Ozerov Group Publications
2013
(60) Ramírez-Contreras, R.; Bhuvanesh, N.; Zhou,P J.; Ozerov, O. V. "Synthesis of a Silylium Zwitterion",
Angew. Chem., Int. Ed. 2013, 52, 10313-10315.
(59) Smith,P D. E.; Herbert,P D. E.; Walensky,P J. R.; Ozerov, O. V. "Monomeric Rh(II) Complexes Supported by a Diarylamido/Bis(Phosphine) PNP Pincer Ligand and Their Reactivity Towards Dihydrogen", Organometallics 2013, 32, 2050-2058.
(58) Lee, C.-I.; Zhou,P J.; Ozerov, O. V. "Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium", J. Am. Chem. Soc. 2013, 135, 3560-3566.
(57) Walensky,P J.; Fafard, C. M.; Guo, C.; Brammell, C. M.; Foxman, B.; Hall, M.; Ozerov, O. "Understanding Pd-Pd Bond Length Variation in (PNP)Pd-Pd(PNP) Dimers", Inorg. Chem. 2013, 52, 2317-2322.
(56) DeMott, J.; Bhuvanesh, N.; Ozerov, O.V. "Frustrated Lewis Pair-Like Splitting of Aromatic C-H Bonds and Abstraction of Halogen Atoms by a Cationic [(FPNP)Pt]+ Species", Chem. Sci. 2013,
4, 642-649.
2012
(55) Kwan, M.-L.; Conry, S. J.; Carfagna, C. S.; Press, L. P.; Ozerov, O. V.; Hoffman, N. W.; Sykora, R. E. "{2,6-Bis[2,6-diisopropylphosphanyl)-oxy]-4-fluorophenyl-κ3P,C1,P'}(1H-pyrazole-κN2)nickel(II)hexafluorophosphate", Acta Cryst. 2012, E68, m1282-m1283.
(54) Ramírez-Contreras, R.; Ozerov, O.V. "Convenient C-Alkylation of the [HCB11Cl11]- Carborane Anion", Dalton Trans. 2012, 41, 7842-7844.
(53) Herbert,P D. E.; Miller,U A. D.; Ozerov, O. V. "Phosphorus(III) Cations Supported by a PNP Pincer Ligand and Sub-Stoichiometric Generation of P4 from Thermolysis of a Nickel Insertion", Chem. Eur. J. 2012, 18, 7696-7704.
(52) Zhu, Y.; Smith,P D. A.; Herbert,P D. E.; Gatard,P S.; Ozerov, O. V. "C-H and C-O Oxidative Addition in Reactions of Aryl Carboxylate with a PNP Pincer-Ligated Rh(I) Fragment", Chem. Commun. 2012, 48, 218-220.
2011
(51) Herbert,P D. E.; Ozerov, O. V. "Binuclear Palladium Complexes Supported by Bridged Pincer Ligands", Organometallics 2011, 30, 6641-6654.
(50) Smith,P D. A.; Ozerov, O. V. "Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium", Chem. Commun. 2011, 47, 10779-10781.
(49) DeMott,U J.; Surawatanawong,P P.; Barnett,U S. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Experimental and Computational Exploration of the Dynamic Behavior of (PNP)BF2, a Boron Compound Supported by an Amido/Bis(Phosphine) Pincer Ligand", Dalton Trans. 2011, 40, 11562-11570.
(48) Zhu, Y.; Chen, C.-H.; Fafard, C. M.; Foxman, B.; Ozerov, O. V. "Net Heterolytic Cleavage of B-H and B-B Bonds Across the N-Pd Bond in a Cationic (PNP)Pd Fragment", Inorg. Chem. 2011, 50, 7980-7987.
(47) Brammell,U C. M.; Pelton,U E. J.; Chen, C.-H.; Yakovenko, A. A.; Weng, W.; Foxman, B. M.; Ozerov, O. V. "Hafnium Alkyl Complexes of the Anionic PNP Pincer Ligand and Possible Alkylidene Formation", J. Organomet. Chem. 2011, 696, 4132-4137.
