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Our Publications

  • 2012-Present
    • Hydro-ionothermal syntheses, crystal structures, and proterties of five new divalent metal iminophosphonates. Andrey V. Prosvirin, Kim R. Dunbar, Simon J. Teat and Abraham Clearfield, Dalton Trans., 2012, 41, 3995-4006. DOI

    • A Mn(III) Chain Derived from Mn12-Acetate that Exhibits Both Glauber Dynamics and Antiferromagnetic Ordering Regimes. Andrey Prosvirin, Hanhua Zhao and Kim R. Dunbar, Inorg. Chim. Acta. (Jon Zubieta special issue), 2012, 389, 118-121. DOI

    • Solid State Coordination Chemistry of the Copper(II)/Pyridyl- and Pyrazine-Tetrazolate/Sulfate System. Kari Darling, Wayne Ouellette, Andrey Prosvirin, Steven Freund, Kim R. Dunbar, and Jon Zubiea, Cryst. Growth Des., 2012, 12, 2662-2672. DOI

    • Magnetic ordering in self-assembled materials consisting of cerium(III) ions and the radical forms of 2,5-TCNQX2 (X = Cl, Br). Maria Ballesteros-Rivas, Eric W. Reinheimer, Hanhua Zhao, Andrey Prosvirin, Ruben A. Toscano, Jesus Valdes-Martinez and Kim R. Dunbar, Angew. Chem. Int. Ed., 2012, 51, 5124-5128. DOI

    • Crystal-to-Crystal Transformation of Magnets Based on [Mo(CN)7]4- with Dramatic Changes in Coordination Mode and Ordering Temperature. Qing-Lun Wang, Heather Southerland, Jian-Rong Li, Andrey V. Prosvirin, Hanhua Zhao, and Kim R. Dunbar, Angew. Chem. Int. Ed., 2012, 51, 9321-9324. DOI

    • Excited State Dynamics of Ru(II) Cyclometallated Dyes: Relation to Cells for Solar Energy Conversion and Comparison to Conventional Systems. Bruno Pena, Nicholas Leed, Kim R. Dunbar, Claudia Turro, J. Phys. Chem. C., 2012, 116, 22186-22195. DOI

    • A Porous Sm(III) Coordination Nanotube with Hydrophobic and Hydrophilic Channels. Nazario Lopez, Hanhua Zhao, Dan Zhao, Hong-Cai Zhou, Joseph P. Riebenspies, and Kim R. Dunbar, Dalton Trans., 2013, 42, 54-57. DOI

    • Spin-Crossover Materials: Properties and Applications in "Charge Transfer-Induced Spin Transitions in Cyanometallate Materials", Chapter 6. "Malcolm Halcrow, Editor. Wiley-Blackwell. Kim R. Dunbar, Michael Shatruk, Catalina Achim, 2013, 171-202.

    • Energy Band Structure and Metal-Organic Interactions in Tetracyanoquinodimethane (TCNQ) and N,N'-Dicyanoquinonediimine (DCNQI) Materials. Hirotaka Kojima, Zhongyue Zhang, Kim R. Dunbar, and Takehiko Mori. J. Mater. Chem. C, 2013, 1, 1781-1790. DOI

    • Conducting Organic Frameworks Based on Main Group Element Cations and Organocyanide Radicals. Zhongyue Zhang, Hanhua Zhao, Hirotaka Kojima, Takehiko Mori, and Kim R. Dunbar, Chem. Eur. J., 2013, 19, 3348-3357. DOI

    • Supramolecular Architectures with π-acidic 3,6-Bis(2-pyridyl-1,2,4,5-Tetrazine Cavities: Role of Anion-π Interactions in the Remarkable Stability of Fe(II) Metallacycles in Solution. Helen T. Chifotides, Ian D. Giles, and Kim R. Dunbar, J. Am. Chem. Soc., 2013, 135, 3039-3055. DOI

    • Reversible Switching from Antiferro- to Ferromagnetic Behavior by Solvent-Mediated, Thermally-Induced Phase Transitions in a Trimorphic MOF-based Magnetic Sponge System. Mario Wriedt, Andrey A. Yakovenko, Gregory J. Hadler, Andrey Prosvirin, Kim R. Dunbar, and Hong-Cai Zhou, J. Am. Chem. Soc., 2013, 135, 4040-4050. DOI

    • An unprecedented double layered Fe36 phosphonate cage. Christine Beavers, Tina Tezgerevska, Andrey V. Prosvirin, John D. Cashion, Brendan F. Abrahams, Carmel Abrahams, Kim R. Dunbar, and Anne F. Richards, Inorg. Chem., 2013, 52, 1670-1672. DOI

    • STM Studies of Isolated Mn12-Ph Single-Molecule Magnets. K. Reaves, K. Kim, K. Iwaya, T. Hitosugi, Helmut G. Katzgraber, H. Zhao, K. R. Dunbar, and W. Teizer, SPIN, 2013, 3, 1350004. DOI

    • Anion-pi Interactions in Supramolecular Architectures. Helen T. Chifotides and Kim R. Dunbar, Acct. Chem. Res., 2013, 46, 894-906. DOI

    • Dinuclear and heptanuclear complexes of copper(II) with 7-azaindole ligand: Synthesis, characterization, magnetic properties, and biological activity. Jacob A. Przyojski, Nicole N. Myers, Hadi D. Arman, Andrey Prosvirin, Kim R. Dunbar, Sumathy Mohan, Manickam Krishnan, Judith A. Walmsley, 2013, J. Bioinorg. Chem., S0162-0134, 13, 00097-4. DOI

    • Photochemistry and DNA Photocleavage by a New Unsupported Dirhodium (II,II) Complex. Zhanyong Li, Scott Burya, Kim R. Dunbar, and Claudia Turro, Phil. Trans. R Doc A, (invited paper for the Royal Society Discussion Meeting on Phtoactivatable Metal Complexes), 2013, 371, 20120128. DOI

    • Cytotoxicity of Cyclometallated Ruthenium Complexes: The Role of Ligand Exchange on the Activity. Alycia Palmer, Bruno Pena, Bryan Sears, Olivia Chen, Randall P. Thummel, Kim R. Dunbar, and Claudia Turro, Phil. Trans. (invited paper for the Royal Society Discussion meeting on Photoactivatable Metal Complexes), 2013, 371, 20120135. DOI

    • Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II) = Co, Ni; tetrazole = 3- and 4- pyridyltetrazole and pyrazinetetrazole). K. Darling, W. Ouellette, A. Prosvirin, S. Walter, K. R. Dunbar, and J. Zubieta, Michelle Millar Special Issue, Polyhedron, 2013, 58, 18-29. DOI

    • A tetranuclear oxofluorovanadium(IV) cluster encapsulating a Na(H2O)n+ subunit. Tiffany M. Smith, Nika Mahne, Andrey Prosvirin, Kim R. Dunbar, and Jon Zubieta, Inorg. Chem. Commun., 2013, 33, 1-5. DOI

    • Cellular Toxicity Induced Through Photorelease of a Caged Bioactive Molecule: Design of Potential Dual-Action Ru(II) Complexes. Mark A. Sgambellone, Amanda David, Robert N. Garer, Kim R. Dunbar, and Claudia Turro, J. Am. Chem. Soc., 2013, 135, 11274-11282. DOI

    • One-Dimensional Square- and Ladder-Type Architectures Incorporating Octacyanometallates of Molybdenum(V) and Tungsten(V). Hanhua Zhao, Andrew J. Brown, Andrey V. Prosvirin, and Kim R. Dunbar, George Christou Special Issue, Polyhedron, 2013, 12, 321-327. DOI

    • A Single-Molecule Magnet Based on [MoIII(CN)7]4- with the Highest Energy Barrier for a Cyanide Compound. Kun Qian, Xing-Cai Huang, Chun Zhou, Xiao-Zeng You, Xin-Yi Wang, and Kim R. Dunbar, J. Am. Chem. Soc., 2013, 135, 13302-13305. DOI

    • A Neutral Fe(III) Compound Exhibiting A Two-Step Spin Transition and Dielectric Anomalies. Zhao-Yang Li, Jing-Wei Dai, Kevin J. Gagnon, Hong-Ling Cai, Takashi Yamamoto, Yasuaki Einaga, Han-hua Zhao, Shinji Kanegawa, Osamu Sato, Kim R. Dunbar, and Ren-Gen Xiong, Dalton Trans., 2013, 42, 14685-14688. DOI

    • Squaring the cube: A Family of Octametallic Lanthanide Complexes Including a Dy8 Single-Molecule Magnet, Ming Fang, Hanhua Zhao, Andrey V. Prosvirin, Dawid Pinkowicz, Kim R. Dunbar, Bin Zhao, Wei Shi, Peng Cheng, Wolfgang Wernsdorfer, and Euan K. Brechin. Dalton Trans., 2013, 42, 14693-14701. (Cover art article). DOI

    • Synthesis, X-ray Structure, Interactions with DNA, Remarkable in vivo Tumor Growth Suppression and Nephroprotective Activity ofcis-Tetrachloro-dipivalato Dirhenium(III). Natalia I. Shtemenko, Konstantin V. Domasevitch, Alexander A. Golichenko, Svetlana A. Babiy, Zhanyong Li, Katherina V. Paramonova, Alexander V. Shtemenko, Helen T. Chifotides, and Kim R. Dunbar, J. Inorg. Biochem., 2013, 129, 127-134. DOI

    • Unprecedented Partial Paddlewheel Dirhodium Methyl Isocyanide Compounds with Unusual Structural and Electronic Properties: A Comprehensive Experimental and Theoretical Study. Zhanyong Li, Helen T. Chifotides, and Kim R Dunbar, Chem. Sci., 2013, 4, 4470-4485. DOI

    • A New Metal-Organic Hybrid Material with Intrinsic Resistance-Based Bistability: Monitoring In Situ Room Temperature Switching Behavior. Zhongyue Zhang, Hanhua Zhao, Michio M. Matsushita, Kunio Awaga, and Kim R. Dunbar. J. Mater. Chem. C, 2014, 2, 399-404. DOI

    • Cadmium TCNQ-Based Semiconductor with Versatile Binding Modes and Non-Integer Redox States. Xuan Zhang, Zhongue Zhang, Hanhua Zhao, Jiang-Gao Mao, and Kim R. Dunbar. Chem. Commun., 2014, 1429-1431. DOI

    • Directional Charge Transfer and Highly Reducing and Oxidizing Excited States of New Dirhodium(II,II) Complexes: Potential Applications in Solar Energy Conversion. Zhanyong Li, Nicholas A. Leed, Nicole M. Dickson, Kim R. Dunbar, and Claudia Turro. Chem. Sci., 2014, 5, 727-737. (Edge Article). DOI

    • New Cyclometallated Ru(II) Complex for Potential Application in Photochemotherapy. Bryan A. Albani, Bruno Pena, Kim R. Dunbar and Claudia Turro, Photochem. Photobiol. Sci. 2014, 13, 272-280. click here

    • 3 Trigonal bipyramidal 5d-4f molecules with SMM behavior. Mohamed R. Saber and Kim R. Dunbar, Chem. Commun, 2014, 50, 2177-2179. click here

    • Cytotoxicity Studies of Cyclometallated Ru(II) Compounds: New Applications for Ruthenium Dyes. Bruno Pena, Amanda David, Jean-Phillipe Pellois, Claudia Turro and Kim R. Dunbar, Organometallics, 2014, 33, 1100-1103. click here

    • Variations in Topology and Magnetic Properties of Hepta- and Octacyanometallates of Molybdenum with Manganese (II). Quin-Lun Wang, Yuan-Zhu Zhang, Heather Southerland, Andrey V. Prosvirin, Hanhua Zhao and Kim R. Dunbar, Dalton. Trans, 2014, 43, 6802-6810. click here

    • Hydrothermal Synthesis, Structure and Magnetic Porperties of a Three-Dimensional Cobalt(II) Aminophenyltetrazolate Coordiantion Polymer. Tiffany M. Smith, Yuan-Zhu Zhang, Kim R. Dunbar and Jon Zubieta, Dalton Trans., 2014, 43, 7263-7268. click here

    • A Fast Metal-Metal Bonded Water Oxidation Catalyst. Sara Goberna-Ferron, Bruno Pena, Hanhua Zhao, Kim R. Dunbar and Jose Ramon Galan-Mascaros, J. Catal., 2014, 315, 25-32. click here

    • Confocal Fluorescence Microscopy Studies of a Fluorophore-labeled Dirhodium Compound: Visualizing Metal-Metal Bonded Molecules in Lung Cancer (A549) Cells. Bruno Pena, Rola Barhoumi, Robert C. Burghardt, Claudia Turro and Kim R. Dunbar, J. Am. Chem. Soc, 2014, 136, 7861-7864. click here

    • Magnetic Coupling between Divalent Metal Ions through the 7,7,8,8-Tetracyanoquinodimethane (TCNQ) Dianion. Mohamed R. Saber, Andrey V. Prosvirin, Brendan F. Abrahams, Robert W. Elliot, Richard Robson and Kim R. Dunbar, Chem Eur. J., 2014, 20, 7593-7597. click here

    • Record antiferromagnetic coupling for a 3d/4d cyanide bridged compound. Dawid Pinkowicz, Heather Southerland, Xin-Yi Wang and Kim R. Dunbar, J. Am. Chem. Soc., 2014, 136, 9922-9924. click here

    • Ligand effects on the magnetic anisotropy of tetrahedral cobalt complexes, Mohamed Saber and Kim R. Dunbar, Chem. Commun., 2014, 50, 12266-12269. click here

    • Isomerization Initiated by Photoinduced Ligand Dissociation in Ru(II) Complexes with the Ligand 2-p-tolylpyridinecarboxaldimine, Bryan A. Albani, Christopher B. Durr, Bruno Pena, Kim R. Dunbar, and Claudia Turro, Dalton Trans. (special issue), 2014, 43, 17828-17837. click here

    • Liposomes Loaded with a Dirhenium Compound and Cisplatin: Preparation, Properties and Improved in vivo Anticancer Activity, Zhanyong Li, Nataliia I. Shtemenko, Dina Y. Yegorova, Svetlana O. Babiy, Andrew J. Brown, Tinglu Yang, Aexander V. Shtemenko, and Kim R. Dunbar, Journal of Liposome Research, 2014, Sep 9:1-10. click here

    • Single-Chain Magnetic Behavior in a Hetero-Tri-Spin Complex Mediated by Supramolecular Interactions with TCNQF·- Radicals, Zhao-Xi Wang, Xuan Zhang, Yuan-Zhu Zhang, Ming-Xing Li, Hanhua Zhao, Marius Andruh, and Kim R. Dunbar, Angew. Chem. Int. Ed., 2014, 53, 11567-70. click here

    • Synthesis, Spectroscopic Properties, and Photoconductivity of Black Absorbers Consisting of Pt(Bipyridine)(Dithiolate) Charge Transfer Complexes in Presence and Absence of Nitrofluorenone Acceptors, Charles Browning, Joshua M. Hudson, Eric W. Reinheimer, Fang-Ling Kuo, Roy N. McDougald, Jr., Hassan Rabaa, Hongjun Pan, John Bacsa, Xiaoping Wang, Kim R. Dunbar, Nigel D. Shepherd, and Mohammed A. Omary, J. Am. Chem. Soc., 2014, 136, 16185-16200. click here

