Publications

 

(M185) Computational Definition of a Mixed Valent Fe(II)Fe(I) Model of the [FeFe]Hydrogenase Active Site Resting State, Christine M. Thomas, Marcetta Y. Darensbourg, and Michael B. Hall, J. Biol. Inorg. Chem. 2007 , 101 , 1752-1757. (Ed Steifel Memorium)

(M184) An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN₂S₂ Complex, Kayla N. Green, Scott M. Brothers, Roxanne M. Jenkins, Cody E. Carson, Craig A. Grapperhaus, Marcetta Y. Darensbourg, Inorg. Chem. 2007 , 46 , 7536-7544.

(M183) Synthesis of Carboxylic Acid Modified [FeFe]-Hydrogenase Model Complexes Amenable to Surface Immobilization, Christine M. Thomas, Olaf Rudiger, Tianbiao Liu, Cody E. Carson, Michael B. Hall and Marcetta Y. Darensbourg, Organometallics , 2007 , 26 , 3976-3984.

(M182) A Mixed Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site, Tianbiao Liu and Marcetta Y. Darensbourg, J. Am. Chem. Soc. , 2007 , 129 , 7008-7009.

(M181) CO and Ethylene Migratory Insertion Reactions and Copolymerizaton Involving Palladium Complexes with a NiN₂S₂ Metallodithiolate Ligand, Marilyn V. Rampersad, Erik Zuidema, Jan Meine Ernsting, Piet W.N.M. van Lee uwen, and Marcetta Y. Darensbourg, Organometallics 2007 , 26 , 783-792.

(M180) The Acetyl CoA Synthase Paradigm for Hybrid Bio-organometallics: Quantitative Measures for Resin-Bound Ni-Rh Complexes, Kayla N. Green, William D. James, Angelica V. Cantillo, Marcetta Y. Darensbourg, Journal of Organometallic Chemistry, 2007 , 692 , 1392-1397.

(M179) Control of S-based Aggregation: Designed Synthesis of NiM₂ and Ni₂M Trinuclear Complexes, Stephen Jeffery, Michael Singleton, Joseph Reibenspies, Marcetta Y. Darensbourg, Inorg. Chem. 2007 , 46 , 179-185.

(M178) The Reaction of Electrophiles with Models of Iron–Iron Hydrogenase: A Switch in Regioselectivity, Jesse W. Tye, Marcetta Y. Darensbourg , Michael B. Hall, Journal of Molecular Structure: THEOCHEM 2006 , 771 , 123-128.

(M177) NiN₂S₂ Complexes as Metallodithiolate Ligands to Rh^I, Rh^II, and Rh^III, Stephen P. Jeffery, Kayla N. Green, Marilyn V. Rampersad, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Dalton Transactions , 2006 , 4244-4252.

(M176) Correlation Between Computed Gas-Phase and Experimentally Determined Solution-Phase Infrared Spectra: Models of the Iron-Iron Hydrogenase Enzyme Active Site, Jesse W. Tye, Marcetta Y. Darensbourg, Michael B. Hall, Journal of Computational Chemistry , 2006 , 27 , 1454-1462.

(M175) A Nickel Tripeptide as a Metallodithiolate Ligand Anchor for Resin-Bound Organometallics, Kayla N. Green, Stephen P. Jeffery, and Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2006 , 128 , 6493-6498.

(M174) Iron Nitrosyl Complexes as Models for Biological Nitric Oxide Transfer Reagents, Chao-Yi Chiang, Marcetta Y. Darensbourg, Journal of Biological Inorganic Chemistry , 2006 , 11 , 359-370.

(M173) De Novo Design in Inorganic Chemistry: Di-Iron(I) Complexes as Accurate Structural Models of the Reduced Form of Iron-Iron Hydrogenase, Jesse W. Tye. Marcetta Y. Darensbourg, and Michael B. Hall, Inorg. Chem. 2006 , 45 , 1552-1559.

(M172) A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands, Andrea L. Phelps, Marilyn V. Rampersad, Shawn B. Fitch, Marcetta Y. Darensbourg, Donald J. Darensbourg, Inorg. Chem. 2006, 45, 119-126.

(M171) Characterization of Steric and Electronic Properties of NiN₂S₂ Complexes as S-donor Metallodithiolate Ligands, Marilyn V. Rampersad, Stephen P. Jeffery, Melissa L. Golden, Jonghyuk Lee, Joseph H. Reibenspies, Donald J. Darensbourg, and Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2005, 127, 17323-17334.

(M170) Synthesis and Molecular Structures of Mononitrosyl (N₂S₂)M(NO) Complexes (M = Fe, Co), Chao-Yi Chiang, Jonghyuk Lee, Christopher Dalrymple, Michael C. Sarahan., Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Inorg. Chem. 2005, 44, 9007-9016.

(M169) Better than platinum?  Fuel cells energized by enzymes, Jesse W. Tye, Michael B. Hall, Marcetta Y. Darensbourg, Proceedings of the National Academy of Sciences 2005, 102, 16911-16912.

(M168) Thiolate-Bridged heterodinuclear Platinum-Zinc chelates as models for ternary Platinum-DNA-Protein Complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-Mass Spectrometry, Qin Liu, Melissa Golden, Marcetta Y. Darensbourg, and Nicholas Farrell, Chem. Comm. 2005, 4360-4362.

(M167) Dual Electron Uptake at Iron and Ligand in an Asymmetric [FeFe] Hydrogenase Model Compound, Jesse W. Tye, Jonghyuk Lee, Hsiao-Wan Wang, Rosario Mejia-Rodriguez, Joseph H. Reibenspies, Michael B. Hall, Marcetta Y. Darensbourg Inorg. Chem. 2005, 44, 5550-5552.

(M166) The Vapochromic Behavior, Desulfoxidation and Structural Characterization of the SO₂ Adducts of Ni(BME-DACH) from Powder Data, Nattamai S. P. Bhuvanesh, Joseph H. Reibenspies, Melissa L. Golden, Marcetta Y. Darensbourg, Yuegang Zhang, Peter L. Lee, Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2005, 35, 11-17.

(M165) N₂S₂Ni Metallodithiolate Complexes as Ligands: Structural and Aqueous Solution Quantitative Studies of the Ability of Metal Ions to Form M-S-Ni Bridges to Mercapto Groups Coordinated to Nickel(II). Implications for Acetyl Coenzyme A Synthase, Melissa L. Golden, Curtis M. Whaley, Marilyn V. Rampersad, Joseph H. Reibenspies, Robert D. Hancock, Marcetta Y. Darensbourg, Inorg. Chem. 2005, 44, 875-883.

(M164) Metallodithiolato Ligands as Bridges in Multiply Bonded Dimolybdenum Complexes, Stephen P. Jeffery, Jonghyuk Lee, and Marcetta Y. Darensbourg, Chem. Comm. 2005, 1122-1124.

(M163) Making a natural fuel cell, Marcetta York Darensbourg, Nature, 2005, 433, 589-591.

