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PUBLICATIONS
2008-2006
[61] M. C. Biel; R. Kessinger; J. Sommer; J. Blümel, "Improved Process for Production of Alkenylphosphonic Acid Derivatives by Addition of Hydrophosphonate Diesters to Alkynes in the Presence of Nickel Catalyst and a Base".  U.S. Patent, WO 2008113777, PCT Int. Appl. 2008, Chemical Abstracts number: 149:402503.
[60] J. Blümel, "Linkers and Catalysts Immobilized on Oxide Supports: New Insights by Solid-State NMR Spectroscopy", Coord. Chem. Rev. 252 (2008) 2410-2423. pdf
[59] Y. Yang, B. Beele, J. Blümel, "Easily Immobilized Di-and Tetraphosphine Linkers: Rigid Scaffolds that Prevent Interactions of Metal Complexes with Oxide Supports", J. Am. Chem. Soc. 130 (2008) 3771-3773. pdf
[58] N. Masciocchi, S. Galli, M. Bogza, J. Blümel, "X-Ray Powder Diffraction Characterization of the Elusive Tetraphosphine Si(CH2PPh2)4", Powder Diffr. 22 (2007) 55-58. pdf
[57] R. Fetouaki, A. Seifert, M. Bogza, T. Oeser, J. Blümel, "Synthesis, Immobilization, and Solid-State NMR of New Phosphine Linkers with Long Alkyl Chains", Inorg. Chim. Acta 359 (2006) 4865-4873. pdf
[56] T. Posset, J. Blümel, "New Mechanistic Insights Regarding Pd/Cu Catalysts for the Sonogashira Reaction: HRMAS NMR Studies of Silica-Immobilized Systems", J. Am. Chem. Soc. 128 (2006) 8394-8395. pdf
[55] J. Blümel, "Solid-State NMR in Catalysis", Nachrichten aus Chemie, Technik und Laboratorium 54 (2006) 632-639. pdf
[54] N. Lewanzik, T. Oeser, J. Blümel, J. A. Gladysz, "Generation of trans-Spanning Diphosphine Ligands via Alkene Metathesis: Synthesis, Structure, and Dynamic Behavior of a Missing Link among Square-Planar Platinum Complexes", J. Mol. Catal. A: Chemical 254 (2006) 20-28. pdf
[53] S. Brenna, T. Posset, J. Furrer, J. Blümel, "14N NMR and Two-Dimensional Suspension 1H and 13C HR-MAS NMR Spectroscopy of Ionic Liquids Immobilized on Silica", Chem. Eur. J. 12 (2006) 2880-2888. pdf
2005-1987
[52] M. Bogza, T. Oeser, J. Blümel, "Synthesis, Structure, Immobilization and Solid-State NMR of New dppp-and tripod-type Chelate Linkers", J. Organomet. Chem. 690 (2005) 3383-3389. pdf
[51] C. Merckle, J. Blümel, "Improved Rhodium Hydrogenation Catalysts Immobilized on Silica", Top. Catal. 34 (2005) 5-15. pdf
[50] F. Piestert, R. Fetouaki, M. Bogza, T. Oeser, J. Blümel, "Easy one-pot synthesis of new dppm-type linkers for immobilizations", Chem. Commun. (2005) 1481-1483. pdf
[49] T. Posset, F. Rominger, J. Blümel, "Immobilization of Bisphosphinoamine Linkers on Silica: Identification of Previously Unrecognized By-Products via 31P CP/MAS and Suspension HR-MAS Studies", Chem. Mater. 17 (2005) 586-595. pdf
[48] J. Sommer, Y. Yang, D. Rambow, J. Blümel, "Immobilization of Phosphines on Silica: Identification of Byproducts via 31P CP/MAS Studies of Model Alkyl-, Aryl-, and Ethoxyphosphonium Salts", Inorg. Chem. 43 (2004) 7561-7563. pdf
