Enantiomers


A pair of enantiomers is a pair of molecules that are non-superimposable mirror images of each other. Shown here are a pair of imaginary enantiomers, with different colors representing different atoms or groups attached to the stereogenic carbon atom. The point being illustrated is that a tetrahedral carbon atom with four different atoms or groups attached will almost always be chiral. This is a consequence of geometry. Two enantiomers will have identical properties unless those properties are measured in a chiral way (i.e. rotation of plane polarized light, taste, smell, etc.). Recall that each enantiomer will rotate plane polarized light an equal magnitude, but opposite direction.