Ozerov Research Group
Organometallics, Catalysis, Energy

Texas A&M University, Department of Chemistry
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Alkyne C-H Borylation Catalyst Aryl Halide Coupling Catalyst C-F Activation Catalyst First Bis(Methylene) Complex First Covalent Pd-Zn Bond Silylium Zwitterion

PUBLICATIONS

 

 

2017

 

(89) Zhou, J.; Lee, C.-I; Ozerov, O. V. "Computational Study of the Mechanism of Dehydrogenative Borylation of Terminal Alkynes by SiNN Iridium Complexes". ACS Catal. 2017, Just Accepted manuscript.

 

(88) Shih, W.-C.; Ozerov, O.V. "Selective ortho-C–H Activation of Pyridines Directed by the Lewis Acidic Boron of PBP Pincer Iridium Complexes". J. Am. Chem. Soc. 2017, Just Accepted manuscript.

 

(87) Zabula, A. V.; Qiao, Y.; Kosanovich, A. J.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Ozerov, O. V.; Schelter, E. J. "Structure, Electronics, and Reactivity of Ce(PNP) Complexes", Chem. Eur. J. 2017, Just Accepted manuscript.

 

(86) Pell, C. J.; Shih, W.-C.; Gatard, S.; Ozerov, O. V. "Formation of (PNP) Rh complexes containing covalent rhodium-zinc bonds in studies of potential Rh-catalysed Negishi coupling", Chem. Commun . 2017, 53, 6456-6459.

(85) Shih, W.-C.; Gu, W.; MacInnis, M. C.; Herbert, D. E.; Ozerov, O. V. "Boryl/Borane Interconversion and Diversity of Binding Modes of Oxygenous Ligands in PBP Pincer Complexes of Rhodium", Organometallics 2017, 36, 1718-1726.

(84) Pell, C. J.; Zhu, Y.; Huacuja, R.; Herbert,P D. E.; Hughes, R.; Ozerov, O. V. "Fluorocarbene, Fluoroolefin, and Fluorocarbyne Complexes of Rh", Chem. Sci. 2017, 8, 3178-3186.

(83) Shih, W.-C.; Ozerov, O. V. "Synthesis and Characterization of PBP Pincer Iridium Complexes and Their Application in Alkane Transfer Dehydrogenation", Organometallics 2017, 36, 228-233.

(82) Kosanovich, A. J.; Press, L. P.; Ozerov, O.V. "Boryl Transfer Reactivity of a POCOP-Supported Ir-diboryl: Reduction of CO2 to CO and Borylation of Other Small Molecules", J. Organomet. Chem. 2017, 23, 19-24.

 

2016

(81) MacInnis,P M. C.; DeMott, J. C.; Zolnhofer, E. M.;Zhou, J. Meyer, K.; Hughes, R. P.; Ozerov, O. V. "Cationic Two-Coordinate Complexes of Pd(I) and Pt(I) Have Longer Metal-Ligand Bonds Than Their Neutral Counterparts", Chem 2016, 1, 902-920.

 

(80) Kosanovich, A. J.; Shih, W.-C.; Ramírez-Contreras, R.; Ozerov, O. V. "N-H Cleavage as a Route to New Pincer Complexes of High-Valent Rhenium", Dalton Trans. 2016, 45, 18532-18540.

 

(79) Press, L. P.; Kosanovich, A. J.; McCulloch, B. J.; Ozerov, O. V. "High-Turnover Aromatic C-H Borylation Catalyzed by POCOP-type Pincer Complexes of Iridium", J. Am. Chem. Soc. 2016, 138, 9487-9497.

 

(78) Shih, W.-C.; Gu, W.; MacInnis,P M. C.; Timpa, S. D.; Bhuvanesh, N.; Zhou, J. Ozerov, O. V. "Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes", J. Am. Chem. Soc. 2016, 138, 2086-2089.

 

(77) Kosanovich, A. J.; Reibenspies, J. H.; Ozerov, O. V. "Complexes of High-Valent Rhenium Supported by the PCP Pincer", Organometallics 2016, 35, 513-519.

