CHEMISTRY 102                    Fall 1999                     Sections 512-522                Dr. Wendy Keeney-Kennicutt
GENERAL INFORMATION
Lecturer (and TAMU Mentor):	Dr. Wendy L. Keeney-Kennicutt		Sections 512-522:  T,R: 9:35 - 10:50 am in Room 100 HELD
Office:		Room 415A, HELD 
		Phone:  845-3256 (work) and 690-1252 (home)
		E-mail:  kennicutt@mail.chem.tamu.edu
		homepage:  http://www.chem.tamu.edu/class/fyp/fypintro.html
Office Hours:	Mondays 3:30 - 9 pm, by appointment and whenever you can catch me. 
Review Sessions:	Sundays, General Review/Problem Solving (2 pm, Rm 100 HELD) - see schedule
		Special Review Session:  Wednesday, 9/1 at 7pm
Lecture Notes:	Copies of my lecture notes will be in the LRC, Room 004 HELD and on the web.

BONUS OPPORTUNITY PROBLEMS (BOP's) 
A total of about 112 problems were carefully selected to complement the lectures.  Additional practice problems, which are NOT to be handed in, are also provided.  Answers to the even-numbered problems are in the textbook and worked out in the Solution Manual.  The BOP's will be divided into four sets as we cover the material in class - the problems due will be announced in class and on the web.  The first three sets will be due on the Thursday following each exam; the last set will be due on the last day of class.  The BOP's may be turned in with a 10% penalty through the next Tuesday.  After that time, the BOP's will absolutely not be accepted without a medical excuse.  Please use regular notebook paper with your name, student ID number, course and section number, date, my name and set number on the first page, and print your name on all additional pages.  The problems submitted must be the "original" (not a photo- or carbon copy).  The problem sets will NOT be returned to you.  Please retain a copy of your work for future reference.  You must show all work (messy is OK).  You must hand in at least 70% to receive 1 BOP point and at least 90% to receive 2 BOP points.  I encourage you to work the problems.  You will find similar problems on the exams.  I am available to answer any questions on BOP's during my office hours and review sessions.  
Chapter 15
(20 questions)

	6, 10, 20, 24, 28, 30, 34, 52(& (c) Calculate E per mol of lead nitrate consumed under the conditions of the experiment - ans.= same as (b). Why?), 54 (& (c) from E and the final T, calculate H in kJ/mol benzene() - ans.= -3270 kJ/mol (-3268 kJ/mol to 4 sig. fig. Note: ngas = -3/2 per 1 mole of benzene), (d) Calculate H from App. K data; compare to (c), ans. = -3267.4 kJ/mol benzene), 58, 62, 64 (& (c) Ni(s) + 4CO(g)  Ni(CO)4(g) at 75oC; ans. = +8680 J/mol), 70, 72, 76, 77, 80, 88, 90, 92
	[not for credit:  8, 12, 18, 50, 56, 60, 74 and others]	
Chapter 16
(16 questions)	2, 6, 12, 14, 18, 20, 22, 24, 30, 34, 44, 46, 56(& exclude (c)), 58, 60, 70
	[not for credit:  20, 26, 42 and others]	
Chapter 17
(14 questions)	6, 10, 14, 16, 22, 28, 32, 38, 46, 48, 52 (Change (b) to read “If 0.20 mol of A and 0.20 mol of B are added to the system, what will the new concentration of A be?” - I don’t want you to do a quadratic equation - ans. is [A]new = 0.44 M), 62, 70, 80
	[not for credit:  12, 18, 24, 26, 42, 44, 50 and others]	
Chapter 18
(16 questions)	6, 24, 26, 30, 34, 36, 38, 40, 44, 50, 60, 62, 65 (ans.= (a) 3.1  (b) 0.72), 72, 78, 85 (ans. = 0.214 M)
	[not for credit:  4, 8, 16, 42, 48, 60, 70, 82 and others]	
Chapter 19
(9 questions)	8, 14, 16, 18, 22, 34, 36, 37, 38
Answers to 37: (a) pH = 10.62  (b) pH = 10.21  (c) pH = 9.62  (d) pH = 9.25  (e) pH = 8.89  (f) pH = 8.30  (g) pH = 8.00  
(h) pH = 5.62  (i) pH = 3.30  (j) pH = 2.70  (k) pH = 2.30.  Indicator:  methyl red or methyl orange  
	[not for credit:  10, 20, 24 and others]	
Chapter 20
(10 questions)	4, 6, 8, 12, 18, 22, 24, 26, 28, 56
	[not for credit:  10, 14, 15, 20 and others]	
Chapter 21
(18 questions)	10, 12, 14, 18, 24, 26, 30, 36, 48, 50, 54, 56, 58, 60, 70, 76, 82, 84
	[not for credit:  2, 20, 22, 34, 38, 52, 68, 72 and others]	
Chapter 27
Chapter 28
(9 questions)	12, 16, 26, 28, 78, 80
4, 12, 18 (may not be covered in class)	
Chapter 26		[not for credit:  4, 6, 10, 26, 28, 30, 34, 36, 38, 40, 46, 48, 68]