(M162) N₂S₂Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity, Marilyn V. Rampersad, Stephen P. Jeffery, Joseph H. Reibenspies, Cesar G. Ortiz, Donald J. Darensbourg and Marcetta Y. Darensbourg, Angew. Chem. 2005. 117, 1243-1246.

(M161) The Hydrophilic Phosphatriazaadamantane Ligand in the Development of H₂-production Electrocatalysts: Iron Hydrogenase Model Complexes, Rosario Mejia-Rodriguez,  Daesung Chong,  Joseph H. Reibenspies, Manuel P. Soriaga and Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2004, 126, 12004-12014.

(M160) Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N₂S₂ Ligand and Its Preference for Zinc(II), Melissa L. Golden, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Inorg. Chem. 2004, 43, 5798-5800.

(M159) Bismercaptoehanediazacyclooctane as a N₂S₂ Chelating Agent and Cys-X-Cys Mimic for Fe(NO) and Fe(NO)₂, Chao-Yi Chiang, Matthew L. Miller, Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2004, 126, 10867-10874.

(M158) Synergy between Theory and Experiment as Applied to H/D Exchange Activity Assays in [Fe]H₂ase Active Site Models, Jesse W. Tye, Michael B. Hall, Irene P. Georgakaki, Marcetta Y. Darensbourg Advances in Inorganic Chemistry 2004, 56, 1-26.

(M157) Sensing of Sulfur Dioxide by Base Metal Thiolates:  Structures and Properties of Molecular NiN₂S₂/SO₂ Adducts, Melissa L. Golden, Jason C. Yarbrough, Joseph H. Reibenspies, Marcetta Y. Darensbourg, Inorg. Chem. 2004, 43, 4702-4707.

(M156) Structures and Energetics of Models for the Active Site of Acetyl-Coenzyme A Synthase: Role of Distal and Proximal Metals in Catalysis, Charles E. Webster, Marcetta Y. Darensbourg, Paul A. Lindahl, Michael B. Hall, J. Am. Chem. Soc.  2004, 126, 3410-3411.

(M155) The Construction of (N₂S₂)Ni-Pd Clusters: A Slant Chair, a Basket and a C4-Paddlewheel, Melissa L. Golden, Stephen P. Jeffery, Matthew L. Miller, Joseph H. Reibenspies, Marcetta Y. Darensbourg  Eur. J. Inorg. Chem. 2004, 231-236.

(M154) Hydrogen Activation: The Metallohydrogenases and Models, Irene P. Georgakaki, Marcetta Y. Darensbourg Comprehensive Coordination Chemistry II 2003, 8, 549-568.

(M153) Electrocatalysis of Hydrogen Production by Active Site Analogues of the Iron Hydrogenase Enzyme: Structure/Function Relationships, Daesung Chong, Irene P. Georgakaki, Matthew L. Miller, Rosario Mejia-Rodriguez, and Marcetta Y. Darensbourg, Dalton Transactions 2003, 4158-4163.

(M152) Capture of Ni^II, Cu^I, and Zn^II by Thiolate Sulfurs of an N₂S₂Ni Complex: A Role for a Metallothiolate Ligand in the Acetyl-coenzyme A Synthase Active Site, Melissa L. Golden, Marilyn Rampersad, Joseph H. Reibenspies, Marcetta Y. Darensbourg, Chem. Comm. 2003, 1824-1825.

(M151) Fundamental Properties of Small Molecule Models of Fe-only Hydrogenase: Computations Relative to the Definition of an Entatic State in the Active Site, Irene P. Georgakaki, Lisa M. Thomson, Erica J. Lyon, Michael B. Hall, Marcetta Y. Darensbourg, Coordination Chemistry Reviews 2003, 238-239, 255-266.

(M150) Adamantane-like Cluster Complexes of Mixed-Valent Copper–Copper and Nickel–Copper Thiolates, Matthew L. Miller, Said A. Ibrahim, Melissa L. Golden, Marcetta Y. Darensbourg, Inorg. Chem. 2003, 42, 2999-3007.

(M149) Requirements for Functional Models of the Fe-Hydrogenase Active Site: D₂/H₂O Exchange Activity in {(m-SMe)(m-pdt)[Fe(CO)₂(PMe₃)]₂}⁺[BF₄]^-  Irene P. Georgakaki, Matthew L. Miller, Marcetta Y. Darensbourg  Inorg. Chem. 2003, 42, 2489-2494.

(M148) The Organometallic Active Site of [Fe]Hydrogenase: Models and Entatic States, Marcetta Y. Darensbourg, Erica J. Lyon, Xuan Zhao, Irene P. Georgakaki, Proceedings of the National Academy of Science 2003, 100, 3683-3688.

(M147) The Activation of Alkenes and H₂ by [Fe]-H₂ase Model Complexes, Xuan Zhao, Chao-Yi Chiang, Matthew L. Miller, Marilyn V. Rampersad, Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2003, 125, 518-524.

(M146) X-ray Structure of [Nb(h⁵-C₅H₅)₂(SCH₂CH₂CH₂S].  ECP Quantum Chemistry of Niobium Five and Six Metallacycle Complexes, Carla V.R. de Moura, Rosalice M. Silva, Amary Cesar, Marcetta Y. Darensbourg, Joseph Reibenspies, Polyhedron, 2002, 21, 2227-2235.

(M145) Catalysis of H₂/D₂ Scrambling and Other H/D Exchange Processes by [Fe]-Hydrogenase Model Complexes, Xuan Zhao, Irene P. Georgakaki, Matthew L. Miller, Rosario Mejia-Rodriguez, Chao-Yi Chiang, M. Y. Darensbourg, Inorg. Chem., 2002, 41, 3917-3928.

(M144) Oxidative Addition of Phosphine Tethered Thiols to Iron Carbonyl: Binuclear Phosphinothiolate Complexes, (m-SCH₂CH₂PPh₂)₂Fe₂(CO)₄ and Hydride Derivatives, Xuan Zhao, Yui-May Hsiao, Chia-Huei Lai, Joseph H. Reibenspies and Marcetta Y. Darensbourg, Inorg. Chem. 2002, 41, 699-708.

(M143) Unique Reactivity of a Tetradentate N₂S₂ Complex of Nickel: Intermediates in the Production of Sulfur Oxygenates Vincent E. Kaasjager, Elisabeth Bouwman, S. Gorter, Jan Reedijk, Craig A. Grapperhaus, Joseph H. Reibenspies, Jason J. Smee, Marcetta Y. Darensbourg, Anges Derecskei-Kovacs, Lisa M. Thomson Inorg. Chem. 2002, 41, 1837-1844.

(M142) H/D Exchange Reactions in Dinuclear Iron Thiolates as Activity Assay Models of Fe-H₂ase, Xuan Zhao, Irene P. Georgakaki, Matthew L. Miller, Jason C. Yarbrough, and Marcetta Y. Darensbourg, J. Am. Chem. Soc. 2001, 123, 9710-9711.

(M141) Bite-Angle Influences on N₂S₂Ni Complexes, Jason J. Smee, Matthew L. Miller, Craig A. Grapperhaus, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Inorg. Chem. 2001, 40, 3601-3605.