    • Marked Improvement in Photoinduced Cell Death by a New Tris-Heteroleptic Complex with Dual Action: Singlet Oxygen Sensitization and Ligand Dissociation, Bryan A. Albani, Bruno Pena, Nicholas N. Leed, Nataly A.B.G. de Paula, Christiane Pavani, Mauricia S. Baptista, Kim R. Dunbar, and Claudia Turro, J. Am. Chem. Soc., 2014, 136, 17095-17101. click here

    • Synthesis, Characterization, and Reactivity of Iron(III) Complexes Supported by a Trianionic ONO3- Pincer Ligand, Matias E. Pascualini, Natali V. Di Russo, Pedro A. Quintero, Annaliese A. Thuijs, Dawid Pinkowicz, Khalil A. Abboud, Kim R. Dunbar, George Christou, Mark W. Meisel, and Adam S. Veige, Inorg. Chem., 2014, 53, 13078-13088. click here

    • Optimizing the Electronic Properties of Photoactive Anticancer Oxypyridine Bridged Dirhodium(II,II) Complexes, Zhanyong Li, Amanda David, Bryan A. Albani, Jean-Philippe Pellois, Claudia Turro, and Kim R. Dunbar, J. Am. Chem. Soc., 2014, 136, 17058-17070. click here

    • A Single-Chain Magnet Tape Based on Hexacyanomanganate(III), Yuan-Zhu Zhang, Han-Hua Zhao, Edward Funck, and Kim R. Dunbar, Angew. Chem. Int. Ed., 2015, 54, 5583-5587. Selected for Hot Topics click here

    • A Trigonal-Pyramidal Erbium(III) Single-Molecule Magnet, Andrew J. Brown, Dawid Pinkowicz, Mohamed R. Saber, and Kim R. Dunbar, Angew. Chem. Int. Ed., 2015, 54, 5864-5868. Selected for Hot Topics click here

    • Strong Direct Magnetic Coupling in a Dinuclear CoII Tetrazine Radical Single-Molecule Magnet, Toby J. Woods, Maria Fernanda Ballesteros-Rivas, Serge click here

    • Synthesis of [CrIII(NCMe)6]3+ and [CrIII(NCMe)5F]2+. Submitted by Kendric J. Nelson and Joel S. Miller. Checked by Toby J. Woods and Kim R. Dunbar, Inorg. Synth, 2015, in press. click here

    • Metal-Organic Frameworks as Platforms for the Controlled Nanostructuring of Single-Molecule Magnets, Darpandeep Aulakh, Joshua B. Pyser, , Xuan Zhang, Andrey A. Yakovenko, Kim R. Dunbar, and Mario Wreidt, J. Am. Chem. Soc., 2015, 137, 9254-9257. click here

    • Group 9: Cobalt, Rhodium, and Iridium, Book Chapter in "Molecular Metal-Metal Bonds. Compounds, Synthesis, Properties", Editor, Stephen Liddle, Wiley, Helen Chifotides, Biswajit Saha, Kim R. Dunbar, and Jitendra K. Bera, 2015.

    • Structural Distortions of the Spin-Crossover Material [Co(pyterpy)2](TCNQ)2 Mediated by Supramolecular Interactions, Xuan Zhang, Haomiao Xie, Maria Ballesteros-Rivas, Zhao-Xi Wang, and Kim R. Dunbar, J. Mater. Chem. C, (invited paper), 2015, 3, 9292-9298. click here

    • A Dinuclear Ru(II) Complex Capable of Photoinduced Ligand Exchange at Both Metal Centers, B. A. Albani, B. Pena, S. Saha, A. Schaeffer, K. R. Dunbar and C. Turro, Chem. Commun., 2015, 51, 16522-16525. click here

    • Magnetic Ordering in TCNQ-Based Metal-Organic Frameworks With Host-Guest Interactions, Xuan Zhang, Mohamed R. Saber, Andrey P. Prosvirin, Joseph H. Reibenspies, Lei Sun, Maria Ballesteros-Rivas, Hanhua Zhao, Kim R. Dunbar submitted to themed issue on 'Molecular Magnetism' Inorganic Chemistry Frontiers, 2015, 2, 904-911. (invited paper) click here

    • Synthesis and X-ray crystal structure of the dirhenium complex Re2(i-C3H7CO2)4Cl2 and its interactions with the DNA purine nucleobases, Alexander V. Shtemenko, Helen T. Chifotides, Dina E. Yegorova, Natalia I. Shtemenko and Kim R. Dunbar, J. Inorg. Biochem., 2015, 153, 114-120. click here

    • A New Rh2(II,II) Architecture for the Catalytic Reduction of H+, Travis A. White, Suzanne E. Witt, Zhanyong Li, Kim R. Dunbar, and Claudia Turro, Inorg. Chem., 2015, 54, 10042-10048. click here

    • Cyanide Single Molecule Magnets Exhibiting Reversible, Solvent Dependent "On" and "Off" Exchange Bias Behavior. Dawid Pinkowicz, Heather I. Southerland, Carolina Avendano, Andrey Prosvirin, Wolfgang Wernsdorfer, Kasper S. Pedersen, Jan Dreiser, Rodolphe Clerac and Kim R. Dunbar, J. Am. Chem. Soc., 2015, 137, 14406-14422. click here


  • 2009-2011
    • Supermicroporous silica-based SiO2-Al2O3-NiO materials: Solid-state NMR, NMR relaxation and magnetic susceptibility. Vladimir I. Bakhmutov, Boris G. Shpeizer, Andrey V. Prosvirin, Kim R. Dunbar, and Abraham Clearfield Microporous and Mesoporous Materials 2009, 118, 78-86. DOI

    • Synthesis and structure of charge transfer salts of tetrathiafulvalene (TTF) and tetramethyl-TTF with 2,4,7-trinitro and 2,4,5,7-tetranitro-9-fluorenone. Eric W. Reinheimer, J.R. Galan-Mascaros, and Kim R. Dunbar Synth. Met. 2009, 159, 45-51. DOI

    • Cyanide-Bridged Complexes of Transition Metals: A Molecular Magnetism Perspective. Michael Shatruk, Carolina Avendano, and Kim R. Dunbar Prog. Inorg. Chem. 2009, 56, 155-334. DOI

    • Electric transport properties of Mn12-acetate films measured with self-assembling tunnelling junction. Lianxi Ma, Chi Chen, Glenn Agnolet, Jiacai Nie, Hanhua Zhao and Kim R Dunbar J. Phys. D: Appl. Phys. 2009, 42, 095104. DOI

    • Preface for the Forum on Molecular Magnetism: The Role of Inorganic Chemistry. Eugenio Coronado and Kim R. Dunbar Inorg. Chem. 2009, 48, 3293-3295. DOI

    • Trigonal-Bipyramidal Metal Cyanide Complexes: A Versatile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials. Kristen E. Funck, Matthew G. Hilfiger, Curtis P. Berlingutte, Michael Shatruk, Wolfgang Wernsdorfer, and Kim R. Dunbar Inorg. Chem. 2009, 48, 3438-3452. DOI

    • Redox-Regulated Inhibition of T7 RNA Polymerase via Establishment of Disulfide Linkages by Substituted Dppz Dirhodium(II,II) Complexes. J. Dafhne Aguirre, Helen T. Chifotides, Alfredo M. Angeles-Boza, Abdellatif Chouai, Claudia Turro, and Kim R. Dunbar Inorg. Chem. 2009, 48, 4435-4444. DOI

    • Water-Free Rare Earth-Prussian Blue Type Analogus: Synthesis, Structure, Computational Analysis, and Magnetic Data of {LnIII(DMF)6FeIII(CN)6} (Ln = Rare Earths Excluding Pm). Duane C. Wilson, Shengming Liu, Xunian Chen, Edward A. Meyers, Xiaoguang Bao, Andrey V. Prosvirin, Kim R. Dunbar, Christopher M. Hadad, and Sheldon G. Shore Inorg. Chem. 2009, 48, 5725-5735. DOI

    • Highly Anisotropic Exchange Interactions in a Trigonal Bipyramidal Cyanide-Bridged OsIII2NiII3 Cluster. Andrei V. Palii, Oleg S. Reu, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Matthew Hilfiger, Michael Shatruk, Andrey Prosvirin, and Kim R. Dunbar J. Phys. Chem. A. 2009, 113, 6886-6890. DOI

    • Molecules based on M(V) (M= Mo,W) and Ni(II) ions: a new class of trigonal bipyramidal cluster and confirmation of SMM behavior for the pentadecanuclear molecule {NiII[NiII(tmphen)(MeOH)]6[Ni(H2O)3]2-CN]30[WV(CN)3]6}. Matthew G. Hilfiger, Hanhua Zhao, Andrey Prosvirin, Wolfgang Wernsdorfer, and Kim R. Dunbar Dalton Trans. 2009, 5155-5163. DOI

    • A Thermally and Hydrolytically Stable Microporous Framework Exhibiting Single-Chain Magnetism: Structure and Properties of [Co2(H0.67bdt)3]·H2O. Wayne Oullette, Andrey V. Prosvirin, Kelly Whitenack, Kim R. Dunbar, and Jon Zubieta Angew. Chem. Int. Ed. 2009, 48, 2140 -2143. DOI

    • Live Cell Cytotoxicity Studies: Documentation of the Interactions of Antitumor Active Dirhodium Compounds with Nuclear DNA. J. Dafhne Aguirre, Alfredo M. Angeles-Boza, Abdellatif Chouai, Jean-Philippe Pellois, Claudia Turro, and Kim R. Dunbar J. Am. Chem. Soc 2009, 131, 11353-11360. DOI

    • Hydrogen Bonding and Sulfur-Sulfur Interactions in the Crystal Structure of the Radical-Cation Salt (BPDT-TTF)2[W6O19]. Eric W. Reinheimer , Marc Fourmigue, and Kim R. Dunbar J. Chem. Cryst. 2009, 39, 723-729. DOI

    • Crystal Structure of the Radical-Cation Salt (o-Me2TTF)I3 with Close Intermolecular Sulfur Contacts. Eric W. Reinheimer, Marc Fourmigue, and Kim R. Dunbar J. Chem. Cryst. 2009, 39, 735-739. DOI

    • Heterospin Single-Molecule Magnets Based on Terbium Ions and TCNQF4 Radicals: Interplay between Single-Molecule Magnet and Phonon Bottleneck Phenomena Investigated by Dilution Studies. Nazario Lopez, Andrey V. Prosvirin, Hanhua Zhao, Wolfgang Wernsdorfer, and Kim R. Dunbar Chem. Eur. J 2009, 15, 11390-11400. DOI

    • Charge-transfer two-dimensional layers constructed from a 2 : 1 assembly of paddlewheel diruthenium(II,II) complexes and bis[1,2,5]thiadizolotetracyanoquinodimethane: bulk magnetic behavior as a function of inter-layer interactions. N. Motokawa, T. Oyama, S. Matsunaga, H. Miyasaka, M. Yamashitaa and K. R. Dunbar Crystal Engineering - Special Issue on Molecular Magnetism 2009, 11, 2121-2130. DOI

    • On 29Si NMR relaxation as a structural criterion for studying paramagnetic supermicroporous silica-based materials: Silica-based materials incorporating Mn2+ ions into the silica matrix of SiO2-Al2O3-MnO. Vladimir I. Bakhmutov, Boris G. Shpeizer, Andrey V. Prosvirin, Kim R. Dunbar, and Abraham Clearfield Solid State Nuclear Mag. Res. 2009, 36, 129-136. DOI

    • Anticancer activity of heteroleptic diimine complexes of dirhodium: A study of intercalating properties, hydrophobicity and in cellulo activity. J. Dafhne Aguirre, Alfredo M. Angeles-Boza, Abdellatif Chouai, Claudia Turro, Jean-Philippe Pellois, and Kim R. Dunbar, sumbitted to Special issue Dalton Transactions on the Chemistry of Metal-Containing Anticancer Compunds Ed, Dr. J. Jumphrey; Guest Editor: Prof. P.J. Sadler 2009, 10806-10812. DOI

    • Cyanide Lability and Linkage Isomerism of Hexacyanochromate(III) Induced by the Co(II) Ion. Carolina Avendano, Ferdi Karadas, Matthew Hilfiger, Michael Shatruk, and Kim R. Dunbar Inorg. Chem. 2010, 49, 583-594. DOI

    • A homologous heterospin series of mononuclear lanthanide/TCNQF4 organic radical complexes. Nazario Lopez, Hanhua Zhao, Andrey V. Prosvirin, Wolfgang Wernsdorfer and Kim R. Dunbar Dalton Trans. 2010, 39, 4341-4352. DOI

    • Control of Charge Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials. Hitoshi Miyasaka, Natsuko Motokawa, Satoshi Matsunaga, Masahiro Yamashita, Kunihisa Sugimoto, Tatsuya Mori, Naoki Toyota and Kim R. Dunbar J. Am. Chem. Soc. 2010, 132, 1532-1544. DOI

    • Transition metal-alumina/silica supermicroporous composites with tunable porosity. Boris G. Shpeizera, Vladimir I. Bakhmoutov, Paul Zhang, Andrey V. Prosvirin, Kim R. Dunbar, Matthias Thommes, and Abraham Clearfield Colloids Surf. A: Physicochem. Eng. Aspects 2010, 357, 105-115. DOI

    • Use of a rhenium cyanide nanomagnet as a building block for new clusters and extended networks. Ferdi Karadas, Carolina Avendano, Matthew G. Hilfiger, Andrey V. Prosvirin and Kim R. Dunbar Dalton Trans. 2010, 39, 4968-4977. DOI

    • Cyanide-Bridged [CoII2MII] and [CoII2MII2] Complexes Based on the [CoII(triphos)(CN)2] Building Block: Syntheses, Structures, Magnetic Properties, and Density Functional Theoretical Studies. Ferdi Karadas, Michael Shatruk, Lisa M. Perez, Kim R. Dunbar Chem. Eur. J. 2010, 16, 4484-4486. DOI

    • Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3-. Xin-Yi Wang, Matthew G. Hilfiger, Andrey Prosvirin and Kim R. Dunbar Chem. Comm. 2010, 46, 4484-4486. DOI

    • A Docosanuclear {Mo8Mn14} Cluster Based on [Mo(CN)7]4-. Xin-Yi Wang, Andrey V. Prosvirin, Kim R. Dunbar Angew. Chem 2010, 122, 5207-5210. DOI

    • Photophysical Properties, DNA Photocleavage, and Photocytotoxicity of a Series of Dppn Dirhodium(II,II) Complexes. Lauren E. Joyce, J. Dafhne Aguirre, Alfredo M. Angeles-Boza, Abdellatif Chouai, Patty K.-L. Fu, Kim R. Dunbar, and Claudia Turro Inorg. Chem. 2010, 49, 5371-5376. DOI

    • Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru2]2TCNQ Charge-Transfer System. Natsuko Motokawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, and Kim R. Dunbar J. Am. Chem. Soc., 2010, 132, 11943-11951. DOI

    • Author Profile, K.R. Dunbar Angew. Chem. Int. Ed., 2010, 49, 5408-5409.
    • Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 Prussian Blue Analog. Carolina Avendano, Matthew G. Hilfiger, Andrey Prosvirin, Codi Sanders, Darryl Stepien, and Kim R. Dunbar J. Am. Chem. Soc., 2010, 132, 13123-13125. DOI

