The Dunbar Research Group

Our Publications

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• 2009-Present
  • Supermicroporous silica-based SiO2–Al2O3–NiO materials: Solid-state NMR, NMR relaxation and magnetic susceptibility. Vladimir I. Bakhmutov, Boris G. Shpeizer, Andrey V. Prosvirin, Kim R. Dunbar, Abraham Clearfield. Microporous and Mesoporous Materials 118 (2009) 78–86
  • Synthesis and structure of charge transfer salts of tetrathiafulvalene (TTF) and tetramethyl-TTF with 2,4,7-trinitro and 2,4,5,7-tetranitro-9-fluorenone. EricW. Reinheimer, J.R. Galán-Mascarós, Kim R. Dunbar. Synthetic Metals 159 (2009) 45–51
  • Cyanide-Bridged Complexes of Transition Metals: A Molecular Magnetism Perspective. MICHAEL SHATRUK, CAROLINA AVENDANO, AND KIM R. DUNBAR. Progress in Inorganic Chemistry, Volume 56
  • Electric transport properties of Mn12-acetate films measured with self-assembling tunnelling junction. Lianxi Ma, Chi Chen, Glenn Agnolet, Jiacai Nie, Hanhua Zhao and Kim R Dunbar. J. Phys. D: Appl. Phys. 42 (2009) 095104 (8pp)
  • Preface for the Forum on Molecular Magnetism: The Role of Inorganic Chemistry. Eugenio Coronado and Kim R. Dunbar. Inorg. Chem. 2009, 48, 3293-3295
  • Trigonal-Bipyramidal Metal Cyanide Complexes: A Versatile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials. Kristen E. Funck, Matthew G. Hilfiger, Curtis P. Berlinguette, Michael Shatruk, Wolfgang Wernsdorfer, and Kim R. Dunbar. Inorg. Chem. 2009, 48, 3438-3452
  • Redox-Regulated Inhibition of T7 RNA Polymerase via Establishment of Disulfide Linkages by Substituted Dppz Dirhodium(II,II) Complexes. J. Dafhne Aguirre, Helen T. Chifotides, Alfredo M. Angeles-Boza, Abdellatif Chouai, Claudia Turro, and Kim R. Dunbar. Inorg. Chem. 2009, 48, 4435-4444
  • Water-Free Rare Earth-Prussian Blue Type Analogues: Synthesis, Structure, Computational Analysis, and Magnetic Data of {LnIII(DMF)6FeIII(CN)6}¥ (Ln = Rare Earths Excluding Pm). Duane C. Wilson, Shengming Liu, Xuenian Chen, Edward A. Meyers, Xiaoguang Bao, Andrey V. Prosvirin, Kim R. Dunbar, Christopher M. Hadad, and Sheldon G. Shore. Inorg. Chem. 2009, 48, 5725–5735
  • Highly Anisotropic Exchange Interactions in a Trigonal Bipyramidal Cyanide-Bridged NiII 3OsIII 2 Cluster. Andrei V. Palii, Oleg S. Reu, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Matthew Hilfiger, Michael Shatruk, Andrey Prosvirin, and Kim R. Dunbar. J. Phys. Chem. A 2009, 113, 6886–6890
  • Molecules based on M(V) (M= Mo,W) and Ni(II) ions: a new class of trigonal bipyramidal cluster and confirmation of SMM behavior for the pentadecanuclear molecule {NiII[NiII(tmphen)(MeOH)]6[Ni(H2O)3]2[l- CN]30[WV(CN)3]6}. Matthew G. Hilfiger, Hanhua Zhao, Andrey Prosvirin, Wolfgang Wernsdorfer and Kim R. Dunbar. Dalton Transactions, 2009, 5155–5163
  • A Thermally and Hydrolytically Stable Microporous Framework Exhibiting Single-Chain Magnetism: Structure and Properties of [Co2(H0.67bdt)3]·20H2O. Wayne Ouellette, Andrey V. Prosvirin, Kelly Whitenack, Kim R. Dunbar, and Jon Zubieta. Angew. Chem. Int. Ed. 2009, 48, 2140 –2143
  • Live Cell Cytotoxicity Studies: Documentation of the Interactions of Antitumor Active Dirhodium Compounds with Nuclear DNA J. Dafhne Aguirre,† Alfredo M. Angeles-Boza,† Abdellatif Chouai,† Jean-Philippe Pellois,‡ Claudia Turro,§ and Kim R. Dunbar*,†
  • Hydrogen Bonding and Sulfur–Sulfur Interactions in the Crystal Structure of the Radical-Cation Salt (BPDT-TTF)2[W6O19] Eric W. Reinheimer Æ Marc Fourmigue´ Æ Kim R. Dunbar
  • Crystal Structure of the Radical-Cation Salt (o-Me2TTF)I3 with Close Intermolecular Sulfur Contacts Eric W. Reinheimer Æ Marc Fourmigue´ Æ Kim R. Dunbar
  • Heterospin Single-Molecule Magnets Based on Terbium Ions and TCNQF4 Radicals: Interplay between Single-Molecule Magnet and Phonon Bottleneck Phenomena Investigated by Dilution Studies Nazario Lopez,[a] Andrey V. Prosvirin,[a] Hanhua Zhao,[a] Wolfgang Wernsdorfer,[b] and Kim R. Dunbar*[a]
  • Charge-transfer two-dimensional layers constructed from a 2 : 1 assembly of paddlewheel diruthenium(II,II) complexes and bis[1,2,5]thiadizolotetracyanoquinodimethane: bulk magnetic behavior as a function of inter-layer interactions† N. Motokawa,a T. Oyama,a S. Matsunaga,‡a H. Miyasaka,*a M. Yamashitaa and K. R. Dunbar*b
  • On 29Si NMR relaxation as a structural criterion for studying paramagnetic supermicroporous silica-based materials: Silica-based materials incorporating Mn2+ ions into the silica matrix of SiO2–Al2O3–MnO Vladimir I. Bakhmutov , Boris G. Shpeizer, Andrey V. Prosvirin, Kim R. Dunbar, Abraham Clearfield
• 2007-2008
  • Lanthanide–3d cyanometalate chains Ln(III)–M(III) (Ln = Pr, Nd, Sm, Eu, Gd, Tb; M = Fe) with the tridentate ligand 2,4,6-tri(2-pyridyl)-1,3,5-triazine (tptz): evidence of ferromagnetic interactions for the Sm(III)–M(III) compounds (M = Fe, Cr). Hanhua Zhao, Nazario Lopez, Andrey Prosvirin, Helen T. Chifotides and Kim R. Dunbar. Dalton Transactions, 2007, 878–888
  • Self-assembly of a High-Nuclearity Chloride-Centered Copper(II) Cluster Structure and Magnetic Properties of [Au(PPh3)2][trans-Cu6(í-OH)6{í-(3,5-CF3)2pz}6Cl]. Ahmed A. Mohamed, Alfredo Burini, Rossana Galassi, Daniele Paglialunga, Jose´-Ramo´n Gala´n-Mascaro´s, Kim R. Dunbar, and John P. Fackler, Jr. Inorg. Chem. 2007, 46, 2348-2349
  • Properties of Prussian Blue Materials Manifested in Molecular Complexes: Observation of Cyanide Linkage Isomerism and Spin-Crossover Behavior in Pentanuclear Cyanide Clusters. Mikhail Shatruk,† Alina Dragulescu-Andrasi,‡ Kristen E. Chambers,† Sebastian A. Stoian,‡ Emile L. Bominaar,‡ Catalina Achim,*,‡ and Kim R. Dunbar. J. AM. CHEM. SOC. 2007, 129, 6104-6116
  • Synthesis and Characterization of Four Metal-Organophosphonates with One-, Two-, and Three-Dimensional Structures. Sanjit Konar,† Jerzy Zon´ ,‡ Andrey V. Prosvirin,† Kim R. Dunbar,† and Abraham Clearfield*,†. Inorganic Chemistry, Vol. 46, No. 13, 2007
  • Systematic Investigation of Trigonal-Bipyramidal Cyanide-Bridged Clusters of the First-Row Transition Metals. Mikhail Shatruk, Kristen E. Chambers, Andrey V. Prosvirin, and Kim R. Dunbar. Inorg. Chem. 2007, 46, 5155-5165
  • Enhanced alignment of Mn12-acetate micro-crystals. D. Seoa, W. Teizera,, H. Zhaob, K.R. Dunbar. Journal of Magnetism and Magnetic Materials 312 (2007) 205–209
  • A Family of Mixed-Metal Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism. Eric J. Schelter,§ Ferdi Karadas,† Carolina Avendano,† Andrey V. Prosvirin,† Wolfgang Wernsdorfer,‡ and Kim R. Dunbar. J. AM. CHEM. SOC. 2007, 129, 8139-8149
  • Variation of Heterometallic Structural Motifs Basedon [W(CN)8]3
    Anions andMn II Ions as a Function of Synthetic Conditions. Hanhua Zhao, Mikhail Shatruk, Andrey V. Prosvirin, and Kim R. Dunbar. Chem. Eur. J. 2007, 13, 6573 – 6589
  • Hydrothermal Synthesis, Structural Chemistry, and Magnetic Properties of Materials of the MII/Triazolate/Anion Family, Where MII ) Mn, Fe, and Ni. Wayne Ouellette,† Andrey V. Prosvirin,‡ Jamie Valeich,† Kim R. Dunbar,‡ and Jon Zubieta. Inorg. Chem. 2007, 46, 9067-9082
  • Conversion of a porous material based on a MnII–TCNQF4 honeycomb net to a molecular magnet upon desolvation. Nazario Lopez, Hanhua Zhao, Andrey V. Prosvirin, Abdellatif Chouai, Michael Shatruk and Kim R. Dunbar. Chem. Commun., 2007, 4611–4613
  • Effect of Axial Coordination on the Electronic Structure and Biological Activity of Dirhodium(II,II) Complexes. J. Dafhne Aguirre,† Daniel A. Lutterman,‡ Alfredo M. Angeles-Boza,† Kim R. Dunbar,*,† and Claudia Turro. Inorg. Chem. 2007, 46, 7494-7502
  • Unprecedented Head-to-Head Right-Handed Cross-Links between the Antitumor Bis(í-N,N¢-di-p-tolylformamidinate) Dirhodium(II,II) Core and the Dinucleotide d(ApA) with the Adenine Bases in the Rare Imino Form. Helen T. Chifotides* and Kim R. Dunbar. J. AM. CHEM. SOC. 2007, 129, 12480-12490
  • Magnetic anisotropy in the octanuclear ReII 4 MnII 4 cluster exhibiting Single-Molecule Magnet behavior: Quantum-spin and classical-spin approaches. A.V. Palii a, S.M. Ostrovsky a,*, S.I. Klokishner a,*, B.S. Tsukerblat b, E.J. Schelter c, A.V. Prosvirin c, K.R. Dunbar. Inorganica Chimica Acta 360 (2007) 3915–3924
  • Effects of vibronic interaction in cyano-bridged clusters containing Mn(III) and Mn(II) ions. S.M. Ostrovsky a,*, S.I. Klokishner a, A.V. Palii a, K.R. Dunbar. Journal of Molecular Structure 838 (2007) 138–143
  • Nanopatterning of Mn12-acetate single-molecule magnet films. K. Kim, A. Ford, V. Meenakshi, and W. Teizer, H. Zhao and K. R. Dunbar. JOURNAL OF APPLIED PHYSICS 102, 094306
    2007
  • Anion-p interactions. Brandi L. Schottel, Helen T. Chifotides and Kim R. Dunbar. Chem. Soc. Rev., 2008, 37, 68–83
  • 2D NMR Study of the DNA Duplex d(CTCTC*A*ACTTCC)âd(GGAAGTTGAGAG) Cross-Linked by the Antitumor-Active Dirhodium(II,II) Unit at the Cytosine-Adenine Step. Mijeong Kang, Helen T. Chifotides, and Kim R. Dunbar. Biochemistry 2008, 47, 2265-2276