(M140) Coordination Sphere Flexibility of Active Site Models for Fe-only Hydrogenase: Studies in Intra- and Intermolecular Diatomic Ligand Exchange, Erica J. Lyon, Irene P. Georgakaki, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, JACS, 2001, 123, 3268-3278.

(M139) The Bio-organometallic Chemistry of Active Site Iron in Hydrogenase Marcetta Y. Darensbourg, Jason J. Smee, and Erica Lyon, Coordination Chem. Rev. 2000, 206-207, 533-561.

(M138) Heterobimetallics of Nickel-Iron Dinitrosyl: Electronic Control by Chelate and Diatomic Ligands, Wen-Feng Liaw, Chao-Yi Chiang, Gene-Hsiang Lee,   Shie-Ming Peng, Chia-Huei Lai and Marcetta Y. Darensbourg, Inorg. Chem., 2000, 39, 480-484

(M137) Correlation of Electrochemistry, Nucleophilicity and Density Functional Calculations of the cis-Dithiolate (bme*-daco)Ni, John. A. Bellefeuille, Craig A. Grapperhaus, Agnes Derecskei-Kovacs, Joseph H. Reibenspies,  and Marcetta Y. Darensbourg, Inorg. Chem. Acta  Inorg., 2000, 300-302, 73-81.

(M136) Nickel Mediated Sulfur-Selenium and Sulfur-Sulfur Bond Formations, Chia-Huei Lai, Joseph H. Reibenspies,  and Marcetta Y. Darensbourg*, Chem. Commun.,  1999, 2473-2474.

(M135) Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-only Hydrogenase.  Erica J. Lyon,  Irene P. Georgakaki, Joseph H. Reibenspies and Marcetta Y. Darensbourg, Angew. Chem. 1999, 38, 3178-3180.

(M134) Synthesis and Dimer Cleavage Reactions of the N₂S Thiolate Bridged Dimer [(mmp-dach)₂Ni₂]Cl₂  Craig A. Grapperhaus, John. A. Bellefeuille, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Inorg. Chem. 1999, 38, 3698-3703.

(M133) Models for Terminal Ni(s-Cysteine) modification in [NiFe]Hydrogenases by Iodoacetamide and Iodoacetate, J. J. Smee, D. C. Goodman, J. H. Reibenspies, M. Y. Darensbourg, Eur. J. Inorg. Chem., 1999, 539-546.

(M132) Sulfur Site Iodine Adduct of a Nickel Thiolate Complex, E. J. Lyon, G. Musie, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem. 1998, 37, 6942.

(M131) Alkylation Induced O-Atom Rearrangement in Nickel S-Oxygenates, J. A. Bellefeuille, C. A. Grapperhaus, R. M. Buonomo, J. H. Reibenspies, and M. Y. Darensbourg, Organometallics, 1998, 17, 4813.

(M130) Responses of the Fe(CN)₂(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase, C-H. Lai, W-Z. Lee, M. L. Miller, J. H. Reibenspies, D. J. Darensbourg, and M. Y. Darensbourg, J. Am. Chem. Soc., 1998, 120, 10103.

(M129) Methylation of Tethered and Securely Coordinated Thiolates in [bme-daco)Zn]₂ and [bme-daco)Cd]₂ as a Model of Zinc Sulfur-Methylation Proteins, C. A. Grapperhaus, T. Tuntulani, J. H. Reibenspies, and M. Y. Darensbourg, Inorganic Chemistry, 1998, 37, 4052.

(M128) Oxygen Capture by Sulfur in Nickel Thiolates, C. A. Grapperhaus and M. Y. Darensbourg, Accounts of Chemical Research, 1998, 31, 451.

(M127) Penta-Coordinate -µOxo-diiron(III) Thiolate Complexes and Dimeric Iron(II) Thiolate Precursors, Ghezai Musie, Chia-Huei Lai, Joseph H. Reibenspies and Marcetta Y. Darensbourg Inorganic Chemistry, 1998, 37, 4086.

(M126) Synthesis, Structures, and Electrochemical Properties of Nickel(II) Complexes of Macrocyclic N₂S₂ Aminothioethers, Ghezai Musie, Joseph H. Reibenspies and Marcetta Y. Darensbourg,  Inorganic Chemistry, 1998, 37, 302, .

(M125) Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase, Donald J. Darensbourg,  Joseph  H. Reibenspies, Chia-Huei Lai, Way-Zen Lee, and Marcetta Y. Darensbourg,  J. Am. Chem. Soc., 1997, 119 7181.

(M124) 1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives, And [N,N'-Bis(2-Mercapto-ethyl)-1,5-Diazacyclooctanato]Nickel(II), Daniel K. Mills, Ivan Font, Patrick J. Farmer, Yui-May Hsiao, Thawatchai Tuntulani, Rizalia M. Buonomo, Dawn C. Goodman, Ghezai Musie, Craig A. Grapperhaus, Michael J. Maguire, Chia-Huei Lai, Michelle L. Hatley, Jason J. Smee, John A. Bellefeuille, and Marcetta Y. Darensbourg, in press, Inorganic Syntheses, 1998, Volume 32, 89.

(M123) A New Macrocyclic N₃S₂ Ligand and its Nickel(II), Cobalt(II), ¹⁰³Rhodium(III) and ¹⁰⁵Rhodium(III) Complexes, D.C. Goodman, J.H. Reibenspies, N. Goswami, S. Jurisson, and M.Y. Darensbourg, J. Am. Chem. Soc., 1997, 119, 4955.

(M122) Singlet Oxygen and the Production of Sulfur-Oxygenates of Nickel(II) and Palladium(II) Thiolates,  C. A. Grapperhaus, M. J. Maguire, T. Tuntulani, M. Y. Darensbourg, Inorg. Chem , 1997, 36, 1860-1866.

(M121) Thiolate Bridged Nickel-Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls, C.-H. Lai, J. H. Reibenspies, and M. Y. Darensbourg, Angew, Chem., Int. Ed. Engl., 1996, 35, 2390.

(M120) Light Induced Sulfur-Dealkylation of Phosphino-Thioether Nickel(0) Complexes, J. S. Kim, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chemica Acta, 1996, 250, 283.

(M119) A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand, D. C. Goodman, P. J. Farmer, M. Y. Darensbourg, and J. H. Reibenspies, Inorg. Chem., 1996, 35, 4989.

(M118) Characteristics of Nickel(0), Nickel(I) and Nickel(II) in Phosphino-Thioether Complexes: Molecular Structure and S-dealkylation of (Ph₂P(o-C₆H₄)SCH₃)₂Ni⁰, J. S. Kim, J. H. Reibenspies, and M. Y. Darensbourg, J. Am. chem. Soc., 1996, 118, 4115.

(M117) Polydentate N₂S₂O and N₂S₂O₂ Ligands as Alcoholic Derivatives of N,N’-bis(mercaptoethyl)1,5-diazacyclooctane nickel(II) and N,N'-bis(2-mercapto-2-methylpropane)1,5- diazacyclooctane Nickel(II), D. C. Goodman, R. M. Buonomo, P. J. Farmer, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem., 1996, 35, 4029.

