soc., 1977, 99, 896-903.
  DOI: 10.1021/ja00445a036
• 51.    Infrared Intensities and Calculation of Infrared Band Shapes of the ν(CO) and ν(C=C) Vibrational Modes in Group VIb (Norbornadiene) M(CO)₄ Derivatives, D.J. Darensbourg, J.E. Tappan, and H.H. Nelson, III, Inorg. Chem., 1977, 16, 534-540.
  DOI: 10.1021/ic50169a006
• 50.    Oxygen Exchange Reactions of Cationic Carbonyl Derivatives of Manganese and Rhenium with H₂¹⁸O H₂¹⁸O and Related Processes, D.J. Darensbourg, invited contribution to volume on "Organometallic and Coordination Compounds," Israel Journal of Chemistry, 1977, 15, 247.
• 49.    Stereospecific Incorporation of ¹³CO into Olefinic Substituted Metal Carbonyl Compounds, D. J. Darensbourg and A. Salzer, J. Organomet. Chem., 1976, 117, C90-C92.
  DOI: 10.1016/S0022-328X(00)87219-8
• 48.    Evidence for the Fluxionality and Structure in Solution of Intermediates of the Type W(CO)₄(L) (L = Lewis Base), D. J. Darensbourg, G. R. Dobson, and A. Moradi-Araghi, J. Organomet. Chem., 1976, 116, C17.
  DOI: 10.1016/S0022-328X(00)91799-6
• 47.    Chromium, Molybdenum, and Tungsten, ANNUAL SURVEY OF ORGANOMETALLIC CHEMISTRY, D. J. Darensbourg and M. Y. Darensbourg, J. Organomet. Chem., 1976, 115, 221-325.
  DOI: 10.1016/S0022-328X(00)88266-2
• 46.    Kinetic Ambiguity between the Id and D Mechanisms in Ligand Substitution Reactions. The Intimate Mechanism for Axial Base-Ligand Exchange Reactions in Alkyl (base) cobaloximes and Related Species, J. A. Ewen and D. J. Darensbourg, J. Am. Chem. Soc., 1976, 98, 4317-4319.
  DOI: 10.1021/ja00430a055
• 45.    Infrared, Conductance and Kinetic Evidence for Alkali Metal Ion Interactions with Derivatives of Managanese Carbonylates, M. Y. Darensbourg, D. J. Darensbourg, D. Burns, and D. A. Drew, J. Am. Chem. Soc., 1976, 98, 3127-3136.
  DOI: 10.1021/ja00427a011
• 44.    Stereospecific Incorporation of 18-Oxygen into Managanese and Rhenium Pentacarbonyl Derivatives via Exchange Reactions with H₂¹⁸O, D. J. Darensbourg and D. Drew, J. Am. Chem. Soc., 1976, 98, 275-276.
  DOI: 10.1021/ja00417a065
• 43.    Book Review, "Metal Carbonyl Spectra," D. J. Darensbourg, Academic Press, New York, J. Organomet. Chem., 1975, 99, C39.
  DOI: 10.1016/S0022-328X(00)88473-9
• 42.    Evidence for Hydrogen Bonded Intermediates in Amine Substitution Reactions Involving Group VIB Metal Pentacarbonyl Amine Derivatives with Phosphines, J. Ewen and D. J. Darensbourg, J. Am. Chem. Soc., 1975, 97, 6874-6876.
  DOI: 10.1021/ja00856a053
• 41.    The Separation of Pure Lateral and Diagonal Isomers of Cyclopentadienyl-dibromodicarbonylrheniu, R. B. King, R. H. Reimann, and D. J. Darensbourg, J. Organomet. Chem., 1975, 93, C23-C25.
  DOI: 10.1016/S0022-328X(00)94054-3
• 40.    Synthesis, Spectral Properties, and Reactions of Manganese and Rhenium Pentacarbonyl Phosphine and Phosphite Cation Derivatives and Related Complexes, D. Drew, D. J. Darensbourg, and M. Y. Darensbourg, Inorg. Chem., 1975, 14, 1579-1584.