 

2015

(76) Shih, W.-C.; Ozerov, O. V. "One Pot Synthesis of 1,3-Bis(phosphinomethyl)arene PCP/PNP Pincer Ligands and their Nickel Complexes", Organometallics 2015, 34, 4591-4597.

 

(75) Lee, C.-I; Shih, W.-C.; Zhou, J; Reibenspies, J. H.; Ozerov, O. V. "Synthesis of Triborylalkenes by Ir-Catalyzed Tandem C-H Borylation and Diboration", Angew. Chem., Int. Ed. 2015, 54, 14003-14007. See highlights in C&EN News.

 

(74) DeMott, J. C.; Dekarske,U J. R.; McCulloch, B. J.; Ozerov, O. V. "Cyclometallation of the NNN Pincer Ligand in Complexes of Platinum", Inorg. Chem. Front. 2015, 2, 912-916.

 

(73) Lee, C.-I; DeMott, J. C.; Pell, C. J.; Christopher, A.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. "Ligand Survey Results in Identification of PNP Pincer Complexes of Iridium as Long-lived and Chemoselective Catalysts for Dehydrogenative Borylation of Terminal Alkynes", Chem. Sci. 2015, 6, 6572-6582.

 

(72) DeMott, J. C.; Gu, W.; McCulloch, B. J.; Herbert,P D. E.; Goshert, M. D.; Walensky,P J. R.; Zhou, J.; Ozerov, O. V. "Silyl-Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum", Organometallics 2015, 34, 3930-3933.

 

(71) Press, L. P.; McCulloch, B. J.; Gu, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Triflyloxy-Substituted Carboranes as Useful Weakly Coordinating Anions", Chem. Commun. 2015, 51, 14034-14037.

 

(70) Pell, C. J.; Ozerov, O. V. "Catalytic Dehydrogenative Borylation of Terminal Alkynes by POCOP-Supported Palladium Complexes", Inorg. Chem. Front. 2015, 2, 720-724.

 

(69) Ramírez-Contreras, R.; Bhuvanesh, N.; Ozerov, O. V. "Cycloaddition and C-H Activation Reactions of a Tantalum Alkylidyne", Organometallics 2015, 34, 1143-1146.

 

(68) Lee, C.-I; Hirscher,U N. A.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. "Adaptability of the SiNN Pincer Ligand in Iridium and Rhodium Complexes Relevant to Borylation Catalysis", Organometallics 2015, 34, 3099-3102. Graphic chosen for the cover. See story.

 

(67) Davidson, J. J.; DeMott, J. C.; Douvris, C.; Fafard, C. M.; Bhuvanesh, N.; Chen, C.-H.; Herbert,P D. E.; Lee, C.-I; McCulloch, B. J.; Foxman, B. M.; Ozerov, O. V. "Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Towards the Metal", Inorg. Chem. 2015, 54, 2916-2935.

 

2014

(66) Timpa, S. D.; Pell, C. J.; Ozerov, O. V. "A Well-Defined (POCOP)Rh Catalyst for the Coupling of Aryl Halides with Thiols", J. Am. Chem. Soc. 2014, 136, 14772-14779.

 

(65) Timpa, S. D.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. "Potential Carbon-Fluorine Reductive Elimination from Pincer-Supported Rh(III) and Dominating Side Reactions: Theoretical and Experimental Examination", Organometallics 2014, 33, 6210-6217.

 

(64) Timpa, S. D.; Pell, C. J.; Zhou, J.; Ozerov, O. V. "Fate of Aryl/Amido Complexes of Rh(III) Supported by a POCOP Pincer Ligand: C-N Reductive Elimination, beta-Hydrogen Elimination, and Relevance to Catalysis", Organometallics 2014, 33, 5254-5262.

 

(63) Pell, C. J.; Ozerov, O. V. "A Series of Pincer-Ligated Rhodium Complexes as Catalysts for the Dimerization of Terminal Alkynes", ACS Catal. 2014, 4, 3470-3480.

