CHEMISTRY 112

SPRING 1996

To The Student:
Chemistry 112 is the second-semester general chemistry laboratory course designed to accompany the second-semester lecture course, Chemistry 102. It is assumed that students are concurrently enrolled in both the lecture and laboratory courses. We hope that through this laboratory course you will gain useful skills and knowledge that will complement what you will be learning in the lecture course.
In this course you will be given instructions on additional useful lab techniques and will gain additional experience in the treatment of laboratory data. Through a variety of applications many concepts of both the first and second semester of general chemistry lecture will be illustrated. To assist you in gaining the most from this course we have, wherever possible: (1) selected exercises with a wide variety of applied chemical principles, (2) designed pre-laboratory instruction to assist you, and (3) arranged for a help desk to provide help outside of the time that you are in lab. Lab office hours will be held at the help desk in Room 415 of Heldenfels Hall. Check the bulletin boards outside of Rooms 100, 401 and 413 for schedules of the help desk, etc. You may also call the First Year Chemistry Electronic Information Center at 862-3456 for information on weekly assignments, quizzes, etc.
Everyone associated with this course wants it to be enjoyable, instructive, and meaningful. Please feel free to call upon us if we can be of assistance during the semester.

The Faculty and Staff
First Year Chemistry Labs

You Will Need:
1. The laboratory manual (Measurement and Synthesis in the Chemistry Laboratory, L. Peck and K. Irgolic).
2. The lab notebook (8 1/2" x 11", perforated alternating white and yellow pages with carbon paper).
3. Approved eye protection. University and Departmental Regulations require that splash-proof, chemical goggles be worn by everyone present any time any experimentation is being conducted or any time chemicals or equipment are being moved by anyone in the laboratory. (The Graduate Chemistry Fraternity will be at the labs the first week of lab to sell suitable goggles). Failure to wear goggles will result in expulsion from the laboratory for the experiment involved. You may also wish to bring a calculator, a laboratory apron, or a nonflammable lab coat. The textbook for Chemistry 102 will also prove helpful. An apron or lab coat will be required if your shorts or skirt do not cover your knees.

Policy on Safety and Breakage
Before working in this laboratory course, every student must read the "Laboratory Safety" rules in the laboratory manual plus the Departmental Rules and agree in writing to abide by these rules. It is imperative for your safety that you and everyone around you strictly adhere to the Safety Rules. Failure to comply with the safety regulations (e.g., by not wearing eye protection at all times; by wearing open-toed shoes, short skirts or shorts; by running an unauthorized experiment; or by removing chemicals or equipment from the lab) may result in dismissal from the course or deduction of points on your reports.
In this course you will be utilizing equipment furnished by the Chemistry Department. It is your responsibility to properly maintain the equipment while it is in your care. If equipment that has been entrusted to you is not returned in satisfactory condition, you will be held responsible for it.

Grading and Absence Policy
Absences
: The schedule on the back of this sheet gives the date that each experiment is to be completed. A make-up session is scheduled for those students who have missed prior experiments due to university approved reasons. Excused absences will need to be reported to your instructor in a timely manner.
Data Sheets: A data sheet must be submitted at the end of the lab period to receive a grade for that day's experiment. The data sheet may not be graded in some sections; however, the Report Form for the corresponding experiment will not be graded if the data sheet is not submitted the day the experiment is conducted.
Reports: For each experiment you will receive a total score between 12 and 0. The Report Form is due the same day that the experiment is performed unless indicated otherwise. The Report Form must reflect information obtained by you while in the laboratory and recorded on your data sheets. The Prelab Exercises associated with each experiment are due before you start the experiment, unless specified otherwise on the "schedule." Neatness and completeness of your data sheets and prelab exercises may be considered when points for organization of data, etc., are assigned as a part of your Report Form grade. Many instructors deduct up to 4 points from the Report Form for incomplete data sheets and/or 4 points for incomplete or messy Prelab Exercises. Points will be deducted for Report Forms not submitted on the date indicated. Reports more than two weeks late will not be graded.
Quizzes: Quizzes (16 points each, usually 3 or 4 points per question) are scheduled at various times during the semester. The quizzes will reflect what you should have gained from previous weeks' experiments, what you should master before beginning the current week's experiment, and your ability to utilize techniques and concepts. You must take the final exam to obtain a final course grade of D or higher. However, taking the final exam does not insure one a grade of D.
Grades: At the end of the semester the scores on all quizzes, reports, and written final (30 points) will be totaled for each student and the final letter grades for the course will be determined based upon the ranking of each student's total points compared to other students in that section. For the past several semesters the average grade in every section has been a mid-B. We do not expect the grade distribution to differ this semester.
Dishonesty: Students are expected to be the sole source for any work submitted in their name or the name of a group designated by the instructor. The utilization or submission of work of other students, tutors, or other agents not authorized by the instructor is a violation of scholastic dishonesty policies and disciplinary steps will be taken. Only authorized electronic or printed materials or equipment may be used in or near the laboratory. Unauthorized programs, materials, or equipment will be confiscated or destroyed.