  • Molybdophosphonate Clusters as Building Blocks in the Oxomolybdate-Organodiphosphonate/Cobalt(II)-Organoimine System: Structural Influences of Secondary Metal Coordination Preferences and Diphosphonate Tether Lengths. N. Gabriel Armatas,† Damian G. Allis,† Andrew Prosvirin,‡ Gabriel Carnutu,§ Charles J. O’Connor, Kim Dunbar,‡ and Jon Zubieta. Inorg. Chem. 2008, 47, 832-854
  • Intercalation Is Not Required for DNA Light-Switch Behavior. Daniel A. Lutterman,† Abdellatif Chouai,‡ Yao Liu,† Yujie Sun,† Cristina D. Stewart,† Kim R. Dunbar,*,‡ and Claudia Turro. J. AM. CHEM. SOC. 2008, 130, 1163-1170
  • Role of Axial Donors in the Ligand Isomerization Processes of Quadruply Bonded Dimolybdenum(II) Compounds. Moumita Majumdar,‡ Sanjib K. Patra,‡ Mukundamurthy Kannan,‡ Kim R. Dunbar,§ and Jitendra K. Bera. Inorg. Chem. 2008, 47, 2212-2222
  • A Family of Cyanide-Bridged Molecular Squares: Structural and Magnetic Properties of [{MIICl2}2{CoII(triphos)(CN)2}2] · xCH2Cl2, M ) Mn, Fe, Co, Ni, Zn. Ferdi Karadas,† Eric J. Schelter,† Michael Shatruk,†,| Andrey V. Prosvirin,† John Bacsa,† Dmitry Smirnov,‡ Andrew Ozarowski,‡ J. Krzystek,‡ Joshua Telser,§ and Kim R. Dunbar. Inorg. Chem. 2008, 47, 2074-2082
  • A series of stable salts of the oxidized donors TTF, o-Me2TTF, TMTTF, and TTF(SCH2CH2CN)4. EricW. Reinheimer, Hanhua Zhao, Kim R. Dunbar. Synthetic Metals 158 (2008) 447–452
  • A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase. Natsuko Motokawa,a Tomomi Oyama,a Satoshi Matsunaga,a Hitoshi Miyasaka,*a Kunihisa Sugimoto,b Masahiro Yamashita,a Nazario Lopezc and Kim R. Dunbar. Dalton Transactions, 2008, 4099–4102
  • A series of strongly one-dimensional organic metals with strictly uniform stacks: (o-DMTTF)2X (X = Cl, Br, I). Marc Fourmigu´e,*a Eric W. Reinheimer,a,b Kim R. Dunbar,*b Pascale Auban-Senzier,c Claude Pasquier*c and Claude Coulon. Dalton Transactions, 2008, 4652–4658
  • An Electron-Transfer Ferromagnet with Tc=107 K Based on a Three- Dimensional [Ru2]2/TCNQ System. Natsuko Motokawa, Hitoshi Miyasaka,* Masahiro Yamashita, and Kim R. Dunbar. Angew. Chem. Int. Ed. 2008, 47, 7760 –7763
  • Head-to-Head Right-Handed Cross-Links ofthe Antitumor-Active Bis(m- N,N’-di-p-tolylformamidinato)dirhodium(II,II) Unit with the Dinucleotides d(GpA) and d(ApG). Helen T. Chifotides* and Kim R. Dunbar. Chem. Eur. J. 2008, 14, 9902 – 9913
  • Hexacyanoosmate(III) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(II). Matthew G. Hilfiger,a Michael Shatruk,b Andrey Prosvirina and Kim R. Dunbar. Chem. Commun., 2008, 5752–5754
  • Radical salts of TTF derivatives with the metal–metal bonded [Re2Cl8]2 anion. Eric W. Reinheimer a,c, José R. Galán-Mascarós b,1, Carlos J. Gómez-García b, Hanhua Zhao a, Marc Fourmigué c,2, Kim R. Dunbar. Journal of Molecular Structure 890 (2008) 81–89
  • A Highly Anisotropic Cobalt(II)-Based Single-Chain Magnet: Exploration of Spin Canting in an Antiferromagnetic Array. Andrei V. Palii,*,† Oleg S. Reu,† Sergei M. Ostrovsky,† Sophia I. Klokishner,† Boris S. Tsukerblat,*,‡ Zhong-Ming Sun,§ Jiang-Gao Mao,§ Andrey V. Prosvirin,| Han-Hua Zhao,| and Kim R. Dunbar. J. AM. CHEM. SOC. 2008, 130, 14729–14738
  • Ultrafast Ligand Exchange: Detection of a Pentacoordinate Ru(II) Intermediate and Product Formation. Yao Liu,† David B. Turner,† Tanya N. Singh, Alfredo M. Angeles-Boza,‡ Abdellatif Chouai,‡ Kim R. Dunbar, and Claudia Turro. J. AM. CHEM. SOC. 2009, 131, 26–27
  • After 118 years, the isolation of two common radical anion reductants as simple, stable solidsw. Thomas A. Scott, Betty A. Ooro, David J. Collins, Michael Shatruk, Andrey Yakovenko, Kim R. Dunbar and Hong-Cai Zhou. Chem. Commun., 2009, 65–67
• 2005-2006
  • Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptx): isolation of the molecular propeller compound [Ag 2 (bptz) 3 ][AsF 6 ] 2. Brandi L. Schottel, John Bacsa and Kim R. Dunbar Chem. Comm. 2005, 46-47.
  • catena -Poly[[diaquacobalt(II)]- m -oxalato]. John Bacsa, Desmond Eve and Kim R. Dunbar Acta Cryst. 2005, C61, m58-m60.
  • Covalent Binding and Interstrand Cross-Linking of Duplex DNA by Dirhodium (II,II) Carboxylate Compounds. Shari U. Dunham, Helen T. Chiforides, Sdzymon Mikulski, Amity E. Burr and Kim R. Dunbar Biochemistry 2005, 44, 996-1003.
  • *Interactions of Metal--Metal-Bonded Antitumor Active Complexes with DNA Fragments and DNA. Helen T. Chifotides and Kim R. Dunbar Acc. Chem. Res. 2005, 38, 146-156.
  • A high spin molecular square based on square pyramidal Co II and tetrahedral Mn II centers: [{Mn II Cl 2 } 2 {Co II (triphos)(CN) 2 ] 2 ]. Ferdi Karadas, Eric J. Schelter, Andrey V. Prosvirin, John Bacsa and Kim R. Dunbar Chem. Comm. 2005, 1414-1416.
  • Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents. Eric J. Schelter, Mikhail Shatruk, Robert A. Heintz, José Ramón Galán-Mascarós and Kim R. Dunbar Chem. Comm. 2005, 1417-1419.
  • New type of single chain magnet based on spin canting in an antiferromagnetically coupled Co(II) chain. Zhong-Ming Sun, Andrey V. Prosvirin, Han-hua Zhao, Jiang-Gao Mao and Kim R. Dunbar J. Appl. Phys. 2005, 97, 10B305-1-10B305-3.
  • A Charge-Transfer-Induced Spin Transition in a Discrete Complex: The Role of Extrinsic Factors in Stabilizing Three Electronic Isomeric Forms of a Cyanide-Bridged Co/Fe Cluster. Curtis P. Berlinguette, Alina Dragulescu-Andrasi, Andreas Sieber, Hans-Ulrich Güdel, Catalina Achim and Kim R. Dunbar J. Amer. Chem. Soc. 2005, 207, 6766-6779.
  • The Step-Wise Assembly of Undecanuclear Heterotrimetallic Cyanide Cluster. Curtis P. Berlinguette, Kim R. Dunbar. Chem. Comm 2005, 2451-2453.
  • Structural and magnetic properties of iron(II) complexes with 1,4,5,8,9,12-hexaazatriphenylene (HAT). Mikhail Shatruk, Abdellatif Chouai, Andrey V. Prosvirin and Kim R. Dunbar. Dalton Trans. 2005, 1897–1902.
  • Manganese(II) chemistry of a new N3O-donor chelate ligand: synthesis, X-ray structures, and magnetic properties of solvent- and oxalate-bound complexes. Amy L. Fuller, Rex W. Watkins, Kim R. Dunbar, Andrey V. Prosvirin, Atta M. Arifc and Lisa M. Berreau. Dalton Trans. 2005, 1891-1896.
  • Control of the Barrier in Cyanide Based Single Molecule Magnets Mn(III)2Mn(II)3: Theoretical Analysis Boris S. Tsukerblat,* Andrew V. Palii,* Sergei M. Ostrovsky, Sergei V. Kunitsky, Sophia I. Klokishner, and Kim R. Dunbar* J. Chem. Theory Comput. 2005, 1, 668-673.
  • Chemical Control of the DNA Light Switch: Cycling the Switch ON and OFF. Yao Liu, Abdellatif Chouai, Natalya N. Degtyareva, Daniel A. Lutterman, Kim R. Dunbar, Claudia Turro. J. Am. Chem. Soc., 2005, 127, 10796-10797.
  • Ruthenium(II) Complexes of 1,12-Diazaperylene and Their Interactions with DNA. Abdellatif Chouai, Sara E. Wicke, Claudia Turro,* John Bacsa, Kim R. Dunbar, Dong Wang, and Randolph P. Thummel* Inorg. Chem., 2005, 44, 5596-6003.
  • Anion Template Effect on the Self-Assembly and Interconversion of Metallacyclophanes. Cristian Saul Campos-Fernández, Brandi L. Schottel, Helen T. Chifotides, Jitendra K. Bera, John Bacsa, John M. Koomen, David H. Russell, and Kim R. Dunbar. J. Am. Chem. Soc., 2005, 127,12909-12923.
  • Synthesis, crystal structures and magnetic properties of two new coordination polymers based on the tricyanoethenolate ligand: {Fe(C 5 N 3 O) 2 (CH 3 CN) 2 } ¥ and {Co(C 5 N 3 O) 2 (C 4 H 4 O) 2 } ¥. Hanhua Zhao, John Bacsa, Andrey Prosvirin, Nazario Lopez and Kim R. Dunbar Polyhedron 2005 , 24 , 1907-1912.
  • Photocytotoxicity of a New Rh 2 (II,II) Complex: Increase in Cytotoxicity upon Irradiation Similar to That of PDT Agent Hematoporphyrin. Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L. Fu, Mikhail Shatruk, Matthew G. Hilfiger, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2005 , 44 , 7262-7264.
  • *Self-Assembled Inorganic Architectures. Jitendra K. Bera, John Bacsa and Kim R. Dunbar Encyclopedia of Inorganic Chemistry , Second Edition (Ed. R. Bruce King), John Wiley & Sons, Inc., 2005.
  • Hydrothermal Synthesis and Structure of a Three-Dimensional Cobalt(II) Triazolate Magnet. Wayne Ouellette, José R. Galán-Mascarós, Kim R. Dunbar and Jon Zubieta Inorganic Chemistry, 2006, 45, 1909-1911.
  • Enhanced Magnetic Anisotrophy of Mn12-Acetate. D.M. Seo, V. Meenakshi, W. Teizer, H. Zhao and K. R. Dunbar. Journal of Magnetism and Magnetic Materials, 2006, 301, 31-36.
  • Coarse and Fine Tuning of the Electronic Energies of Triimineplatinum (II) Square-Planar Complexes. Wei-Hsuan Chen, Eric W. Reinheimer, Kim R. Dunbar and Mohammed A. Omary. Inorganic Chemistry, 2006, 45, 2770-2772.
  • Highly Anisotropic Orbitally-Dependent Superexchange in Cyano-Bridged Clusters Containing Mn(III) and Mn(II) Ions. Boris Tsukerblat, Andrew Palii, Sergey Ostrovsky, Sophia Klokishner, Boris Tsukerblat, Kim R. Dunbar. ChemPhysChem, 2006, 7, 871-879.