    • The π-Accepting Arene HAT(CN)6 as a Halide Receptor through Charge Transfer: Multisite Anion Interactions and Self-Assembly in Solution and the Solid State. Helen Chifotides, Brandi Schottel, and Kim R. Dunbar Angew. Chem. Int. Ed., 2010, 49, 7202-7207. DOI

    • Tetranuclear, Oxygen Centered Copper(II) Clusters Linked Together with Guanidine-Guanidinate Ligands. Gina M. Chiarella, Doris Y. Melgarejo, Andrey V. Prosvirin, Kim R. Dunbar, and John P. Fackler, Jr. J. Clust. Sci., 2010, 21, 551-565. DOI

    • Structural Studies of the 1:1 complex of o-3,4-Dimethyltetrathiafulvalene (o-Me2TTF) and 1,2,4,5-tetracyanobenzene (TCNB). Eric Reinheimer, Hanhua Zhao, and Kim R. Dunbar J. Chem Cryst., 2010, 40, 514-519. DOI

    • Light-Induced Excited Spin State Trapping and Charge Transfer in Trigonal Bipyramidal Cyanide-Bridged Complexes. Kristen E. Funck, Andrey Prosvirin, Corine Mathoniere, Rodolphe Clerac, and Kim R. Dunbar Inorg. Chem., 2011, 50, 2782-2789. DOI

    • Molecular Magnetic Materials Based on 4d and 5d Transition Metals. Xin-Yi Wang, Carolina Avendano, and Kim R. Dunbar Chem. Soc. Rev.(invited critical review), 2011, 40, 3213-2338. DOI

    • Beyond the spin model: Exchange coupling in molecular magnets with unquenched orbital angular momenta. Andrei Palii, Boris Tsukerblat, Sophia Klokishner, Kim R. Dunbar, Juan Modesto Clemente-Juan, Eugenio Coronado Chem. Soc. Rev. (invited critical review), 2011, 40, 3130-3156. DOI

    • Dramatically Different Conductivity Properties of Metal-Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room-Temperature Crystal-to-Crystal Phase Transition. Carolina Avendano, Zhongyue Zhang, Akira Ota, Hanhua Zhao, Kim R. Dunbar Angew. Chem., 2011, 50, 6543-6547. DOI

    • Layered, Two-Dimensional Hydrogen Bonding Nets in the Structure of the 1:1 Encounter Complex TMTTF-TCNB: Combined Structural and Spectroscopic Study. Eric W. Reinheimer , Maria Fernandez Ballesteros Rivas, Hanhua Zhao and Kim R. Dunbar J. Chem. Crystallogr., 2011, 41, 936-943. DOI

    • Conducting coordination polymers based on infinite M(4,4'-bpy) chains flanked by regular stacks of non-integer TCNQ radicals. Akira Ota, Maria Ballesteros Rivas, Eric Reinheimer, Andrey Prosvirin, and Kim R. Dunbar Angew. Chem. Int. Ed., 2011, 123, 9877-9881. (Hot Paper). DOI

    • A vibronic model for cooperative spin-crossover in pentanuclear{[MIII(CN)6]2[M'III(tmphen)2]3} (M/M' = Co/Fe, Fe/Fe) compounds. Ostrovsky, S.; Andrei Palii, A.; Sophia Klokishner, S.; Michael Shatruk, Funck, K.E.; Achim, C.; Dunbar, K.R.; Tsukerblat, B. J. Phys. Chem. C, 2011, 115, 21666-21667. DOI

    • [Ru(bpy)2(5CNU)2]2+ as a Potential Dual-Action PDT Agent. Robert N. Garner, Kim R. Dunbar, and Claudia Turro Inorg. Chem., 2011, 50, 9213-9215. DOI

    • Syntheses, Structural Characterization and Properties of Transition Metal Complexes of 5,5'-(1,4-phenylene)bis(1H-tetrazole) (H2bdt) and 5,5',5''-(1,3,5-phenylene)tris((1H-tetrazole) (H3btt). Wayne Ouellette, Kari Darling, Andrey Prosvirin, Kelly Whitenack, Kim R. Dunbar, and Jon Zubieta Dalton Trans., 2011, 40, 12288-12300. ("Dalton Transactions themed issue entitled: Self-Assembly in Inorganic Chemistry"). DOI

    • Anion-Templated Self-Assembly of Highly Stable Fe(II) Pentagonal Metallacycles with Short Anion-π Contacts. Ian D. Giles, Helen T. Chifotides, Michael Shatruk and Kim R. Dunbar Chem. Commun., 2011, 47, 12604-12606. DOI

    • Insight into the Reaction Pathway of DNA Model Chelates with Photoactivated cis-[Rh2-O2CCH3)2(CH3CN)6)2+. Helen T. Chifotides, Daniel A. Lutterman, Kim R. Dunbar and Claudia Turro, Inorg. Chem., 2011, 50, 12099-12107. DOI


  • 2007-2008
    • Lanthanide-3d cyanometalate chains Ln(III)-M(III) (Ln = Pr, Nd, Sm, Eu, Gd, Tb; M = Fe) with the tridentate ligand 2,4,6-tri(2-pyridyl)-1,3,5-triazine (tptz): evidence of ferromagnetic interactions for the Sm(III)-M(III) compounds (M = Fe, Cr). Hanhua Zhao, Nazario Lopez, Andrey Prosvirin, Helen T. Chifotides and Kim R. Dunbar Dalton Transactions 2007, 878-888. DOI

    • Self-assembly of a High-Nuclearity Chloride-Centered Copper(II) Cluster: Structure and Magnetic Properties of [Au(PPh3)2][trans-Cu6(CF3)2pz)6(OH)6Cl]. Ahmed A. Mohamed, Alfredo Burini, Rossana Galassi, Daniele Paglialunga, Jose-Ramon Galan-Mascaros, Kim R. Dunbar, and John P. Fackler, Jr. Inorg. Chem. 2007, 46, 2348-2349. DOI

    • Properties of Prussian Blue Materials Manifested in Molecular Complexes: Observation of Cyanide Linkage Isomerism and Spin-Crossover Behavior in Pentanuclear Cyanide Clusters. Mikhail Shatruk, Alina Dragulescu-Andrasi, Kristen E. Chambers, Sebastian A. Stoian, Emile L. Bominaar, Catalina Achim, and Kim R. Dunbar J. Am. Chem. Soc. 2007, 129, 6104-6116. DOI

    • Synthesis and Characterization of Four Metal-Organophosphonates with One-, Two-, and Three-Dimensional Structures. Sanjit Konar, Jerzy Zon, Andrey V. Prosvirin, Kim R. Dunbar, and Abraham Clearfield* Inorg. Chem. 2007, 46, 5229-5236. DOI

    • Systematic Investigation of Trigonal-Bipyramidal Cyanide-Bridged Clusters of the First-Row Transition Metals. Mikhail Shatruk, Kristen E. Chambers, Andrey V. Prosvirin, and Kim R. Dunbar Inorg. Chem. 2007, 46, 5155-5165. DOI

    • Enhanced alignment of Mn12-acetate micro-crystals. D. Seo, W. Teizer, H. Zhao, K.R. Dunbar Journal of Magnetism and Magnetic Materials 2007, 312, 205-209. DOI

    • A Family of Mixed-Metal Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism. Eric J. Schelter, Ferdi Karadas, Carolina Avendano, Andrey V. Prosvirin, Wolfgang Wernsdorfer, and Kim R. Dunbar J. Am. Chem. Soc 2007, 129, 8139-8149. DOI

    • Variation of Heterometallic Structural Motifs Based on [W(CN)8]33- Anions and MnII Ions as a Function of Synthetic Conditions. Hanhua Zhao, Mikhail Shatruk, Andrey V. Prosvirin, and Kim R. Dunbar Chem. Eur. J. 2007, 13, 6573-6589. DOI

    • Hydrothermal Synthesis, Structural Chemistry, and Magnetic Properties of Materials of the MII/Triazolate/Anion Family, Where MII = Mn, Fe, and Ni. Wayne Oullette, Andrey V. Prosvirin, Jamie Valeich, Kim R. Dunbar, and Jon Zubieta Inorg. Chem. 2007, 46, 9067-9082. DOI

    • Conversion of a porous material based on a MnII-TCNQF4 honeycomb net to a molecular magnet upon desolvation. Nazario Lopez, Hanhua Zhao, Andrey V. Prosvirin, Abdellatif Chouai, Michael Shatruk and Kim R. Dunbar Chem. Comm. 2007, 4611-4613. DOI

    • Effect of Axial Coordination on the Electronic Structure and Biological Activity of Dirhodium(II,II) Complexes. J. Dafhne Aguirre, Daniel A. Lutterman, Alfredo M. Angeles-Boza, Kim R. Dunbar, and Claudia Turro. Inorg. Chem. 2007, 46, 7494-7502. DOI

    • Unprecedented Head-to-Head Right-Handed Cross-Links between the Antitumor Bis(i-N,N,-di-p-tolylformamidinate) Dirhodium(II,II) Core and the Dinucleotide d(ApA) with the Adenine Bases in the Rare Imino Form. Helen T. Chifotides and Kim R. Dunbar J. Am. Chem. Soc. 2007, 129, 12480-12490. DOI

    • Magnetic anisotropy in the octanuclear (Re4Mn4)-MnII cluster exhibiting Single-Molecule Magnet behavior: Quantum-spin and classical-spin approaches. A.V. Palii, S.M. Ostrovsky, S.I. Klokishner, B.S. Tsukerblat, E.J. Schelter, A.V. Prosvirin, and K.R. Dunbar Inorg. Chim. Acta. 2007 360, 3915-3924.

    • Effects of vibronic interaction in cyano-bridged clusters containing Mn(III) and Mn(II) ions. S.M. Ostrovsky, S.I. Klokishner, A.V. Palii, and K.R. Dunbar. J. Mol. Structure 2007, 838, 138-143. DOI

    • Nanopatterning of Mn12-acetate single-molecule magnet films. K. Kim, A. Ford, V. Meenakshi, W. Teizer, H. Zhao and K. R. Dunbar J. Appl. Phys 2007, 102, 094306:1-5. DOI

    • Anion-π interactions: A Tutorial Review. Brandi L. Schottel, Helen T. Chifotides and Kim R. Dunbar Chem. Soc. Rev. 2008, 37, 68-83. DOI

    • 2D NMR Study of the DNA Duplex d(CTCTC*A*ACTTCC)ad(GGAAGTTGAGAG) Cross-Linked by the Antitumor-Active Dirhodium(II,II) Unit at the Cytosine-Adenine Step. Mijeong Kang, Helen T. Chifotides, and Kim R. Dunbar Biochemistry 2008, 47, 2265-2276. DOI

    • Molybdophosphonate Clusters as Building Blocks in the Oxomolybdate-Organodiphosphonate/Cobalt(II)-Organoimine System: Structural Influnces of Secondary Metal Coordination Preferences and Diphosphonate Tether Lengths. N. Gabriel Armatas, Damian G. Allis, Andrew Prosvirin, Gabriel Carnutu, Charles J. O'Connor, Kim Dunbar, and Jon Zubieta Inorg. Chem. 2008, 47, 832-854.

    • Intercalation Is Not Required for DNA Light-Switch Behavior. Daniel A. Lutterman, Abdellatif Chouai, Yao Liu, Yujie Sun, Cristina D. Stewart, Kim R. Dunbar, and Claudia Turro J. Am. Chem. Soc. 2008, 130, 1163-1170. DOI

    • Role of Axial Donors in the Ligand Isomerization Processes of Quadruply Bonded Dimolybdenum(II) Compounds. Moumita Majumdar, Sanjib K. Patra, Mukundamurthy Kannan, Kim R. Dunbar, and Jitendra K. Bera Inorg. Chem. 2008, 47, 2212-2222. DOI

    • A Family of Cyanide-Bridged Molecular Squares: Structural and Magnetic Properties of [{MIICl2}2{CoII(triphos)(CN)2}2]·xCH2Cl2, M = Mn, Fe, Co, Ni, Zn. Ferdi Karadas, Eric J. Schelter, Michael Shatruk, Andrey V. Prosvirin, John Bacsa, Dmitry Smirnov, Andrew Ozarowski, J. Krzystek, Joshua Telser, and Kim R. Dunbar Inorg. Chem. 2008, 47, 2074-2082. DOI

    • A series of stable salts of the oxidized donors TTF, o-Me2TTF, TMTTF, and TTF(SCH2CH2CN)4. Eric W. Reinheimer, Hanhua Zhao, and Kim R. Dunbar Synth. Met. 2008 158 447-452. DOI

    • A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase. Natsuko Motokawa,Tomomi Oyama, Satoshi Matsunaga, Hitoshi Miyasaka, Kunihisa Sugimoto, Masahiro Yamashita, Nazario Lopez and Kim R. Dunbar Dalton Trans. 2008, 4099-4102. DOI

    • A series of strongly one-dimensional organic metals with strictly uniform stacks: (o-DMTTF)2X (X = Cl, Br, I). Marc Fourmigue, Eric W. Reinheimer, Kim R. Dunbar, Pascale Auban-Senzier, Claude Pasquier, and Claude Coulon Dalton Trans. 2008, 4652-4658. DOI

    • An Electron-Transfer Ferromagnet with Tc=107 K Based on a Three- Dimensional [Ru2]2/TCNQ System. Natsuko Motokawa, Hitoshi Miyasaka, Masahiro Yamashita, and Kim R. Dunbar Angew. Chem. Int. Ed. 2008, 47, 7760-7763. DOI

    • Head-to-Head Right-Handed Cross-Links of the Antitumor-Active Bis(µ-N,N'-di-p-tolylformamidinato)dirhodium(II,II) Unit with the Dinucleotides d(GpA) and d(ApG). Helen T. Chifotides and Kim R. Dunbar Chem. Eur. J. 2008, 14, 9902-9913. DOI

    • Hexacyanoosmate(III) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian Blue analogue with Ni(II). Matthew G. Hilfiger, Michael Shatruk, Andrey Prosvirina and Kim R. Dunbar Chem. Comm. 2008, 5752-5754. DOI

    • Radical salts of TTF derivatives with the metal-metal bonded [Re2Cl8]2- anion. Eric W. Reinheimer, Jose R. Galan-Mascaros, Carlos J. Gomez-Garcia, Hanhua Zhao, Marc Fourmigue, and Kim R. Dunbar J. Mol. Structure, Special Issue dedicated to F.A. Cotton 2008, 890, 81-89. DOI

    • A Highly Anisotropic Cobalt(II)-Based Single-Chain Magnet: Exploration of Spin Canting in an Antiferromagnetic Array. Andrei V. Palii, Oleg S. Reu, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Zhong-Ming Sun, Jiang-Gao Mao, Andrey V. Prosvirin, Han-Hua Zhao, and Kim R. Dunbar J. Am. Chem. Soc. 2008, 130, 14729-14738. DOI

    • Ultrafast Ligand Exchange: Detection of a Pentacoordinate Ru(II) Intermediate and Product Formation. Yao Liu, David B. Turner, Tanya N. Singh, Alfredo M. Angeles-Boza, Abdellatif Chouai, Kim R. Dunbar, and Claudia Turro J. Am. Chem. Soc. 2009, 131, 26-27. DOI