  DOI: 10.1021/ic50149a027
• 39.    The Stereochemical Course of Reactions Leading to Formation of Mono-ligated (Phenylacetyl) manganese tetracarbonyl Compounds, D. Drew, M. Y. Darensbourg, and D. J. Darensbourg, J. Organomet. Chem., 1975, 85, 73-84.
  DOI: 10.1016/S0022-328X(00)89490-5
• 38.    Chromium, Molybdenum, and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, D. J. Darensbourg and M. Y. Darensbourg, J. Organomet. Chem., 1974, 83, 309-425.
  DOI: 10.1016/0022-328X(74)80009-4
• 37.    The Synthesis and Spectral Properties of Manganese Pentacarbonyl Phosphine and Phosphite Cation Derivatives and Related Complexes, D. J. Darensbourg, M. Y. Darensbourg, D. Drew, and H. L. Conder, J. Organomet. Chem., 1974, 74, C33-C36.
  DOI: 10.1016/S0022-328X(00)83603-7
• 36.    Stereospecific Photochemical Reactions of Group VIb Metal Tetracarbonyl Norbornadiene Complexes with ¹³CO, D. J. Darensbourg and H. H. Nelson, III, J. Am. Chem. Soc., 1974, 96, 6511-6513.
  DOI: 10.1021/ja00827a043
• 35.    Reactions of Phenylacetylmanganesepentacarbonyl with Phosphine and Phosphite Ligands, M.Y. Darensbourg, D. J. Darensbourg, and D. Drew, J. Organomet. Chem., 1974, 73, C25-C27.
  DOI: 10.1016/S0022-328X(00)85645-4
• 34.    Infrared Determination of Stereochemistry in Metal Complexes. An Application of Group Theory. Part II. The Determination of Symmetry Coordinates, D. J. Darensbourg and M. Y. Darensbourg, J. Chem. Ed., 1974, 51, 787-789.
• 33.    Detailed Analysis of the Carbonyl Stretching Vibrations in Axial and Equatorial Substituted Iron Carbonyl Compounds: Absolute Infrared Intensities and Force Constants of the Carbonyl Ligands, D. J. Darensbourg, H. H. Nelson, III, and C. L. Hyde, Inorg. Chem., 1974, 13, 2135-2145.
  DOI: 10.1021/ic50139a017
• 32.    Stereospecific Introduction of Carbon Monoxide into Metal Carbonyl Chelate Complexes, R.J. Angelici, W.J. Knebel, O.A. Gansow, and D.J. Darensbourg, J. Organomet. Chem., 1974, 66, C11-C13.
  DOI: 10.1016/S0022-328X(00)93872-5
• 31.    Preparation of Dinitrogen-Rhenium Complexes with Tertiary Arsines as Coligands. Interaction of Indium Trichloride with Rhenium(I)-Dinitrogen Species, D. J. Darensbourg and D. Madrid, Inorg. Chem., 1974, 13, 1532-1534.
  DOI: 10.1021/ic50136a061
• 30.    Kinetic Studies of Phosphine and Phosphite Exchange Reactions of Substituted Iron Tricarbonyl Carbene Complexes. A Competitive Study of Lewis Bases for the Intermediate [Fe(CO)₃C(OC₂H₅)CH₃], D.J. Darensbourg and H.L. Conder, Inorg. Chem., 1974, 13, 374-379.
  DOI: 10.1021/ic50132a028
• 29.    Book Review, "Encounters in Experimental Chemistry," D. J. Darensbourg, Harcourt Brace Jovanovich, Inc., New York, J. Chem. Ed., 1973, 50, A381.
• 28.    Chromium, Molybdenum, and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, D.J. Darensbourg, J. Organomet. Chem., 1973, 62, 299-410.