  • Anion Interactions as controlling elements in Self-Assembly Reactions of Ag. (I) Complexes with Acidic Aromatic Rings. Brandi Schottel, Helen Chifolttides, Mikail Shatruk, Abdellatif Chouai, Lisa Perez, John Bacsa, Kim R. Dunbar. J. Am. Chem. Soc., 2006, 128, 5895-5912.
  • Influence of anions on the dimensionality of extended networks based on Cu cations and 1, 4, 5, 8, 9, 12-hexaazatriphenylene (HAT) ligands. Mikhail Shatruk, Abdellatif Chouai and Kim R. Dunbar. Dalton Transactions, 2006, 2184-2191.
  • Syntheses and reactivity studies of solvated dirhenium acetonitrile complexes. Jitendra K. Bera, Eric J. Schelter, Sanjib K. Patra, John Bacsa and Kim R. Dunbar. Dalton Transactions, 2006, 4011-4019
  • Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constituents. Mei-Ling Feng, Andrey V. Prosvirin, Jiang-Gao Mao, and Kim R. Dunbar. Chem. Eur. J. 2006, 12, 8312 – 8323
  • Head-to-Head Cross-Linked Adduct between the Antitumor Unit Bis(m-N,N’-di-p-tolylformamidinato)dirhodium(II,II) and the DNA Fragment d(GpG). Helen T. Chifotides and Kim R. Dunbar. Chem. Eur. J. 2006, 12, 6458 – 6468
  • Long-Range Ordered Magnet of a Charge-Transfer Ru2 4+/TCNQ Two-Dimensional Network Compound. Hitoshi Miyasaka, Toru Izawa, Nao Takahashi, Masahiro Yamashita and Kim R. Dunbar. J. AM. CHEM. SOC. 2006, 128, 11358-11359
  • Magnetic Relaxation and Magnetic Moment of Mn12-rcetate Film Material. D. M. Seo, V. Meenakshi, W. Teizer,H. Zhao, and K. R. Dunbar. CP850, Low Temperature Physics: 24'th Intemational Conference on Low,Temperature Physics
  • 2D NMR Spectroscopic Evidence for Unprecedented Interactions of cis-[Rh2(dap)- (m-O2CCH3)2(h1-O2CCH3)(CH3OH)](O2CCH3) with a DNA Oligonucleotide: Combination of Intercalative and Coordinative Binding. Mijeong Kang, Abdellatif Chouai, Helen T. Chifotides, and Kim R. Dunbar. Angew. Chem. Int. Ed. 2006, 45, 6148 –6151
  • Solid-State Coordination Chemistry of the Cu/Triazolate/X System (X ) F-, Cl-, Br-, I-, OH-, and SO4 2-). Wayne Ouellette, Andrey V. Prosvirin, Vincent Chieffo, Kim R. Dunbar, Bruce Hudson, and Jon Zubieta. Inorg. Chem. 2006, 45, 9346-9366
  • A series of complexes of the phosphorus-based TTF ligand o-P2 with the metal ions FeII, CoII, NiII, PdII, PtII, and AgI, Calvin E. Uzelmeier,, Bradley W. Smucker, Eric W. Reinheimer, Mikhail Shatruk, Amanda W. O’Neal, Marc Fourmigue, Kim R. Dunbar. Dalton Transactions, 2006, 5259–5268
  • Dirhodium(II,II) Complexes: Molecular Characteristics that Affect in Vitro Activity. Alfredo M. Angeles-Boza, Helen T. Chifotides, J. Dafhne Aguirre, Abdellatif Chouai, Patty K.-L. Fu, Kim R. Dunbar, and Claudia Turro. J. Med. Chem. 2006, 49, 6841-6847
  • Origin of the Single Chain Magnet Behavior of the Co(H2L)(H2O) Compound with a 1D Structure. Andrei V. Palii, Sergei M. Ostrovsky, Sophia I. Klokishner, Oleg S. Reu, Zhong-Ming Sun, Andrei V. Prosvirin, Han-Hua Zhao,, Jiang-Gao Mao and K. R. Dunbar. J. Phys. Chem. A 2006, 110, 14003-14012
• 2003-2004
  • Deuterium isotope effects and fractionation factors of hydrogen-bonded A:T base pairs of DNA. Ioannis Vakonakis, Miguel Salazar, Mijeong Kang, Kim R. Dunbar and Andy C. LiWang J. of Biomolecular NMR 2003 , 25 , 105-112.
  • Synthesis, X-ray Studies and Magnetic Properties of Dinuclear Ni II and Cu II Complexes Bridged by the Azo-2,2´-bipyridine Ligand. Cristian S. Campos-Fernández, José-Ramón Galán-Mascarós, Bradley W. Smucker and Kim R. Dunbar Eur. J. Inorg. Chem. 2003 , 988-994.
  • A Rare-Earth Metal TCNQ Magnet: Synthesis, Structure, and Magnetic Properties of {[Gd 2 (TCNQ) 5 (H 2 O) 9 ][Gd(TCNQ) 4 (H 2 O) 3 ]}·4H 2 O . Hanhua Zhao, Mervin J. Bazile, Jr., José-Ramón Galán-Mascarós and Kim R. Dunbar Angew. Chem. Int. Ed. 2003 , 42 , 1015-1018.
  • Isolation of the Novel Dirhodium (II/II) Thiolate Compound Rh 2 ( h 1 -C 6 H 5 S) 2 ( m -C 6H 5S) 2 (bpy) 2 . Karn Sorasaenee, José-Ramón Galán-Mascarós and Kim R. Dunbar Inorg. Chem. 2003 , 42 , 661-663.
  • Inhibition of Transcription in Vitro by Anticancer Active Dirhodium(II) Complexes . Karn Sorasaenee, Patty K.-L. Fu, Alfredo M. Angeles-Boza, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2003 , 42 , 1267-1271.
  • A Trigonal-Bipyramidal Cyanide Cluster with Single-Molecule-Magnet Behavior: Synthesis, Structure, and Magnetic Properties of {[Mn 11 (tmphen) 2 ] 3 [Mn 11 (CN) 6 ] 2 . Curtis P. Berlinguette, Derek Vaughn, Cristina Cañada-Vilalta, José-Ramón Galán-Mascarós and Kim R. Dunbar. Angew. Chem. Int. Ed. 2003 , 42 , 1523-1526.
  • A Self-Assembled 2D Molecule-Based Magnet: The Honeycomb Layered Material {Co 3 Cl 4 (H 2 O) 2 [Co(Hbbiz) 3 ] 2 } . José-Ramón Galán-Mascarós and Kim R. Dunbar Angew. Chem. Int. Ed. 2003 , 42 , 2289-2293.
  • Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ) 2 (M = Mn, Fe, Co., Ni). Rodolphe Clérac, Shannon O'Kane, Jerry Cowen, Xiang Ouyang, Robert Heintz, Hanhua Zhao, Mervin J. Bazile, Jr. and Kim R. Dunbar Chem. Mater. 2003 , 15 , 1840-1850.
  • Recognition of Topological Isomerism: Synthesis, Strucutre, and Magnetic Properties of Two Pentanuclear High-Spin Molecules of the Type [Ni II (N-N) 2 ] 3 [Fe III (CN) 6 ] 2 . Curtis P. Berlinguette, José-Ramón Galán-Mascarós and Kim R. Dunbar Inorg. Chem. 2003 , 42 , 3416-3422.
  • Structural, electronic and magnetic properties of metal-metal bonded dinuclear rhenium complexes bridged by organocyanide acceptor ligands. Stuart L. Bartley, Mervin J. Bazile, Jr., Rodolphe Clérac, Hanhua Zhao, Xiang Ouyang and Kim R. Dunbar Dalton Trans. 2003 , 2937-2944.
  • Magnetic properties of complex d 1 and d 5 ions: crystal field model and Jahn-Teller effect. Kim R. Dunbar, Eric J. Schelter, Boris S. Tsukerblat, Sergei M. Ostrovsky, Vadim Yu. Mirovitsky and Andrew V. Palii Polyhedron , 2003 , 22 , 2545-2556.
  • Structural, Magnetic, and Optoelectronic Properties of (Diimine)(dithiolato)platinum(II) and -palladium(II) Complexes and Their Charge-Transfer Adducts with Nitrile Acceptors. Bradley W. Smucker, Joshua M. Hudson, Mohammad A. Omary and Kim R. Dunbar Inorg. Chem. 2003 , 42 , 4714-4723.
  • Unprecedented Head-to-Head Conformers of d(GpG) Bound to the Antitumor Active Compound Tetrakis ( m -carboxylato)dirhodium(II,II). Helen T. Chifotides, Karl M. Koshlap, Lisa M. Pérez and Kim R. Dunbar J. Am. Chem. Soc. 2003 , 125 , 10703-10713.
  • Novel Binding Interactions of the DNA Fragment d(pGpG) Cross-Linked by the Antitumor Active Compound Tetrakis ( m -carboxylato)dirhodium(II,II). Helen T. Chifotides, Karl M. Koshlap, Lisa M. Pérez and Kim R. Dunbar J. Am. Chem. Soc. 2003 , 125 , 10714-10724.
  • New Paramagnetic Re(II) Compounds with Nitrile and Cyanide Ligands Prepared by Homolytic Scission of Dirhenium Complexes. Eric J. Schelter, Jitendra K. Bera, John Bacsa, José-Ramón Galán-Mascarós and Kim R. Dunbar Inorg. Chem. 2003 , 42 , 4256-4258.
  • Hydrogen-bonding as a tool for building one-dimensional structures based on dimetal building blocks. Jitendra K. Bera, Thanh-Trang Vo, Richard A. Walton and Kim R. Dunbar. Polyhedron 2003 , 22 , 3009-3014.
  • Structural evidence for monodentate binding of guanine to the dirhodium(II,II) core in a manner akin to that of cisplatin. Helen T. Chiforides, Jennifer S. Hess, Alfredo M. Angeles-Boza, José-Ramón Galán-Mascarós, Karn Sorasaenee and Kim R. Dunbar Dalton Trans. 2003 4426-4430.
  • Magnetic Properties of a Low-Symmetry d5 Complex-Adiabatic Pseudo Jahn-Teller Problem. Kim R. Dunbar, Eric J. Schelter, Boris S. Tsukerblat, Andrei V. Palii, Sergei M. Ostrovsky, Vadim Yu. Mirovitskii, Sophia I. Klokishner Adv. Quantum Chem. 2003 , 44 , 414-428.
  • Two new soluble iron-oxo complexes: [Fe2(m -O)(m -O2CCF3)2(O2CCF3)2(C10H8N2)2] and [Fe4(m3-O)2(m-O2CCF3)6(O2CCF3)2(C10H8N2)2] CF3CO2H. John Bacsa, Hanhua Zhao and Kim R. Dunbar Acta Cryst. 2003 , C59 , m561-m564.
  • Synthesis, Characterization, and Physical Properties of Two Trinuclear, Mixed-Valence Species of Type [mOMnIIMn2III(O2CCF3)6(R)3] (R=H2O,CH3COOH). Hanhua Zhao, Curtis P. Berlinguette, John Bacsa, Shane E. Tichy and Kim R. Dunbar J. Cluster Science 2003 , 14 , 235-252.
  • *Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature-Independent Paramagnetism. Kim R. Dunbar, Eric J. Schelter, Andrei V. Palii, Sergei M. Ostrovsky, Vadim Yu. Mirovitskii, Joshua M. Hudson, Mohammad A. Omary, Sophia I. Klokishner and Boris S. Tsukerblat J. Phys. Chem. A 2003, 107, 11102-11111.
  • Dirhodium Formamidinate Compounds with Bidentate Nitrogen Chelating Ligands. Helen T. Chifotides, Kemal V. Catalan and Kim R. Dunbar Inorg. Chem. 2003, 42, 8739-8747.
  • Magnetic Property Studies of Manganese-Phosphate Complexes. C. V. Krishnamohan Sharma, Charles C. Chusuei, Rodolphe Clérac, Teresia Moller, Kim R. Dunbar and Abraham Clearfield Inorg. Chem. 2003, 42, 8300-8308.