(46) Surawatanawong,P P.; Ozerov, O. V. "Computational Studies of Reactions of Insertion of Rh(I) and Ir(I) into N-H, N-CH3, and NCH2-H Bonds of the Diarylamine-Based PNP Pincer Ligands", Organometallics 2011, 30, 2972-2979.
(45) Puri,U M.; Gatard,P S.; Smith,P D. A.; Ozerov, O. V. "Competition Studies of Oxidative Addition of Aryl Halides to the (PNP)Rh Fragment", Organometallics 2011, 30, 2472-2482.
(44) Timpa, S. D.; Fafard, C. M.; Herbert,P D. E.; Ozerov, O. V. "Catalysis of Kumada-Tamao-Corriu Coupling by a (POCOP)Rh Pincer Complex", Dalton Trans. 2011, 40, 5426-5429.
(43) Gu, W.; Ozerov, O. V. "Exhaustive Chlorination of [B12H12]2- without Chlorine Gas and the Use of [B12Cl12]2- as Supporting Anion in Catalytic Hydrodefluorination of Aliphatic C-F Bonds", Inorg. Chem. 2011, 50, 2726-2728.
(42) Huacuja, R.; Graham,U D. J.; Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Herbert,P D. E.; Alliger, G.; Thomas, C. M.; Ozerov, O. V. "Reactivity of a Pd(I)-Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium", J. Am. Chem. Soc. 2011, 133, 3820-3823.
(41) Hollas,U A. M.; Gu, W.; Bhuvanesh, N.; Ozerov, O. V. "Synthesis and Characterization of Pd Complexes of a Carbazolyl/Bis(Imine) NNN Pincer Ligand", Inorg. Chem. 2011, 50, 3673-3679.
(40) Gusev, D. G.; Ozerov, O. V. "Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and C6H5Cl Solution", Chem. Eur. J. 2011, 17, 634-640.
2010
(39) Huacuja, R.; Herbert,P D. E.; Fafard, C. M.; Ozerov, O. V. "A Terminal Palladium Fluoride Complex Supported by an Anionic PNP Pincer Ligand", J. Fluor. Chem. 2010, 131, 1257-1261 (special issue in honor of R. P. Hughes).
(38) Bacciu,P D.; Chen, C.-H.; Surawatanawong,P P.; Foxman, B. M.; Ozerov, O. V. "High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand", Inorg. Chem. 2010, 49, 5328-5334.
(37) Gu, W.; McCulloch, B. J.; Reibenspies, J. H.; Ozerov, O. V. "Improved Methods for the Halogenation of the [HCB11 H11]− Anion", Chem. Commun. 2010, 46, 2820-2822. See also the addition/correction online.
(36) Douvris,P C.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon-Halogen Bonds Using Silylium Catalysis", J. Am. Chem. Soc. 2010, 132, 4946-4953.
(35) Gregor,U L. C.; Chen, C.-H.; Fafard,
C. M.; Fan,
L.; Guo, C.; Foxman, B. M.; Gusev, D. G.; Ozerov, O. V. "Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center", Dalton Trans. 2010, 39, 3195-3202.
2009
(34) Radosevich, A.
T.; Melnick, J. G.; Stoian,
S. A.; Bacciu,P D.; Chen, C-H.; Foxman, B. M.; Ozerov, O. V.; Nocera,
D. G. "Ligand Reactivity in PNP-Complexes of Mn(CO)3 and Re(CO)3", Inorg. Chem. 2009, 48, 9214-9221.
(33) Gu, W.; Haneline,P M. R.; Douvris,P C.; Ozerov, O. V. "Carbon−Carbon
Coupling of C(sp3)−F Bonds Using Alumenium Catalysis", J. Am. Chem. Soc. 2009,
131, 11203-11212.
(32) Whited, M. T.; Zhu, Y.; Timpa,U S. D.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.;
Grubbs, R. H. "Probing
the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir", Organometallics 2009, 28,
4560-4570.