    • After 118 years, the isolation of two common radical anion reductants as simple, stable solids. Thomas A. Scott, Betty A. Ooro, David J. Collins, Michael Shatruk, Andrey Yakovenko, Kim R. Dunbar and Hong-Cai Zhou Chem. Comm. 2009, 65-67. DOI


  • 2005-2006
    • Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): Isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2. Brandi L. Schottel, John Bacsa and Kim R. Dunbar Chem. Comm. 2005, 46-47. DOI

    • catena-Poly[[diaquacobalt(II)]-µ-oxalato]. John Bacsa, Desmond Eve and Kim R. Dunbar Acta Cryst. 2005, C61, m58-m60. DOI

    • Covalent Binding and Interstrand Cross-Linking of Duplex DNA by Dirhodium (II,II) Carboxylate Compounds. Shari U. Dunham, Helen T. Chiforides, Sdzymon Mikulski, Amity E. Burr and Kim R. Dunbar Biochemistry 2005, 44, 996-1003. DOI

    • Interactions of Metal--Metal-Bonded Antitumor Active Complexes with DNA Fragments and DNA. Helen T. Chifotides and Kim R. Dunbar Acc. Chem. Res. 2005, 38, 146-156. DOI

    • A high spin molecular square based on square pyramidal CoII and tetrahedral MnII centers: [{MnIICl2}2{CoII(triphos)(CN)2}2]. Ferdi Karadas, Eric J. Schelter, Andrey V. Prosvirin, John Bacsa and Kim R. Dunbar Chem. Comm. 2005, 1414-1416. DOI

    • Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substitunts. Eric J. Schelter, Mikhail Shatruk, Robert A. Heintz, Jose Ramon Galan-Mascaros and Kim R. Dunbar Chem. Comm. 2005, 1417-1419. DOI

    • New type of single chain magnet based on spin canting in an antiferromagnetically coupled Co(II) chain. Zhong-Ming Sun, Andrey V. Prosvirin, Han-Hua Zhao, Jiang-Gao Mao and Kim R. Dunbar J. Appl. Phys. 2005, 97, 10B305-1-10B305-3. DOI

    • A Charge-Transfer-Induced Spin Transition in a Discrete Complex: The Role of Extrinsic Factors in Stabilizing Three Electronic Isomeric Forms of a Cyanide-Bridged Co/Fe Cluster. Curtis P. Berlingutte, Alina Dragulescu-Andrasi, Andreas Sieber, Hans-Ulrich Gudel, Catalina Achim and Kim R. Dunbar J. Amer. Chem. Soc. 2005, 207, 6766-6779. DOI

    • The Step-Wise Assembly of Undecanuclear Heterotrimetallic Cyanide Cluster. Curtis P. Berlingutte, Kim R. Dunbar. Chem. Comm. 2005, 2451-2453. DOI

    • Structural and magnetic properties of iron(II) complexes with 1,4,5,8,9,12-hexaazatriphenylene (HAT). Mikhail Shatruk, Abdellatif Chouai, Andrey V. Prosvirin and Kim R. Dunbar Dalton Trans. 2005, 1897-1902. DOI

    • Manganese(II) chemistry of a new N3O-donor chelate ligand: synthesis, X-ray structures, and magnetic properties of solvent- and oxalate-bound complexes. Amy L. Fuller, Rex W. Watkins, Kim R. Dunbar, Andrey V. Prosvirin, Atta M. Arifc and Lisa M. Berreau. Dalton Trans. 2005, 1891-1896. DOI

    • Control of the Barrier in Cyanide Based Single Molecule Magnets Mn(III)2Mn(II)3: Theoretical Analysis. Boris S. Tsukerblat,* Andrew V. Palii,* Sergei M. Ostrovsky, Sergei V. Kunitsky, Sophia I. Klokishner, and Kim R. Dunbar* J. Chem. Theory Comput. 2005, 1, 668-673. DOI

    • Chemical Control of the DNA Light Switch: Cycling the Switch ON and OFF. Yao Liu, Abdellatif Chouai, Natalya N. Degtyareva, Daniel A. Lutterman, Kim R. Dunbar, Claudia Turro J. Am. Chem. Soc. 2005, 127, 10796-10797. DOI

    • Ruthenium(II) Complexes of 1,12-Diazaperylene and Their Interactions with DNA. Abdellatif Chouai, Sara E. Wicke, Claudia Turro,* John Bacsa, Kim R. Dunbar, Dong Wang, and Randolph P. Thummel* Inorg. Chem. 2005, 44, 5596-6003. DOI

    • Anion Template Effect on the Self-Assembly and Interconversion of Metallacyclophanes. Cristian Saul Campos-Fernandez, Brandi L. Schottel, Helen T. Chifotides, Jitendra K. Bera, John Bacsa, John M. Koomen, David H. Russell, and Kim R. Dunbar J. Am. Chem. Soc. 2005, 127, 12909-12923. DOI

    • Synthesis, crystal structures and magnetic properties of two new coordination polymers based on the tricyanoethenolate ligand: {Fe(C5N3O)2(CH3CN)2}, and {Co(C5N3O)2(C4H4O)2}. Hanhua Zhao, John Bacsa, Andrey Prosvirin, Nazario Lopez and Kim R. Dunbar Polyhedron 2005, 24, 1907-1912. DOI

    • Photocytotoxicity of a New Rh2(II,II) Complex: Increase in Cytotoxicity upon Irradiation Similar to That of PDT Agent Hematoporphyrin. Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L. Fu, Mikhail Shatruk, Matthew G. Hilfiger, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2005, 44, 7262-7264. DOI

    • *Self-Assembled Inorganic Architectures. Jitendra K. Bera, John Bacsa and Kim R. Dunbar Encyclopedia of Inorganic Chemistry, Second Edition (Ed. R. Bruce King), John Wiley & Sons, Inc., 2005.

    • Hydrothermal Synthesis and Structure of a Three-Dimensional Cobalt(II) Triazolate Magnet. Wayne Oullette, Jose R. Galan-Mascaros, Kim R. Dunbar and Jon Zubieta Inorg. Chem. 2006, 45, 1909-1911. DOI

    • Enhanced Magnetic Anisotrophy of Mn12-Acetate. D.M. Seo, V. Meenakshi, W. Teizer, H. Zhao and K. R. Dunbar Journal of Magnetism and Magnetic Materials 2006, 301, 31-36. DOI

    • Coarse and Fine Tuning of the Electronic Energies of Triimineplatinum (II) Square-Planar Complexes. Wei-Hsuan Chen, Eric W. Reinheimer, Kim R. Dunbar and Mohammed A. Omary Inorg. Chem. 2006, 45, 2770-2772. DOI

    • Highly Anisotropic Orbitally-Dependent Superexchange in Cyano-Bridged Clusters Containing Mn(III) and Mn(II) Ions. Boris Tsukerblat, Andrew Palii, Sergey Ostrovsky, Sophia Klokishner, Boris Tsukerblat, Kim R. Dunbar ChemPhysChem 2006, 7, 871-879. DOI

    • Anion-π Interactions as controlling elements in Self-Assembly Reactions of Ag(I) Complexes with Acidic Aromatic Rings. Brandi Schottel, Helen Chifotides, Mikail Shatruk, Abdellatif Chouai, Lisa Perez, John Bacsa, Kim R. Dunbar J. Am. Chem. Soc. 2006, 128, 5895-5912. DOI

    • Influnce of anions on the dimensionality of extended networks based on Cu cations and 1, 4, 5, 8, 9, 12-hexaazatriphenylene (HAT) ligands. Mikhail Shatruk, Abdellatif Chouai and Kim R. Dunbar Dalton Transactions 2006, 2184-2191. DOI

    • Syntheses and reactivity studies of solvated dirhenium acetonitrile complexes. Jitendra K. Bera, Eric J. Schelter, Sanjib K. Patra, John Bacsa and Kim R. Dunbar Dalton Transactions 2006, 4011-4019. DOI

    • Syntheses, Structural Studies, and Magnetic Properties of Divalent Cu and Co Selenites with Organic Constitunts. Mei-Ling Feng, Andrey V. Prosvirin, Jiang-Gao Mao, and Kim R. Dunbar Chem. Eur. J. 2006, 12, 8312-8323. DOI

    • Head-to-Head Cross-Linked Adduct between the Antitumor Unit Bis(µ-N,N'-di-p-tolylformamidinato)dirhodium(II,II) and the DNA Fragment d(GpG). Helen T. Chifotides and Kim R. Dunbar Chem. Eur. J. 2006, 12, 6458 -6468. DOI

    • Long-Range Ordered Magnet of a Charge-Transfer Ru24+/TCNQ Two-Dimensional Network Compound. Hitoshi Miyasaka, Toru Izawa, Nao Takahashi, Masahiro Yamashita and Kim R. Dunbar J. Am. Chem. Soc. 2006, 128, 11358-11359. DOI

    • Magnetic Relaxation and Magnetic Moment of Mn12-acetate film material. D. M. Seo, V. Meenakshi, W. Teizer, H. Zhao, and K. R. Dunbar AIP Conference Proceedings of the 24th International Conference on Low Temperature Physics 2006, 850, 1137-1138.

    • 2D NMR Spectroscopic Evidence for Unprecedented Interactions of cis-[Rh2(dap)-µ-O2CCH3)21-O2CCH3)(CH3OH)](O2CCH3) with a DNA Oligonucleotide: Combination of Intercalative and Coordinative Binding. Mijeong Kang, Abdellatif Chouai, Helen T. Chifotides, and Kim R. Dunbar Angew. Chem. Int. Ed. 2006, 45, 6148 -6151. DOI

    • Solid-State Coordination Chemistry of the Cu/Triazolate/X System (X = F-, Cl-, Br-, I-, OH-, and SO42-). Wayne Oullette, Andrey V. Prosvirin, Vincent Chieffo, Kim R. Dunbar, Bruce Hudson, and Jon Zubieta Inorg. Chem. 2006, 45, 9346-9366. DOI

    • A series of complexes of the phosphorus-based TTF ligand o-P2 with the metal ions FeII, CoII, NiII, PdII, PtII, and AgI. Calvin E. Uzelmeier, Bradley W. Smucker, Eric W. Reinheimer, Mikhail Shatruk, Amanda W. O'Neal, Marc Fourmigu, Kim R. Dunbar Dalton Transactions 2006, 5259-5268. DOI

    • Dirhodium(II,II) Complexes: Molecular Characteristics that Affect in Vitro Activity. Alfredo M. Angeles-Boza, Helen T. Chifotides, J. Dafhne Aguirre, Abdellatif Chouai, Patty K.-L. Fu, Kim R. Dunbar, and Claudia Turro, J. Med. Chem. 2006, 49, 6841-6847. DOI

    • Origin of the Single Chain Magnet Behavior of the Co(H2L)(H2O) Compound with a 1D Structure. Andrei V. Palii, Sergei M. Ostrovsky, Sophia I. Klokishner, Oleg S. Reu, Zhong-Ming Sun, Andrei V. Prosvirin, Han-Hua Zhao, Jiang-Gao Mao and K. R. Dunbar J. Phys. Chem. A 2006, 110, 14003-14012. DOI


  • 2003-2004
    • Deuterium isotope effects and fractionation factors of hydrogen-bonded A:T base pairs of DNA. Ioannis Vakonakis, Migul Salazar, Mijeong Kang, Kim R. Dunbar and Andy C. LiWang J. of Biomolecular NMR 2003, 25, 105-112. DOI

    • Synthesis, X-ray Studies and Magnetic Properties of Dinuclear NiII and CuII Complexes Bridged by the Azo-2,2,-bipyridine Ligand. Cristian S. Campos-Fernandez, Jose-Ramon Galan-Mascaros, Bradley W. Smucker and Kim R. Dunbar Eur. J. Inorg. Chem. 2003, 988-994. DOI

    • A Rare-Earth Metal TCNQ Magnet: Synthesis, Structure, and Magnetic Properties of {[Gd2(TCNQ)5(H2O)9][Gd(TCNQ)4(H2O)3]}·H2O. Hanhua Zhao, Mervin J. Bazile, Jr., Jose-Ramon Galan-Mascaros and Kim R. Dunbar Angew. Chem. Int. Ed. 2003, 42, 1015-1018. DOI

    • Isolation of the Novel Dirhodium (II/II) Thiolate Compound Rh21-C6H5S)2-C6H5S)2(bpy)2. Karn Sorasnee, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Inorg. Chem. 2003, 42, 661-663. DOI

    • Inhibition of Transcription in Vitro by Anticancer Active Dirhodium(II) Complexes. Karn Sorasaenee, Patty K.-L. Fu, Alfredo M. Angeles-Boza, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2003, 42, 1267-1271. DOI

    • A Trigonal-Bipyramidal Cyanide Cluster with Single-Molecule-Magnet Behavior: Synthesis, Structure, and Magnetic Properties of {[Mn11(tmphen)2]3[Mn11(CN)6]2. Curtis P. Berlingutte, Derek Vaughn, Cristina Canada-Vilalta, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Angew. Chem. Int. Ed. 2003, 42, 1523-1526. DOI

    • A Self-Assembled 2D Molecule-Based Magnet: The Honeycomb Layered Material {Co3Cl4(H2O)2[Co(Hbbiz)3]2}. Jose-Ramon Galan-Mascaros and Kim R. Dunbar Angew. Chem. Int. Ed. 2003, 42, 2289-2293. DOI

    • Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ)2 (M = Mn, Fe, Co., Ni). Rodolphe Clerac, Shannon O'Kane, Jerry Cowen, Xiang Ouyang, Robert Heintz, Hanhua Zhao, Mervin J. Bazile, Jr. and Kim R. Dunbar Chem. Mater. 2003, 15, 1840-1850. DOI

    • Recognition of Topological Isomerism: Synthesis, Strucutre, and Magnetic Properties of Two Pentanuclear High-Spin Molecules of the Type [NiII(N-N)2]3[FeIII(CN)6]2. Curtis P. Berlingutte, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Inorg. Chem. 2003, 42, 3416-3422. DOI

    • Structural, electronic and magnetic properties of metal-metal bonded dinuclear rhenium complexes bridged by organocyanide acceptor ligands. Stuart L. Bartley, Mervin J. Bazile, Jr., Rodolphe Clerac, Hanhua Zhao, Xiang Ouyang and Kim R. Dunbar Dalton Trans. 2003, 2937-2944. DOI

    • Magnetic properties of complex d1 and d5 ions: crystal field model and Jahn-Teller effect. Kim R. Dunbar, Eric J. Schelter, Boris S. Tsukerblat, Sergei M. Ostrovsky, Vadim Yu. Mirovitsky and Andrew V. Palii Polyhedron, 2003, 22, 2545-2556. DOI

    • Structural, Magnetic, and Optoelectronic Properties of (Diimine)(dithiolato)platinum(II) and -palladium(II) Complexes and Their Charge-Transfer Adducts with Nitrile Acceptors. Bradley W. Smucker, Joshua M. Hudson, Mohammad A. Omary and Kim R. Dunbar Inorg. Chem. 2003, 42, 4714-4723. DOI

    • Unprecedented Head-to-Head Conformers of d(GpG) Bound to the Antitumor Active Compound Tetrakis (µ-carboxylato)dirhodium(II,II). Helen T. Chifotides, Karl M. Koshlap, Lisa M. Perez and Kim R. Dunbar J. Am. Chem. Soc. 2003, 125, 10703-10713. DOI

    • Novel Binding Interactions of the DNA Fragment d(pGpG) Cross-Linked by the Antitumor Active Compound Tetrakis(µ-carboxylato)dirhodium(II,II). Helen T. Chifotides, Karl M. Koshlap, Lisa M. Perez and Kim R. Dunbar J. Am. Chem. Soc. 2003, 125, 10714-10724. DOI

    • New Paramagnetic Re(II) Compounds with Nitrile and Cyanide Ligands Prepared by Homolytic Scission of Dirhenium Complexes. Eric J. Schelter, Jitendra K. Bera, John Bacsa, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Inorg. Chem. 2003, 42, 4256-4258. DOI

    • Hydrogen-bonding as a tool for building one-dimensional structures based on dimetal building blocks. Jitendra K. Bera, Thanh-Trang Vo, Richard A. Walton and Kim R. Dunbar Polyhedron 2003, 22, 3009-3014.