  • Heterometallic Molecular Squares and Polymers Based On Self-Assembly Reactions of Multiply Bonded Dirhenium Complexes. Jitendra K. Bera, John Bacsa, Bradley W. Smucker and Kim R. Dunbar Eur. J. Inorg. Chem. 2004, 368-375.
  • Effect of Equatorial Ligands of Dirhodium(II,II) Complexes on the Efficiency and Mechanism of Transcription Inhibition in Vitro. Helen T. Chifotides, Patty K.-L. Fu, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004, 43, 1175-1183.
  • Structural Characterization, Magnetic Properties, and Electrospray mass Spectrometry of Two Jahn-Teller Isomers of the Single-Molecule Magnet [Mn12O12(CF3Coo)16(H2O)4]. Hanhua Zhao, Curtis P. Berlinguette, John Bacsa, Andrey V. Prosvirin, Jitendra K. Bera, Shane E. Tichy, Eric J. Schelter and Kim R. Dunbar Inorg. Chem. 2004, 43, 1359-1369.
  • Direct DNA Photocleavage by a New Intercalating Dirhodium(II/II) Complex: Comparison to Rh 2 ( µ -O 2 CCH 3 ) 4 . Patricia M. Bradley, Alfredo M. Angeles-Boza, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004 , 43 , 2450-2452.
  • New Types of Layered and Pillared Layered Metal Carboxylate-Phosphonates Based on the 4,4 ¢ -Bipyridine Ligand. Jun-Ling Song, Han-Hua Zhao, Jiang-Gao Mao and Kim R. Dunbar Chem. Mater. 2004 , 16 , 1884-1880.
  • Tetrakis(2,2 ¢ -bipyridine)tetra- m 3 -hydroxo-di- m -tri-fluoroacetato-tetracobalt(II) diiodide diaceto-nitrile monohydrate: a compound containing a tetranuclear 'cubane'-type cobalt(II) core. Hanhua Zhao, John Bacsa and Kim R. Dunbar Acta Cyrst. 2004 , E60 , m637-m640.
  • A Charge-Transfer-Induced Spin Transition in the Discrete Cyanide-Bridged Complex {[Co(tmphen) 2 ] 3 [Fe(CN) 6 ] 2 }. Curtis P. Berlinguette, Alina Bragulescu-Andrasi, Andreas Sieber, José-Ramón Galán-Mascarós, Hans-Ulrich Güdel, Catalina Achim and Kim R. Dunbar J. Am. Chem. Soc. 2004 , 126 , 6222-6223.
  • Electrochemical, Spectroscopic, and Structural Evidence for the Mild Hydrolysis of Tetracyanoethylene, TCNE, To Form the 2,3,3-Tricyanoacrylamidate Ligand: Isolation of an Unexpected Quadruply-Bonded Polymeric Material [Mo 2 (O 2 CCMe 3 ) 3 ((NC) 2 CC(CN)CONH)] ¥ . Fran ç oise Conan, Beno î t Le Gall, Jean-Michel Kerbaol, Sylvie Le Stang, Jean Sala-Pala, Yves Le Mest, John Bacsa, Xiang Ouyang, Kim R. Dunbar, and Charles F. Campana Inorg. Chem. 2004 , 43 , 3673-3681.
  • *A two-dimensional magnetic architecture with bridging polynitrile and 2,2´-bipyrimidine ligands. J-R. Galán-Mascarós, F. Thétiot, S. Triki, J. Sala Pala and K.R. Dunbar J. Phys. IV France 2004 , 114 , 625-626.
  • 1,3-Dithiolan-2-one. Eric Reinheimer, John Bacsa and Kim R. Dunbar Acta Cryst. Section E 2004 , E60 , 01206-01207.
  • Bis(pyridine-2-ylmethanolato- k 2 N,O ) bis(trifluoroacetato )nickel(II). John Bacsa, Hanjhua Zhao and Kim R. Dunbar Acta Cryst. 2004 , E60 , m1040-m1042.
  • Syntheses, Structure, and Magnetic Properties of New Types of Cu(II), Co(II), and Mn(II) Organophosphonate Materials: Three-Dimensional Frameworks and a One-Dimensional Chain Motif. Deyuan Kong, Yang Li, Xiang Ouyang, Andrey V. Prosvirin, Hanhua Zhao, Joseph H. Ross, Jr., Kim R. Dunbar and Abraham Clearfield Chem. Mater. 2004 , 16 , 3020-3031.
  • Unusual Magnetic Metal-Cyanide Cubes of Re II with Alternating Octahedral and Tetrahedral Corners. Eric J. Schelter, Andrey V. Prosvirin, William M. Reiff and Kim R. Dunbar Angew. Chem. Int. Ed. 2004 , 43 , 4912-4915.
  • Discrete Dinuclear Complexes and Two-Dimensional Architectures from Bridging Polynitrile and Bipyrimidine (bpym) Ligands: Syntheses, Structures and Magnetic Properties of [M 2 (bpym)(dcne) 4 (H 2 O) 2 ] (M = Mn II , Co II ) and [M 2 (bpym)(dcne) 4 (H 2 O) 4 ] · 2H 2 O (M = Fe II , Cu II ) (dcne - = [(CN) 2 CC(O)Oet)] - ). Frank Thétiot, Smail Triki, Jean Sala Pala, José-Ramón Galán-Mascarós, José M. Martínez-Agudo and Kim R. Dunbar Eur. J. Inorg. Chem. 2004 , 3783-3791.
  • Building Block Approaches to Nanomagnetic Materials. Kim R. Dunbar Foundations of Nanoscience Proc. 2004 , 171.
  • Single Molecule Magnet Mn5-Cyanide-Control of the Magnetic Anisotropy. A.V. Palii, S.M. Ostrovsky, S.V. Kunitsky, S. I. Klokishner, B.S. Tsukerblat, J.R. Galán-Mascarós and K.R. Dunbar Proc. of the Third International Conference on Mathematical Modeling and Computer Simulation of Material Technologies 2004, 1-16.
  • Binding of DNA Purine Sites to Dirhodium Compounds Probed by Mass Spectrometry. Helen T. Chifotides, John M. Koomen, Mijeong Kang, Shane E. Tichy, Kim R. Dunbar and David H. Russell Inorg. Chem. 2004, 43, 6177-6187.
  • Films of Mn12-acetate by pulsed laser evaporation. V. Meenakshi, W. Teizer, D.G. Naugle, H. Zhao and K.R. Dunbar Solid State Comm. 2004, 132, 471-476.
  • Molecular Cube of Re II and Mn II That Exhibits Single-Molecule Magnetism. Eric J. Schelter, Andrey V. Prosvirin and Kim R. Dunbar J. Am. Chem. Soc. 2004 , 126 , 15004-15005.
  • Experimental and Computational Studies of Charge-Transfer and Reduction Products of 1,4,5,8,9,11-Hexaazatriphenylene-Hexacarbonitrile:HAT-(CN)6. P.S. Szalay, J.R. Galán-Mascarós, B.L. Schottel, J. Bacsa, L.M. Pérez, A.S. Ichimura, A. Chouai and K.R. Dunbar J. Cluster Science 2004, 15, 503-530.
  • Films of Mn12-acetate deposited by low-energy laser ablation. J. Means, V. Meenakshi, R.V.A. Srivastava, W. Teizer, Al.A. Kolomenskii, H.A. Schuessler, H. Zhao and K.R. Dunbar J. Magnetism & Mater. 2004, 284, 215-219.
  • DNA Binding and Photocleavage in Vitro by New Dirhodium(II) dppz Complexes: Correlation to Cytotoxicity and Photocytotoxicity. Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L Fu, Sara E. Wicke, John Bacsa, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004 , 43 , 8510-8519.
  • Mn 12 -acetate film pattern generated by photolithography methods. K. Kim, D.M. Seo, J. Means, V. Meenakshi, W. Teizer, H. Zhao, K.R. Dunbar Appl. Physics Lett. 2004, 85, 3872-3874.
  • Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[Mn II (tmphen) 2 ] 3 [Mn III (CN) 6 ] 2 } (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). Andrei V. Palli, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Curtis P. Berlinguette, Kim R. Dunbar, and J.R. Galán-Mascarós J. Am. Chem. Soc. 2004, 126, 16860-16867.
• 2001-2002
  • A microporous framework from a magnetic molecular square: [Co(HAT)Cl 2 ] 4 (HAT = 1,4,5,8,9,11-hexaazatriphenylene). José R. Galán-Mascarós and Kim R. Dunbar, Chem . Commun. 2001 , 217-218.
  • Structural and magnetic properties of Co 3 (dpa) 4 Br 2 . Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang, J. Chem. Soc., Dalton Trans. 2001 , 386-391.
  • Dinuclear and Heteropolynuclear Complexes Containing Mo 2 4+ Units. Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang, Inorg. Chem. 2001 , 40 , 420-426.
  • Fine-Tuning the Ring-Size of Metallacyclophanes: A Rational Approach to Molecular Pentagons. Cristian Saul Campos-Fernández, Rodolphe Clérac, John M. Koomen, David H. Russell and Kim R. Dunbar, J. Am. Chem. Soc. 2001 , 123 , 773-774.
  • The first crystal structure of a one-dimensional chain of linked RuII=RuII units. Hitoshi Miyasaka, Rodolphe Clérac, Cristian S. Campos-Fernández and Kim R. Dunbar, J. Chem. Soc., Dalton Trans. 2001 , 858-861.
  • Tuning the Metal-Metal Bonds in the Linear Tricobalt Compound Co 3 (dpa) 4 Cl 2 : Bond-Stretch and Spin-State Isomers. Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang, Inorg. Chem. 2001 , 40 , 1256-1264.
  • Crystal structure and magnetic behavior of the Cu 3 (O 2 C 16 H 23 ) 6 . 1.2 C 6 H 12 . An unexpected structure and an example of spin frustration . Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Elizabeth A. Hillard, Carlos A. Murillo, Marina A. Petrukhina and Bradley W. Smucker, C.R. Acad. Sci. Paris, Chimie/Chemistry 2001 , 4 , 315-319.
  • Metal-Metal Bonded Diruthenium(II, III) Assemblies with the Polycyano Anionic Linkers N(CN) 2 - , C(CN) 3 - , and 1,4-Dicyanamido-2,5-dimethylbenzene (DM-Dicyd 2- ): Syntheses, Structures, and Magnetic Properties. Hitoshi Miyasaka, Rodolphe Clérac, Cristian S. Campos-Fernández and Kim R. Dunbar, Inorg. Chem. 2001 , 40 , 1663-1671.
  • A Comparative Structural and Magnetic Study of Three Compounds Based on the Cluster Unit M 4 Cl 8 (THF) 6 (M = Mn, Fe, Co). H. Zhao, X. Ouyang, J.-S. Sun, R. Clérac, J. M. Clementé-Juan, E. Coronado and K. R. Dunbar, J. Solid State Chem ., 2001 , 159 , 281-292.
  • *HAT(CN) 6 : a new building block for molecule-based magnetic materials. P. S. Szalay, J. R. Galán-Mascarós, R. Clérac, and K. R. Dunbar, Synth. Met . 2001 , 122 , 535-542.
  • New approaches to magnetic clusters with hexacyanometallate building blocks. Jennifer A. Smith, José-Ramón Galán-Mascarós, Rodolphe Clérac, Jui-Sui Sun, Xiang Ouyang and Kim R. Dunbar, "Proceedings of the VIIth International Conference on Molecule-based Magnets ", Polyhedron, San Antonio, TX Sept. 16-21, 2001 , 20 , 1727-1734.
  • New compounds with bridging dicyanamide and bis-chelating 2,2'-bipyrimidine ligands: syntheses, structural characterisation and magnetic properties of the two-dimensional materials [Fe 2 (dca) 4 (bpm)]·H 2 O and [Fe 2 (dca) 4 (bpm)(H 2 O) 2 ]. Smail Triki, Frank Thétiot, J. Galán-Mascarós, Jean Sala Pala and Kim R. Dunbar, New J. Chem. , 2001 , 25 , 954-958.