[47] T. J. J. Müller, J. Blümel, "Synthesis, Structure, Electronic Properties, and Thermal Behavior of Butadiynyl Substituted PhenylCr(CO)3 Complexes", J. Organomet. Chem. 683 (2003) 354. pdf
[46] S. Reinhard, K. D. Behringer, J. Blümel, "Immobilized Nickel Catalysts for Cyclotrimerizations of Acetylenes: Enhancement of Activities, Stabilities, and Lifetimes", New J. Chem. 27 (2003) 776-778. pdf
[45] S. Reinhard, J. Blümel, "31P CP/MAS NMR of Polycrystalline and Immobilized Phosphines and Catalysts with fast Sample Spinning", Magn. Reson. Chem. 41 (2003) 406-416. pdf
[44] S. Reinhard, P. Soba, F. Rominger, J. Blümel, "New Silica-Immobilized Nickel Catalysts for Cyclotrimerizations of Acetylenes", Adv. Synth. Catal. 345 (2003) 589-602. pdf
[43] C. Merckle, J. Blümel, "Improved Rhodium Hydrogenation Catalysts Immobilized on Oxidic Supports", Adv. Synth. Catal. 345 (2003) 584-588. pdf
[42] C. Merckle, J. Blümel, "Bifunctional Phosphines Immobilized on Inorganic Oxides", Chem. Mater. 13 (2001) 3617-3623. pdf
[41] C. Merckle, S. Haubrich, J. Blümel, "Immobilized Hydrogenation Catalysts", J. Organomet. Chem. 627 (2001) 44-54. pdf
[40] G. Tsiavaliaris, S. Haubrich, C. Merckle, J. Blümel, "New Bifunctional Chelating Phosphine Ligands for Immobilization of Metal Complexes on Oxidic Supports", Synlett (2001) 391-393. pdf
[39] J. Blümel, Buchbesprechung über "Struktur- und Stoffanalytik mit spektroskopischen Methoden" von W. Bechmann und J. Schmidt, für Nachrichten aus Chemie, Technik und Laboratorium 49 (2001) 519.
[38] J. Blümel, Buchbesprechung über "150 and More Basic NMR Experiments" von S. Braun, H.-O. Kalinowski und S. Berger, für Nachrichten aus Chemie, Technik und Laboratorium 47 (1999) 573.
[37] Q. Xing, W. Milius, H. L. Krauss, J. Blümel, H. Hilbig, F. H. Köhler, W. Strauß, G. Bayreuther, "Oberflächenverbindungen von Übergangsmetallen: Darstellung und Eigenschaften von Chromorganylen aus Phillips-Katalysatoren und Ethylen", Z. anorg. allg. Chem. 625 (1999) 521-529. pdf
[36] M. Schnellbach, J. Blümel, "The Union Carbide Catalyst", Chimia 51 (1997) 484.
[35] W. A. Herrmann, R. Kratzer, J. Blümel, D. C. Apperley, H. B. Friedrich, R. W. Fischer, J. Mink, O. Berkesi, "Polymer-bound Osmium Oxide Catalysts", J. Mol. Catal. A 120 (1997) 197-205. pdf
[34] J. Blümel, B. Werner, T. Kräuter, B. Neumüller, "Synthese und Eigenschaften von Trimesitylthallium. Ein Vergleich der Trimesitylelement-Verbindungen der 13.  Gruppe", Z. Anorg. Allg. Chem. 623 (1997) 309-315. pdf
[33] R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, "Two Types of Intramolecular Lewis-Base Adducts with the [2-(Dimethylamino)ethyl]cyclopentadienyl Ligand: Synthesis and Crystal Structures of {h5:h1-C5H4[(CH2)2NMe2]}Ni-I and {h5-m-C5H4[(CH2)2NMe2]}(Me3P)Ni-InI2", Organometallics 15 (1996) 5746-5752. pdf
[32] K. D. Behringer, J. Blümel, "Reactions of Ethoxysilanes with Silica: A Solid-State NMR Study", J. Liq. Chromatogr. 19 (1996) 2753-2765. pdf
[31] J. Blümel, "Die Immobilisierung homogener Katalysatoren", GIT Fachz. Lab. 10 (1996) 963.