(M116) The Influence of sulfur Metalation on the Accessibility of the Ni^II/I Couple in [N,N'-Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]Nickel(II): Insight into the Redox Properties of {NiFe}-Hydrogenses, G. Musie, P. J. Farmer, T. Tuntulani, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem., 1996, 35, 2176.

(M115) A Template Effect for O₂Addition Across cis-Sulfur in Nickel Dithiolates, C. A. Grapperhaus, M. Y. Darensbourg, L. W. Sumner, and D. H. Russell, J. Am. Chem. Soc., 1996, 118, 1791.

(M114) Structural and Electrochemical Comparison of Ni^II in an N₂S₂ Plane with Two, One, and No Axial Ligands: Isolation and Characterization of a Five-Coordinate Nickel(II) Complex, R. M. Buonomo, J. H. Reibenspies, and M. Y. Darensbourg, Chem. Ber., 1996, 129, 779.

(M113) Crystal Structures of Tetrakis [m³-methoxo-2,4-pentanedionatomethanol-nickel(II)], C₂₈H₅₆Ni₄O₁₆, M. Y. Darensbourg, R. M. Buonomo, and J. H. Reibenspies, Zeitschrift fur Kristallographie, 1995, 210, 469.

(M112) Metallo Sulfoxides and Sulfones: Sulfur Oxygenates of [1,5-Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]Palladium(II), T. Tuntulani, G. Musie, J. H. Reibenspies, and M. Y. Darensbourg, Inorg. Chem., 1995, 34, 6279.

(M111) Structure/Function Relationships in Ligand-Based SO₂/O₂ Conversion to Sulfate as Promoted by Nickel and Palladium Thiolates, M.Y. Darensbourg, T. Tuntulani, and J.H. Reibenspies, Inorg. Chem. 1995, 34, 6287.

(M110) Crystal Structure of Methyl(1s,3aR,4S,9aR)-1-(acetoxy)methyl-2-N-benzoxycarbonyl-(1,3a,4,4a,5,6,7,8,9a)nonahydrobenzo[f]-isoindol-3-one-4-carbonxylate, C₂₅H₂₉NO₇, M. Darensbourg, D.C. Goodman, and J.H. Reibenspies, Zeitschrift fur Kristallographie, 1995, 210, 465.

(M109) A Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in N,N'-bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanenickel(II), R. M. Buonomo, I. Font, M. J. Maguire, J. H. Reibenspies, T. Tuntulani, and M. Y. Darensbourg, J. Am. Chem. Soc., 1995, 117, 963.

(M108) Synthetic Strategies for N₂S₂O-Penta-Coordinate Nickel(II) Based on the Highly Sterically Encumbered Ligand N,N'-Bis(2-Mercapto-2-Methylpropane)-1,5-Diazacyclooctane, Marcetta Y. Darensbourg, Ivan Font, Magdalena Pala, and Joseph H. Reibenspies, J. Coord. Chem., 1994, 32, 39.

(M107) Reduction-Promoted Sulfur-Oxygen Bond Cleavage in a Nickel Sulfenate as a Model for the Activation of [NiFe] Hydrogenase, Patrick J. Farmer, Jean-Noël Verpeaux, Christian Amatore, Marcetta Y. Darensbourg, and Ghezai Musie, J. Am. Chem. Soc., 1994, 116, 9355.

(M106) Sulfur Site Adducts of Sulfur Dioxide in Nickel-bound Thiolates and Their Conversion to Sulfate, Marcetta Y. Darensbourg, Thawatchai Tuntulani, and Joseph H. Reibenspies, Inorg. Chem., 1994, 33, 611.

(M105) Synthesis and Characterization of a Stable Iron(II) Hydride-Thiolate Complex:  (PhS)Fe(H)(CO)₂(P(OPh)₃)₂, Sheryl A. Wander, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Inorg. Chem., 1994, 33, 1421.

(M104) Variable Oxygenation Levels of Sulfur in Sterically Hindered Thiolates: Molecular Structure of N-(2-mercapto,2-methylpropyl), N'-(2'-sulfenatomethylpropyl)-1,5-diazacyclooctanenickel(II), Ivan Font, Rizalia Buonomo, Joseph H. Reibenspies and Marcetta Y. Darensbourg, Inorg. Chem., 1993, 32, 5897.

(M103) Divergent Pathways for the Reaction of Dioxygen and Nickel cis-Dithiolates: An Isotopomeric Analysis, Patrick J. Farmer, Touradj Solouki, Takako Soma, David H. Russell and Marcetta Y. Darensbourg, Inog. Chem., 1993, 32, 4171.

(M102) Mechanism of Dioxygen Addition to Nickel-Bound Thiolates, M. Y. Darensbourg, P. J. Farmer, T. Soma, D. H. Russell, T. Solouki, and J. H. Reibenspies, Proceedings of the 5th International Symposium on The Activation of Dioxygen and Homogeneous Catalytic Oxidation, 1993, D. H. R. Barton, A. E. Martell, D. T. Sawyer, Plenum Press, New York, pp. 209-223.

(M101) The Hydride Transfer Ability of a Neutral Hydride CP₂Nb(H)CO, Rosalice Mendonca Silva and Marcetta Y. Darensbourg, J. Brazilian Chem. Soc., 3, 55 (1992). 1992

(M100) X-ray Structure and Solution Characterization of Ni(Ph 2 PCH 2 CH 2 S) 2 -Mo(CO) 4 , Stephen S. Chojnacki, Yui-May Hsiao, Marcetta Y. Darensbourg, and Joseph H. Reibenspies, Inorg. Chem ., 1993 , 32 , 3573-3576.

(M99) Effects of Sulfur Site Modification on the Redox Potentials of Derivatives of N,N'-Bis[2-Mercaptoethyl]-1,5-Diazacyclooctanenickel(II), Patrick J. Farmer, Joseph H. Reibenspies, Paul A. Lindahl, and Marcetta Y. Darensbourg, J. Am. Chem. Soc., 1993, 115, 4665.

(M98) Organometallic Chemistry of Sulfur/Phosphorus Donor Ligand Complexes of Nickel(II) and Nickel(0), Yui-May Hsiao, Stephen S. Chojnacki, Pamela Hinton, Joseph H. Reibenspies, and Marcetta Y. Darensbourg, Organomet., 1993, 12, 870.

(M97) Axial Ligation  of Diazacyclooctanenickel and -Zinc Complexes,Dawn C. Goodman, Thawatchai Tuntulani, Patrick J. Farmer, Marcetta Y. Darensbourg, and Joseph H. Reibenspies, Angew. Chem. Internat. Ed., 1993, 105, 72.

(M96) Variable Coordination Modes of NI^II with Macrocyclic Ligands-Based on Bismercaptoethyldiazacyclooctane, BME-DACO.  M.Y. Darensbourg, Ivan Font, Dan Mills, Magdalena Pala, and Joseph Reibenspies, Inorg. Chem., 1992, 31, 4965.