  • Preface to the Proceedings of ICMM 2000. Kim R. Dunbar, Polyhedron 2001 , 20 , XXVII-XXVIII.
  • Preface for the Special Issue on New Horizons for Magnetic Solids Based on Molecules: From High - T c Magnets to Nanomagnets to Devices. Kim R. Dunbar, J. Solid State Chem. 2001 , 159 , 251-252.
  • A New ~Hybrid~ Molecular Square Composed of Alternating Multiply-Bonded Dinuclear and Mononuclear Corners. Jitendra K. Bera, Bradley W. Smucker, Richard A. Walton and Kim R. Dunbar, Chem. Commun. 2001 , 2562.
  • Reactivity Studies of Anticancer Active Dirhodium Complexes with 2-Aminothiophenol . Karn Sorasaenee, José-Ramón Galán-Mascarós and Kim R. Dunbar, Inorg. Chem. 2002 , 41 , 433-436.
  • Homologous Series of Redox-Active, Dinuclear Cations [M 2 (O 2 CCH 3 ) 2 (pynp) 2 ] 2+ (M = Mo, Ru, Rh) with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine (pynp). Cristian Saul Campos- Fernández, Lisa M. Thomson, José-Ramón Galán-Mascarós, Xiang Ouyang and Kim R. Dunbar, Inorg. Chem. 2002 , 41 , 1523-1533.
  • Unusual Magnetic Behavior in the Layered Ferromagnet [Ni(C 6 H 14 N 2 ) 2 ] 3 [Fe(CN) 6 ] 2 X2H 2 O. Frederic Bellouard, Miguel Clemente-León, Eugenio Coronado, José-Ramón Galán-Mascarós, Carlos J. Gómez-García, Francisco Romero and Kim R. Dunbar, Eur. J. Inorg. Chem. 2002 , 1603-1606.
  • Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H 2 O) 2 ]} ¥ . José-Ramón Galán-Mascarós, Juan-Modesto Clemente-Juan and Kim R. Dunbar, J. Chem. Soc., Dalton Trans . 2002 , 2710-2713.
  • Convenient Route to Salts of the (m - oxo)bis[Trichloroferrate(III)]Dianion, [FeOCl 6 ] 2 -. Kim R. Dunbar, John J. Longridge, Jeremy M. Rawson and Jui-Sui Sun, Inorg . Synth . 2002 , 33 , 103-107.
  • Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions. Robert A. Heintz, Jennifer A. Smith, Paul S. Szalay, Amy Weisgerber and Kim R. Dunbar, Inorg. Synth. 2002 , 33 , 75-83.
  • A Study of Structural and Bonding Variations in the Homologous Series [Mo 2 (CN) 6 (dppm) 2 ] n - (n = 2, 1 and 0). Jitendra K. Bera, Paul S. Szalay and Kim R. Dunbar, Inorg. Chem. 2002 , 41 , 3429-3436.
  • Reactivity Studies of 2,3,5,6-Tetra(2-pyridyl) pyrazine (tppz) with First-Row Transition Metal Ions. Cristian S. Campos-Fernández, Bradley W. Smucker, Rodolphe Clérac and Kim R. Dunbar, Israel J. Chem. 2002 , 41 , 207-218.
  • Oligonucleotide analysis with MALDI-ion-mobility-TOFMS. John M. Koomen, Brandon T. Ruotolo, Kdent J. Gillig, John A. McLean, David H. Russell, Mijeong Kang, Kim R. Dunbar, Katrin Fuhrer, Marc Gonin and J. Albert Schultz, Anal. Bioanal. Chem. 2002 , 373 , 612-617.
  • Coupling dirhodium units through terpyridine bridges: synthesis and structure of a novel molecular rectangle. Jitendra K. Bera, Cristian S. Campos-Fernández, Rodolphe Clérac and Kim R. Dunbar, Chem. Comm. , 2002 , 2536-2537.
  • Facile Conversion of the Face-Centered Cubic Prussian-Blu Material K 2 [Mn 2 (CN) 6 ] into the Spinel Oxide Mn 3 O 4 at the Solid/Water Interface. Aurelie Buckelew, Jose-Ramon Galan-Mascaros and Kim R. Dunbar. Adv. Mater. 2002 , 14 , 1646-1648.
  • *Chain Compounds Based on Trasition Metal Backbones: New Life For an Old Topic. Jitendra Bera and Kim R. Dunbar. Angew. Chem. Int. Ed. 2002 , 41 , 4453-4457.
  • Structural diversity of cyanide-bridged bimetallic clusters based on hexacyanometallate building blocks . Curtis P. Berlinguette, Jennifer A. Smith, Jose-Ramon Galan-Mascaros and Kim R. Dunbar. C.R. Chimie 2002 , 5 , 665-672.
  • Future directions in solid state chemistry: report of the NSF-sponsored workshop. Robert J. Cava, Francis J. DiSalvo, Louis E. Brus, Kim R. Dunbar, Christopher B. Gorman, Sossina, M. Haile, Leonard V. Interrante, Janice L. Musfeldt, Alexandra Navrotsky, Ralph G. Nuzzo, Warren E. Pickett, Angus P. Wilkinson, Channing Ahn, James W. Allen, Peter C. Burns, Gerdrand Ceder, Christopher E.D. Chidsey, William Clegg, Eugenio Coronado, Hongjie Dai, Michael W. Deem, Bruce S. Dunn, Giulia Galli, Allan J. Jacobson, Mercouri Kanatzidis, Wengin Lin, Arumugam Manthiram, Milan Mrksich, David J. Norris, Arthur J. Nozik, Xiaogang Peng, Claudia Rawn, Debra Rolison, David J. Singh, Brian H. Toby, Sara Tolbert, Ulrich B. Wiesner, Patrick M. Woodward and Peidong Yang Progress in Solid State Chemistry 2002 , 30 , 1-101.
• 1996-2000
  • Photochemistry of deca(acetonitrile) dirhodium(II) cation: evidence for kilosecond-lived photoinduced charge separation. Chris A. James, David E. Morris, Stephen K. Doorn, C. Anthony Arrington, Jr., Kim R. Dunbar, Gary M. Finnis, Laura E. Pence and William H. Woodruff, Gray Honor Special Volume Inorg. Chim. Acta 1996 , 242 , 91-96.
  • N 7 ,O 6 bridging 9-ethylguanine (9-EtGH) groups in dinuclear metal-metal bonded complexes with bond orders of one, two or four. Charles A. Crawford, Elizabeth F. Day, Vijay P. Saharan, Kirsten Folting, John C. Huffman, Kim R. Dunbar and George Christou, Chem. Commun. 1996 , 1113-1114.
  • Organocyanide Acceptor Molecules as Novel Ligands. Kim R. Dunbar, Angew. Chem. Int. Ed. Engl. 1996 , 35 , 1659-1661.
  • Ligand Effects On The d ® d * Band Energies And Intensities In A Series Of Diimine Complexes Of Dimolybdenum. D. M. Baird, F. L. Yang, D. J. Kavanaugh, G. Finniss and K. R. Dunbar Polyhedron 1996 , 15 , 2597-2606.
  • "Design, Synthesis And Processing Of Molecular-Organic And Inorganic-Magnetic Materials" NATO ASI Series Molecular Magnetism: From Molecular Assemblies to the Devices . S. DeCurtins, K. R. Dunbar, C. J. Gomez-Garcia, T. Mallah, R. G. Raptis, D. Talham and J. Veciana (Eds: E. Coronado, P. Delhaès, D. Gatteschi, J. S. Miller) Kluwer, 1996 , NATO ASI Series vol. E321, 571-582.
  • *Bioinorganic chemistry: Antitumor chemistry. Kim R. Dunbar and Kemal V. Catalan, McGraw Hill Encyclopedia of Science &Technology 1997 , McGraw-Hill, 1996 , 40-43.
  • A novel one-dimensional structure involving m 4 -TCNQ ligands and quadruply bonded dimolybdenum units (TCNQ = 7,7,8,8-tetracyanoquinodimethane). Charles Campana, Kim R. Dunbar and Xiang Ouyang, Chem. Commun . 1996 , 2427-2428.
  • Unprecedented Two-Dimensional Polymers of Mn(II) with TCNQ- . (TCNQ = 7,7,8,8-Tetracyanoquinodimethane). Hanhua Zhao, Robert A. Heintz, Kim R. Dunbar and Robin D. Rogers, J. Am. Chem. Soc. 1996 , 118 , 12844-12845.
  • Preparation, Molecular and Electronic Structures, and Magnetic Properties of Face-Sharing Bioctahedral Titanium(III) Compounds: [PPh 4 ][Ti 2 ( m -Cl) 3 Cl 4 (PR 3 ) 2 ]. Linfeng Chen, F. Albert Cotton, Kim R. Dunbar, Xuejun Feng, Robert A. Heintz and Calvin Uzelmeier, Inorg. Chem . 1996 , 35 , 7358-7363.
  • A One-Dimensional Metallopolymer of 2,5-Dimethyl- N,N' -Dicyanoquinone Diimine (2,5-DM-DCNQI). Xiang Ouyang, Charles Campana and Kim R. Dunbar, Inorg . Chem . 1996 , 35 , 7188-7189.
  • Unprecedented Conversion of a Compound with Metal-Metal Bonding into a Solvated Molecular Wire. Gary M. Finniss, Enric Canadell, Charles Campana and Kim R. Dunbar, Angew. Chem. Int. Ed. Engl. 1996 , 35 , 2772-2774.
  • *Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives. Kim R. Dunbar and Robert A. Heintz, Prog. Inorg. Chem. 1997 , 45 , 283-391.
  • Bis- and tetrakis-(diphenylphosphino)tetrathiafulvalenes as precursors of redox-active organic-inorganic polymeric networks . M. Fourmigué, C. E. Uzelmeier, K. Boubekeur, S. L. Bartley and K. R. Dunbar, J. Organomet. Chem . 1997 , 529 , 343-350.
  • Reaction of Nitrogen Chelates with the [Rh 2 ] 4+ Core: Bis-Chelate Products and Demonstration of Reversible, Chelate-Based Reduction Processes. Charles A. Crawford, John H. Matonic, John C. Huffman, Kirsten Folting, Kim R. Dunbar and George Christou, Inorg. Chem. 1997 , 36 , 2361-2371.
  • A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine Ligands. Kemal V. Catalan, Daniel J. Mindiola, Donald L. Ward and Kim R. Dunbar, Inorg. Chem. 1997 , 36 , 2458-2460.
  • Analysis of Transition-Metal Compounds Containing Tetrathiafulvalene Phosphine Ligands by Fast Atom Bombardment Mass Spectrometry: Limitations and the Development of Matrix Additives for the Desorption of Multiply Charged Complexes. John M. Asara, Calvin E. Uzelmeier, Kim R. Dunbar and John Allison, Inorg. Chem . 1998 , 37 , 1833-1840.
  • Pd(II) and Pt(II) complexes with mixed phosphorus-oxygen donor ligands . Jui-Sui Sun, Calvin E. Uzelmeier, Donald L. Ward and Kim R. Dunbar, Polyhedron 1998 , 17 , 2049-2063.
  • 3,4-Dimethyltetrathiafulvalene. Calvin E. Uzelmeier, Marc Fourmigué and Kim R. Dunbar, Acta. Cryst. 1998 , C54 , 1047-1049.
  • Reaction of Octachlorodirhenate with a Redox-Active Tetrathiafulvalene Phosphine Ligand: Spectroscopic, Magnetic, and Structural Characterization of the Unusual Paramagnetic Salt [ReCl 2 ( o -P2) 2 ][Re 2 Cl 6 ( o -P2)] ( o -P2 = o -{P(C 6 H 5 ) 2 } 2 (CH 3 ) 2 TTF). Calvin E. Uzelmeier, Stuart L. Bartley, Marc Fourmigué, Robin Rogers, Giulio Grandinetti and Kim R. Dunbar, Inorg. Chem . 1998 , 37 , 6706-6713.