    • Structural evidence for monodentate binding of guanine to the dirhodium(II,II) core in a manner akin to that of cisplatin. Helen T. Chiforides, Jennifer S. Hess, Alfredo M. Angeles-Boza, Jose-Ramon Galan-Mascaros, Karn Sorasaenee and Kim R. Dunbar Dalton Trans. 2003, 4426-4430. DOI

    • Magnetic Properties of a Low-Symmetry d5 Complex-Adiabatic Pseudo Jahn-Teller Problem. Kim R. Dunbar, Eric J. Schelter, Boris S. Tsukerblat, Andrei V. Palii, Sergei M. Ostrovsky, Vadim Yu. Mirovitskii, Sophia I. Klokishner Adv. Quantum Chem. 2003, 44, 414-428. DOI

    • Two new soluble iron-oxo complexes: [Fe2-O)(µ-O2CCF3)2(O2CCF3)2(C10H8N2)2] and [Fe43-O)2-O2CCF3)6(O2CCF3)2(C10H8N2)2]·CF3CO2H. John Bacsa, Hanhua Zhao and Kim R. Dunbar Acta Cryst. 2003, C59, m561-m564. DOI

    • Synthesis, Characterization, and Physical Properties of Two Trinuclear, Mixed-Valence Species of Type [µ3-OMnIIMnIII2(O2CCF3)6(R)3] (R=H2O, CH3COOH). Hanhua Zhao, Curtis P. Berlingutte, John Bacsa, Shane E. Tichy and Kim R. Dunbar J. Cluster Science 2003, 14, 235-252. DOI

    • *Unusual Magnetic Behavior of Six-Coordinate, Mixed-Ligand Re(II) Complexes: Origin of a Strong Temperature-Independent Paramagnetism. Kim R. Dunbar, Eric J. Schelter, Andrei V. Palii, Sergei M. Ostrovsky, Vadim Yu. Mirovitskii, Joshua M. Hudson, Mohammad A. Omary, Sophia I. Klokishner and Boris S. Tsukerblat J. Phys. Chem. A 2003, 107, 11102-11111. DOI

    • Dirhodium Formamidinate Compounds with Bidentate Nitrogen Chelating Ligands. Helen T. Chifotides, Kemal V. Catalan and Kim R. Dunbar Inorg. Chem. 2003, 42, 8739-8747. DOI

    • Magnetic Property Studies of Manganese-Phosphate Complexes. C. V. Krishnamohan Sharma, Charles C. Chusui, Rodolphe Clerac, Teresia Moller, Kim R. Dunbar and Abraham Clearfield Inorg. Chem. 2003, 42, 8300-8308. DOI

    • Heterometallic Molecular Squares and Polymers Based On Self-Assembly Reactions of Multiply Bonded Dirhenium Complexes. Jitendra K. Bera, John Bacsa, Bradley W. Smucker and Kim R. Dunbar Eur. J. Inorg. Chem. 2004, 368-375. DOI

    • Effect of Equatorial Ligands of Dirhodium(II,II) Complexes on the Efficiency and Mechanism of Transcription Inhibition in Vitro. Helen T. Chifotides, Patty K.-L. Fu, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004, 43, 1175-1183. DOI

    • Structural Characterization, Magnetic Properties, and Electrospray Mass Spectrometry of Two Jahn-Teller Isomers of the Single-Molecule Magnet [Mn12O12(CF3COO)16(H2O)4]. Hanhua Zhao, Curtis P. Berlingutte, John Bacsa, Andrey V. Prosvirin, Jitendra K. Bera, Shane E. Tichy, Eric J. Schelter and Kim R. Dunbar Inorg. Chem. 2004, 43, 1359-1369. DOI

    • Direct DNA Photocleavage by a New Intercalating Dirhodium(II/II) Complex: Comparison to Rh2-O2CCH3)4. Patricia M. Bradley, Alfredo M. Angeles-Boza, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004, 43, 2450-2452. DOI

    • New Types of Layered and Pillared Layered Metal Carboxylate-Phosphonates Based on the 4,4,-Bipyridine Ligand. Jun-Ling Song, Han-Hua Zhao, Jiang-Gao Mao and Kim R. Dunbar Chem. Mater. 2004, 16, 1884-1880. DOI

    • Tetrakis(2,2,-bipyridine)tetra-µ3-hydroxo-di-µ-tri-fluoroacetato-tetracobalt(II) diiodide diaceto-nitrile monohydrate: a compound containing a tetranuclear 'cubane'-type cobalt(II) core. Hanhua Zhao, John Bacsa and Kim R. Dunbar Acta Cyrst. 2004, E60, m637-m640. DOI

    • A Charge-Transfer-Induced Spin Transition in the Discrete Cyanide-Bridged Complex {[Co(tmphen)2]3[Fe(CN)6]2}. Curtis P. Berlingutte, Alina Bragulescu-Andrasi, Andreas Sieber, Jose-Ramon Galan-Mascaros, Hans-Ulrich Gudel, Catalina Achim and Kim R. Dunbar J. Am. Chem. Soc. 2004, 126, 6222-6223. DOI

    • Electrochemical, Spectroscopic, and Structural Evidence for the Mild Hydrolysis of Tetracyanoethylene, TCNE, To Form the 2,3,3-Tricyanoacrylamidate Ligand: Isolation of an Unexpected Quadruply-Bonded Polymeric Material [Mo2(O2CCMe3)3((NC)2CC(CN)CONH)]. Francoise Conan, Benoit Le Gall, Jean-Michel Kerbaol, Sylvie Le Stang, Jean Sala-Pala, Yves Le Mest, John Bacsa, Xiang Ouyang, Kim R. Dunbar, and Charles F. Campana Inorg. Chem. 2004, 43, 3673-3681. DOI

    • *A two-dimensional magnetic architecture with bridging polynitrile and 2,2,-bipyrimidine ligands. J-R. Galan-Mascaros, F. Thetiot, S. Triki, J. Sala Pala and K.R. Dunbar J. Phys. IV France 2004, 114, 625-626.

    • 1,3-Dithiolan-2-one. Eric Reinheimer, John Bacsa and Kim R. Dunbar Acta Cryst. Section E 2004, E60, 01206-01207. DOI

    • Bis(pyridine-2-ylmethanolato- k2N,O )bis(trifluoroacetato)nickel(II). John Bacsa, Hanjhua Zhao and Kim R. Dunbar Acta Cryst. ,b>2004, E60, m1040-m1042. DOI

    • Syntheses, Structure, and Magnetic Properties of New Types of Cu(II), Co(II), and Mn(II) Organophosphonate Materials: Three-Dimensional Frameworks and a One-Dimensional Chain Motif. Deyuan Kong, Yang Li, Xiang Ouyang, Andrey V. Prosvirin, Hanhua Zhao, Joseph H. Ross, Jr., Kim R. Dunbar and Abraham Clearfield Chem. Mater. 2004, 16, 3020-3031. DOI

    • Unusual Magnetic Metal-Cyanide Cubes of ReII with Alternating Octahedral and Tetrahedral Corners. Eric J. Schelter, Andrey V. Prosvirin, William M. Reiff and Kim R. Dunbar Angew. Chem. Int. Ed. 2004, 43, 4912-4915. DOI

    • Discrete Dinuclear Complexes and Two-Dimensional Architectures from Bridging Polynitrile and Bipyrimidine (bpym) Ligands: Syntheses, Structures and Magnetic Properties of [M2(bpym)(dcne)4(H2O)2] (M = MnII, CoII) and [M2(bpym)(dcne)4(H2O)4]·H2O (M = FeII, CuII) (dcne- = [(CN)2CC(O)Oet)]-). Frank Thetiot, Smail Triki, Jean Sala Pala, Jose-Ramon Galan-Mascaros, Jose M. Martinez-Agudo and Kim R. Dunbar Eur. J. Inorg. Chem. 2004, 3783-3791. DOI

    • Building Block Approaches to Nanomagnetic Materials. Kim R. Dunbar Foundations of Nanoscience Proc. 2004, 171.

    • Single Molecule Magnet Mn-Cyanide-Control of the Magnetic Anisotropy. A.V. Palii, S.M. Ostrovsky, S.V. Kunitsky, S. I. Klokishner, B.S. Tsukerblat, J.R. Galan-Mascaros and K.R. Dunbar Proc. of the Third International Conference on Mathematical Modeling and Computer Simulation of Material Technologies 2004, 1-16.

    • Binding of DNA Purine Sites to Dirhodium Compounds Probed by Mass Spectrometry. Helen T. Chifotides, John M. Koomen, Mijeong Kang, Shane E. Tichy, Kim R. Dunbar and David H. Russell Inorg. Chem. 2004, 43, 6177-6187. DOI

    • Films of Mn12-acetate by pulsed laser evaporation. V. Meenakshi, W. Teizer, D.G. Naugle, H. Zhao and K.R. Dunbar Solid State Comm. ,b>2004, ,i>132, 471-476. DOI

    • Molecular Cube of ReII and MnII That Exhibits Single-Molecule Magnetism. Eric J. Schelter, Andrey V. Prosvirin and Kim R. Dunbar J. Am. Chem. Soc. 2004, 126, 15004-15005. DOI

    • Experimental and Computational Studies of Charge-Transfer and Reduction Products of 1,4,5,8,9,11-Hexaazatriphenylene-Hexacarbonitrile:HAT-(CN)6. P.S. Szalay, J.R. Galan-Mascaros, B.L. Schottel, J. Bacsa, L.M. Perez, A.S. Ichimura, A. Chouai and K.R. Dunbar J. Cluster Science 2004, 15, 503-530. DOI

    • Films of Mn12-acetate deposited by low-energy laser ablation. J. Means, V. Meenakshi, R.V.A. Srivastava, W. Teizer, Al.A. Kolomenskii, H.A. Schussler, H. Zhao and K.R. Dunbar J. Magnetism & Mater. 2004, 284, 215-219. DOI

    • DNA Binding and Photocleavage in Vitro by New Dirhodium(II) dppz Complexes: Correlation to Cytotoxicity and Photocytotoxicity. Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L Fu, Sara E. Wicke, John Bacsa, Kim R. Dunbar and Claudia Turro Inorg. Chem. 2004, 43, 8510-8519. DOI

    • Mn12-acetate film pattern generated by photolithography methods. K. Kim, D.M. Seo, J. Means, V. Meenakshi, W. Teizer, H. Zhao, K.R. Dunbar Appl. Physics Lett. 2004, 85, 3872-3874. DOI

    • Role of the Orbitally Degenerate Mn(III) Ions in the Single-Molecule Magnet Behavior of the Cyanide Cluster {[MnII(tmphen)2]3[MnIII(CN)6]2} (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). Andrei V. Palli, Sergei M. Ostrovsky, Sophia I. Klokishner, Boris S. Tsukerblat, Curtis P. Berlingutte, Kim R. Dunbar, and J.R. Galan-Mascaros J. Am. Chem. Soc. 2004, 126, 16860-16867. DOI


  • 2001-2002
    • A microporous framework from a magnetic molecular square: [Co(HAT)Cl2]4 (HAT = 1,4,5,8,9,11-hexaazatriphenylene). Jose R. Galan-Mascaros and Kim R. Dunbar Chem . Commun. 2001, 217-218. DOI

    • Structural and magnetic properties of Co3(dpa)4Br2. Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang J. Chem. Soc., Dalton Trans. 2001, 386-391.

    • Dinuclear and Heteropolynuclear Complexes Containing Mo24+ Units. Rodolphe Clerac, F. Albert Cotton, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang Inorg. Chem. 2001, 40, 420-426. DOI

    • Fine-Tuning the Ring-Size of Metallacyclophanes: A Rational Approach to Molecular Pentagons. Cristian Saul Campos-Fernandez, Rodolphe Clerac, John M. Koomen, David H. Russell and Kim R. Dunbar J. Am. Chem. Soc. 2001, 123, 773-774. DOI

    • The first crystal structure of a one-dimensional chain of linked RuII=RuII units. Hitoshi Miyasaka, Rodolphe Clerac, Cristian S. Campos-Fernandez and Kim R. Dunbar J. Chem. Soc., Dalton Trans. 2001, 858-861.

    • Tuning the Metal-Metal Bonds in the Linear Tricobalt Compound Co3(dpa)4Cl2: Bond-Stretch and Spin-State Isomers. Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Xiaoping Wang Inorg. Chem. 2001, 40, 1256-1264. DOI

    • Crystal structure and magnetic behavior of the Cu3(O2C16H23)6 · 1.2C6H12. An unexpected structure and an example of spin frustration. Rodolphe Clerac, F. Albert Cotton, Kim R. Dunbar, Elizabeth A. Hillard, Carlos A. Murillo, Marina A. Petrukhina and Bradley W. Smucker C.R. Acad. Sci. Paris, Chimie/Chemistry 2001, 4, 315-319. DOI

    • Metal-Metal Bonded Diruthenium(II, III) Assemblies with the Polycyano Anionic Linkers N(CN)2-, C(CN)3-, and 1,4-Dicyanamido-2,5-dimethylbenzene (DM-Dicyd 2- ): Syntheses, Structures, and Magnetic Properties. Hitoshi Miyasaka, Rodolphe Clerac, Cristian S. Campos-Fernandez and Kim R. Dunbar Inorg. Chem. 2001, 40, 1663-1671. DOI

    • A Comparative Structural and Magnetic Study of Three Compounds Based on the Cluster Unit M4Cl8(THF)6 (M = Mn, Fe, Co). H. Zhao, X. Ouyang, J.-S. Sun, R. Clerac, J. M. Clemente-Juan, E. Coronado and K. R. Dunbar J. Solid State Chem., 2001, 159, 281-292. DOI

    • *HAT(CN)6: a new building block for molecule-based magnetic materials. P. S. Szalay, J. R. Galan-Mascaros, R. Clerac, and K. R. Dunbar Synth. Met. 2001, 122, 535-542. DOI

    • New approaches to magnetic clusters with hexacyanometallate building blocks. Jennifer A. Smith, Jose-Ramon Galan-Mascaros, Rodolphe Clerac, Jui-Sui Sun, Xiang Ouyang and Kim R. Dunbar "Proceedings of the VIIth International Conference on Molecule-based Magnets ", Polyhedron, San Antonio, TX Sept. 16-21, 2001, 20, 1727-1734. DOI

    • New compounds with bridging dicyanamide and bis-chelating 2,2'-bipyrimidine ligands: syntheses, structural characterisation and magnetic properties of the two-dimensional materials [Fe2(dca)4(bpm)]·H2O and [Fe2(dca)4(bpm)(H2O)2]. Smail Triki, Frank Thetiot, J. Galan-Mascaros, Jean Sala Pala and Kim R. Dunbar New J. Chem., 2001, 25, 954-958.