(M95) Synthesis and Characterization of the Electron-Rich Iron Hydride, HFe(CO)₂[P(OPh)₃]₂^- and Its Ligand Based Redox Substitution with Thiolates, Marcetta Y. Darensbourg, Sheryl A. Wander, and Joseph H. Reibenspies, Organometallics, 1992, 11, 3185.

(M94) Preparations and Structures of a Zinc(II) Dimer and Zinc(II)/Nickel(II) Pentanuclear derivatives of N,N'-Bix(Mercaptoethyl)-1,5-Diazacyclooctane: [(BME-DACO)Zn]₂ and {[(BME-DACO)Ni]₃[ZnCl]₂}{BF₄}₂, Thawatchai Tuntulani, Joseph H. Reibenspies, Patrick J. Farmer, and Marcetta Y. Darensbourg, Inorg. Chem., 1992, 31, 3497.

(M93) The Complexation of Organotin Halides with Ambidentate, S, N, and O Donor Ligands, Gerimario F. de Sousa, Carlos A.L. Filgueiras, M.Y. Darensbourg, and Joseph H. Reibenspies, Inorganic Chemistry, 1992, 31, 3044.

(M92) Isotopic Labelling Investigation of the Oxygenation of Ni-Bound Thiolates by Molecular Oxygen, Patrick J. Farmer, Touradj Solouki, Daniel K. Mills, Takako Soma, David H. Russell, Joseph H. Reibenspies and Marcetta Y. Darensbourg, J. Am. Chem. Soc., 1992, 114, 4601.

(M91) Stereochemical Nonrigidity in Heterobimetallic Complexes Containing the Bent Metallocene-Thilate Fragment, M. Y. Darensbourg, Magdalena Pala, Stephen A. Houliston, K. Paul Kidwell, David Spencer, Stephen S. Chojnacki, and Joseph H. Reibenspies, Inorg. Chem., 1992, 31, 1487.

(M90) Applications of the N₂S₂ Ligand, N, N'-Bismercaptoethyl-1,5-Diazacyclooctane, Towards the Formation of Hetero- and Bimetallics: [(BME-DACO)Fe]₂ and [BME-DACO)NiFeCl₂]₂, D. K. Mills, Y-M. Hsiao, P. J. Farmer, E. V. Atnip, J. H. Reibenspies, and M. Y. Darensbourg, Journal of the American Chemical Society, 1991, 113, 1421.

(M89) Direct synthesis of mixed metal sulfide catalysts and their hydrodenitrogenation activity, M. M. Luchsinger, B. Bozkurt, and A. Akgerman, Applied Catalysis, 1991, 68, 229-247.

(M88) Sterically Protected Nickel(II) in a N₂S₂ Donor Environment:  N,N' Bismercapto-1,5-Diazacyclooctane and its Methylated Derivative, M. Y. Darensbourg, D. K. Mills, and J. H. Reibenspies, Inorganic Chemistry, 1990, 29, 4364.

(M87) The Conformations of (h⁵-C₅5)₂Nb(S-p-C₆H₄X)₂ⁿ(n=0, 1): Responsiveness to Para-Substituents on Aryl and to d-Electron Count, M. Y. Darensbourg, C. J.  Bischoff, S. A. Houliston, M. Pala, and J. H. Reibenspies, Journal of the American Chemical Society, 1990, 112, 6905.

(M86) The Synthesis and Molecular Structure of (Ph₃PAu)₂Fe(CO)₃P(OEt)₃: A Triangular Au₂Fe Cluster, L. W. Arndt, C. E. Ash, M. Y. Darensbourg, Y. M. Hsiao, C. M. Kim, J. H. Reibenspies, and K. A. Youngdahl, Journal of Organometallic Chemistry, 1990, 394, 733-741.

(M85) Isolation of Chromium(O) Thiols:  Molecular Structure of (t-BuSH)Cr(CO)₅, M. Y. Darensbourg, E. M. Longridge, V. A. Payne, Joseph H. Reibenspies, C. G. Riordan, J. J. Springs, and J. C. Calabrese, Inorganic Chemistry, 1990, 29, 2721.

(M84) An Electron Paramagnetic Resonance and Electrochemical Study of the Oxidation Chemistry of Mononuclear and Binuclear Chromium Carbonyl Thiolates, J. J.  Springs, C. P. Janzen, M. Y. Darensbourg, J. C. Calabrese, P. J. Krusic, J.-N. Verpeaux, and C. Amatore, J. Am. Chem. Soc., 1990, 112, 5789.

(M83) h³-Allylhydrido(Bisdiphenylphosphinoethane) Molybdenum(II), C. J. Bischoff, J. M. Hanckel, M. M. Ludvig, and M. Y. Darensbourg, Inorganic Syntheses, 1990, Vol. 28.

(M82) Reactions of Anionic Transition Metal Carbonyl Hydrides with Electrophilic Metal Carbonyls:  Nucleophilic Addition (Hydride Transfer) vs. Electron Transfer Mechanisms, M. Y. Darensbourg, C. E. Ash, L. W. Arndt, C. P. Janzen, Y. K. Park and  K. A. Youngdahl, Journal of Organometallic Chemistry, 1990, 383, 191-199.

(M81) Heterobinuclear Noncarbonyl Complexes and Hydride Complexes of Iron-Chromium, Iron Molybdenum, and Iron-Tungsten, L. W. Arndt, C. J. Bischoff, and M. Y. Darensbourg, Inorganic Syntheses, Vol. 26, 1989, Herbert D. Kaesz, Ed., Wiley-Interscience, pp. 335-341.

(M80) Protonation Sites in Thiolato Iron Carbonylates:  Evidence for an Arrested Fe(RS-H) Oxidative Addition, M. Y. Darensbourg, W.-F. Liaw, and C. G. Riordan, J. Am. Chem. Soc., 1989, 111, 8051.

(M79) Addition of Arylonitrile to Anionic Transition Metal Hydrides.  An Ionic Model for Homogeneous Olefin Processes, M. Y. Darensbourg, B. Floris, K. A. Youngdahl, Tetrahedron Letters, 1989, 30, (14), 1781-1784.

(M78) Kinetic Studies of Reactions of Transition Metal Carbonyl Anion with Allyl Halides, Y. K. Park, I. S. Han, T. S. Huh, and M. Y. Darensbourg, Bulletin of the Korean Chemical Society, 1989, 10, (2), 134-137.

(M77) Spectroscopic and Chemical Studies of Nickel(II) Hydrides, M. Y. Darensbourg, M. M. Ludvig, and C. G. Riordan, Inorganic Chemistry, 1989, 28, 1630.

(M76) Structural Studies of (h⁵-C₅H₅)₂Nb(SC₆H₅)₂, [h⁵-C₅H₅)₂Nb(SC₆H₅)₂⁺], and h⁵- C₅H₅)₂Nb (µ-SC₆H₅)₂)Mo(CO)₄⁺],” M. Y. Darensbourg, R. Silva, J. H. Reibenspies, and C. K. Prout, Organometallics, 1989, 8, 1315.