(31) Ozerov, O. V., "Oxidative
Addition of Water to Transition Metal Complexes", Chem. Soc.
Rev. 2009, 38, 83-88.
2008
(30) Sircoglou, M.;
Bontemps, S.; Bouhadir, G.; Saffon,
N.; Miqueu, K.; Gu,
W.; Mercy, M.; Chen, C.-H.; Foxman, B.; Maron, L.; Ozerov, O. V.; Bourissou,
D. "Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from
a Triphosphine–Borane", J. Am. Chem.
Soc. 2008, 130, 16729-16738.
(29) Gatard,P S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment", Organometallics 2008, 27, 6257-6263.
(28) Douvris,P C.; Ozerov, O. V. "Hydrodefluorination
of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts", Science 2008, 321, 1188-1190. Please see the press coverage summary here.
(27) Masuda, J. D.; Jantunen,
K. C.; Ozerov, O. V.; Noonan, K. J. T.; Gates, D. P.; Scott, B. L.; Kiplinger,
J. L. "A
Lanthanide Phosphinidene Complex: Synthesis,
Structure, and Phospha-Wittig Reactivity", J.
Am. Chem. Soc. 2008, 130, 2408-2409. See a highlight in the February 11th,
2008 issue of Chemical and Engineering News 2008, 86(6),
46.
(26) Bontemps, S.; Bouhadir,
G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov,
O. V.; Bourissou D. "Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C3 Symmetry Supported by a Z-Type Ligand", Angew. Chem., Int. Ed. 2008, 47, 1481-1484.
2007
Book chapter: Ozerov, O. V. "Rigid PNP Pincer Ligands and their Transition Metal Complexes", in The Chemistry of Pincer Compounds (ISBN-10: 0-444-53138-6), Elsevier, 2007.
(25) Zhu, Y.; Fan, L.; Chen, C.-H.; Finnell,U S. R.; Foxman, B. M.; Ozerov, O. V. "C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity", Organometallics 2007, 26, 6701-6703.
(24) Gatard,P S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions", Organometallics 2007, 26, 6066-6075.
(23) Fafard,
C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Covalent
Palladium-Zinc Bonds and Their Reactivity", Chem.
Commun. 2007, 4465-4467.
(22) Gerber,U L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O.
V. "A Bis(methylidene) Complex of Tantalum Supported by a PNP
Ligand", Organometallics 2007, 26, 4866-4868.
(21) Fafard,
C. M.; Adhikari, D.; Foxman,
B. M.; Mindiola, D. J.; Ozerov, O. V. "Addition
of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond", J. Am. Chem. Soc. 2007, 129, 10318-10319.
(20) Weng, W.;
Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Palladium
Complexes of a P2C= Ligand Containing a Central Carbene Moiety", Organometallics 2007, 26, 3315-3320.
(19) DeMott,U J. C.; Basuli, F.; Kilgore, U. J.; Foxman, B. M.; Huffman, J. C.; Ozerov, O. V., Mindiola, D. J. "Silver(I)
and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer
Reagents", Inorg. Chem. 2007, 46,
6271-6276.
(18) DeMott,U J. C.; Guo, C.; Foxman, B.
M.; Yandulov, D. V.; Ozerov, O. V., "Five-coordinate
aluminum complexes of a PNP ligand", Mendeleev Commun. 2007, 17,
63-65. (invited contribution to the Higher Chemical College issue)
(17) Fafard,
C. M.; Ozerov, O. V. "Retardation
of beta-Hydrogen Elimination in PNP Pincer Complexes of Pd", Inorg. Chim. Acta. 2007, 360, 286-292. (invited contribution for the Next Generation issue)
(16) Ozerov, O. V.; Moura, C. P.; Hoffman, N. W. "Experiments in Thermodynamics and Kinetics of Phosphine Substitution in (p-Cymene)RuCl2(PR3)", J. Chem. Ed. 2007, 84, 489.