  • A quadruply-bonded dirhenium complex bridged by two N 1 /N 6 adenate ligands. Matthew E. Prater, Daniel J. Mindiola, X. Ouyang and Kim R. Dunbar, Inorg. Chem. Commun . 1998 , 1 , 475-477.
  • Insight Into The Behavior Of M(TCNQ)Properties. Hanhua Zhao, Robert A. Heintz, Xiang Ouyang, Giulio n (n = 1, 2) Crystalline Solids And Films: X-ray, Magnetic And Conducting Grandinetti, Jerry Cowen and Kim R. Dunbar, and Magnets , Ed: J. Veciana, Kluwer: Dordrecht, 1999 , 518 , 353-376. NATO ASI: Supramolecular Engineering of Synthetic Metallic Materials: Conductors
  • New Insight into the Nature of Cu(TCNQ): Solution Routes to Two Distinct Polymorphs and Their Relationship to Crystalline Films that Display Bistable Switching Behavior. Robert A. Heintz, Hanhua Zhao, Xiang Ouyang, Giulio Grandinetti, Jerry Cowen and Kim R. Dunbar, Inorg. Chem. 1999 , 38 , 144-156.
  • Spectroscopic, Thermal, and Magnetic Properties of Metal/TCNQ Network Polymers with Extensive Supramolecular Interactions between Layers. H. Zhao, R. A. Heintz, X. Ouyang, K .R. Dunbar, C. F. Campana and R. D. Rogers, Chem. Mater. 1999 , 11 , 736-746.
  • Reactions of DNA Purines with Dirhodium Formamidinate Compounds That Display Antitumor Behavior . K. V. Catalan, J. S. Hess, M. M. Maloney, D. J. Mindiola, D. L. Ward and K. R. Dunbar, Inorg. Chem. 1999 , 38 , 3904-3913.
  • A Remarkable Family of Rhodium Acetonitrile Compounds Spanning Three Oxidation States and with Nuclearities Ranging from Mononuclear and Dinuclear to One-Dimensional Chains. M. E. Prater, L. E. Pence, R. Clérac, G. M. Finniss, C. Campana, P. Auban-Senzier, D. Jérome, E. Canadell and K. R. Dunbar, J. Am. Chem. Soc. 1999 , 121 , 8005-8016.
  • The Use of Organic Acceptors as Ligands for Paramagnetic Metal Centers: a New Spin on Charge-Transfer Solids. Jerry Cowen, Rodolphe Clérac, Robert A. Heintz, Shannon O'Kane, Xiang Ouyang, Hanhua Zhao and Kim R. Dunbar, Mol. Cryst. and Liq. Cryst. Proceedings of the VIth International Conference on Molecule Based Magnets , September, Seignosse Le Penon, France, 1999 , 335 , 113-132.
  • A One-Pot, High-Yield Synthesis of a Paramagnetic Nickel Square from Divergent Precursors by Anion Template Assembly. Cristain S. Campos-Fernández, Rodolphe Clérac and Kim R. Dunbar, Angew. Chem. Int. Ed. 1999 , 38 , 3477-3479.
  • Structures, Magnetic Properties, and Reactivity Studies of Salts Containing the Dinuclear Anion [M 2 Cl 6 ] 2- (M = Mn, Fe, Co). Jui-Sui Sun, Hanhua Zhao, Xiang Ouyang, Rodolphe Clérac, Jennifer A. Smith, Juan M. Clemente-Juan, Carlos Gómez-Garcia, Eugenio Coronado and Kim R. Dunbar, Inorg. Chem. 1999 , 38 , 5841-5855.
  • A Reinvestigation by Circular Dichroism and NMR: Ruthenium(II) and Rhodium(III) Metallointercalators Do Not Bind Cooperatively to DNA. (Research by S. J. Franklin, C. R. Treadway and J. K. Barton.) Summary by Karn Sorasaenee and Kim R. Dunbar, CHEMTRACTS 1999 , 12 , 870-883.
  • Further Study of the Linear Trinickel(II) Complex of Dipyridylamide. Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Carlos A. Murillo, Isabel Pascual and Xiaoping Wang, Inorg. Chem . 1999 , 38 , 2655-2657.
  • Evidence for Binding of Dirhodium Bis-Acetate Units to Adjacent GG and AA Sites on Single-Stranded DNA. John M. Asara, Jennifer S. Hess, Elizabeth Lozada, Kim R. Dunbar and John Allison, J. Am. Chem. Soc. 2000 , 122 , 8-13.
  • A new family of dimolybdenum compounds with cyanide and phosphine ligands. Paul S. Szalay and Kim R. Dunbar, Inorg. Chem. Commun. 2000 , 3 , 49-51.
  • Linear Trichromium Complexes with Direct Cr to Cr Contacts. 1. Compounds with Cr 3 (dipyridylamide) 4 2+ Cores. Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Isabel Pascual, Inorg. Chem . 2000 , 39 , 748-751.
  • Linear Trichromium Complexes with Direct Cr to Cr Contacts. 2. Compounds with Cr 3 (dipyridylamide) 4 3+ Cores. Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Isabel Pascual, Inorg. Chem . 2000 , 39 , 752-756.
  • Homoleptic complexes of Ag(I), Cu(I), Pd(II) and Pt(II) with tetrathiafulvalene-functionalized phosphine ligands. Bradley W. Smucker and Kim R. Dunbar, J. Chem. Soc., Dalton Trans . 2000 , 1309-1315.
  • A New Linear Tricobalt Compound with Di(2-pyridyl)amide (dpa) Ligands: Two-Step Spin Crossover of [Co 3 (dpa) 4 Cl 2 ][BF 4 ]. Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Tongbu Lu, Carlos A. Murillo and Xiaoping Wang, J. Am. Chem. Soc . 2000 , 122 , 2272-2278.
  • New Crystalline Polymers of Ag(TCNQ) and Ag(TCNQF 4 ): Structures and Magnetic Properties. Shannon A. O'Kane, Rodolphe Clérac, Hanhua Zhao, Xiang Ouyang, José-Ramón Galán-Mascarós, Robert Heintz and Kim R. Dunbar, J. Solid State Chem. 2000 , 152 , 159-173.
  • {Mn(OH 2 ) 2 [Mn(bpym)(OH 2 )] 2 [Fe(CN) 6 ] 2 } ¥ : a two-dimensional ferrimagnet with a partial cubane motif. Jennifer A. Smith, José-Ramón Galán-Mascarós, Rodolphe Clérac and Kim R. Dunbar, Chem. Commun. 2000 , 1077-1078.
  • A Homologous Series of Redox-Active, Dinuclear Cations with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine. Cristian Saul Campos-Fernández, Xiang Ouyang and Kim R. Dunbar, Inorg. Chem. 2000 , 39 , 2432-2433.
  • New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co 3 (dpa) 4 (CH 3 CN) 2 ][PF 6 ] 2 . Rodolphe Clérac, F. Albert Cotton, Kim R. Dunbar, Tongbu Lu, Carlos A. Murillo and Xiaoping Wang, Inorg. Chem. 2000 , 39 , 3065-3070.
  • Linear Trichromium Complexes with the Anion of 2,6-Di(phenylimino)piperidine . Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Hong-Cai Zhou, Inorg. Chem. 2000 , 39 , 3414-3417.
  • Linear Tricobalt Compounds with Di(2-pyridyl)amide (dpa) Ligands: Temperature Dependence of the Structural and Magnetic Properties of Symmetrical and Unsymmetrical Forms of Co 3 (dpa) 4 Cl 2 in the Solid State. Rodolphe Clérac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Kristin Kirschbaum, Carlos A. Murillo, A. Alan Pinkerton, Arthur J. Schultz and Xiaoping Wang, J. Am. Chem Soc . 2000 , 122 , 6226-6236.
  • Hexagonal Layered Materials Composed of [M 2 (O 2 CCF 3 ) 4 ] (M = Ru and Rh) Donors and TCNQ Acceptors. Hitoshi Miyasaki, Cristian S. Campos-Fernández, Rodolphe Clérac and Kim R. Dunbar, Angew. Chem. Int. Ed. 2000 , 39 , 3831-3835.
  • One-Dimensional Assemblies of Dirhodium Units Bridged by N , N' -Dicyanoquinonediimine Ligands. Hitoshi Miyasaka, Cristian S. Campos-Fernández, José Ramón Galán-Mascarós and Kim R. Dunbar, Inorg. Chem. 2000 , 39 , 5870-5873.
• 1991-1995
  • Structure of [HTMPP] 3 W 2 Cl 9 [HTMPP = Tris(2,4,6-trimethoxyphenyl)-phosphonium]. K. R. Dunbar and L. E. Pence, Acta Cryst. 1991 , C47 , 23-26.
  • Binding of 2,2¢-Bipyridine to the Dirhodium(II) Tetraacetate Core: Unusual Structural Features and Biological Relevance of the Product Rh 2 (OAc) 4 (bpy). Spiros P. Perlepes, John C. Huffman, John H. Matonic, Kim R. Dunbar and George Christou, J. Am. Chem. Soc. 1991 , 113 , 2770-2771.
  • [{Re 2 Cl 4 (dppm) 2 } 2 (m-TCNQ)], a Novel Charge Transfer Complex Derived from a Donor with a Metal-Metal Multiple Bond. Stuart L. Bartley and Kim R. Dunbar, Angew. Chem. Int. Ed. Eng. 1991 , 30 , 448-450.
  • Elucidation of the Reversible Carbon Monoxide Reactions of a Paramagnetic Rhodium(II) Complex. Kim R. Dunbar, Steven C. Haefner and Paul N. Swepston, J. Chem. Soc., Chem. Commun. 1991 , 460-462.
  • Chemistry of Tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) with Dirhodium Tetraacetate: Synthesis and Spectroscopic, Electrochemical, and Structural Characterization of a Binuclear Complex That Contains an Unusual Phenoxy-Phosphine Ligand. S. J. Chen and K. R. Dunbar, Inorg. Chem. 1991 , 30 , 2018-2023.
  • Oxidative Addition of Halogens to the Quadruple Bond of Mo 2 X 4 (dppm) 2 (X = Cl, I, Br): Synthesis, Structural Characterization, and Magnetic Properties of Mo 2 Cl 4 I 2 (dppm) 2 ,Mo 2 Br 6 (dppm) 2 , and Mo 2 I 6 (dppm) 2 . F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Charles J. O'Connor and Andrew C. Price, Inorg. Chem. 1991 , 30 , 2509-2514.
  • Bis(diphenylphosphino)methane complexes of rhodium(III) halides as synthons for dinuclear rhodium(III) complexes. F. Albert Cotton, Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello, Seong-Joo Kang, Andrew C. Price and Mark G. Verbruggen, Inorg. Chim. Acta 1991 , 184 , 35-42.
  • Isomerism in the Mo 2 ( m -O 2 CCF 3 ) 4 /bpy Reaction System: Thermal and Photochemical Conversion of the Ion-Pair Complex [Mo 2 ( m -O 2 CCF 3 ) 2 (bpy) 2 ](O 2 CCF 3 )0 2 to the Unbridged Neutral Isomer Mo 2 ( h 1 -O 2 CCF 3 ) 4 (bpy) 2 . John H. Matonic, Sue-Jane Chen, Spiros P. Perlepes, Kim R. Dunbar and George Christou, J. Am. Chem. Soc. 1991 , 113 , 8169-8171.
  • Reversible Carbon Monoxide Reactions of Cationic Rh(I) and Rh(II) Complexes. Steven C. Haefner, Kim R. Dunbar and Christopher Bender, J. Am. Chem. Soc . 1991 , 113 , 9540-9553.
  • Structure of [CH 3 TMPP] 2 Co 2 Cl 6 [CH 3 TMPP = Tris(2,4,6-trimethoxyphenyl)-methylphosphonium]. K. R. Dunbar, A. Quillevéré and S. C. Haefner, Acta Cryst. 1991 , C47 , 2319-2321.