(M75) Thiolate and Thioether Derivatives of Iron(O) Carbonyls, W.-F. Liaw, C. M. Kim, M. Y.  Darensbourg, and A. L. Rheingold, J. Am. Chem. Soc., 1989, 111, 3591.

(M74) EPR Spectrum of the Ion-Pair [Cr(CO)₅^-]₂ in Irradiated Crystals of PPh₄⁺ HCr(CO)₅^-, J. R. Morton, K. F. Preston and M. Y. Darensbourg, Journal of Magnetic Resonance in Chemistry, 1988, 26, 787-792.

(M73) Binuclear Reductive Elimination of Water:  A New Route to the Triphenyltinpenta-carbonyltungsten Anion, Ph₃SnW(CO)₅^-,” M. Y. Darensbourg, W-F. Liaw and J. Reibenspies, Inorganic Chemistry, 1988, 27, 2555.

(M72) Promotion of Migratory Insertion by Transition Metal Lewis Acids. Synthesis, Structure and Reactivity of a Transition Metal Heterobimetallic Carbonyl Alkyl Anion, L. W. Arndt, B. T. Bancroft, M. Y. Darensbourg, C. P. Janzen, C. Kim, K. E. Varner, and K. A. Youngdahl, Organometallics, 1988, 7, 1302.

(M71) Anionic Transition Metal Hydrides, M. Y. Darensbourg and C. E. Ash, Adv. Organomet. Chem., 1987, 27, 1.

(M70) Mechanisms of Group Transfer in Anionic Transition Metal Hydrides and Alkyls, Marcetta Y. Darensbourg, C. E. Ash, S. C. Kao, R. Silva, and J. Springs, Pure and Applied Chemistry, 1988, 60, 131.

(M69) The Reaction of (Cy₃P)₂Ni(H)(CH₃) with Carbon Dioxide.  Formation of an Hydridonickelformate Complex, HNi(O₂CH)(Cy₃P)₂, D. J. Darensbourg, M. Y. Darensbourg, L. Y. Goh, M. M. Ludvig, and P. W.  Wiegreffe, J. Am. Chem. Soc., 1987, 109, 7539.

(M68) The Temperature and Solvent Dependence of Scalar Coupling Constants in trans -HFe (CO)₃PR₃^-, C. E. Ash, M. Y. Darensbourg and M. B. Hall, J. Am. Chem. Soc., 1987, 109, 4173.

(M67) Competing Nucleophilic Displacement and Radical Chain Reduction in Reaction of Transition Metal Hydride Anions with Alkyl Bromides, C. E. Ash, P. W. Hurd, M. Y. Darensbourg, M. Newcomb, J. Am. Chem. Soc., 1987, 109, 3313.

(M66) Properties and X-Ray Structure of PPN⁺ cis-HFe (CO)₃P(OPh)₃^-:  An Unexpected Structural Isomer, C. E. Ash, C. M. Kim, M. Y. Darensbourg, and A. L. Rheingold, Inorg. Chem. 1987, 26, 1357.

(M65) Anionic Group 6 Hydrides and Carboxylates as Homogeneous Catalysts for Reduction of Aldehydes and Ketones, P. A. Tooley, C. Ovalles, S. C. Kao , D. J. Darensbourg, and M. Y. Darensbourg, J. Am. Chem. Soc., 1986, 108, 5465.

(M64) The Deprotonation of [HMo(CO)₂(P P)₂]BF₄ Complexes:  Hard Anions as Proton Carriers, M. Y. Darensbourg and M. M. Ludvig, Inorg. Chem., 1986, 25, 2894.

(M63) Intramolecular Ligand  Rearrangements in Anionic Group 6 Metal Pentacarbonyl Hydride Derivatives, D. J. Darensbourg, M. Y. Darensbourg, R. L. Gray, D. Simmons, and L. W. Arndt, Inorg. Chem., 1986, 25, 880.

(M62) Metal Donor ^__>Metal Acceptor Complexes:  Fe(CO)₄⁼, HFe(CO)₄^-, trans-HFe(CO)₃P^- as Anionic Ligands to M(CO)₅˚ M = Cr, W,” L. W. Arndt, M. Y. Darensbourg, T. Delord, and B. T. Bancroft, J. Am. Chem. Soc., 1986, 108, 2617.

(M61) Solution and Solid State Structures of Salts of trans-HFe(CO)₃PR₃^- Including a Study of Alkali Cation Contact Ion Pairing, C. E. Ash, T. Delord, D. Simmons, and M. Y. Darensbourg, Organometallics, 1986, 5, 17.

(M60) Comparisons of the Heterobimetallic and Heterotrimetallic Anions:  HFeW(CO)₉^- and Ph₃PAuFeW(CO)₉^-, L. W. Arndt, M. Y. Darensbourg, J. P. Fackler, R. J. Lusk, D. O. Marler, and K. A. Youngdahl, J. Am. Chem. Soc., 1985, 107, 7281.

(M59) Ion Pairing Effects on Transition Metal Carbonyl Anions, M. Y. Darensbourg, Progress in Inorganic Chemistry, 1985, 33, 221.

(M58) Anionic Group 6 Transition Metal Carbonyl Hydrides as Reducing Agents.  Ketones, Aldehydes, and Epoxides, P. L. Gaus, S. C. Kao, K. Youngdahl, and M. Y. Darensbourg, J. Am. Chem. Soc., 1985, 107, 2428.

(M57) Olefin Isomerization Catalysis by Heterobimetallic Hydrides, HFeM(CO)₈L^- (M = Cr, Mo, W;  L = CO, PR₃), P. A. Tooley, L. W. Arndt, and M. Y. Darensbourg, J. Am. Chem. Soc., 1985, 107, 2422.

(M56) Relative Reactivity and Mechanistic Studies of the Hydride Transfer Reagents:  HM (CO)₄L^- (M = Cr, W:  L = CO, PR₃), S. C. Kao, C. T. Spillett, C. Ash, R. Lusk, Y. K. Park, and M. Y. Darensbourg, Organometallics, 1985, 4, 83.

(M55) Selective Reduction of Acyl Chlorides to Aldehydes by Anionic 6b Transition Metal Hydrides, S. C. Kao, P. L. Gaus, Kay Youngdahl and M. Y. Darensbourg,  Organometallics, 1984, 3, 1601.

(M54) Hydrogen-Deuterium Exchange of the Anionic Group VIB Transition Metal Hydrides.  Convenient, in situ Deuterium Transfer Reagents, P. L. Gaus, S. C. Kao, M. Y. Darensbourg, and L. W. Arndt, J. Am. Chem. Soc., 1984, 106, 4752.

(M53) The Nature of Alkali Cation Contact Ion Pairs with Anionic Transition Metal Hydrides:  HM(CO)₄ L^-(M = Cr, W;  L = CO, PR₃), S. C. Kao, M. Y. Darensbourg, and W. Schenk, Organometallics, 1984, 3, 871.

