Vladimir I. Bakhmutov (Bakhmoutov)

NMR Expert at Department of Chemistry, Texas A & M University, College Station, Texas 77842 e-mail: bakhmoutov@mail.chem.tamu.edu Phone: (979) 845 8993

Fields of Expertise:

The Solution/Solid-state Nuclear Magnetic Resonance Spectroscopy and its applications to chemistry, molecular physics and materials science

Current Research Interests:

H^d+...H^d- bonds as weak organizing interactions in molecular aggregations and reactions of proton-transfer.

Solid-state multinuclear NMR of the silica-based porous materials.

Nuclear magnetic resonance relaxation in paramagnetic solids.

Education:

DOCTOR of CHEMICAL SCIENCES DEGREE

in Physical Chemistry, obtained at Institute of Organo-Element Compounds, Russian Academy of Sciences, Moscow (1984).

Ph.D. Degree

In Organo-metallic Chemistry, obtained the Moscow State University, (1974)

M.S. Degree

in Chemistry, obtained at the Moscow State University, (1971).

Professional Experience:

2002-present: NMR expert at Department of Chemistry of the Texas A&M University

2000-2002: Professor of Chemistry at Department of Chemistry, Centro de Investigacion y de Estudios Avanzados del I. P. N. , A. P. 14-740, C. P. 07000, Mexico D. F. Mexico

1974-2000: Researcher Fellow, Senior Researcher, Head of the NMR Department and Professor at Institute of Organo-Element Compounds, the Russian Academy of Sciences, Moscow, Russia

1971-1974: PhD student, Department of Chemistry, the Moscow State University, Moscow, USSR.

Visiting Professor at: the Rennes and Bourgogne Universities (France, 1999, 1994, 1995), the Zaragoza University (Spain, 1997, 1996), the Zurich University (Switzerland, 1993).

Publications: over 300 papers including 5 topical reviews with Total citation number 1520

Books and Chapters in Books:

“Practical Nuclear Magnetic Resonance Relaxation for Chemists”, Wiley&Sons 2004, 2005, “Ejemplos prácticos del uso de la RMN en la Química”Ed. CINVESTAV, Mexico, 2006, “Dihydrogen Bonds: Principles, Experiments and Applications” Wiley&Sons 2008, "Unusual structures and physical properties in organometallic chemistry" Editor M. Gielen, Wiley& Sons, 2002,"Recent Advances on Hydride Chemistry", Editor R. Poli, Elsevier Science, 2001.

Selected Articles:

1. Bakhmutov V. I. “Magnetic Resonance Spectrometry”, Encyclpedia of Applied Spectroscopy (submitted)

2. Bakhmutov V. I. “The ²⁹Si T₁ and T₂ NMR Relaxation in Porous Paramagnetic Material SiO₂-MnO-Al₂O₃” Solid State NMR spectroscopy (submitted).

3. Bakhmutov VI. “Proton Transfer to Hydride Ligands with Formation of Dihydrogen Complexes: Physicochemical View”. Eur. J. Inorg. Chem. 2005, 245.

4. Bakhmutov V.I. “Orientations of the principal components of electric field gradients and internal motions in dihydrogen ligands”. Magn. Reson. Chem. 2004, 42, 66.

5. T.J. Taylor, V.I. Bakhmutov, F. P. Gabbai. Hydrocarbon Uptake in the alkylated micropores of a columnar supramolecular solid. Angew. Chem. 2006, 45, 1.

6. Bakhmutov, V.I.; Shpeizer, B.G., Clearfield, A. ‘²⁹Si Spin-Lattice NMR Relaxation in Microporous Silica-Based Materials with high Mn⁺² concentrations. Magn. Reson. Chem. 2006, 44, 985.

7. Macgregor, S.A.; Roe, D.C.; Marshall, W. J.; Bloch, K.M.; Bakhmutov, V. I.; Grushin, V. V. ‘The F/Ph Rearrangement Reaction of [(Ph3P)3RhF], the Fluoride Congener of Wilkinson’s Catalyst. J. Am. Chem. Soc. 2005, 127, 15304.

8. G. Merino, V. I. Bakhmutov, A. Vela. Do cooperative proton-hydride interactions explain the gas-solid structural difference of BH₃NH₃? J Phys. Chem. 2002, 106, 8491.