[30] M. Schnellbach, J. Blümel, F. H. Köhler, "The Union Carbide Catalyst (Cp2Cr +SiO2), Studied by Solid-State NMR", J. Organomet. Chem. 520 (1996) 227-230. pdf
[29] J. Blümel, W. Hiller, M. Herker, F. H. Köhler, "Solid-State Paramagnetic NMR Spectroscopy of Chromocenes", Organometallics 15 (1996) 3474-3476. pdf
[28] S. Westernacher, J. Blümel, H. Kisch, "Heterogeneous Rh(I)-Catalysis: Synthesis of  N-Anilino-2,3-diphenylindole from Azobenzene and Diphenylacetylene", J. Mol. Catal. 109 (1996) 169.
[27] K. D. Behringer, J. Blümel, "The Immobilization of Carbonylnickel Complexes: A Solid-State NMR Study", Inorg. Chem. 35 (1996) 1814-1819. pdf
[26] K. D. Behringer, J. Blümel, "Immobilization and Chelation of Metal Complexes with Bifunctional Phosphine Ligands: a Solid-State NMR Study", Chem. Commun. 1996, 653-654. pdf
[25] J. Blümel, "Anchoring of Phosphanes on Silica", in Synthetic Methods of Organometallic and Inorganic Chemistry (Herrmann/Brauer), Vol. 1: "Literature, Laboratory Techniques, and Common Starting Materials"; Ed. W. A. Herrmann, A. Salzer, Georg Thieme Verlag Stuttgart, New York, 1996, pp. 79-80.
[24] J. Blümel, "Reactivity and Dynamics of Bifunctional Phosphines Immobilized on Oxidic Supports: A Solid-State NMR Study", Ber. Bunsenges. Phys. Chem. 99 (1995) 1343.
[23] K. D. Behringer, J. Blümel, "Suspension NMR Spectroscopy of Phosphines and Carbonylnickel Complexes Immobilized on Silica", Z. Naturforsch. 50 b (1995) 1723-1728. pdf
[22] K. D. Behringer, J. Blümel, "61Ni NMR Spectroscopy of Di- and Tricarbonylnickel Complexes", Magn. Reson. Chem. 33 (1995) 729-733. pdf
[21] J. Blümel, "Reactions of Ethoxysilanes with Silica: A Solid-State NMR Study", J. Am. Chem. Soc. 117 (1995) 2112-2113. pdf
[20] W. A. Herrmann, W. Scherer, R. W. Fischer, J. Blümel, M. Kleine, W. Mertin, R. Gruehn, J. Mink, H. Boysen, C. Wilson, R. M. Ibberson, L. Bachmann, M. Mattner, "Multiple Bonds between Main-Group Elements and Transition Metals. 137. Polymeric Methyltrioxorhenium: An Organometallic Nanoscale Double-Layer Structure of Corner-Sharing Re05(CH3) Octahedra with Intercalated Water Molecules", J. Am. Chem. Soc. 117 (1995) 3231. pdf
[19] J. Blümel, "Reactions of Phosphines with Silica: A Solid-State NMR Study", Inorg. Chem. 33 (1994) 5050-5056. pdf
[18] J. Blümel, E. Born, T. Metzger, "Solid-State NMR Study Supporting the Lithium Vacancy Defect Model in Congruent Lithium Niobate", J. Phys. Chem. Sol. 55 (1994) 589-593. pdf
[17] J. Blümel, "Festkörper-NMR-spektroskopische Untersuchung der Reaktionen sekundärer und tertiärer Phosphine mit Kieselgel", GIT Fachz. Lab. 5 (1994) 510.