2006
(15) Weng, W.; Parkin, S.; Ozerov, O. V. "Double
C-H Activation Results in Ru Complexes of a Neutral PCP Ligand With a Central
Carbene Moiety", Organometallics 2006, 25, 5345-5354.
(14) Ozerov, O. V.; Guo,
C.; Foxman, B. M. "Missing
Link: PCP Pincer Ligands Containing P-N Bonds And Their Pd Complexes", J. Organomet. Chem. 2006, 691, 4802-4806.
(13) Gatard,P S.; Çelenligil-Çetin,P R.; Guo, C.; Foxman, B. M.;
Ozerov, O. V. "Carbon-Halide
Oxidative Addition and Carbon-Carbon Reductive Elimination at a (PNP)Rh Center", J.
Am. Chem. Soc. 2006, 128, 2808-2809.
(12) Weng, W.; Guo,
C.; Çelenligil-Çetin,P R.; Foxman, B. M.;
Ozerov, O. V. "Skeletal
Change In The PNP Pincer Ligand Leads To A Highly Regioselective Alkyne
Dimerization Catalyst", Chem. Commun. 2006, 197-199.
2005
(11) Fan. L.; Parkin,
S.; Ozerov, O. V. "Halobenzenes
and Ir(I): Kinetic C-H Oxidative Addition and Thermodynamic C-Hal Oxidative
Addition", J.
Am. Chem. Soc. 2005, 127, 16772-16773.
(10) Fan,
L.; Ozerov, O. V. "Efficient Nickel Catalyst For Coupling Of Acetonitrile With
Aldehydes", Chem. Commun. 2005, 4450-4452.
(9) Weng, W.; Guo, C.; Moura,
C. P.; Yang, L.; Foxman, B. M.; Ozerov, O. V. "Competitive
Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and
Iridium", Organometallics 2005, 24, 3487-3499.
(8) Scott,U V. J.; Çelenligil-Çetin,P R.;
Ozerov, O. V. "Room-Temperature
Catalytic Hydrodefluorination of Aliphatic C-F Bonds", J.
Am. Chem. Soc. 2005, 127, 2852-2853. (See a highlight in the March 14th,
2005 issue of Chemical and Engineering News 2005, 83(11),
33.)
(7) Bailey, B. C.; Huffman, J. C.; Mindiola, D. J.; Weng,
W.; Ozerov, O. V. "Remarkably
Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene and
Imide Functionalities", Organometallics 2005, 24, 1390-1393.
(6) Çelenligil-Çetin,P R.; Watson, L. A.; Guo, C.; Foxman,
B. M.; Ozerov, O. V. "Decarbonylation of Acetone and
Carbonate at a Pincer-Ligated Ru Center", Organometallics 2005, 24, 186-189.
2004
(5) Weng, W.;
Yang, L.; Foxman, B. M.; Ozerov, O. V. "Chelate-Enforced
Phosphine Coordination Enables a-Abstraction
to Give Zirconium Alkylidenes", Organometallics 2004, 23, 4700-4705.
(4) Ozerov, O. V.; Guo,
C.; Fan. L.; Foxman, B. M. "Oxidative Addition of N-C and N-H
Bonds to Zero-Valent Nickel, Palladium, and Platinum", Organometallics 2004, 23, 5573-5580.
(3) Fan, L.; Yang, L.; Guo,
C.; Foxman, B. M.; Ozerov, O. V. "N-C
Cleavage in Pincer PNP Complexes of Palladium", Organometallics 2004, 23, 4778-4787.
(2) Ozerov, O. V.; Guo,
C.; Papkov, V. A.; Foxman,
B. M. "Facile
Oxidative Addition of N-C and N-H Bonds to Monovalent Rhodium and Iridium", J.
Am. Chem. Soc. 2004, 126, 4792-4793.
(1) Fan, L.; Foxman,
B. M.; Ozerov, O. V. "N-H
Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand", Organometallics 2004, 23, 326-328.
Ozerov
group members:
UndergraduatesU, Graduate Students, and PostdocsP.
For
Oleg’s pre-Brandeis publications, see here.