 

(62) Davidson, J. J.; Nagaraja,P C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Palladium Complexes of a New Phosphine-Amido-Siloxide Pincer Ligand with Variable Degrees of Protonation", Inorg. Chim. Acta 2014, 422, 70-77.

 

(61) Palit, C. M.; Graham,U D. J.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Reduction of CO2 to Free CO by a Pd(I)-Pd(I) Dimer", Chem. Commun. 2014, 50, 12840-12842.

 

2013

(60) Ramírez-Contreras, R.; Bhuvanesh, N.; Zhou,P J.; Ozerov, O. V. "Synthesis of a Silylium Zwitterion", Angew. Chem., Int. Ed. 2013, 52, 10313-10315.

 

(59) Smith,P D. E.; Herbert,P D. E.; Walensky,P J. R.; Ozerov, O. V. "Monomeric Rh(II) Complexes Supported by a Diarylamido/Bis(Phosphine) PNP Pincer Ligand and Their Reactivity Towards Dihydrogen", Organometallics 2013, 32, 2050-2058.

 

(58) Lee, C.-I; Zhou,P J.; Ozerov, O. V. "Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium", J. Am. Chem. Soc. 2013, 135, 3560-3566.

 

(57) Walensky,P J. R.; Fafard, C. M.; Guo, C.; Brammell,U C. M.; Foxman, B. M.; Hall, M. B.; Ozerov, O. V. "Understanding Pd-Pd Bond Length Variation in (PNP)Pd-Pd(PNP) Dimers", Inorg. Chem. 2013, 52, 2317-2322.

 

(56) DeMott, J. C.; Bhuvanesh, N.; Ozerov, O.V. "Frustrated Lewis Pair-Like Splitting of Aromatic C-H Bonds and Abstraction of Halogen Atoms by a Cationic [(FPNP)Pt]+ Species", Chem. Sci. 2013, 4, 642-649.

 

2012

(55) Kwan, M.-L.; Conry, S. J.; Carfagna, C. S.; Press, L. P.; Ozerov, O. V.; Hoffman, N. W.; Sykora, R. E. "{2,6-Bis[2,6-diisopropylphosphanyl)-oxy]-4-fluorophenyl-κ3P,C1,P'}(1H-pyrazole-κN2)nickel(II)hexafluorophosphate", Acta Cryst. 2012, E68, m1282-m1283.

 

(54) Ramírez-Contreras, R.; Ozerov, O.V. "Convenient C-Alkylation of the [HCB11Cl11]- Carborane Anion", Dalton Trans. 2012, 41, 7842-7844.

 

(53) Herbert,P D. E.; Miller,U A. D.; Ozerov, O. V. "Phosphorus(III) Cations Supported by a PNP Pincer Ligand and Sub-Stoichiometric Generation of P4 from Thermolysis of a Nickel Insertion", Chem. Eur. J. 2012, 18, 7696-7704.

 

(52) Zhu, Y.; Smith,P D. A.; Herbert,P D. E.; Gatard,P S.; Ozerov, O. V. "C-H and C-O Oxidative Addition in Reactions of Aryl Carboxylate with a PNP Pincer-Ligated Rh(I) Fragment", Chem. Commun. 2012, 48, 218-220.

 

2011

(51) Herbert,P D. E.; Ozerov, O. V. "Binuclear Palladium Complexes Supported by Bridged Pincer Ligands", Organometallics 2011, 30, 6641-6654.

 

(50) Smith,P D. A.; Ozerov, O. V. "Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium", Chem. Commun. 2011, 47, 10779-10781.

 

(49) DeMott,U J. C.; Surawatanawong,P P.; Barnett,U S. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Experimental and Computational Exploration of the Dynamic Behavior of (PNP)BF2, a Boron Compound Supported by an Amido/Bis(Phosphine) Pincer Ligand", Dalton Trans. 2011, 40, 11562-11570.

 

(48) Zhu, Y.; Chen, C.-H.; Fafard, C. M.; Foxman, B. M.; Ozerov, O. V. "Net Heterolytic Cleavage of B-H and B-B Bonds Across the N-Pd Bond in a Cationic (PNP)Pd Fragment", Inorg. Chem. 2011, 50, 7980-7987.