    • Preface to the Proceedings of ICMM 2000. Kim R. Dunbar, Polyhedron 2001, 20, XXVII-XXVIII. DOI

    • Preface for the Special Issue on New Horizons for Magnetic Solids Based on Molecules: From High -Tc Magnets to Nanomagnets to Devices. Kim R. Dunbar J. Solid State Chem. 2001, 159, 251-252. DOI

    • A New 'hybrid' Molecular Square Composed of Alternating Multiply-Bonded Dinuclear and Mononuclear Corners. Jitendra K. Bera, Bradley W. Smucker, Richard A. Walton and Kim R. Dunbar Chem. Commun. 2001, 2562.

    • Reactivity Studies of Anticancer Active Dirhodium Complexes with 2-Aminothiophenol . Karn Sorasnee, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Inorg. Chem. 2002, 41, 433-436. DOI

    • Homologous Series of Redox-Active, Dinuclear Cations [M2(O2CCH3)2(pynp)2]2+ (M = Mo, Ru, Rh) with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine (pynp). Cristian Saul Campos- Fernandez, Lisa M. Thomson, Jose-Ramon Galan-Mascaros, Xiang Ouyang and Kim R. Dunbar Inorg. Chem. 2002, 41, 1523-1533. DOI

    • Unusual Magnetic Behavior in the Layered Ferromagnet [Ni(C6H14N2)2]3[Fe(CN)6]2· 2H2O. Frederic Bellouard, Migul Clemente-Leon, Eugenio Coronado, Jose-Ramon Galan-Mascaros, Carlos J. Gomez-Garcia, Francisco Romero and Kim R. Dunbar Eur. J. Inorg. Chem. 2002, 1603-1606. DOI

    • Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}. Jose-Ramon Galan-Mascaros, Juan-Modesto Clemente-Juan and Kim R. Dunbar J. Chem. Soc., Dalton Trans. 2002, 2710-2713.

    • *Convenient Route to Salts of the (µ-oxo)bis[Trichloroferrate(III)]Dianion, [FeOCl6]2-. Kim R. Dunbar, John J. Longridge, Jeremy M. Rawson and Jui-Sui Sun Inorg. Synth. 2002, 33, 103-107.

    • *Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions. Robert A. Heintz, Jennifer A. Smith, Paul S. Szalay, Amy Weisgerber and Kim R. Dunbar Inorg. Synth. 2002, 33, 75-83.

    • A Study of Structural and Bonding Variations in the Homologous Series [Mo2(CN)6(dppm)2]n- (n = 2, 1 and 0). Jitendra K. Bera, Paul S. Szalay and Kim R. Dunbar Inorg. Chem. 2002, 41, 3429-3436. DOI

    • *Reactivity Studies of 2,3,5,6-Tetra(2-pyridyl) pyrazine (tppz) with First-Row Transition Metal Ions. Cristian S. Campos-Fernandez, Bradley W. Smucker, Rodolphe Clerac and Kim R. Dunbar Israel J. Chem. 2002, 41, 207-218.

    • Oligonucleotide analysis with MALDI-ion-mobility-TOFMS. John M. Koomen, Brandon T. Ruotolo, Kdent J. Gillig, John A. McLean, David H. Russell, Mijeong Kang, Kim R. Dunbar, Katrin Fuhrer, Marc Gonin and J. Albert Schultz Anal. Bioanal. Chem. 2002, 373, 612-617. DOI

    • Coupling dirhodium units through terpyridine bridges: synthesis and structure of a novel molecular rectangle. Jitendra K. Bera, Cristian S. Campos-Fernandez, Rodolphe Clerac and Kim R. Dunbar Chem. Comm., 2002, 2536-2537. DOI

    • Facile Conversion of the Face-Centered Cubic Prussian-Blue Material K2[Mn2(CN)6] into the Spinel Oxide Mn3O4 at the Solid/Water Interface. Aurelie Buckelew, Jose-Ramon Galan-Mascaros and Kim R. Dunbar Adv. Mater. 2002, 14, 1646-1648. DOI

    • *Chain Compounds Based on Trasition Metal Backbones: New Life For an Old Topic. Jitendra Bera and Kim R. Dunbar Angew. Chem. Int. Ed. 2002, 41, 4453-4457. DOI

    • Structural diversity of cyanide-bridged bimetallic clusters based on hexacyanometallate building blocks. Curtis P. Berlingutte, Jennifer A. Smith, Jose-Ramon Galan-Mascaros and Kim R. Dunbar C.R. Chimie 2002, 5, 665-672. DOI

    • Future directions in solid state chemistry: report of the NSF-sponsored workshop. Robert J. Cava, Francis J. DiSalvo, Louis E. Brus, Kim R. Dunbar, Christopher B. Gorman, Sossina, M. Haile, Leonard V. Interrante, Janice L. Musfeldt, Alexandra Navrotsky, Ralph G. Nuzzo, Warren E. Pickett, Angus P. Wilkinson, Channing Ahn, James W. Allen, Peter C. Burns, Gerdrand Ceder, Christopher E.D. Chidsey, William Clegg, Eugenio Coronado, Hongjie Dai, Michael W. Deem, Bruce S. Dunn, Giulia Galli, Allan J. Jacobson, Mercouri Kanatzidis, Wengin Lin, Arumugam Manthiram, Milan Mrksich, David J. Norris, Arthur J. Nozik, Xiaogang Peng, Claudia Rawn, Debra Rolison, David J. Singh, Brian H. Toby, Sara Tolbert, Ulrich B. Wiesner, Patrick M. Woodward and Peidong Yang Progress in Solid State Chemistry 2002, 30, 1-101. DOI


  • 1996-2000
    • Photochemistry of deca(acetonitrile) dirhodium(II) cation: evidence for kilosecond-lived photoinduced charge separation. Chris A. James, David E. Morris, Stephen K. Doorn, C. Anthony Arrington, Jr., Kim R. Dunbar, Gary M. Finnis, Laura E. Pence and William H. Woodruff Gray Honor Special Volume Inorg. Chim. Acta 1996, 242, 91-96.

    • N7,O6 bridging 9-ethylguanine (9-EtGH) groups in dinuclear metal-metal bonded complexes with bond orders of one, two or four. Charles A. Crawford, Elizabeth F. Day, Vijay P. Saharan, Kirsten Folting, John C. Huffman, Kim R. Dunbar and George Christou Chem. Commun. 1996, 1113-1114. DOI

    • Organocyanide Acceptor Molecules as Novel Ligands. Kim R. Dunbar Angew. Chem. Int. Ed. Engl. 1996, 35, 1659-1661.

    • Ligand Effects On The δ→δ* Band Energies And Intensities In A Series Of Diimine Complexes Of Dimolybdenum. D. M. Baird, F. L. Yang, D. J. Kavanaugh, G. Finniss and K. R. Dunbar Polyhedron 1996, 15, 2597-2606. DOI

    • "Design, Synthesis And Processing Of Molecular-Organic And Inorganic-Magnetic Materials" NATO ASI Series Molecular Magnetism: From Molecular Assemblies to the Devices. S. DeCurtins, K. R. Dunbar, C. J. Gomez-Garcia, T. Mallah, R. G. Raptis, D. Talham and J. Veciana (Eds: E. Coronado, P. Delhaes, D. Gatteschi, J. S. Miller) Kluwer, 1996, NATO ASI Series vol. E321, 571-582.

    • *Bioinorganic chemistry: Antitumor chemistry. Kim R. Dunbar and Kemal V. Catalan McGraw Hill Encyclopedia of Science & Technology 1997, McGraw-Hill, 1996, 40-43.

    • A novel one-dimensional structure involving η4-TCNQ ligands and quadruply bonded dimolybdenum units (TCNQ = 7,7,8,8-tetracyanoquinodimethane). Charles Campana, Kim R. Dunbar and Xiang Ouyang Chem. Commun. 1996, 2427-2428. DOI

    • Unprecedented Two-Dimensional Polymers of Mn(II) with TCNQ- (TCNQ = 7,7,8,8-Tetracyanoquinodimethane). Hanhua Zhao, Robert A. Heintz, Kim R. Dunbar and Robin D. Rogers J. Am. Chem. Soc. 1996, 118, 12844-12845. DOI

    • Preparation, Molecular and Electronic Structures, and Magnetic Properties of Face-Sharing Bioctahedral Titanium(III) Compounds: [PPh4][Ti2-Cl)3Cl4(PR3)2]. Linfeng Chen, F. Albert Cotton, Kim R. Dunbar, Xujun Feng, Robert A. Heintz and Calvin Uzelmeier Inorg. Chem. 1996, 35, 7358-7363. DOI

    • A One-Dimensional Metallopolymer of 2,5-Dimethyl-N,N'-Dicyanoquinone Diimine (2,5-DM-DCNQI). Xiang Ouyang, Charles Campana and Kim R. Dunbar Inorg. Chem. 1996, 35, 7188-7189. DOI

    • Unprecedented Conversion of a Compound with Metal-Metal Bonding into a Solvated Molecular Wire. Gary M. Finniss, Enric Canadell, Charles Campana and Kim R. Dunbar Angew. Chem. Int. Ed. Engl. 1996, 35, 2772-2774.

    • *Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives. Kim R. Dunbar and Robert A. Heintz Prog. Inorg. Chem. 1997, 45, 283-391.

    • Bis- and tetrakis-(diphenylphosphino)tetrathiafulvalenes as precursors of redox-active organic-inorganic polymeric networks. M. Fourmigu, C. E. Uzelmeier, K. Boubekeur, S. L. Bartley and K. R. Dunbar J. Organomet. Chem. 1997, 529, 343-350. DOI

    • Reaction of Nitrogen Chelates with the [Rh2]4+ Core: Bis-Chelate Products and Demonstration of Reversible, Chelate-Based Reduction Processes. Charles A. Crawford, John H. Matonic, John C. Huffman, Kirsten Folting, Kim R. Dunbar and George Christou Inorg. Chem. 1997, 36, 2361-2371. clcik here

    • A Novel Dirhodium Compound with Neutral, Bridging 9-Ethyladenine Ligands. Kemal V. Catalan, Daniel J. Mindiola, Donald L. Ward and Kim R. Dunbar Inorg. Chem. 1997, 36, 2458-2460. DOI

    • Analysis of Transition-Metal Compounds Containing Tetrathiafulvalene Phosphine Ligands by Fast Atom Bombardment Mass Spectrometry: Limitations and the Development of Matrix Additives for the Desorption of Multiply Charged Complexes. John M. Asara, Calvin E. Uzelmeier, Kim R. Dunbar and John Allison Inorg. Chem. 1998, 37, 1833-1840. DOI

    • Pd(II) and Pt(II) complexes with mixed phosphorus-oxygen donor ligands. Jui-Sui Sun, Calvin E. Uzelmeier, Donald L. Ward and Kim R. Dunbar Polyhedron 1998, 17, 2049-2063. DOI

    • 3,4-Dimethyltetrathiafulvalene. Calvin E. Uzelmeier, Marc Fourmigu and Kim R. Dunbar Acta. Cryst. 1998, C54, 1047-1049. DOI

    • Reaction of Octachlorodirhenate with a Redox-Active Tetrathiafulvalene Phosphine Ligand: Spectroscopic, Magnetic, and Structural Characterization of the Unusual Paramagnetic Salt [ReCl2(o-P2)2][Re2Cl6(o-P2)](o-P2 = o -{P(C6H5)2}2(CH3)2TTF). Calvin E. Uzelmeier, Stuart L. Bartley, Marc Fourmigu, Robin Rogers, Giulio Grandinetti and Kim R. Dunbar Inorg. Chem. 1998, 37, 6706-6713. DOI

    • A quadruply-bonded dirhenium complex bridged by two N1/N6 adenate ligands. Matthew E. Prater, Daniel J. Mindiola, X. Ouyang and Kim R. Dunbar Inorg. Chem. Commun. 1998, 1, 475-477. DOI

    • Insight Into The Behavior Of M(TCNQ)n (n = 1,2) Crystalline Solids And Films: X-ray, Magnetic And Conducting Properties. Hanhua Zhao, Robert A. Heintz, Xiang Ouyang, Giulio Grandinetti, Jerry Cowen and Kim R. Dunbar NATO ASI:Supramolecular Engineering of Synthetic Metallic Materials: Conductors and Magnets, Ed: J. Veciana, Kluwer: Dordrecht, 1999, 518, 353-376.

    • New Insight into the Nature of Cu(TCNQ): Solution Routes to Two Distinct Polymorphs and Their Relationship to Crystalline Films that Display Bistable Switching Behavior. Robert A. Heintz, Hanhua Zhao, Xiang Ouyang, Giulio Grandinetti, Jerry Cowen and Kim R. Dunbar Inorg. Chem. 1999, 38, 144-156.

    • Spectroscopic, Thermal, and Magnetic Properties of Metal/TCNQ Network Polymers with Extensive Supramolecular Interactions between Layers. H. Zhao, R. A. Heintz, X. Ouyang, K .R. Dunbar, C. F. Campana and R. D. Rogers Chem. Mater. 1999, 11, 736-746. DOI

    • Reactions of DNA Purines with Dirhodium Formamidinate Compounds That Display Antitumor Behavior . K. V. Catalan, J. S. Hess, M. M. Maloney, D. J. Mindiola, D. L. Ward and K. R. Dunbar Inorg. Chem. 1999, 38, 3904-3913. DOI

    • A Remarkable Family of Rhodium Acetonitrile Compounds Spanning Three Oxidation States and with Nuclearities Ranging from Mononuclear and Dinuclear to One-Dimensional Chains. M. E. Prater, L. E. Pence, R. Clerac, G. M. Finniss, C. Campana, P. Auban-Senzier, D. Jerome, E. Canadell and K. R. Dunbar J. Am. Chem. Soc. 1999, 121, 8005-8016. DOI

    • The Use of Organic Acceptors as Ligands for Paramagnetic Metal Centers: a New Spin on Charge-Transfer Solids. Jerry Cowen, Rodolphe Clerac, Robert A. Heintz, Shannon O'Kane, Xiang Ouyang, Hanhua Zhao and Kim R. Dunbar Mol. Cryst. and Liq. Cryst. Proceedings of the VIth International Conference on Molecule Based Magnets, September, Seignosse Le Penon, France, 1999, 335, 113-132.