(M52) Relative Reactivities of Anionic Transition Metal Hydrides: Reduction of Alkyl Halides, S. C. Kao and M. Y. Darensbourg, Organometallics, 1984, 3, 646.

(M51) Chemistry of New Heteronuclear Bridging Hydrides:  µ-H[Fe(CO)₄ M(CO)₅]^-(M = Cr, Mo, W), L. W. Arndt, T. Delord, and M. Y. Darensbourg, J. Am. Chem. Soc., 1984, 106, 456.

(M50) Binuclear Molybdenum Carbonyls Bridged Both by Hydride and Bidentate Phosphine Ligands.  Crystal and Molecular Structures of Salts of (µ-H) -(µ-Ph₂P (CH₂)_nPPh₂)Mo₂(CO)₈^- (n = 1, 4) and Their Reactions With Acids, M. Y. Darensbourg, R. El Mehdawi, T. J. Delord, F. R. Fronczek, and S. F. Watkins, J. Am. Chem. Soc., 1984, 106, 2583.

(M49) Mononuclear Pentacarbonyl Hydrides of Chromium, Molybdenum, and Tungsten, Marcetta Y. Darensbourg and Sydney Slater, Inorganic Syntheses, 1983, Volume 22, S. L. Holt, Jr. , Ed., Wiley-Interscience, pp. 181-187.

(M48) Anion-Assisted Transfer of a Sterically Constrained Proton:  Molecular Structure of HMo(CO)₂ (Ph₂PCH₂PPh₂)₂⁺AlCl₄^-, J. M. Hanckel and M. Y. Darensbourg, J. Am. Chem. Soc., 1983, 105, 6979.

(M47) Structural Characterizations of Salts of HCr(CO)₅^- and  (µ-H)₂BH₂Cr(CO)₄^- and Studies of their Interconversions, M. Y. Darensbourg, M. Marks, R. Bau, R. R. Burch, Jr., J. C. Deaton, and S. Slater, J. Am. Chem. Soc., 1982, 104, 6961.

(M46) The Chemistry of Hydrido-carbonyl VIB Metallates Substituted by P-Donor Ligands, Sydney G. Slater, R. Lusk, B. Schumann, and M. Y. Darensbourg, Organometallics, 1982, 1, 1662.

(M45) Interactions of CpM' (CO)₃^- (M" = Cr, Mo, W) With Cations:  Effects on CO Exchange and RX Addition Reactions, M. Y. Darensbourg, P. Jimenez, J. R. Sackett, J. M. Hanckel, and R. L. Kump, J. Am. Chem. Soc., 1982, 104, 1521.

(M44) Site Specific Ion-Pairing of Mono-Substituted Vanadium Carbonylates, LV(CO)₅^-, M. Y. Darensbourg and J. M. Hanckel, Organometallics, 1982, 1, 82.

(M43) Chromium, Molybdenum, and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, J. D. Atwood, M. Y. Darensbourg, and D. J. Darensbourg, J. Organomet. Chem., 1981, 223, 49.

(M42) Alternate Synthetic Routes to the Pentacarbonylhydrides of Cr, Mo, and W, M. Y. Darensbourg and S. Slater, J. Am. Chem. Soc., 1981, 103, 5914.

(M41) The Use of Ion-Pairing Phenomena in the Assignment of n(CO) IR Bands of PV (CO)₅^-, M. Y. Darensbourg and J. M. Hanckel,  J. Organomet Chem., 1981, 217, C9-C13.

(M40) The Facile Reduction of Carbon Dioxide by Anionic Group 6 Metal Hydrides.  Chemistry Relevant to Catalysis of the Water-Gas Shift  Reaction, D. J. Darensbourg, A. Rokicki, and M. Y. Darensbourg, J. Am. Chem. Soc., 1981, 103, 3223.

(M39) The HCr(CO)₅^- Anion, M. Y. Darensbourg and J. C. Deaton, Inorg. Chem., 1981, 20, 1644.

(M38) Studies Using (n-Bu)₃P=O as a Carbon Monoxide Labilizing Ligand in the Synthesis of Metal Carbonyl Complexes Highly Enriched in ¹³CO, D. J. Daresnbourg, M. Y. Darensbourg, and N. Walker, Inorg. Chem., 1981, 20, 1918.

(M37) A Reactivity Study of Addition of Organic Halides to CpMo(CO)₃^-: Counterion and RX Dependences, M. Y. Darensbourg, P. Jimenez, and J. R. Sackett, J. Organomet. Chem., 1980, 202, C68.

(M36) Synthesis Metal Carbonyl Complexes Highly Enriched in Carbon-13: Utilization of the CO-Labilizing Ability of (n-Bu)₃P=O, D. J. Darensbourg, N. Walker, and M. Y. Darensbourg, J. Am. Chem. Soc., 1980, 102, 1213.

(M35) The µ-H[Mo(CO)₃ (PMePh₃)]₃^– Anion:  An example of Phosphine Enhancement of Metal-Metal Interaction, M. Y. Darensbourg, J. L. Atwood, W. E. Hunter, and R. R. Burch, Jr., J. Am. Chem. Soc., 1980, 102, 3290.

(M34) The Reaction of Iron Pentacarbonyl with Oxygen-18 Enriched Hydroxide.  Decarboxylation vs. Oxygen Exchange in the [Fe(COOH)] Intermediate, D. J. Darensbourg, M. Y. Darensbourg, N. Walker, J. A. Froelich, and H. L. C. Barros,  Inorg. Chem., 1979, 18, 1401.

(M33) Cation Interaction with Transition Metal Carbonylates and Cyanocarbonylates, M. Y. Darensbourg and H. L. C. Barros, Inorg. Chem., 1979, 11, 3286.

(M32) Structural and Chemical Characterization of a Phosphine Bound M-H-M Bridged Carbonylate: Et₄N⁺(µ-H)[Mo₂(CO)₉PPh₃]^-, M. Y. Darensbourg, J. L. Atwood, R. R. Burch, Jr., W. E. Hunter, and N. Walker, J. Am. Chem. Soc., 1979, 101, 2631.

(M31) Arene-Transition Metal Chemistry.  2.  Hydrogenation of Metal-Arene and Allylmetal-Arene Complexes, E. L. Muetterties, H. Schaeffer, R. I. Mink, M. Y. Darensbourg, M. Millar, T. Groshens, and K. J. Klabunde, Inorg. Chem., 1979, 18, 883.

(M30) Oxygen-Exchange and Ligand Substitution Reactions in Cr(CO)₆ and  µ-H[Cr(CO)₅]₂^- and the Water-Gas  Shift Reaction, D. J. Darensbourg, M. Y. Darensbourg, R. R. Burch, Jr., J. A. Froelich, and M. J. Incorvia, Adv. Chem. Ser., 1979, 173, 106.

(M29) The Preparation of a Stereospecifically ¹³CO Labelled µ-H[Mo(CO)₅]₂ Species and an Analysis of its CO Stretching Vibrational Modes, D. J. Darensbourg, R. R. Burch, Jr., and M. Y. Darensbourg, Inorg. Chem., 1978, 17, 2677.