  DOI: 10.1016/S0022-328X(00)80759-7
• 27.    Infrared Intensity Measurements of the Pt-H Stretching Vibration in Pt(II) Complexes and Their Relationship to Similar Measurements for Hydrogen Chemisorbed on Platinum, D. J. Darensbourg and C. L. Hyde, J. Chem. Phys., 1973, 59, 3869.
• 26.    Electronic and Steric Control of Reactions of Benzylmagnesium Chloride with Substituted Metal Carbonyls, M. Y. Darensbourg, H. L. Conder, D. J. Darensbourg, and C. Hasday, J. Am. Chem. Soc., 1973, 95, 5919-5924.
  DOI: 10.1021/ja00799a015
• 25.    The Interaction of Lewis Bases With (Acrylic acid) iron Tetracarbonyl in Solution, D. J. Darensbourg, J. E. Tappan, and B. J. Marwedel, J. Organomet. Chem., 1973, 54, C39-C44.
  DOI: 10.1016/S0022-328X(00)84977-3
• 24.    Kinetic Studies of Thermal Decomposition and Substitution Reactions of cis-Mo (CO)₄[P(C₆H₅)₃](amine) Compounds. A Competitive Study of Lewis Bases for the Intermediate [Mo(CO)₄P(C₆H₅)₃], C. L. Hyde and D. J. Darensbourg, Inorg. Chem., 1973, 12, 1286-1291.
  DOI: 10.1021/ic50124a015
• 23.    Infrared Intensities and Calculation of Infrared Band Shapes of the CO Stretching Vibrations in Substituted Tungsten Carbonyl Derivatives, C. L. Hyde and D. J. Darensbourg, Inorg. Chem., 1973, 12, 1075-1081.
  DOI: 10.1021/ic50123a019
• 22.    Reactions of Transition Metal Carbonyls with Organolithium Compounds, III. Synthesis of Tetracarbonyl (Tertiary Phosphite) Oxy- and Amino-Carbene Complexes of the Group VIB Metals, C. L. Hyde and D. J. Darensbourg, Inorg. Chim. Acta, 1973, 7, 145-149.
  DOI: 10.1016/S0020-1693(00)94799-6
• 21.    Book Review, "Advances in Catalysis," Volume 22, D. J. Darensbourg, Academic Press, New York, J. Am. Chem. Soc., 1972, 94, 7218.
• 20.    Photochemical Substitution Reactions of Substituted Group VI Metal Carbonyls, G. Schwenzer, M. Y. Darensbourg and D. J. Darensbourg, Inorg. Chem., 1972, 11, 1967-1970.
  DOI: 10.1021/ic50114a055
• 19.    Photochemical Reactions of Transition Metal Dinitrogen Compounds in the Presence of Carbon Monoxide, D. J. Darensbourg, J. Inorg. Nucl. Chem. Letters, 1972, 8, 529.
• 18.    Chromium, Molybdenum, and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, D. J. Darensbourg, J. Organomet. Chem., 1972, 45, 257-334.
  DOI: 10.1016/S0022-328X(00)88508-3
• 17.    Infrared Intensities of the Carbonyl Stretching Vibrations in Cyclopentadienyliron Dicarbonyl Derivatives, D. J. Darensbourg, Inorg. Chem., 1972, 11, 1606-1609.
  DOI: 10.1021/ic50113a029
• 16.    The Nature of Binuclear Dinitrogen Complexes of Rhenium(I) and Rhenium(V) in Solution, D. J. Darensbourg, Inorg. Chim. Acta, 1972, 6, 527-530.
  DOI: 10.1016/S0020-1693(00)91852-8
• 15.    Correlation Between the Stretching Frequency and the Absolute Infrared Intensity of the Dinitrogen Ligand in Isoelectronic Transition Metal Compounds, D. J. Darensbourg, Inorg. Chem., 1972, 11, 1436-1437.
  DOI: 10.1021/ic50112a057
• 14.    Infrared Study of the Effect of Preadsorbed Oxygen for Hydrogen Chemisorption on Platinum, D.J. Darensbourg and R. P. Eischens, International Congress of Catalysis, Miami, Florida, 1972.