 

(47) Brammell,U C. M.; Pelton,U E. J.; Chen, C.-H.; Yakovenko, A. A.; Weng, W.; Foxman, B. M.; Ozerov, O. V. "Hafnium Alkyl Complexes of the Anionic PNP Pincer Ligand and Possible Alkylidene Formation", J. Organomet. Chem. 2011, 696, 4132-4137.

 

(46) Surawatanawong,P P.; Ozerov, O. V. "Computational Studies of Reactions of Insertion of Rh(I) and Ir(I) into N-H, N-CH3, and NCH2-H Bonds of the Diarylamine-Based PNP Pincer Ligands", Organometallics 2011, 30, 2972-2979.

 

(45) Puri,U M.; Gatard,P S.; Smith,P D. A.; Ozerov, O. V. "Competition Studies of Oxidative Addition of Aryl Halides to the (PNP)Rh Fragment", Organometallics 2011, 30, 2472-2482.

 

(44) Timpa, S. D.; Fafard, C. M.; Herbert,P D. E.; Ozerov, O. V. "Catalysis of Kumada-Tamao-Corriu Coupling by a (POCOP)Rh Pincer Complex", Dalton Trans. 2011, 40, 5426-5429.

 

(43) Gu, W.; Ozerov, O. V. "Exhaustive Chlorination of [B12H12]2- without Chlorine Gas and the Use of [B12Cl12]2- as Supporting Anion in Catalytic Hydrodefluorination of Aliphatic C-F Bonds", Inorg. Chem. 2011, 50, 2726-2728.

 

(42) Huacuja, R.; Graham,U D. J.; Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Herbert,P D. E.; Alliger, G.; Thomas, C. M.; Ozerov, O. V. "Reactivity of a Pd(I)-Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium", J. Am. Chem. Soc. 2011, 133, 3820-3823.

 

(41) Hollas,U A. M.; Gu, W.; Bhuvanesh, N.; Ozerov, O. V. "Synthesis and Characterization of Pd Complexes of a Carbazolyl/Bis(Imine) NNN Pincer Ligand", Inorg. Chem. 2011, 50, 3673-3679.

 

(40)  Gusev, D. G.; Ozerov, O. V. "Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and C6H5Cl Solution", Chem. Eur. J. 2011, 17, 634-640.

2010

(39)  Huacuja, R.; Herbert,P D. E.; Fafard, C. M.; Ozerov, O. V. "A Terminal Palladium Fluoride Complex Supported by an Anionic PNP Pincer Ligand", J. Fluor. Chem. 2010, 131, 1257-1261 (special issue in honor of R. P. Hughes).

 

(38) Bacciu,P D.; Chen, C.-H.; Surawatanawong,P P.; Foxman, B. M.; Ozerov, O. V. "High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand", Inorg. Chem. 2010, 49, 5328-5334.

 

(37Gu, W.; McCulloch, B. J.; Reibenspies, J. H.; Ozerov, O. V. "Improved Methods for the Halogenation of the [HCB11 H11] Anion", Chem. Commun. 2010, 46, 2820-2822. See also the addition/correction online.

 

(36) Douvris,P C.; Nagaraja,P, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon-Halogen Bonds Using Silylium Catalysis", J. Am. Chem. Soc. 2010, 132, 4946-4953.

 

(35) Gregor,U L. C.; Chen, C.-H.; Fafard, C. M.; Fan, L.; Guo, C.; Foxman, B. M.; Gusev, D. G.; Ozerov, O. V. "Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center", Dalton Trans. 2010, 39, 3195-3202.

2009

(34)  Radosevich, A. T.; Melnick, J. G.; Stoian, S. A.; Bacciu,P D.; Chen, C-H.; Foxman, B. M.; Ozerov, O. V.; Nocera, D. G. "Ligand Reactivity in PNP-Complexes of Mn(CO)3 and Re(CO)3", Inorg. Chem. 2009, 48, 9214-9221.

