SODIUM CARBONATE ANHYDROUS

MSDS Number: S3242 --- Effective Date: 06/30/98


1. Product Identification

Synonyms: Carbonic acid, disodium salt; disodium carbonate; soda ash
CAS No.: 497-19-8
Molecular Weight: 105.99
Chemical Formula: Na2CO3
Product Codes:
J.T. Baker: 3602, 3604, 3605, 4502, 4923, 5198, 5834
Mallinckrodt: 1338, 7468, 7521, 7527, 7528, 7698

2. Composition/Information on Ingredients

  Ingredient                                CAS No         Percent   Hazardous                                       
  ---------------------------------------   ------------   -------   ---------        
 
  Sodium Carbonate                          497-19-8       99 - 100%    Yes

3. Hazards Identification

Emergency Overview
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DANGER! MAY CAUSE EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.

J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 1 - Slight
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Orange (General Storage)
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Potential Health Effects
----------------------------------

Inhalation:
Inhalation of dust may cause irritation to the respiratory tract. Symptoms from excessive inhalation of dust may include coughing and difficult breathing. Excessive contact is known to cause damage to the nasal septum.
Ingestion:
Sodium carbonate is only slightly toxic, but large doses may be corrosive to the gastro-intestinal tract where symptoms may include severe abdominal pain, vomiting, diarrhea, collapse and death.
Skin Contact:
Excessive contact may cause irritation with blistering and redness. Solutions may cause severe irritation or burns.
Eye Contact:
Contact may be corrosive to eyes and cause conjuctival edema and corneal destruction. Risk of serious injury increases if eyes are kept tightly closed. Other symptoms may appear from absorption of sodium carbonate into the bloodstream via the eyes.
Chronic Exposure:
Prolonged or repeated skin exposure may cause sensitization.
Aggravation of Pre-existing Conditions:
No information found.


4. First Aid Measures

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Note to Physician:
Consider endoscopy in all suspected cases of sodium carbonate poisoning. Perform blood analysis to determine if dehydration, acidosis, or other electrolyte imbalances occurred.


5. Fire Fighting Measures

Fire:
Not considered to be a fire hazard.
Explosion:
Not considered an explosion hazard, but sodium carbonate may explode when applied to red-hot aluminum.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
Use protective clothing and breathing equipment appropriate for the surrounding fire.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
White powder or granules.
Odor:
Odorless.
Solubility:
45.5 g/100 ml water @ 100C (212F)
Specific Gravity:
2.53
pH:
11.6 Aqueous solution
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
Decomposes.
Melting Point:
851C (1564F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage. Hygroscopic. Readily absorbs moisture from the air. Solutions are strong bases.
Hazardous Decomposition Products:
Oxides of carbon and sodium oxide.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Fluorine, aluminum, phosphorous pentoxide, sulfuric acid, zinc, lithium, moisture, calcium hydroxide and 2,4,6-trinitrotoluene. Reacts violently with acids to form carbon dioxide.
Conditions to Avoid:
Moisture, heat, dusting and incompatibles.

11. Toxicological Information

 
For Sodium Carbonate:
Oral rat LD50: 4090 mg/kg; inhalation rat LC50: 2300 mg/m3/2H; irritation eye rabbit: 50 mg severe; investigated as a mutagen, reproductive effector.
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Sodium Carbonate (497-19-8)             No          No            None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Sodium Carbonate (497-19-8)                       Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Sodium Carbonate (497-19-8)                       Yes   Yes   No     Yes                             
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Sodium Carbonate (497-19-8)                No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Sodium Carbonate (497-19-8)                No         No         No                   
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)
 

Australian Hazchem Code: No information found.
Poison Schedule: S5
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.


16. Other Information

NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0
Label Hazard Warning:
DANGER! MAY CAUSE EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Avoid breathing dust.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In all cases, get medical attention.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3, 8, 16.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Strategic Services Division
Phone Number: (314) 539-1600 (U.S.A.)