• 13.    Infrared and Kinetic Studies of Group VI Metal Pentacarbonyl Amine Compounds, R. J. Dennenberg and D. J. Darensbourg, Inorg. Chem., 1972, 11, 72-77.
  DOI: 10.1021/ic50107a016
• 12.    The Relative Importance of s and π Bonding of Molecular Nitrogen and Carbonyl in Osmium(II) Complexes as Determined by Infrared Intensities of the Molecular Nitrogen and Carbonyl Stretching Vigrations, D. J. Darensbourg, Inorg. Chem., 1971, 10, 2399-2403.
  DOI: 10.1021/ic50105a006
• 11.    The Nature of the Intermediate Procreated in Substitution Reactions of Group VI Metal Carbonyls, D. J. Darensbourg, M. Y. Darensbourg, and R. J. Dennenberg, J. Am. Chem. Soc., 1971, 93, 2807-2808.
  DOI: 10.1021/ja00740a051
• 10.    Reactions of Transition Metal Carbonyls with Nucleophilic Reagents, Reactivity and Bonding, D. J. Darensbourg and M. Y. Darensbourg, Inorg. Chim. Acta, 1971, 5, 247-253.
  DOI: 10.1016/S0020-1693(00)95922-X
• 9.      Infrared Intensities of the Molecular Nitrogen and Carbonyl Stretching Vibrations in Iridium(I) Complexes, D. J. Darensbourg and C. L. Hyde, Inorg. Chem., 1971, 10, 431-432.
  DOI: 10.1021/ic50096a056
• 8.      Reactions of Transition Metal Carbonyls with Nucleophilic Reagents Reactivity and Bonding, Proceedings of the 3rd International Symposium of Inorg. Chim. Acta, D. J. Darensbourg and M. Y. Darensbourg, Venice, Italy, p. D-5 (1970).
• 7.      Reactions of Transition Metal Carbonyls with Organolithium Compounds, II. Prediction of Nucleophilic Attack at Carbon and Resulting Stereochemistry, D. J. Darensbourg and M. Y. Darensbourg, Inorg. Chem., 1970, 9, 1691-1694.
  DOI: 10.1021/ic50089a016
• 6.      Spectroscopic Studies of Some Carbene Pentacarbonyl Complexes of Chromium (O) and Tungsten(O), M. Y. Darensbourg and D. J. Darensbourg, Inorg. Chem., 1970, 9, 32-39.
  DOI: 10.1021/ic50083a007
• 5.      Infrared Spectroscopy and Its Uses in Determining Stereochemistry in Metal Complexes. An Application of Group Theory, M. Y. Darensbourg and D. J. Darensbourg, J. Chem. Ed., 1970, 47, 33-35.
• 4.      Infrared Intensities of the Carbonyl Stretching Modes in Trigonal Bipyramidal Cobalt and Iron Tetracarbonyl Compounds, D. J. Darensbourg, Inorg. Chim. Acta, 1970, 4, 597-601.
  DOI: 10.1016/S0020-1693(00)93358-9
• 3.      Kinetics of the Thermal Decomposition and Substitution Reactions of Molybdenum Pentacarbonyl Amines Compounds, D. J. Darensbourg and T. L. Brown, Inorg. Chem., 1968, 7, 1679-1680.
  DOI: 10.1021/ic50066a053
• 2.      Infrared Intensities of the CO Stretching Modes and Electronic Spectra of Substituted Molybdenum Carbonyls, D. J. Darensbourg and T. L. Brown, Inorg. Chem., 1968, 7, 959-966.
  DOI: 10.1021/ic50063a023
• 1.      Intensities of CO stretching Modes in the Infrared Spectra of Absorbed CO and Metal Carbonyls, T. L. Brown and D. J. Darensbourg, Inorg. Chem., 1967, 6, 971-977.
  DOI: 10.1021/ic50051a026

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