9. Marisol Güizado-Rodríguez, Armando Ariza-Castolo, Gabriel Merino, Alberto Vela, Heinrich Noth, Vladimir I. Bakhmutov,* and Rosalinda Contreras*. Weak Intramolecular Proton–Hydride and Proton Fluoride Interactions: Experimental (NMR, X-Ray) and DFT Studies of the bis(NBH₃) and bis(NBF₃) Adducts of 1,3-Dimethyl-1,3-diazolidine. J. Am. Chem. Soc. 2001, 123, 9144.

10. Vladimir I. Bakhmutov, Ekaterina V. Bakhmutova, Natalia V. Belkova, Claudio Bianchini, Lina M. Epstein, Dante Masi, Maurizio Peruzzini, Elena S. Shubina, Evgenii V. Vorontsov, Fabrizio Zanobini. In-Depth NMR and IR Study of the Proton Transfer Equilibrium between [{(MeC(CH₂PPh₂)₃}Ru(CO)H₂] and Hexafluoroisopropanol. Can. J. Chem. 2001. 79, 479.

11. V. I. Bakhmutov, C. Bianchini, M. Peruzzini, F. Vizza, E. V. Vorontsov. ¹H and ²H T₁ relaxation behavior of the Rhodium dihydrogen complexes ((triphos)Rh(H₂)H₂)⁺. Inorg. Chem. 2000, 39, 1655.

12. V. I. Bakhmutov, J. A. K. Howard, D. A. Keen, L. G. Kuzmina, M. A. Leech, G. I. Nikonov, E. V. Vorontsov, C. C. Wilson. Combined single crystal neutron diffraction and solution NMR relaxation studies of mono- and bis(sylil) substituted niobocene hydrides with nonclassical interligand interactions. J. Chem. Soc. Dalton Trans. 2000, 10, 1631.

13. E. Sola, V. I. Bakhmutov, F. Torres, A. Elduque, J. A. Lopez, F. J. Lahoz, H. Werner, L. A. Oro: Cooperative Bimetallic Effects on New Ir (III) Pyrazolate Complexes: Hydrogen - Hydrogen, Carbon - Hydrogen and Carbon - Chlorine Bond Activations. Organometallics, 1998, 17, 683.

14. V. I. Bakhmutov, E. V. Vorontsov: NMR spin- lattice relaxation approaches to characterization of transition metal hydride complexes in solution. Rev. Inorg. Chem 1998, 18, 183.

15. Feracin, S., Burgi, T., Bakhmutov V.I., Eremenko, I.L. Vorontsov. EV.,Vimenits, AB., Berke, H. Hydrogen/hydrogen exchange and formation of dihydrogen derivatives of Re hydride complexes in acidic solutions. Organometallics, 1994, 13, 4194.

17. A. Albinati, V. I. Bakhmutov, K. G. Caulton, E. Clot, J. Eckert, O. Eisenstein, D. G. Gusev, V. V. Grushin, B. E. Hauger, W. Klooster, T. F. Koetzle, R. K. McMullan, T. J. O’Loughlin, M. Pelissier, J. S. Ricci, M. P. Sigalas, A. E. Vymenits, Reaction of H₂ with IrH₂Cl₂P₂: stereo-chemical control of the stability of molecular H2 transition metal complexes. J. Am. Chem. Soc. 1993, 115, 7300.

18. D. Nietlishpach, V. I. Bakhmutov, H. Berke: Deuterium Quadrupole Coupling Constants and Ionic Bond Character in transition metal hydride complexes. J. Am. Chem. Soc. 1993, 115, 9191.

19. V.I. Bakhmutov, Burgi, T., Burger, P. Ruppli, U., Berke H. Nonrigidity of pseudooctahedral Re(CO)H₂L₂(NO) complexes in solution. Organometallics, 1994, 13, 4203.

20. V. I. Bakhmutov, J. Bertran, M. A. Esteruelas, A. Lledos, F. Maseras, J. Modrego, L. A. Oro, E. Sola: Dynamic Behavior in solution of the trans-hydridodihydrogen complex [OsHCl(H₂)(CO)(PⁱPr₃)₂. Chem. Eur. J. 1996, 2, 815.