CHEMISTRY
316
HOMEWORK For
Fall Semester
M.
W. Rowe
HOMEWORK ASSIGNMENTS
From Analytical Chemistry: An Introduction, Douglas A. Skoog, Donald M. West, James Holler and Stanley Crouch, 7th Edition, Saunders Publishing Company, Philadelphia, PA, 1999.
Chapter
1 What is analytical Chemistry?
Read
and study chapter 1
Chapter
2 The Tools of Analytical Chemistry.
Read
and study chapter 2
Chapter
3 Important Chemical Concepts: Expressing Quantities and Concentrations
Read
and study chapter 3; this is essential review of general chemistry concepts
necessary for success in this course.
Work
problems 2 (very important), 7, 9 a, b, d, 11 d, 14 a,b, 15 a,c,e, 16 a,c,e,g,
17 a,c,e, 18, a,c,e,g, 21, 23, and 31
Chapter
4 The Basic Approach to Chemical Equilibrium.
Read
and study chapter 4; this is essential review of general chemistry concepts
necessary for success in this course.
Work
problems 8 a, b, c & d; 10 a, c & e; 11; 13; 15; 17; 20 a, c, e
& g; and 22 a, c, e.
Chapter
10 How Equilibrium Calculations Can Be Applied To Complex Systems
Read
and study chapter 10
Work
problems 7 a, c, 13, 15, and 16
Chapter
11 Titrations: Taking Advantage of Stoichiometric Reactions
Read
and study chapter 11
Work
problems 10, 12 a, c, 27, and 32
Chapter
12 Principles of Neutralization Titrations: Determining Acids, Bases, and
the pH of Buffer Solutions.
Read
and study chapter 12.
Work
problems 10 a, c, 15, 18, 23, 26 a, c, 27 a, c, 28 a, c, 29 a, c, 30 a,
c, 32, 34, 39 a, c, e, 43, and 50 a, c (with or without spreadsheet).
Chapter
13 Titrating Polyfunctional Acids and Bases.
Read
and study chapter 13.
Work
problems 9 a, c, e, 10 a, c, e, 11 a, c, e, 12, 14, 18, and 20.
Generate
the titration curve for the titration curve of 50 ml of 0.1000 M H3PO4
with 0.1000 M NaOH. Calculate the pH after the addition of 0, 10, 25, 40,
50, 60, 75, 90, 100, 110, 125, 140, 150, 160, and 200 ml of NaOH.
Chapter
15 Complexation and Precipitation Titrations: Taking Advantage of Complexing
and Precipiting Agents.
Read
and study chapter 15.
Work
problems 14, a, c, 16, 22, 26, 34 and 20.
Chapter
16 Elements of Electrochemistry.
Read
and study chapter 16.
Work
problems 7, a, c, e, g, i, 11 a, b, 13, 16, a, d, f, 18, 20, 24, and 25.
Chapter
17 Using Electrode Potentials.
Read
and study chapter 17.
Work
problems 8, 11 a, c, e, g, and 25 a, c, e either with or without the use
of a spreadsheet.