    • A One-Pot, High-Yield Synthesis of a Paramagnetic Nickel Square from Divergent Precursors by Anion Template Assembly. Cristain S. Campos-Fernandez, Rodolphe Clerac and Kim R. Dunbar Angew. Chem. Int. Ed. 1999, 38, 3477-3479. DOI

    • Structures, Magnetic Properties, and Reactivity Studies of Salts Containing the Dinuclear Anion [M2Cl6]2- (M = Mn, Fe, Co). Jui-Sui Sun, Hanhua Zhao, Xiang Ouyang, Rodolphe Clerac, Jennifer A. Smith, Juan M. Clemente-Juan, Carlos Gomez-Garcia, Eugenio Coronado and Kim R. Dunbar Inorg. Chem. 1999, 38, 5841-5855. DOI

    • A Reinvestigation by Circular Dichroism and NMR: Ruthenium(II) and Rhodium(III) Metallointercalators Do Not Bind Cooperatively to DNA. (Research by S. J. Franklin, C. R. Treadway and J. K. Barton.) Summary by Karn Sorasnee and Kim R. Dunbar, CHEMTRACTS 1999, 12, 870-883.

    • Further Study of the Linear Trinickel(II) Complex of Dipyridylamide. Rodolphe Clerac, F. Albert Cotton, Kim R. Dunbar, Carlos A. Murillo, Isabel Pascual and Xiaoping Wang Inorg. Chem. 1999, 38 , 2655-2657. DOI

    • Evidence for Binding of Dirhodium Bis-Acetate Units to Adjacent GG and AA Sites on Single-Stranded DNA. John M. Asara, Jennifer S. Hess, Elizabeth Lozada, Kim R. Dunbar and John Allison J. Am. Chem. Soc. 2000, 122, 8-13. DOI

    • A new family of dimolybdenum compounds with cyanide and phosphine ligands. Paul S. Szalay and Kim R. Dunbar Inorg. Chem. Commun. 2000, 3 , 49-51. DOI

    • Linear Trichromium Complexes with Direct Cr to Cr Contacts. 1. Compounds with Cr3(dipyridylamide)42+ Cores. Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Isabel Pascual Inorg. Chem. 2000, 39, 748-751. DOI

    • Linear Trichromium Complexes with Direct Cr to Cr Contacts. 2. Compounds with Cr3(dipyridylamide)43+ Cores. Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Isabel Pascual Inorg. Chem. 2000, 39, 752-756. DOI

    • Homoleptic complexes of Ag(I), Cu(I), Pd(II) and Pt(II) with tetrathiafulvalene-functionalized phosphine ligands. Bradley W. Smucker and Kim R. Dunbar J. Chem. Soc., Dalton Trans. 2000, 1309-1315.

    • A New Linear Tricobalt Compound with Di(2-pyridyl)amide (dpa) Ligands: Two-Step Spin Crossover of [Co3(dpa)4Cl2][BF4]. Rodolphe Clerac, F. Albert Cotton, Kim R. Dunbar, Tongbu Lu, Carlos A. Murillo and Xiaoping Wang J. Am. Chem. Soc. 2000, 122, 2272-2278. DOI

    • New Crystalline Polymers of Ag(TCNQ) and Ag(TCNQF4): Structures and Magnetic Properties. Shannon A. O'Kane, Rodolphe Clerac, Hanhua Zhao, Xiang Ouyang, Jose-Ramon Galan-Mascaros, Robert Heintz and Kim R. Dunbar J. Solid State Chem. 2000, 152, 159-173. DOI

    • {Mn(OH2)2[Mn(bpym)(OH2)]2[Fe(CN)6]2}: a two-dimensional ferrimagnet with a partial cubane motif. Jennifer A. Smith, Jose-Ramon Galan-Mascaros, Rodolphe Clerac and Kim R. Dunbar Chem. Commun. 2000, 1077-1078. DOI

    • A Homologous Series of Redox-Active, Dinuclear Cations with the Bridging Ligand 2-(2-Pyridyl)-1,8-naphthyridine. Cristian Saul Campos-Fernandez, Xiang Ouyang and Kim R. Dunbar Inorg. Chem. 2000, 39, 2432-2433.

    • New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2][PF6]2. Rodolphe Clerac, F. Albert Cotton, Kim R. Dunbar, Tongbu Lu, Carlos A. Murillo and Xiaoping Wang Inorg. Chem. 2000, 39, 3065-3070. DOI

    • Linear Trichromium Complexes with the Anion of 2,6-Di(phenylimino)piperidine . Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Carlos A. Murillo and Hong-Cai Zhou Inorg. Chem. 2000, 39, 3414-3417. DOI

    • Linear Tricobalt Compounds with Di(2-pyridyl)amide (dpa) Ligands: Temperature Dependence of the Structural and Magnetic Properties of Symmetrical and Unsymmetrical Forms of Co3(dpa)4Cl2 in the Solid State. Rodolphe Clerac, F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Kristin Kirschbaum, Carlos A. Murillo, A. Alan Pinkerton, Arthur J. Schultz and Xiaoping Wang J. Am. Chem Soc. 2000, 122, 6226-6236. DOI

    • Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M = Ru and Rh) Donors and TCNQ Acceptors. Hitoshi Miyasaki, Cristian S. Campos-Fernandez, Rodolphe Clerac and Kim R. Dunbar Angew. Chem. Int. Ed. 2000, 39 , 3831-3835. click

    • One-Dimensional Assemblies of Dirhodium Units Bridged by N,N'-Dicyanoquinonediimine Ligands. Hitoshi Miyasaka, Cristian S. Campos-Fernandez, Jose Ramon Galan-Mascaros and Kim R. Dunbar Inorg. Chem. 2000, 39, 5870-5873. DOI


  • 1991-1995
    • Structure of [HTMPP]3W2Cl9 [HTMPP = Tris(2,4,6-trimethoxyphenyl)-phosphonium]. K. R. Dunbar and L. E. Pence Acta Cryst. 1991, C47, 23-26. DOI

    • Binding of 2,2',-Bipyridine to the Dirhodium(II) Tetraacetate Core: Unusual Structural Features and Biological Relevance of the Product Rh2(OAc)4(bpy). Spiros P. Perlepes, John C. Huffman, John H. Matonic, Kim R. Dunbar and George Christou J. Am. Chem. Soc. 1991, 113, 2770-2771. DOI

    • [{Re2Cl4(dppm)2}2-TCNQ)], a Novel Charge Transfer Complex Derived from a Donor with a Metal-Metal Multiple Bond. Stuart L. Bartley and Kim R. Dunbar Angew. Chem. Int. Ed. Eng. 1991, 30, 448-450. DOI

    • Elucidation of the Reversible Carbon Monoxide Reactions of a Paramagnetic Rhodium(II) Complex. Kim R. Dunbar, Steven C. Haefner and Paul N. Swepston J. Chem. Soc., Chem. Commun. 1991, 460-462. DOI

    • Chemistry of Tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) with Dirhodium Tetraacetate: Synthesis and Spectroscopic, Electrochemical, and Structural Characterization of a Binuclear Complex That Contains an Unusual Phenoxy-Phosphine Ligand. S. J. Chen and K. R. Dunbar Inorg. Chem. 1991, 30, 2018-2023. DOI

    • Oxidative Addition of Halogens to the Quadruple Bond of Mo2X4(dppm)2 (X = Cl, I, Br): Synthesis, Structural Characterization, and Magnetic Properties of Mo2Cl4I2(dppm)2, Mo2Br6(dppm)2, and Mo2I6(dppm)2. F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Charles J. O'Connor and Andrew C. Price Inorg. Chem. 1991, 30, 2509-2514. DOI

    • Bis(diphenylphosphino)methane complexes of rhodium(III) halides as synthons for dinuclear rhodium(III) complexes. F. Albert Cotton, Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello, Seong-Joo Kang, Andrew C. Price and Mark G. Verbruggen Inorg. Chim. Acta 1991, 184, 35-42. DOI

    • Isomerism in the Mo2-O2CCF3)4/bpy Reaction System: Thermal and Photochemical Conversion of the Ion-Pair Complex [Mo2-O2CCF3)2(bpy)2](O2CCF3)O2 to the Unbridged Neutral Isomer Mo21-O2CCF3)4(bpy)2. John H. Matonic, Su-Jane Chen, Spiros P. Perlepes, Kim R. Dunbar and George Christou J. Am. Chem. Soc. 1991, 113, 8169-8171. DOI

    • Reversible Carbon Monoxide Reactions of Cationic Rh(I) and Rh(II) Complexes. Steven C. Haefner, Kim R. Dunbar and Christopher Bender J. Am. Chem. Soc. 1991, 113, 9540-9553. DOI

    • Structure of [CH3TMPP]2Co2Cl6 [CH3TMPP = Tris(2,4,6-trimethoxyphenyl)-methylphosphonium]. K. R. Dunbar, A. Quillevere and S. C. Haefner Acta Cryst. 1991, C47, 2319-2321. DOI

    • Decakis(Acetonitrile)Dirhodium(II) Tetrafluoroborate. Kim R. Dunbar and Laura E. Pence Inorganic Syntheses, 1992, 29 182-185.

    • An Unusual Complex Derived From MoCl3(THF)3 and AgBF4 in Acetonitrile: Synthesis And Structure Of [Mo2-F)(NCCH3)8O2][BF4]3. John H. Matonic, Su-Jane Chen, Laura E. Pence and Kim R. Dunbar Polyhedron 1992, 11, 541-546. DOI

    • Structural and Spectroscopic Characterization of a Paramagnetic Isocyanide Complex of Rhodium(II). Kim R. Dunbar and Steven C. Haefner Organometallics 1992, 11, 1431-1433. DOI

    • Reversible Carbon Monoxide Addition to Sol-Gel Derived Composite Films Containing a Cationic Rhodium(I) Complex: Toward the Development of a New Class of Molecule-Based CO Sensors. Joel I. Dulebohn, Steven C. Haefner, Kris A. Berglund and Kim R. Dunbar Chem. of Materials 1992, 4, 506-508. DOI

    • Crystallographic Disorder in the Orthorhombic Form of RhCl(CO)(PPh3)2: Relevance to the Reported Structure of the Paramagnetic Impurity in Wilkinson's Catalyst. Kim R. Dunbar and Steven C. Haefner Inorg. Chem. 1992, 31, 3676-3679. DOI

    • *New Applications of Weak Donor Atoms to Coordination, Organometallic and Materials Chemistry. Kim R. Dunbar Comments Inorg. Chem. 1992, 13, 313-357.

    • Unusual Structural Features of Tetrakis(µ-carboxylato)dirhodium(II), an Antitumor Agent, Bound to Azathioprine, a Biologically Active Mercaptopurine Derivative. H.T. Chifotides, K. R. Dunbar, J. H. Matonic and N. Katsaros Inorg. Chem. 1992, 31, 4628-4634. DOI

    • Novel Strategies for the Synthesis and Crystallization of Electrophilic Dinuclear Cations: Solution and Solid-State Properties of [Re2(NCCH3)10][Mo6O19]2. Stacey N. Bernstein and Kim R. Dunbar Angew. Chem. Int. Ed. Engl. 1992, 31, 1360-1362.

    • [Fe2Cl6]2-: A Discrete Form of Ferrous Chloride. Kim R. Dunbar and Anne Quillevere Angew. Chem. Int. Ed. Engl. 1993, 32, 293-295.

    • The Oxygenation of the Electron-rich Triple Bond in the Complexes [Re2X4-dppm)2] [X = Cl or Br; dppm = bis(diphenylphosphino)methane]. Multielectron Redox Behaviour Involving Retention of the Re2X4P4 Unit. Stuart L. Bartley, Kim R. Dunbar, Keng-Yu Shih, Phillip E. Fanwick and Richard A. Walton, J. Chem. Soc., Chem. Commun. 1993, 98-100. DOI

    • An Unusual Heterobimetallic Compound with a Rhodium(I) η4-Arene Interaction. Kim R. Dunbar and Anne Quillevere Organometallics 1993, 12, 618-620. DOI

    • Investigation Of The Intermediates In The Oxidation Of A Bulky Arylphosphine Ligand With Ferric Chloride. Kim R. Dunbar and Anne Quillevere Polyhedron 1993, 12, 807-819. DOI

    • Reactions of the Electron-Rich Triply Bonded Dirhenium(II) Complexes Re2X4-dppm)2 (X = Cl, Br) with Dioxygen. 1. Multielectron Redox Chemistry with Preservation of the Re2X4(dppm)2 Unit. Stuart L. Bartley, Kim R. Dunbar, Keng-Yu Shih, Phillip E. Fanwick and Richard A. Walton Inorg. Chem. 1993, 32, 1341-1349. DOI

    • Reaction of 2,2,-Bipyridine (bpy) with Dirhodium Carboxylates: Mono-bpy Products with Variable Chelate Binding Modes and Insights into the Reaction Mechanism. Charles A. Crawford, John H. Matonic, William E. Streib, John C. Huffman, Kim R. Dunbar and George Christou Inorg. Chem. 1993, 32, 3125-3133. DOI

    • *Acetonitrile and cyanide compounds containing metal-metal bonds: syntheses, structures and applications to solid-state chemistry. Stuart L. Bartley, Stacey N. Bernstein and Kim R. Dunbar, Topical Volume of Inorg. Chim. Acta. Entitled "Metal-Metal Bonds/Clusters/Polynuclear Metal Complexes" 1993, 213, 213-231. DOI

    • *Review of the Coordination Chemistry of Tungsten for 1991 . Kim R. Dunbar and Gary M. Finniss Coord. Chem. Rev. 1993, 127, 65-97. DOI

    • The Interaction of Dinuclear Rhodium(II) Complexes With Nitrogen Donor Ligands of Biological Relevance. K. R. Dunbar, J. H. Matonic, V. P. Saharan, C. A. Crawford, G. Christou J. Inorg. Biochem. 1993, 51, 401.

    • Complexes Containing Heteronuclear and Homonuclear Quadruple Bonds. Preparation and Characterization of MoWCl4(dmpm)2 and Mo2X4(dmpm)2 (X = Br, I). F. A. Cotton, K. R. Dunbar, B. Hong, C. A. James, J. H. Matonic and J. L. C. Thomas Inorg. Chem. 1993, 32, 5183-5187. DOI

    • Polynuclear Rhodium(II) Compounds with Phosphino-Phenoxide Ligands. Kim R. Dunbar, John H. Matonic and Vijay P. Saharan Inorg. Chem. 1994, 33, 25-31. DOI

    • Structural Evidence for a New Metal-Binding Mode for Guanine Bases: Implications for the Binding of Dinuclear Antitumor Agents to DNA. Kim R. Dunbar, John H. Matonic, Vijay P. Saharan, Charles A. Crawford and George Christou J. Am. Chem. Soc. 1994, 116, 2201-2202. DOI

    • Synthesis And Properties Of Tris(2,4,6-Trimethoxyphenyl)Phosphine And Tris(2,4,6-Trimethoxyphenyl)Phosphine Oxide. Kim R. Dunbar and Steven C. Haefner Polyhedron 1994, 13, 727-736. DOI

    • A mixed-metal salt comprised of metal-metal bonded dinuclear ions: structure and properties of [Rh2(OAc)2(MeCN)6][Re2Cl8]. Kim R. Dunbar, Laura E. Pence and Julie L. C. Thomas Inorg. Chim. Acta. 1994, 217, 79-84. DOI

    • Incorporation of Quadruply-Bonded Units into Solid-State Materials. Kim R. Dunbar J. Cluster Science 1994, 5, 125-143.