[16] A. P. Kahn, R. Boese, J. Blümel, K. P. C. Vollhardt, "Synthesis and Chemistry of Heterobimetallic Fulvalene Complexes Containing W, Mo, and Rh", J. Organomet. Chem. 472 (1994) 149-162. pdf
[15] F. E. Kühn, W. A. Herrmann, R. Hahn, M. Elison, J. Blümel, E. Herdtweck, "Multiple Bonds between Main-Group Elements and Transition Metals. 1301. (Cyclopentadienyl)trioxorhenium (VII): Synthesis, Derivatives, and Properties", Organometallics 13 (1994) 1601-1606. pdf
[14] H. P. Fritz, J. Blümel, D. Dengler, "Diphenylphosphin-substituiertes, chirales Polyepichlorhydrin, ein Träger für die heterogene, asymmetrische Katalyse", Z. Naturforsch. 48b (1993) 1589-1594. pdf
[13] M. Baier, P. Bissinger, J. Blümel, H. Schmidbaur, "The Intriguing Structural Characteristics of the Heterosiloxane Molecule Na4[Sb2O(OSiMe3)8]", Chem. Ber. 126 (1993) 947-950. pdf
[12] H. Handwerker, M. Paul, J. Blümel, C. Zybill, "Photochemische 1,2-Verschiebung der Phosphanliganden im Silandiylkomplex [(2-Ph2PCH2C6H4)2Si=Cr(CO)5]", Angew. Chem. 105 (1993) 1375, Angew. Chem. Int. Ed. Engl. 32 (1993) 1313-1315. pdf
[11] H. Handwerker, C. Leis, R. Probst, P. Bissinger, A. Grohmann, P. Kiprof, E. Herdtweck, J. Blümel, N. Auner, C. Zybill, "Reversible Intramolecular Base Stabilization in Silylene (Silanediyl) Complexes: Surprising Reactivity for Silylene Coordination Compounds with a Dynamic N...Si...N Bond", Organometallics 12 (1993) 2162-2176. pdf
[10] J. Blümel, N. Hertkorn, B. Kanellakopulos, F. H. Köhler, J. Lachmann, G. Müller, F. E. Wagner, "Metallocene Analogues with Split (2+4)-p-Electron Ligands", Organometallics 12 (1993) 3896-3905. pdf
[9] J. Blümel, F. H. Köhler, "Metallated Bicyclo[3.2.2]nona-2,6,8-trienes, their Rearrangement to Barbaralanes, and a Short Synthesis of Bicyclo[3.2.2]nona-2,6,8-trien-4-yl Anion", Chem. Ber. 126 (1993) 1283-1290. pdf
[8] J. Blümel, N. Hebendanz, P. Hudeczek, F. H. Köhler, A. Steck, W. Strauss, "The Ferromagnetic Coupling Mechanism in Metallocenium/p-Anion Stacks as seen by NMR Spectroscopy", Mol. Cryst. Liq. Cryst. 233 (1993) 153.
[7] J. Blümel, P. Hofmann, F. H. Köhler, "NMR Spectroscopy of Paramagnetic Complexes", Magn. Reson. Chem. 31 (1993) 2-6. pdf
[6] J. Blümel, N. Hebendanz, P. Hudeczek, F. H. Köhler, W. Strauss, "Synthesis and NMR Spectroscopy of Metallocenium Ions. Support for a New Ferromagnetic Coupling Mechanism in Decamethylmetallocenium Tetracyanoethenides", J. Am. Chem. Soc. 114 (1992) 4223-4230. pdf
[5] P. Bergerat, J. Blümel, M. Fritz, J. Hiermeier, P. Hudeczek, O. Kahn, F. H. Köhler, "Stufenweise Stapelung von drei paramagnetischen Metalloceneinheiten: [CpNiCp(SiMe2)2CpCrCp(SiMe2)2CpNiCp]", Angew. Chem. 104 (1992) 1285, Angew. Chem. Int. Ed. Eng. 31 (1992) 1258-1260. pdf
[4] J. Blümel, F. H. Köhler, "Direkte und indirekte Metallierung von endo-Dicyclopentadien",  J. Organomet. Chem. 340 (1988) 303-315. pdf
[3] J. Blümel, F. H. Köhler, G. Müller, D. L. Wilkinson, "Blockieren der Retro-Diels-Alder-Reaktion durch Komplexbildung: h5-Cyclopentadienyl(h5-dicyclopentadienyl)-eisen", Angew. Chem. 100 (1988) 1011, Angew. Chem. Int. Ed. Engl. 27 (1988) 977-979. pdf
[2] J. Blümel, F. H. Köhler, G. Müller, "Bis(2,3,4,6,7-h5-bicyclo[3.2.2]nona-2,6,8-trien-4-yl)iron, a Ferrocene Analogue with Separated Allyl and Olefin Systems",  J. Am. Chem. Soc. 110 (1988) 4846-4848. pdf
[1]
F. H. Köhler, N. Hertkorn, J. Blümel, "Die Metallierung von N,N,N',N'-Tetramethylethylendiamin (TMEDA)", Chem. Ber. 120 (1987) 2081-2082. pdf