  • Decakis(Acetonitrile)Dirhodium(II) Tetrafluoroborate. Kim R. Dunbar and Laura E. Pence, Inorganic Syntheses Vol. 29, 1992, 182-185.
  • An Unusual Complex Derived From MoCl 3 (THF) 3 And AgBF 4 In Acetonitrile: Synthesis And Structure Of [Mo 2 ( m -F)(NCCH 3 ) 8 O 2 ][BF 4 ] 3 . John H. Matonic, Sue-Jane Chen, Laura E. Pence and Kim R. Dunbar, Polyhedron 1992 , 11 , 541-546.
  • Structural and Spectroscopic Characterization of a Paramagnetic Isocyanide Complex of Rhodium (II). Kim R. Dunbar and Steven C. Haefner, Organometallics 1992 , 11 , 1431-1433.
  • Reversible Carbon Monoxide Addition to Sol-Gel Derived Composite Films Containing a Cationic Rhodium(I) Complex: Toward the Development of a New Class of Molecule-Based CO Sensors. Joel I. Dulebohn, Steven C. Haefner, Kris A. Berglund and Kim R. Dunbar, Chem. of Materials 1992 , 4 , 506-508.
  • Crystallographic Disorder in the Orthorhombic Form of RhCl(CO)(PPh 3 ) 2 : Relevance to the Reported Structure of the Paramagnetic Impurity in Wilkinson's Catalyst. Kim R. Dunbar and Steven C. Haefner, Inorg. Chem. 1992 , 31 , 3676-3679.
  • *New Applications of Weak Donor Atoms to Coordination, Organometallic and Materials Chemistry. Kim R. Dunbar, Comments Inorg. Chem. 1992 , 13 , 313-357.
  • Unusual Structural Features of Tetrakis( m -carboxylato)dirhodium(II), an Antitumor Agent, Bound to Azathioprine, a Biologically Active Mercaptopurine Derivative. H.T. Chifotides, K. R. Dunbar, J. H. Matonic and N. Katsaros, Inorg. Chem. 1992 , 31 , 4628-4634.
  • Novel Strategies for the Synthesis and Crystallization of Electrophilic Dinuclear Cations: Solution and Solid-State Properties of [Re 2 (NCCH 3 ) 10 ][Mo 6 O 19 ] 2 . Stacey N. Bernstein and Kim R. Dunbar, Angew. Chem. Int. Ed. Engl. 1992 , 31 , 1360-1362.
  • [Fe 2 Cl 6 ] 2- : A Discrete Form of Ferrous Chloride. Kim R. Dunbar and Anne Quillevéré, Angew. Chem. Int. Ed. Engl. 1993 , 32 , 293-295.
  • The Oxygenation of the Electron-rich Triple Bond in the Complexes [Re 2 X 4 (m-dppm) 2 ] [X = Cl or Br; dppm = bis(diphenylphosphino)methane]. Multielectron Redox Behaviour involving Retention of the Re 2 X 4 P 4 Unit. Stuart L. Bartley, Kim R. Dunbar, Keng-Yu Shih, Phillip E. Fanwick and Richard A. Walton, J. Chem. Soc., Chem. Commun. 1993 , 98-100.
  • An Unusual Heterobimetallic Compound with a Rhodium(I) _ h 4 -Arene Interaction. Kim R. Dunbar and Anne Quillevéré, Organometallics 1993 , 12 , 618-620.
  • Investigation Of The Intermediates In The Oxidation Of A Bulky Arylphosphine Ligand With Ferric Chloride. Kim R. Dunbar and Anne Quillevéré, Polyhedron 1993 , 12 , 807-819.
  • Reactions of the Electron-Rich Triply Bonded Dirhenium(II) Complexes Re 2 X 4 ( m -dppm) 2 (X = Cl, Br) with Dioxygen. 1. Multielectron Redox Chemistry with Preservation of the Re 2 X 4 (dppm) 2 Unit. Stuart L. Bartley, Kim R. Dunbar, Keng-Yu Shih, Phillip E. Fanwick and Richard A. Walton, Inorg. Chem. 1993 , 32 , 1341-1349.
  • Reaction of 2,2´-Bipyridine (bpy) with Dirhodium Carboxylates: Mono-bpy Products with Variable Chelate Binding Modes and Insights into the Reaction Mechanism. Charles A. Crawford, John H. Matonic, William E. Streib, John C. Huffman, Kim R. Dunbar and George Christou, Inorg. Chem. 1993 , 32 , 3125-3133.
  • *Acetonitrile and cyanide compounds containing metal-metal bonds: syntheses, structures and applications to solid-state chemistry. Stuart L. Bartley, Stacey N. Bernstein and Kim R. Dunbar, Topical Volume of Inorg. Chim. Acta. entitled "Metal-Metal Bonds/Clusters/Polynuclear Metal Complexes" 1993 , 213 , 213-231.
  • *Review of the Coordination Chemistry of Tungsten for 1991 . Kim R. Dunbar and Gary M. Finniss, Coord. Chem. Rev . 1993 , 127 , 65-97.
  • The Interaction of Dinuclear Rhodium (II) Complexes With Nitrogen Donor Ligands of Biological Relevance. K. R. Dunbar, J. H. Matonic, V. P. Saharan, C. A. Crawford, G. Christou, J. Inorg. Biochem . 1993 , 51 , 401.
  • Complexes Containing Heteronuclear and Homonuclear Quadruple Bonds. Preparation and Characterization of MoWCl 4 (dmpm) 2 and Mo 2 X 4 (dmpm) 2 (X = Br, I). F. A. Cotton, K. R. Dunbar, B. Hong, C. A. James, J. H. Matonic and J. L. C. Thomas, Inorg. Chem . 1993 , 32 , 5183-5187.
  • Polynuclear Rhodium(II) Compounds with Phosphino-Phenoxide Ligands. Kim R. Dunbar, John H. Matonic and Vijay P. Saharan, Inorg. Chem . 1994 , 33 , 25-31.
  • Structural Evidence for a New Metal-Binding Mode for Guanine Bases: Implications for the Binding of Dinuclear Antitumor Agents to DNA. Kim R. Dunbar, John H. Matonic, Vijay P. Saharan, Charles A. Crawford and George Christou, J. Am. Chem. Soc . 1994 , 116 , 2201-2202.
  • Synthesis And Properties Of Tris(2,4,6-Trimethoxyphenyl)Phosphine And Tris(2,4,6-Trimethoxyphenyl)Phosphine Oxide. Kim R. Dunbar and Steven C. Haefner, Polyhedron 1994 , 13 , 727-736.
  • A mixed-metal salt comprised of metal-metal bonded dinuclear ions: structure and properties of [Rh 2 (OAc) 2 (MeCN) 6 ][Re 2 Cl 8 ] . Kim R. Dunbar, Laura E. Pence and Julie L. C. Thomas, Inorg. Chim. Acta . 1994 , 217 , 79-84.
  • Incorporation of Quadruply-Bonded Units into Solid-State Materials. Kim R. Dunbar, J. Cluster Science 1994 , 5 , 125-143.
  • Synthesis, Spectroscopic and Magnetic Resonance Studies of Mercury(II) and Methylmercury(II) Complexes of Azathioprine, a Biologically Active Mercaptopurine Derivative . Helen T. Chifotides, Kim R. Dunbar, Nikos Katsaros and George Pneumatikakis, J. Inorg. Biochem . 1994 , 55 , 203-216.
  • Carbon Monoxide Reactions of the Fluxional Phosphine Complex ( h 3 -PR 3 )Mo(CO) 3 (R = 2,4,6-Trimethoxyphenyl). Kim R. Dunbar, Jui-Sui Sun, Steven C. Haefner and John H. Matonic, Organometallics 1994 , 13 , 2713-2720.
  • Spectroscopic and Structural Investigation of Nickel(II) and Nickel(III) Compounds Stabilized by Identical P,O Ligands. Kim R. Dunbar, Jui-Sui Sun and Anne Quillevéré, Inorg. Chem . 1994 , 33 , 3598-3601.
  • New Metal-Binding Mode for Adenine: A Bidentate (N6, N7) Bridging Mode in the Complex [Mo 2 (O 2 CCHF 2 ) 2 (9-EtAH) 2 (MeCN) 2 ](BF 4 ) 2 . 2MeCN. Elizabeth F. Day, Charles A. Crawford, Kirsten Folting, Kim R. Dunbar and George Christou, J. Am. Chem. Soc . 1994 , 116 , 9339-9340.
  • Synthesis and Structure of the Distorted Octahedral Palladium(II) Complex [Pd(tmpp) 2 ][BF 4 ] 2 [tmpp = tris(2,4,6-trimethoxyphenyl)phosphine]. Kim R. Dunbar and Jui-Sui Sun, J. Chem. Soc., Chem. Commun. 1994 , 2387-2388.
  • *Review of the Coordination Chemistry of Tungsten for 1992 . Kim R. Dunbar and Vijay P. Saharan, Coord. Chem. Rev. 1995 , 138 , 39-70.
  • Review of "Multiple Bonds Between Metal Atoms. Second Edition." Kim R. Dunbar, J. Am. Chem. Soc . 1994 , 116 , 7957.
  • Acetonitrile complexes of diiridium Part 1. Isolation and characterization of the partially solvated cations [Ir 2 (COD)( µ -form) 2 (MeCN) 3 ] 2+ and [Ir 2 ( µ -form) 2 (MeCN) 6 ] 2+ (COD = 1,5-cyclooctadiene, form = N,N' -di- p -tolylformamidinate). Kim R. Dunbar, Shannon O. Majors and Jui-Sui Sun, F. A. Cotton Honor Inorg. Chim. Acta. Special Issue 1995 , 229 , 373-382.
  • Paramagnetic Transition Metal Complexes With s-Bonded Tetracyanoethylene (TCNE). Kim R. Dunbar and Xiang Ouyang, Mol. Cryst. Liq. Cryst., Proceedings of the IV International Conference on Molecule Based Magnets, 16-21 October 1994, Salt Lake City, Utah, 1995 , 273 , 21-28.
  • Magnetic Studies Of Polynuclear Iron (II) Complexes And Their Application To The Synthesis Of Extended Structures. Kim R. Dunbar and Jui-Sui Sun, Mol. Cryst. Liq. Cryst., Proceedings of the IV International Conference on Molecule Based Magnets, 16-21 October 1994, Salt Lake City, Utah, 1995 , 274 , 51-62.
  • Chemistry of tris(2,4,6-trimethoxyphenyl)phosphine with rhodium(I) and iridium(I) olefin complexes. Kim R. Dunbar, Steven C. Haefner, Calvin E. Uzelmeier and Anthony Howard, Basolo Honor Special Volume Inorg. Chim. Acta 1995 , 240 , 527-534.
• 1983-1990
  • Synthesis and Structural Characterization of [Re 2 Cl 4 (PMe 2 Ph) 4 ] n + ( n = 0, 1, or 2): A Series of Complexes Possessing Metal-Metal Bond Orders of 4, 3.5, and 3 and the Dependence of Bond Length upon Bond Order. F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Milagros Tomas and Richard A. Walton, J. Am. Chem. Soc . 1983 , 105 , 4950-4954.
  • The Reactions of Carbon Monoxide with the Series of Dirhenium Species [Re 2 Cl 4 -(PMe 2 Ph) 4 ] n+ (n = 0, 1, 2) Possessing Rhenium-Rhenium Bond Orders of 4, 3.5 and 3. Kim R. Dunbar and Richard A. Walton, Inorg. Chim. Acta 1984 , 87 , 185-191.
  • Redox Chemistry Associated With Electron-Rich Metal-Metal Triple Bonds. Kim R. Dunbar, Stephen M. Tetrick and Richard A. Walton, Abstracts of The International Conference on Coordination Chemistry 1984 , 487.