 

(33)   Gu, W.; Haneline,P M. R.; Douvris,P C.; Ozerov, O. V. "Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis", J. Am. Chem. Soc. 2009, 131, 11203-11212.

 

(32)  Whited, M. T.; Zhu, Y.; Timpa,U S. D.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.; Grubbs, R. H. "Probing the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir", Organometallics 2009, 28, 4560-4570.

 

(31)  Ozerov, O. V., "Oxidative Addition of Water to Transition Metal Complexes", Chem. Soc. Rev. 200938, 83-88.

2008

(30)  Sircoglou, M.; Bontemps, S.; Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. "Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane", J. Am. Chem. Soc. 2008, 130, 16729-16738.

 

(29)  Gatard,P S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment", Organometallics 2008, 27, 6257-6263.

 

(28) Douvris,P C.; Ozerov, O. V. "Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts", Science 2008, 321, 1188-1190.  Please see the press coverage summary here.

 

(27)  Masuda, J. D.; Jantunen, K. C.; Ozerov, O. V.; Noonan, K. J. T.; Gates, D. P.; Scott, B. L.; Kiplinger, J. L. "A Lanthanide Phosphinidene Complex: Synthesis, Structure, and Phospha-Wittig Reactivity", J. Am. Chem. Soc. 2008, 130, 2408-2409.  See a highlight in the February 11th, 2008 issue of Chemical and Engineering News 2008, 86(6), 46.

 

(26)  Bontemps, S.; Bouhadir, G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou D. "Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C3 Symmetry Supported by a Z-Type Ligand", Angew. Chem., Int. Ed. 2008, 47, 1481-1484.

2007

Book chapter: Ozerov, O. V. "Rigid PNP Pincer Ligands and their Transition Metal Complexes", in The Chemistry of Pincer Compounds (ISBN-10: 0-444-53138-6), Elsevier, 2007.

 

(25) Zhu, Y.; Fan, L.; Chen, C.-H.; Finnell,U S. R.; Foxman, B. M.; Ozerov, O. V. "C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity", Organometallics 2007, 26, 6701-6703.

 

(24) Gatard,P S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions", Organometallics 2007, 26, 6066-6075.

 

(23)  Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V."Covalent Palladium-Zinc Bonds and Their Reactivity", Chem. Commun. 2007, 4465-4467.

 

(22)  Gerber,U L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O. V. "A Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand", Organometallics 2007, 26, 4866-4868.

 

(21)  Fafard, C. M.; Adhikari, D.; Foxman, B. M.; Mindiola, D. J.; Ozerov, O. V. "Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond",J. Am. Chem. Soc. 2007, 129, 10318-10319.

 

(20)  Weng, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Palladium Complexes of a P2C= Ligand Containing a Central Carbene Moiety", Organometallics 2007, 26, 3315-3320.

 

(19)  DeMott,U J. C.; Basuli, F.;   Kilgore, U. J.;  Foxman, B. M.; Huffman, J. C.; Ozerov, O. V., Mindiola, D. J. "Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents", Inorg. Chem. 2007, 46, 6271-6276.

 

(18)  DeMott,U J. C.; Guo, C.; Foxman, B. M.; Yandulov, D. V.; Ozerov, O. V., "Five-coordinate aluminum complexes of a PNP ligand", Mendeleev Commun. 2007, 17, 63-65. (invited contribution to the Higher Chemical College issue)

 

(17)  Fafard, C. M.; Ozerov, O. V.  "Retardation of beta-Hydrogen Elimination in PNP Pincer Complexes of Pd", Inorg. Chim. Acta. 2007, 360, 286-292. (invited contribution for the Next Generation issue)

 

(16)  Ozerov, O. V.; Moura, C. P.; Hoffman, N. W. "Experiments in Thermodynamics and Kinetics of Phosphine Substitution in (p-Cymene)RuCl2(PR3)", J. Chem. Ed. 2007, 84, 489.

2006

(15)  Weng, W.; Parkin, S.; Ozerov, O. V. "Double C-H Activation Results in Ru Complexes of a Neutral PCP Ligand With a Central Carbene Moiety", Organometallics 2006, 25, 5345-5354.

