.: Current Research Activities :.

 

Metal‐Templated, Tight Loop Conformation of a Cys‐X‐Cys Biomimetic Assembles a Dimanganese Complex

M269 TOC
(M269) T. Le, H. Nguyen, L. M. Perez, D. J. Darensbourg, M. Y. Darensbourg. Angew. Chem. Int. Ed., 2020, 59, 2-7.

Controlling O2 Reactivity in Synthetic Analogues of [NiFeS]- and [NiFeSe]-Hydrogenase Active Sites

M256 TOC
(M267) X. Yang, L. C. Elrod, T. Le, V. S. Vega, H. Naumann, Y. Rezenom, J. H. Reibenspies, M. B. Hall, M. Y. Darensbourg. J. Am. Chem. Soc. 2019, 141, 15338-15347.

Toward the Optimization of Dinitrosyl Iron Complexes as
Therapeutics for Smooth Muscle Cells

MYD 261 TOC
(M265) D. C. Pectol, S. Kahn, R. B. Chupik, M. Elsabahy, K. L. Wooley, M. Y. Darensbourg,
S.-M. Lim. Mol. Pharmaceutics. 2019, 16(7), 3178 - 3187.

Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites

M249 TOC
(M264) X. Yang, L. C. Elrod, J. H. Reibenspies, M. B. Hall, M. Y. Darensbourg. Chem. Sci. 2019, 10, 1368 - 1373.

Bridging cyanides from cyanoiron metalloligands to redox-active dinitrosyl iron units

M256 TOC
(M260) P. Ghosh, M. Quiroz, R. Pulukkody, N. Bhuvanesh,
M. Y. Darensbourg. Dalton Trans. 201847, 11812 - 11819.

Interplay of hemilability and redox activity in models of
hydrogenase active sites

MYD 261 TOC
(M258) S. Ding, P. Ghosh, M. Y. Darensbourg, M. B. Hall. PNAS,
2017
,114 (46), E9775-E9782.

Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process

261 Figure
(M261) D. Sil, Z. Martinez, S. Ding, N. Bhuvanesh, D. J. Darensbourg, M. B. Hall, M. Y. Darensbourg. J. Am. Chem. Soc. 2018, 140 (31), 9904–9911.

Complexes of MN2S2•Fe(η5-C5R5)(CO) as Platform for Exploring Cooperative Heterobimetallic Effects in HER Electrocatalysis

M255 TOC
(M255) P. Ghosh; M. Quiroz; N. Wang; N. Bhuvanesh; M. Y. Darensbourg,
Dalton Trans.
2017, 46, 5617 - 5624.

Discrete Air-Stable Nickel-Palladium(II) Complexes as
Catalysts for Suzuki-Miyaura Reactions

M256 TOC
(M256) T. Zhao; P. Ghosh; Z. Martinez; Xu. Liu; X. Meng; M. Y. Darensbourg,
Organometallics, 2017, 36, 1822–1827.

Hemi-labile Bridging Thiolates as Proton Shuttle in
Bio-inspired H2 Production Electrocatalysts

M252 TOC
(M252) S. Ding, P. Ghosh, A. M. Lunsford, N. Wang, N. Bhuvanesh, M. B. Hall, M. Y. Darensbourg, J. Am. Chem. Soc. 2016, 138 (39), 12920–12927.

Toward Biocompatible Dinitrosyl Iron Complexes:
Sugar-Appended Thiolates

M253 TOC
(M253) R. Pulukkody, R. B. Chupik; Steven K. Montalvo; Sarosh Khan; Nattamai Bhuvanesh; Soon-Mi Lim; Marcetta Y. Darensbourg, Chem. Commun. 2017, 53, 1180-1183.

Chemistry Department -- Texas A&M University -- 3255 TAMU, College Station, TX 77843 -- 979.845.5417