  • The Monocation and Monoanion of Re 2 (m-Cl) 2 (m-dppm) 2 Cl 4 (dppm = Ph 2 PCH 2 PPh 2 ). An Unusual Pair of Complexes possessing MetalMetal Bond Orders of 1.5 that differ in Electronic Configuration. Kim R. Dunbar, Douglas Powell and Richard A. Walton, J. Chem. Soc., Chem. Commun . 1985 , 114-116.
  • Cobaltocene Reductions of Multiply Bonded Dirhenium Complexes: Isolation, Characterization, and Reactivity Studies of [( h 5 -C 5 H 5 ) 2 Co][Re 2 (O 2 CR) 4 Cl 2 ], [( h 5 -C 5 H 5 ) 2 Co][Re 2 Cl 6 (PR 3 ) 2 ], and [( h 5 -C 5 H 5 ) 2 Co][Re 2 Cl 5 (PR 3 ) 3 ]. Kim R. Dunbar and R. A. Walton, Inorg. Chem . 1985 , 24 , 5-10.
  • Reactions of Re 2 Cl 4 (dppm) 2 with Carbon Monoxide That Proceed with Retention of the Metal-Metal Bond: Synthesis of Re 2 Cl 4 (dppm) 2 (CO) n ( n = 1,2) and the Structural Characterization of Cl 2 Re( m -Cl)( m -Co)( m -dppm) 2 ReCl(CO). F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Stephen M. Tetrick and Richard A. Walton, J. Am. Chem. Soc . 1985 , 107 , 3524-3530.
  • Redox Chemistry of a Pair of Complexes That Contain the Bridging Bis(diphenyl-phosphino)methane Ligand and the Re 2 6+ and Re 2 4+ Cores: Re 2 ( m -Cl) 2 ( m -dppm) 2 Cl 4 and [Re 2 ( m -dppm) 2 Cl 3 (NCR) 2 ]PF 6 (R = CH 3 , C 2 H 5 , C 6 H 5 ). Kim R. Dunbar, Douglas Powell and Richard A. Walton, Inorg. Chem . 1985 , 24 , 2842-2846.
  • Structural Characterization of the Triply Bonded Dirhenium(II) Complexes Re 2 Cl 4 ( m -Ph 2 PCH 2 PPh 2 ) 2 and a -Re 2 Cl 4 (Me 2 P(CH 2 ) 2 PMe 2 ). Timothy J. Barder, F. Albert Cotton, Kim R. Dunbar, Gregory L. Powell, Willi Schwotzer and Richard A. Walton, Inorg. Chem . 1985 , 24 , 2550-2554.
  • Reactions of the Dicarbonyl Complex Re 2 Cl 4 (dppm) 2 (CO) 2 with Nitriles and Isocyanides. Synthesis of [Re 2 Cl 3 (dppm) 2 (CO) 2 L] n + ( n = 0, 1; L = RCN, RNC) and the Structural Characterization of [Re 2 Cl 3 (dppm) 2 (CO) 2 (NCC 2 H 5 )]PF 6 . F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello and Richard A. Walton, Inorg. Chem . 1985 , 24 , 4180-4187.
  • Synthesis, Spectroscopy, and X-ray Structure of Os 2 Cl(chp) 4 : An Unusual Os 2 5+ Complex with a Polar Arrangement of 6-Chloro-2-hydroxypyridinato Ligands and One Axial Chloride. F. Albert Cotton, Kim R. Dunbar and Marek Matusz, Inorg. Chem . 1986 , 25 , 1585-1589.
  • Preparation And Structural Characterization Of Os 2 Cl 4 (Ph 2 Ppy) 2 (O 2 CCH 3 ): A Mixed-Ligand Compound With An Os 2 5+ Core And A Bond Order of 2.5. F. Albert Cotton, Kim R. Dunbar and Marek Matusz, Polyhedron 1986 , 5 , 903-905.
  • Preparation and Structural Characterization of Os 2 Cl 4 (chp) 2 (L) (chp = 6-Chloro-2-hydroxypyridinato; L = H 2 O, Pyridine): A New Class of M 2 X 4 (LL) 2 Complexes Possessing an Eclipsed Conformation Where LL Is a Substituted Hydroxypyridinato Ligand. F. Albert Cotton, Kim R. Dunbar and Marek Matusz, Inorg. Chem . 1986 , 25 , 1589-1594.
  • Reactions of the Dirhenium(II) Complexes Re 2 X 4 (dppm) 2 (X = Cl or Br; dppm = Ph 2 PCH 2 PPh 2 ) with Isocyanides. 3. Dinuclear Species Containing Two or Three Isocyanide Ligands. Lori Beth Anderson, Timothy J. Barder, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello and Richard A. Walton, Inorg. Chem . 1986 , 25 , 3629-3636.
  • Mixed Carbonyl-Isocyanide and Carbonyl-Nitrile Complexes Derived from the Reactions of the Multiply Bonded Dirhenium(II) Complexes Re 2 X 4 (dppm) 2 (CO) (X = Cl or Br; dppm = Ph 2 PCH 2 PPh 2 ). The Structural Characterization of Cl 2 Re( m -Cl)( m -dppm) 2 ReCl(CO) and Cl 2 Re( m -Cl)( m -CO)( m -dppm) 2 ReCl(CNxylyl). F. Albert Cotton, Kim R. Dunbar, Andrew C. Price, Willi Schwotzer and Richard A. Walton, J. Am. Chem. Soc . 1986 , 108 , 4843-4850.
  • The Multiply Bonded Octahalodiosmate(III) Anions. 2. Structure and Bonding. Pradyot A. Agaskar, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Stephen M. Tetrick and Richard A. Walton, J. Am. Chem. Soc . 1986 , 108 , 4850-4855.
  • Synthesis and Molecular Structure of Mo 2 I 4 (dppm) 2 ·2C 7 H 8 (dppm = Bis(diphenyl-phosphino)methane). F. Albert Cotton, Kim R. Dunbar and Rinaldo Poli, Inorg. Chem . 1986 , 25 , 3700-3703.
  • Quadruply Bonded Mo 2 I 4 (dppe) 2 (dppe = Bis(diphenylphosphino)ethane): Twisted and Eclipsed Rotational Conformations and Their Significance. F. Albert Cotton, Kim R. Dunbar and Marek Matusz, Inorg. Chem . 1986 , 25 , 3641-3649.
  • Isolation and Structure of Os 2 Cl 4 [(C 6 H 5 ) 2 P(C 6 H 4 )] 2 . An M 2 L 8 Compound with an Unprecedented Geometry and a Short Os-Os Bond. F. A. Cotton and Kim R. Dunbar, J. Am. Chem. Soc . 1987 , 109 , 2199-2200.
  • Conversion of an Electron-Rich Triple Bond to a Double Bond by Oxidative Addition of Diphenyl Diselenide to Re 2 Cl 4 ( m -dppm) 2 . Preparation and Characterization of Re 2 Cl 4 ( m -SePh) 2 ( m -dppm) 2 (dppm = Bis(diphenylphosphino)methane). F. Albert Cotton and Kim R. Dunbar, Inorg. Chem . 1987 , 26 , 1305-1309.
  • Isolation and Structure of the Novel Dirhodium(II) Compound Rh 2 (dmpm) 2 [(C 6 H 5 ) 2 P(C 6 H 4 )] 2 Cl 2 with Bridging Bis(dimethylphosphino)methane and Ortho-Metalated Triphenylphosphine Ligands. F. A. Cotton and Kim R. Dunbar, J. Am. Chem. Soc . 1987 , 109 , 3142-3143.
  • Reactions of the Dirhenium(II) Complexes Re 2 X 4 (dppm) 2 (X = Cl or Br; dppm = Ph 2 PCH 2 PPh 2 ) with Isocyanides. 4. Isomerism in Mixed Carbonyl-Isocyanide Complexes of Stoichiometry [Re 2 Cl 3 (dppm) 2 (CO) 2 (CNR)] n + ( n = 0 or 1) and [Re 2 Cl 3 (dppm) 2 (CO)(CNR) 2 ] + (R = t -Bu or Xylyl), Which Possess Edge-Shared Bioctahedral Structures. Lori Beth Anderson, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Andrew C. Price, Austin H. Reid and Richard A. Walton, Inorg. Chem . 1987, 26 , 2717-2725.
  • New Directions in the Chemistry of Dirhodium(II) Compounds. F. Albert Cotton, Kim R. Dunbar and Mark G. Verbruggen, J. Am. Chem. Soc . 1987 , 109 , 5498-5506.
  • Oxidative Addition to M-M Quadrulple Bonds. Preparation of New Edge-Sharing Bioctahedral Complexes of the Type (L-L)Cl 2 M( m -Cl) 2 MCl 2 (L-L) (M = Mo, W, L-L = 1,2-Bis(diphenyl-phosphino)ethane; M = Mo, L-L = 1-(Diethylphosphino)-2-(diphenylphosphino)ethane). P. A. Agaskar, F. A. Cotton, K. R. Dunbar, L. R. Falvello and C. J. O'Connor, Inorg. Chem . 1987 , 26 , 4051-4057.
  • Reactions of Rh 2 (O 2 CCH 3 ) 2 (C 6 H 4 PPh 2 ) 2 ·2CH 3 COOH with Chlorotrimethylsilane in the Presence of Monodentate Phosphines To Give [Rh 2 Cl 2 (C 6 H 4 PPh 2 ) 2 (PPh 3 ) 2 ] and [Rh 2 Cl 2 (C 6 H 4 PPh 2 ) 2 (PMe 3 ) 2 ]. F. Albert Cotton, Kim R. Dunbar and Cassandra T. Eagle, Inorg. Chem . 1987 , 26 , 4127-4130.
  • Oxidative-Addition Reactions of S-S and Se-Se Bonds to Mo 2 and W 2 Quadruple Bonds. Jo Ann M. Canich, F. Albert Cotton, Kim R. Dunbar and Larry R. Falvello, Inorg. Chem . 1988 , 27 , 804-811.
  • Spectroscopic and Structural Investigation of the Unbridged Dirhodium Cation [Rh 2 (CH 3 CN) 10 ] 4+ . K. R. Dunbar, J. Am. Chem. Soc . 1988 , 110 , 8247-8249.
  • Edge-Sharing Bioctahedral Molecules without Metal-Metal Bonds: The d 6 -d 6 Complexes Rh 2 X 4 (m-X) 2 ( m -dppm) 2 (X = Cl, Br). F. Albert Cotton, Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello and Andrew C. Price, Inorg. Chem. 1989 , 28 , 1754-1757.
  • Isolation, Structure, and Magnetic Properties of a Novel Mononuclear Rhodium(II) Complex. K. R. Dunbar, S. C. Haefner and L. E. Pence, J. Am. Chem. Soc. 1989 , 111 , 5504-5506.
  • Synthesis, Spectroscopic Studies, and Structure of an Unusual Dirhenium Complex with a Bridging Hydride Ligand. S. J. Chen and K. R. Dunbar, Inorg. Chem. 1990 , 29 , 529-534.
  • Synthesis and Characterization of Rh 2 (O 2 CCH 3 ) 3 [{C 6 H 2 (OMe) 3 } 2 P{C 6 H 2 (OMe) 2 O}](MeOH) with a Novel Tridentate Ligand Derived from Tris(2,4,6-trimethoxyphenyl)phosphine. S. J. Chen and K. R. Dunbar, Inorg. Chem. 1990 , 29 , 588-590.
  • Isolation and Structure of the Fluxional Phosphine Complex ( h 3 -PR 3 )Mo(CO) 3 (R = 2,4,6-Trimethoxyphenyl). K. R. Dunbar, S. C. Haefner and D. J. Burzynski, Organometallics 1990 , 9 , 1347-1349.
  • Synthesis And Characterization Of [{2,4,6-(CH 3 O) 3 C 6 H 2 } 3 P=O]FeCl 3 : A Four-Coordinate Phosphine Oxide Adduct Of FeCl 3 . Kim R. Dunbar, Steven C. Haefner and Anne Quillevéré, Polyhedron 1990 , 9 , 1695-1702.