CHEMISTRY 316
 

HOMEWORK For Fall Semester
 
 

M. W. Rowe
 
 

HOMEWORK ASSIGNMENTS



From Analytical Chemistry: An Introduction, Douglas A. Skoog, Donald M. West, James Holler and Stanley Crouch, 7th Edition, Saunders Publishing Company, Philadelphia, PA, 1999.

Chapter 1 What is analytical Chemistry?
Read and study chapter 1

Chapter 2 The Tools of Analytical Chemistry.
Read and study chapter 2

Chapter 3 Important Chemical Concepts: Expressing Quantities and Concentrations
Read and study chapter 3; this is essential review of general chemistry concepts necessary for success in this course.
Work problems 2 (very important), 7, 9 a, b, d, 11 d, 14 a,b, 15 a,c,e, 16 a,c,e,g, 17 a,c,e, 18, a,c,e,g, 21, 23, and 31

Chapter 4 The Basic Approach to Chemical Equilibrium.
Read and study chapter 4; this is essential review of general chemistry concepts necessary for success in this course.
Work problems 8 a, b, c & d; 10 a, c & e; 11; 13; 15; 17; 20 a, c, e & g; and 22 a, c, e.

Chapter 10 How Equilibrium Calculations Can Be Applied To Complex Systems
Read and study chapter 10
Work problems 7 a, c, 13, 15, and 16

Chapter 11 Titrations: Taking Advantage of Stoichiometric Reactions
Read and study chapter 11
Work problems 10, 12 a, c, 27, and 32

Chapter 12 Principles of Neutralization Titrations: Determining Acids, Bases, and the pH of Buffer Solutions.
Read and study chapter 12.
Work problems 10 a, c, 15, 18, 23, 26 a, c, 27 a, c, 28 a, c, 29 a, c, 30 a, c, 32, 34, 39 a, c, e, 43, and 50 a, c (with or without spreadsheet).

Chapter 13 Titrating Polyfunctional Acids and Bases.
Read and study chapter 13.
Work problems 9 a, c, e, 10 a, c, e, 11 a, c, e, 12, 14, 18, and 20.
Generate the titration curve for the titration curve of 50 ml of 0.1000 M H3PO4 with 0.1000 M NaOH. Calculate the pH after the addition of 0, 10, 25, 40, 50, 60, 75, 90, 100, 110, 125, 140, 150, 160, and 200 ml of NaOH.

Chapter 15 Complexation and Precipitation Titrations: Taking Advantage of Complexing and Precipiting Agents.
Read and study chapter 15.
Work problems 14, a, c, 16, 22, 26, 34 and 20.

Chapter 16 Elements of Electrochemistry.
Read and study chapter 16.
Work problems 7, a, c, e, g, i, 11 a, b, 13, 16, a, d, f, 18, 20, 24, and 25.

Chapter 17 Using Electrode Potentials.
Read and study chapter 17.
Work problems 8, 11 a, c, e, g, and 25 a, c, e either with or without the use of a spreadsheet.
 



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