    • Synthesis, Spectroscopic and Magnetic Resonance Studies of Mercury(II) and Methylmercury(II) Complexes of Azathioprine, a Biologically Active Mercaptopurine Derivative. Helen T. Chifotides, Kim R. Dunbar, Nikos Katsaros and George Pneumatikakis J. Inorg. Biochem. 1994, 55, 203-216. DOI

    • Carbon Monoxide Reactions of the Fluxional Phosphine Complex (η3-PR3)Mo(CO)3 (R = 2,4,6-Trimethoxyphenyl). Kim R. Dunbar, Jui-Sui Sun, Steven C. Haefner and John H. Matonic Organometallics 1994, 13, 2713-2720. DOI

    • Spectroscopic and Structural Investigation of Nickel(II) and Nickel(III) Compounds Stabilized by Identical P,O Ligands. Kim R. Dunbar, Jui-Sui Sun and Anne Quillevere Inorg. Chem. 1994, 33, 3598-3601. DOI

    • New Metal-Binding Mode for Adenine: A Bidentate (N6, N7) Bridging Mode in the Complex [Mo2(O2CCHF2)2(9-EtAH)2(MeCN)2](BF4)2· 2MeCN. Elizabeth F. Day, Charles A. Crawford, Kirsten Folting, Kim R. Dunbar and George Christou J. Am. Chem. Soc. 1994, 116, 9339-9340. DOI

    • Synthesis and Structure of the Distorted Octahedral Palladium(II) Complex [Pd(tmpp)2][BF4]2 [tmpp = tris(2,4,6-trimethoxyphenyl)phosphine]. Kim R. Dunbar and Jui-Sui Sun J. Chem. Soc., Chem. Commun. 1994, 2387-2388. DOI

    • *Review of the Coordination Chemistry of Tungsten for 1992 . Kim R. Dunbar and Vijay P. Saharan Coord. Chem. Rev. 1995, 138, 39-70. DOI

    • Review of "Multiple Bonds Between Metal Atoms. Second Edition." Kim R. Dunbar J. Am. Chem. Soc. 1994, 116, 7957.

    • Acetonitrile complexes of diiridium Part 1. Isolation and characterization of the partially solvated cations [Ir2(COD)(µ-form)2(MeCN)3]2+ and [Ir2-form)2(MeCN)6]2+ (COD = 1,5-cyclooctadiene, form = N,N'-di-p-tolylformamidinate). Kim R. Dunbar, Shannon O. Majors and Jui-Sui Sun F. A. Cotton Honor Inorg. Chim. Acta. Special Issue 1995, 229, 373-382.

    • Paramagnetic Transition Metal Complexes With σ-Bonded Tetracyanoethylene (TCNE). Kim R. Dunbar and Xiang Ouyang Mol. Cryst. Liq. Cryst., Proceedings of the IV International Conference on Molecule Based Magnets, 16-21 October 1994, Salt Lake City, Utah, 1995, 273, 21-28.

    • Magnetic Studies Of Polynuclear Iron(II) Complexes And Their Application To The Synthesis Of Extended Structures. Kim R. Dunbar and Jui-Sui Sun Mol. Cryst. Liq. Cryst., Proceedings of the IV International Conference on Molecule Based Magnets, 16-21 October 1994, Salt Lake City, Utah, 1995, 274, 51-62.

    • Chemistry of tris(2,4,6-trimethoxyphenyl)phosphine with rhodium(I) and iridium(I) olefin complexes. Kim R. Dunbar, Steven C. Haefner, Calvin E. Uzelmeier and Anthony Howard Basolo Honor Special Volume Inorg. Chim. Acta 1995, 240, 527-534.


  • 1983-1990
    • Synthesis and Structural Characterization of [Re2Cl4(PMe2Ph)4]n+ (n=0,1, or 2): A Series of Complexes Possessing Metal-Metal Bond Orders of 4, 3.5, and 3 and the Dependence of Bond Length upon Bond Order. F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Milagros Tomas and Richard A. Walton J. Am. Chem. Soc. 1983, 105, 4950-4954. DOI

    • The Reactions of Carbon Monoxide with the Series of Dirhenium Species [Re2Cl4(PMe2Ph)4]n+ (n = 0, 1, 2) Possessing Rhenium-Rhenium Bond Orders of 4, 3.5 and 3. Kim R. Dunbar and Richard A. Walton, Inorg. Chim. Acta 1984, 87, 185-191. DOI

    • Redox Chemistry Associated With Electron-Rich Metal-Metal Triple Bonds. Kim R. Dunbar, Stephen M. Tetrick and Richard A. Walton Abstracts of The International Conference on Coordination Chemistry 1984, 487.

    • The Monocation and Monoanion of Re2-Cl)2-dppm)2Cl4 (dppm = Ph2PCH2PPh2). An Unusual Pair of Complexes possessing Metal-Metal Bond Orders of 1.5 that differ in Electronic Configuration. Kim R. Dunbar, Douglas Powell and Richard A. Walton J. Chem. Soc., Chem. Commun. 1985, 114-116. DOI

    • Cobaltocene Reductions of Multiply Bonded Dirhenium Complexes: Isolation, Characterization, and Reactivity Studies of [(η5-C5H5)2Co][Re2(O2CR)4Cl2], [(η5-C5H5)2Co][Re2Cl6(PR3)2], and [(η5-C5H5)2Co][Re2Cl5(PR3)3]. Kim R. Dunbar and R. A. Walton Inorg. Chem. 1985, 24, 5-10.

    • Reactions of Re2Cl4(dppm)2 with Carbon Monoxide That Proceed with Retention of the Metal-Metal Bond: Synthesis of Re2Cl4(dppm)2(CO)n (n = 1,2) and the Structural Characterization of Cl2Re(µ-Cl)(µ-Co)(µ-dppm)2ReCl(CO). F. Albert Cotton, Lee M. Daniels, Kim R. Dunbar, Larry R. Falvello, Stephen M. Tetrick and Richard A. Walton J. Am. Chem. Soc. 1985, 107, 3524-3530. DOI

    • Redox Chemistry of a Pair of Complexes That Contain the Bridging Bis(diphenyl-phosphino)methane Ligand and the Re26+ and Re24+ Cores: Re2-Cl)2-dppm)2Cl4 and [Re2-dppm)2Cl3(NCR)2]PF6 (R = CH3, C2H5, C6H5). Kim R. Dunbar, Douglas Powell and Richard A. Walton Inorg. Chem. 1985, 24, 2842-2846. DOI

    • Structural Characterization of the Triply Bonded Dirhenium(II) Complexes Re2Cl4-Ph2PCH2PPh2)2 and α-Re2Cl4(Me2P(CH2)2PMe2). Timothy J. Barder, F. Albert Cotton, Kim R. Dunbar, Gregory L. Powell, Willi Schwotzer and Richard A. Walton Inorg. Chem. 1985, 24, 2550-2554. DOI

    • Reactions of the Dicarbonyl Complex Re2Cl4(dppm)2(CO)2 with Nitriles and Isocyanides. Synthesis of [Re2Cl3(dppm)2(CO)2L]n+ (n = 0, 1; L = RCN, RNC) and the Structural Characterization of [Re2Cl3(dppm)2(CO)2(NCC2H5)]PF6. F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello and Richard A. Walton Inorg. Chem. 1985, 24, 4180-4187. DOI

    • Synthesis, Spectroscopy, and X-ray Structure of Os2Cl(chp)4: An Unusual Os25+ Complex with a Polar Arrangement of 6-Chloro-2-hydroxypyridinato Ligands and One Axial Chloride. F. Albert Cotton, Kim R. Dunbar and Marek Matusz Inorg. Chem. 1986, 25, 1585-1589. DOI

    • Preparation And Structural Characterization Of Os2Cl4(Ph2Ppy)2(O2CCH3): A Mixed-Ligand Compound With An Os25+ Core And A Bond Order of 2.5. F. Albert Cotton, Kim R. Dunbar and Marek Matusz Polyhedron 1986, 5, 903-905. DOI

    • Preparation and Structural Characterization of Os2Cl4(chp)2(L) (chp = 6-Chloro-2-hydroxypyridinato; L = H2O, Pyridine): A New Class of M2X4(LL)2 Complexes Possessing an Eclipsed Conformation Where LL Is a Substituted Hydroxypyridinato Ligand. F. Albert Cotton, Kim R. Dunbar and Marek Matusz Inorg. Chem. 1986, 25, 1589-1594. DOI

    • Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with Isocyanides. 3. Dinuclear Species Containing Two or Three Isocyanide Ligands. Lori Beth Anderson, Timothy J. Barder, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello and Richard A. Walton Inorg. Chem. 1986, 25, 3629-3636. DOI

    • Mixed Carbonyl-Isocyanide and Carbonyl-Nitrile Complexes Derived from the Reactions of the Multiply Bonded Dirhenium(II) Complexes Re2X4(dppm)2(CO) (X = Cl or Br; dppm = Ph2PCH2PPh2). The Structural Characterization of Cl2Re(η-Cl)(η-dppm)2ReCl(CO) and Cl2Re(η-Cl)(η-CO)(η-dppm)2ReCl(CNxylyl). F. Albert Cotton, Kim R. Dunbar, Andrew C. Price, Willi Schwotzer and Richard A. Walton J. Am. Chem. Soc. 1986, 108, 4843-4850. DOI

    • The Multiply Bonded Octahalodiosmate(III) Anions. 2. Structure and Bonding. Pradyot A. Agaskar, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Stephen M. Tetrick and Richard A. Walton J. Am. Chem. Soc. 1986, 108, 4850-4855. DOI

    • Synthesis and Molecular Structure of Mo2I4(dppm)2-2C7H8 (dppm = Bis(diphenyl-phosphino)methane). F. Albert Cotton, Kim R. Dunbar and Rinaldo Poli Inorg. Chem. 1986, 25, 3700-3703. DOI

    • Quadruply Bonded Mo2I4(dppe)2 (dppe = Bis(diphenylphosphino)ethane): Twisted and Eclipsed Rotational Conformations and Their Significance. F. Albert Cotton, Kim R. Dunbar and Marek Matusz Inorg. Chem. 1986, 25, 3641-3649. DOI

    • Isolation and Structure of Os2Cl4[(C6H5)2P(C6H4)]2 . An M2L8 Compound with an Unprecedented Geometry and a Short Os-Os Bond. F. A. Cotton and Kim R. Dunbar J. Am. Chem. Soc. 1987, 109, 2199-2200. DOI

    • Conversion of an Electron-Rich Triple Bond to a Double Bond by Oxidative Addition of Diphenyl Diselenide to Re2Cl4-dppm)2. Preparation and Characterization of Re2Cl4-SePh)2-dppm)2 (dppm = Bis(diphenylphosphino)methane). F. Albert Cotton and Kim R. Dunbar Inorg. Chem. 1987, 26, 1305-1309. DOI

    • Isolation and Structure of the Novel Dirhodium(II) Compound Rh2(dmpm)2[(C6H5)2P(C6H4)]2Cl2 with Bridging Bis(dimethylphosphino)methane and Ortho-Metalated Triphenylphosphine Ligands. F. A. Cotton and Kim R. Dunbar J. Am. Chem. Soc. 1987, 109, 3142-3143. DOI

    • Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with Isocyanides. 4. Isomerism in Mixed Carbonyl-Isocyanide Complexes of Stoichiometry [Re2Cl3(dppm)2(CO)2(CNR)]n+ ( n = 0 or 1) and [Re2Cl3(dppm)2(CO)(CNR)2]+ (R = t -Bu or Xylyl), Which Possess Edge-Shared Bioctahedral Structures. Lori Beth Anderson, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, Andrew C. Price, Austin H. Reid and Richard A. Walton Inorg. Chem. 1987, 26, 2717-2725. DOI

    • New Directions in the Chemistry of Dirhodium(II) Compounds. F. Albert Cotton, Kim R. Dunbar and Mark G. Verbruggen J. Am. Chem. Soc. 1987, 109, 5498-5506. DOI

    • Oxidative Addition to M-M Quadrulple Bonds. Preparation of New Edge-Sharing Bioctahedral Complexes of the Type (L-L)Cl2M(µ-Cl)2MCl2(L-L) (M = Mo, W, L-L = 1,2-Bis(diphenyl-phosphino)ethane; M = Mo, L-L = 1-(Diethylphosphino)-2-(diphenylphosphino)ethane). P. A. Agaskar, F. A. Cotton, K. R. Dunbar, L. R. Falvello and C. J. O'Connor, Inorg. Chem. 1987, 26, 4051-4057. DOI

    • Reactions of Rh2(O2CCH3)2(C6H4PPh2)2ܨCH3COOH with Chlorotrimethylsilane in the Presence of Monodentate Phosphines To Give [Rh2Cl2(C6H4PPh2)2(PPh3)2] and [Rh2Cl2(C6H4PPh2)2(PMe3)2]. F. Albert Cotton, Kim R. Dunbar and Cassandra T. Eagle, Inorg. Chem. 1987, 26, 4127-4130. DOI

    • Oxidative-Addition Reactions of S-S and Se-Se Bonds to Mo2 and W2 Quadruple Bonds. Jo Ann M. Canich, F. Albert Cotton, Kim R. Dunbar and Larry R. Falvello, Inorg. Chem. 1988, 27, 804-811. DOI

    • Spectroscopic and Structural Investigation of the Unbridged Dirhodium Cation [Rh2(CH3CN)10]4+. K. R. Dunbar, J. Am. Chem. Soc. 1988, 110, 8247-8249. DOI

    • Edge-Sharing Bioctahedral Molecules without Metal-Metal Bonds: The d6-d6 Complexes Rh2X4-X)2-dppm)2 (X = Cl, Br). F. Albert Cotton, Kim R. Dunbar, Cassandra T. Eagle, Larry R. Falvello and Andrew C. Price, Inorg. Chem. 1989, 28, 1754-1757. DOI

    • Isolation, Structure, and Magnetic Properties of a Novel Mononuclear Rhodium(II) Complex. K. R. Dunbar, S. C. H,fner and L. E. Pence, J. Am. Chem. Soc. 1989, 111, 5504-5506. DOI

    • Synthesis, Spectroscopic Studies, and Structure of an Unusual Dirhenium Complex with a Bridging Hydride Ligand. S. J. Chen and K. R. Dunbar, Inorg. Chem. 1990, 29, 529-534. DOI

    • Synthesis and Characterization of Rh2(O2CCH3)3[{C6H2(OMe)3}2P{C6H2(OMe)2O}](MeOH) with a Novel Tridentate Ligand Derived from Tris(2,4,6-trimethoxyphenyl)phosphine. S. J. Chen and K. R. Dunbar, Inorg. Chem. 1990, 29, 588-590. DOI

    • Isolation and Structure of the Fluxional Phosphine Complex (η3-PR3)Mo(CO)3 (R = 2,4,6-Trimethoxyphenyl). K. R. Dunbar, S. C. Haefner and D. J. Burzynski, Organometallics 1990, 9, 1347-1349. DOI

    • Synthesis And Characterization Of [{2,4,6-(CH3O)3C6H 2}3P=O]FeCl3: A Four-Coordinate Phosphine Oxide Adduct Of FeCl3. Kim R. Dunbar, Steven C. Hsefner and Anne Quillevere, Polyhedron 1990, 9 , 1695-1702. DOI


Department of Chemistry | Texas A&M University | State of Texas