 

(14)  Ozerov, O. V.; Guo, C.; Foxman, B. M. "Missing Link: PCP Pincer Ligands Containing P-N Bonds And Their Pd Complexes", J. Organomet. Chem. 2006, 691, 4802-4806.

 

(13)  Gatard,P S.; Çelenligil-Çetin,P R.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Carbon-Halide Oxidative Addition and Carbon-Carbon Reductive Elimination at a (PNP)Rh Center", J. Am. Chem. Soc. 2006, 128, 2808-2809.

 

(12)  Weng, W.; Guo, C.; Çelenligil-Çetin,P R.; Foxman, B. M.; Ozerov, O. V. "Skeletal Change In The PNP Pincer Ligand Leads To A Highly Regioselective Alkyne Dimerization Catalyst", Chem. Commun. 2006, 197-199.

 

2005

(11)  Fan. L.; Parkin, S.; Ozerov, O. V. "Halobenzenes and Ir(I): Kinetic C-H Oxidative Addition and Thermodynamic C-Hal Oxidative Addition", J. Am. Chem. Soc. 2005, 127, 16772-16773.

 

(10)  Fan, L.; Ozerov, O. V. "Efficient Nickel Catalyst For Coupling Of Acetonitrile With Aldehydes",Chem. Commun. 2005, 4450-4452.

 

(9)  Weng, W.; Guo, C.; Moura, C. P.; Yang, L.; Foxman, B. M.; Ozerov, O. V. "Competitive Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and Iridium", Organometallics 2005, 24, 3487-3499.

 

(8)  Scott,U V. J.; Çelenligil-Çetin,P R.; Ozerov, O. V. "Room-Temperature Catalytic Hydrodefluorination of Aliphatic C-F Bonds", J. Am. Chem. Soc. 2005, 127, 2852-2853. (See a highlight in the March 14th, 2005 issue of Chemical and Engineering News 2005, 83(11), 33.)

 

(7)  Bailey, B. C.; Huffman, J. C.; Mindiola, D. J.; Weng, W.; Ozerov, O. V. "Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene and Imide Functionalities", Organometallics 2005, 24, 1390-1393.

 

(6)  Çelenligil-Çetin,P R.; Watson, L. A.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center", Organometallics 2005, 24, 186-189.

 

2004

(5)  Weng, W.; Yang, L.; Foxman, B. M.; Ozerov, O. V. "Chelate-Enforced Phosphine Coordination Enables a-Abstraction to Give Zirconium Alkylidenes", Organometallics 2004, 23, 4700-4705.

 

(4)  Ozerov, O. V.; Guo, C.; Fan. L.; Foxman, B. M. "Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nickel, Palladium, and Platinum", Organometallics 2004, 23, 5573-5580. 

 

(3)  Fan, L.; Yang, L.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "N-C Cleavage in Pincer PNP Complexes of Palladium", Organometallics 2004, 23, 4778-4787.

 

(2)  Ozerov, O. V.; Guo, C.; Papkov, V. A.; Foxman, B. M. "Facile Oxidative Addition of N-C and N-H Bonds to Monovalent Rhodium and Iridium", J. Am. Chem. Soc. 2004, 126, 4792-4793.

 

(1)  Fan, L.; Foxman, B. M.; Ozerov, O. V. "N-H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand", Organometallics 2004, 23, 326-328.

 

Key for Ozerov group members: UndergraduatesU,Graduate Students, and PostdocsP.

 

Oleg's older (pre-Brandeis U) publications:

 

From postdoctoral work at Indiana University:

 

(9) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. "Operationally Unsaturated Pincer/Rhenium Complexes Form Metal Carbenes from Cycloalkenes and Metal Carbynes from Alkanes", J. Am. Chem. Soc. 2007, 129, 6003-6016.

(8) Ozerov, O. V.; Watson, L. A.; Pink, M.; Baik, M.-H.; Caulton, K. G. "Terminal Acetylenes React to Increase Unsaturation in [(tBu2PCH2SiMe2)2N]Re(H)4", Organometallics 2004, 23, 4934-4943.