SCHEDULE CHEMISTRY 112 - SPRING 1996



1/16-1/19
No lab meeting this week.

1/22-1/26
Check-in and Lecture on Safety. (Everyone must read the safety rules and agree in writing to follow them before they can begin any experimentation.) Perform Investigation #20 - Analysis of an Unknown Oxalate (part B only). Run three trials. Review standard deviation and relative standard deviation as described in Inv. #2, page 11. Review balancing redox equation (refer to your lecture textbook or first semester notes if necessary). Your instructor will give a brief lecture on redox. A completed Report Form and a Data Sheet must be left with your instructor. Someone from the Graduate Chemistry Fraternity (PLU) will visit the labs this week selling safety goggles. There will be a brief lecture on topics covered on the Prelab Exercises for Inv. #21.

1/29-2/2
Investigation #21 - Determination of Iron in Pyrites (parts E, F, G-1 and G-2 only). Prelab Exercises #21 due at beginning of lab. A completed Report Form and a Data Sheet for Inv. #21 are to be left with your instructor when you leave the lab. Quiz over Inv. #20 and redox rxns (description, balancing, oxidizing agent, reducing agent, etc.) Make-up quizzes will be given the week of 4/22-4/26. There will be a brief lecture on topics covered on the Prelab Exercises for Inv. #14.

2/5-2/9
Investigation #14 - Heat Storage for Solar Heating. Prelab #14 is due at beginning of lab. A completed Report Form and a Data Sheet for Inv. #14 are to be left with your instructor. There will be a brief lecture on topics covered on the Prelab Exercises for Inv. #22.

2/12-2/16
Investigation #22 - The Kinetics of the Decomposition of Hydrogen Peroxide. Prelab Exercises #22 due at beginning of lab. Work in groups of three during this Investigation and its Report. A completed Report Form and a Data Sheet for Inv. #22 are to be left with your instructor when you leave the lab. Quiz over redox reactions plus Inv. #21, #14, and #22. There will be a brief lecture on topics covered on the Prelab Exercises for Inv. #26.

2/19-2/23
Investigation #26 - Enthalpy of Dissociation of Acetic Acid. Prelab Exercises and Data Sheet for #26 are due this week. The completed Report Form for Inv. #26 is due at the end of next week's lab period.

2/26-3/1
Investigation #24 - Determination of an Ionization Constant. Prelab Exercises for Inv. #24 will not be collected until next week. Leave a copy of your Data Sheet for Inv. #22 with your instructor before you leave the lab this week. Bring your copy of your data sheet to lab next week. Don't complete the Report Form before coming to lab next week.

3/4-3/8
Your instructor will guide you through the Report Form for Inv. #24 during lab this week. The Prelab Exercises and the Report Form for Inv. #24 are due at the end of the period. Quiz.

3/11-3/15

SPRING BREAK (no classes)


3/18-3/22
Investigation #25 - The NH3/NH4Cl Buffer System. Prelab Exercises and Data Sheet for Inv. #25 are due before you leave the lab. If you are unable to complete the Report Form, there will be help available during lab next week. Sign-up for the replacement experiment the week of 3/25-3/29 if you need to replace a missed experiment. Be prepared to verify your excuse.

3/25-3/29
There will be a brief lecture on topics covered on the Prelab Exercises for Inv. #32. Report Form for Investigation #25 is due. You may wish to work on this during this lab time. If you have missed one of the prior investigations, have a verifiable excuse, and have made arrangements with your instructor, you may run Investigation #29 - Calcium in Natural Materials as a REPLACEMENT EXPERIMENT. If you run Inv. #29, you may not also be able to work on the Report Form for Investigation #25 .

4/1-4/4
Investigation #32 - Colorimetric Determination of Copper. Completed Prelab Exercises, Report Form, and Data Sheet for Inv. #32 are due before you leave the lab. (Friday sections will have this opportunity on April 30.)

4/8-4/12
Investigation #28 - A Cobalt Complex. Completed Prelab Exercises, Report Form, and Data Sheet for Inv. #32 are due before you leave the lab. Quiz. There will be a lecture on topics covered on the Prelab Exercises for Inv. #33.

4/15-4/19
Investigation #33 - Models of Organic Compounds. Completed Prelab Exercises, Report Form, and Data Sheet for Inv. #33 are due before you leave the lab.

4/22-4/26
Written (30 points) Final. Make-up quizzes will be given to those students who have missed a quiz due to University-approved reasons. All missing work, make-up finals, requests of the grade of "incomplete", make-up of prior incomplete grades, etc., must be completed and all forms submitted before 5 PM. May 2 if they are to be considered in this semester's records.

4/30
Friday sections only! Investigation #32 - Colorimetric Determination of Copper. Completed Prelab Exercises, Report Form, and Data Sheet for Inv. #32 are due before you leave the lab.