(M28) Solution Structure and Reactivity of Hydridoirontetracarbonyl Anion, [HFe (CO)₄], M. Y. Darensbourg, D. J. Darensbourg, and H. L. C. Barros, Inorg. Chem., 1978, 17, 2677.

(M27) Ligand  Lability Studies in Bridging Hydride Complexes of Groups 6b Metal Carbonylates, M. Y. Darensbourg, N. Walker, and R. R. Burch, Jr., Inorg. Chem., 1978, 17, 52.

(M26) Arene-Transition Metal Complexes. 1. Site Exchange and  Chemical Characteristics of h⁶-C₆(CH₃)₆Ru-h⁴-C₆(CH)₆, M. Y. Darensbourg, E. L. Muetterties, J. Am. Chem. Soc., 1978, 100, 7425.

(M25) The Extent of Association of the Bis-triphenylphosphineiminium Cation with Organometallic Anions in THF Solution, M. Y. Darensbourg, H. Barros, and C. Borman, J. Am. Chem. Soc., 1977, 99, 1647.

(M24) Conductivity Studies of Ion-Pairing in Transition Metal Organics,  M. Y. Darensbourg and C. Borman, Inorg. Chem., 1976, 15, 3121.

(M23) Carbonyl Ligand Lability in the µ-H[Cr(CO)₅]₂ Anion, M. Y. Darensbourg and N. Walker, J. Organomet. Chem., 1976, 117, C68.

(M22) Chromium, Molybdenum, and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, D. J. Darensbourg and M. Y. Darensbourg, J. Organomet. Chem., 1976, 115, 221.

(M21) Infrared, Conductance and Kinetic Evidence for Alkali Metal Ion Interaction with Derivatives of Manganese Carbonylates, M. Y. Darensbourg, D. J. Darensbourg, D. Burns, and D. A. Drew, J. Am. Chem. Soc., 1976, 98, 3127.

(M20) Molecular Structure and Spectral Properties of Phosphatriazaadamantane- molybdenum Pentacarbonyl Complex, J. R. DeLerno, L. M. Trefonas, M. Y. Darensbourg, and R. J. Majeste, Inorg. Chem., 1976, 15, 816.

(M19) Synthesis and Spectral Properties of Metal Carbonyl Derivatives of the Tetrabasic, Nonchelating Phosphatriazaadamantane Ligand, M. Y. Darensbourg, and D. Daigle, Inorg. Chem., 1975, 14, 1217.

(M18) The Synthesis, Spectral Properties  and Reactions of Manganese Pentacarbonyl Phosphine and Phosphite Cation Derivatives and Related Complexes, D. Drew, D. J. Darensbourg, and M. Y. Darensbourg, Inorg. Chem., 1975, 14, 1579.

(M17) The Stereochemical Course of Reactions Leading to Formation of Mono-Ligated (Phenylacetyl) manganesetetracarbonyl Compounds, D. Drew, M. Y. Darensbourg, and D. J. Darensbourg, J. Organometal. Chem., 1975, 85, 73.

(M16) Solvent Effects on the Solution Structure and Chemical Properties of Lithium and Magnesium Salts of trans-Phenylacyltricarbonyl(triphenylphosphine) iron (-I), M. Y. Darensbourg and D. Burns, Inorg. Chem., 1974, 13, 2970.

(M15) The Synthesis and Spectral Properties of Manganese Pentacarbonyl Phosphine and Phosphite Cation Derivatives and Related Complexes, D. J. Darensbourg, M. Y. Darensbourg, D. Drew, and H. L. Conder, J. Organometal. Chem., 1974, 73, C33.

(M14) Reactions of Phenylacetylmanganesepentacarbonyl with Phosphine and Phosphite Ligands, M. Y. Darensbourg, D. J. Darensbourg, and D. Drew, J. Organometal. Chem., 1974, 73, C25.

(M13) The Synthesis of Group V Substituted Derivatives of Iron Pentacarbonyl in High Yield, H. L. Conder and M. Y. Darensbourg, J. Organometal. Chem., 1974, 67, 93.

(M12) Alkylation and Substitution Reactions of Metal Carbonyl Acylate and Carbene Complexes, H. L. Conder and M. Y. Darensbourg, Inorg. Chem., 1974, 13, 506.

(M11) Chromium, Molybdenum and Tungsten, ANNUAL SURVEYS OF ORGANOMETALLIC CHEMISTRY, D. J. Darensbourg and M. Y. Darensbourg, J. Organometal. Chem., 1974, 83, 309.

(M10) Infrared Spectroscopy and Its Uses in Determining Stereochemistry in Metal Complexes. An Application of Group Theory. Part II. The Determination of Symmetry Coordinates, D. J. Darensbourg and M. Y. Darensbourg, J. Chem. Educ., 1974, 51, 787.

(M9) Electronic and Steric Control of Reactions of Benzylmagnesium Chloride with Substituted Metal Carbonyls, M. Y. Darensbourg, H. L. Conder, D. J. Darensbourg, and C. Hasday, J. Amer. Chem. Soc., 1973, 95, 5919.

(M8) Photochemical Substitution Reactions of Substituted Group VI Metal Carbonyls, G. Schwenzer, M. Y. Darensbourg, and D. J. Darensbourg, Inorg. Chem., 1972, 11, 1967.

(M7) Reactions of Organolithium and Grignard Reagents with the Cyclopentadienyliron Tricarbonyl Cation and its Derivatives, M. Y. Darensbourg, J. Organometal. Chem., 1972, 38, 133.

(M6) The Nature of the Intermediate Procreated in Substitution Reactions of Group VI Metal Carbonyls, D. J. Darensbourg, M. Y. Darensbourg, and R. J. Dennenberg, J. Amer. Chem. Soc., 1971, 93, 2807.

(M5) Reactions of Transition Metal Carbonyls with Nucleophilic Reagents: Reactivity and Bonding, D. J. Darensbourg and M. Y. Darensbourg, Inorg. Chim. Acta, 1971, 5, 247.

(M4) Reactions of Transition Metal Carbonyls with Organolithium Compounds. II. Prediction of Nucleophilic Attack at Carbon and Resulting Stereochemistry, D. J. Darensbourg and M. Y. Darensbourg, Inorg.Chem., 1970, 9, 1691.

(M3) Spectroscopic Studies of Some Carbene Pentacarbonyl Complexes of Chromium(O) and Tungsten(O), M. Y. Darensbourg and D. J. Darensbourg, Inorg. Chem., 1970, 9, 32.

(M2) Infrared Spectroscopy and Its Uses in Determining Stereochemistry in Metal Complexes.  An Application of Group Theory, D. J. Darensbourg and M. Y. Darensbourg, J. Chem. Educ., 1970, 47, 33.

(M1) Cross-Association of t-Butyllithium.  Kinetics of t-Butyllithium Dissociation,” M. Y. Darensbourg, B. Y. Kimura, G. E. Hartwell, and T. L. Brown, J. Amer. Chem. Soc., 1970, 92, 1236.