(7) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. "Transformation of Acyclic Alkenes to Hydrido Carbynes by (PNPR)Re Complexes", J. Am. Chem. Soc. 2004, 126, 6363-6378.

(6) Ozerov, O. V.; Pink, M.; Watson, L. A.; Caulton, K. G. "Aromatic vs. Aliphatic C-H Cleavage of alkyl-Substituted Pyridines By (PNPiPr)Re Compounds", J. Am. Chem. Soc. 2004, 126, 2105-2113.

(5) Ozerov, O. V.; Huffman, J. C.; Watson, L. A.; Caulton, K. G. "Conversion of Ethylene to Hydride and Ethylidyne by an Amido Rhenium Polyhydride", Organometallics 2003, 22, 2539-2541.

(4) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. "A π-basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand", J. Am. Chem. Soc. 2003, 125, 9604-9605.

(3) Watson, L. A.; Ozerov, O.; Pink, M.; Caulton, K. G. "Four-coordinate, Planar Ru(II). A Triplet State as a Response to 14 Valence Electron Configuration", J. Am. Chem. Soc. 2003, 125, 8426-8427.

(2) Watson, L. A.; Coalter, J. N. III; Ozerov, O.; Pink, M.; Huffman, J. C.; Caulton, K. G. "Amido/phosphine pincer hydrides of ruthenium ", New J. Chem. 2003, 27, 263-273.

(1) Ozerov, O.V.; Gerard, H. F.; Watson, L. A.; Huffman, J. C.; Caulton, K. G. "Double Silyl Migration Converting ORe[(NSiMe2CH2PCy2)2] to NRe[(OSiMe2CH2PCy2)2] Substructures", Inorg. Chem. 2002, 41, 5615-5625.

 

From graduate work at University of Kentucky:

 

(6) Kingston, J. V.; Ozerov, O. V.; Parkin, S. Brock, C. P.; Ladipo, F. T. "Mechanistic Insight into Fragmentation Reactions of Titanapinacolate Complexes" J. Am. Chem. Soc. 2002, 124, 12217-12224.

(5) Ozerov, O. V.; Brock, C. P.; Carr, S.; Parkin, S.; Ladipo, F. T. "Unusual Reductive Coupling of Alkynes and Ketones: Reactivity of Titanacycles Supported by Dimethylsilylcalix[4]arene (DMSC) Ligand", Organometallics 2000, 19, 5016-5025.

(4) Ozerov, O. V.; Parkin, S.; Brock, C. P.; Ladipo, F. T. "Reactivity of a Well-Characterized Titananorbornadiene(η6-arene) Complex with Ketones and Aldehydes", Organometallics 2000, 19, 4187-4190.

(3) Ozerov, O. V.; Patrick, B. O.; Ladipo, F. T. "Highly Regioselective [2 + 2 + 2] Cycloaddition of Terminal Alkynes Catalyzed by η6-Arene Complexes of Titanium Supported by Dimethylsilyl-Bridged p-tert-Butyl Calix[4]arene Ligand", J. Am. Chem. Soc. 2000, 122, 6423-6431.

(2) Ozerov, O. V.; Ladipo, F. T.; Patrick, B. O. "Highly Regioselective Alkyne Cyclotrimerization Catalyzed by Titanium Complexes Supported by Proximally Bridged p-tert-Butylcalix[4]arene Ligands", J. Am. Chem. Soc. 1999, 121, 7941-7942.

(1) Ozerov, O. V.; Ladipo, F. T.; Rath, N. P. "Synthesis, Characterization, and Reactivity of Titanium(IV) Complexes Supported by Proximally Bridged p-tert-Butylcalix[4]arene Ligands", J. Organomet. Chem. 1999, 586, 223-233.

 

Dr. Oleg Ozerov
Department of Chemistry
Texas A&M University
P.O. Box 30012
College Station, Texas 77842-3012
PHONE: 979-845-5870 | EMAIL: ozerov@chem.tamu.edu

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